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2,2':6',2''-terpyridine substituted in the 4'-position by the solubilizing and sterically demanding tert-butyl group: a surprisingly new ligand

artículo científico publicado en 2012

2D → 2D Parallel interpenetration of (4,4) sheets constructed from a ditopic bis(4,2′:6′,4′′-terpyridine)

4′-(Pyrimidin-5-yl)- and 4′-(2-methylpyrimidin-5-yl)-4,2′:6′,4″-terpyridines: Selective coordination to zinc(II) through the 4,2′:6′,4″-terpyridine domain

4′-Chloro-2,2′:6′,2″-terpyridine (L): ethyl sulfate salts of [H2L]2+ and the single crystal structures of [H2L][EtOSO3]Cl·H2O and [ML2][PF6]2 with M=Fe and Ru

4′-Hydrazone Derivatives of 2,2′:6′,2"-Terpyridine: Protonation and Substituent Effects

6-(Thien-2-yl)-2,2′-bipyridine: Presenting an N^N or N^N^S donor set to silver(I)

9-Anthracenyl-substituted pyridyl enones revisited: photoisomerism in ligands and silver(I) complexes

artículo científico publicado en 2011

A homage to Alfred Werner: Exploring the stereochemical complexity of cyclometallated [Ir(ppy)2XY]n+ complexes (Hppy=2-phenylpyridine)

A matter of greasy tails: Interdigitation of alkyl chains in free and coordinated 4′-(4-dodecyloxyphenyl)-4,2′:6′,4″-terpyridines

A new polymorph of 4′-tolyl-2,2′:6′,2′′-terpyridine (ttpy) and the single crystal structures of [Fe(ttpy)2][PF6]2 and [Ru(ttpy)2][PF6]2

A strategy for controlling charge and conformation in 2,2′-bipyridine complexes for use in photonic applications

Adding the second dimension with cadmium: two-dimensional sheets assembled from cadmium(ii) and 4′-phenyl-4,2′:6′,4′′-terpyridine and locked by π-stacked interactions

Amalgamating metalloligands with coordination networks

artículo científico publicado en 2010

Assembling and dissembling zinc-containing coordination polymers of 4′-phenyl-4,2′:6′,4″-terpyridine

Assembling chiral salan–copper(II) complexes into a 2D-network with carboxylic acid functionalization

Assembling model tris(bipyridine)ruthenium(ii) photosensitizers into ordered monolayers in the presence of the polyoxometallate anion [Co4(H2O)2(α-PW9O34)2]10−

scholarly article in RSC Advances, vol. 4 no. 23, 2014

Bright and stable light-emitting electrochemical cells based on an intramolecularly π-stacked, 2-naphthyl-substituted iridium complex

scholarly article by Gabriel E. Schneider et al published 2014 in Journal of Materials Chemistry C

Bucky-blocks: templating a coordination network with C60

Capturing copper(II) ions using {Cu(tpy)(bpy)} domains

Chiral tetranuclear and dinuclear copper(ii) complexes for TEMPO-mediated aerobic oxidation of alcohols: are four metal centres better than two?

artículo científico publicado en 2014

Chloride ion impact on materials for light-emitting electrochemical cells

artículo científico publicado en 2014

Cobalt(ii) coordination polymers with 4′-substituted 4,2′:6′,4′′- and 3,2′:6′,3′′-terpyridines: engineering a switch from planar to undulating chains and sheets

scholarly article by Edwin C. Constable et al published 2012 in CrystEngComm

Coordination polymers with 4′-(4-(anthracen-9-yl)phenyl)- and 4′-(4-(naphthalen-1-yl)phenyl)-4,2′:6′,4″-terpyridines: Mono-, di- and heptazinc(II) nodes

Coordination polymers with divergent 4′-tert-butyl-4,2′:6′,4′′-terpyridine linkers: from aryl-aryl to ball-and-socket packing

Copper(i) complexes for sustainable light-emitting electrochemical cells

Copper(i) dye-sensitized solar cells with [Co(bpy)3]2+/3+ electrolyte

artículo científico publicado en 2013

Curly-curly, loop-loop: homoleptic metal(ii) complexes of pyridinecarbaldehyde 4'-(2,2':6',2''-terpyridyl)hydrazones and their coordination polymers

artículo científico publicado en 2008

Diastereoisomeric dinuclear ruthenium complexes of 2,5-di(2-pyridyl)thiazolo[5,4-d]thiazole

artículo científico publicado en 2004

Diastereoselective Assembly of Helicates Incorporating a Hexadentate Chiral Scaffold

Disulfide struts: Assembly motifs supporting a cuprocapsule

Do perfluoroarene⋯arene and C–H⋯F interactions make a difference to the structures of 4,2′:6′,4′′-terpyridine-based coordination polymers?

Efficient green-light-emitting electrochemical cells based on ionic iridium complexes with sulfone-containing cyclometalating ligands

artículo científico publicado en 2013

Enantioselective catalysts for the Henry reaction: fine-tuning the catalytic components

Environmental control in the assembly of metallomacrocycles and one-dimensional polymers with 4,2′:6′:4′′-terpyridine linkers and zinc(ii) nodes

Environmental control of solution speciation in cobalt(ii) 2,2′:6′,2′′-terpyridine complexes: anion and solvent dependence

artículo científico publicado en 2011

Exceptionally long-lived light-emitting electrochemical cells: multiple intra-cation π-stacking interactions in [Ir(C^N)2(N^N)][PF6] emitters

artículo científico publicado en 2015

Factors controlling the photoresponse of copper(i) diimine dyes containing hole-transporting dendrons in dye-sensitized solar cells: substituent and solvent effects

scholarly article in RSC Advances, vol. 4 no. 66, 2014

Fe-only hydrogenase active site mimics: Fe2(CO)6(μ-ADT) (ADT=azadithiolate) clusters bearing pendant 2,2′:6′,2″-terpyridine domains and containing alkynylthienylene or alkynylphenylene spacers

Fine-Tuning of Photophysical and Electronic Properties of Materials for Photonic Devices Through Remote Functionalization

First example of a CLICK reaction of a coordinated 4′-azido-2,2′:6′,2″-terpyridine ligand

Gold-decorated 2,2′-bipyridine ligands with sterically demanding phosphanes

Greasy tails switch 1D-coordination [{Zn2(OAc)4(4′-(4-ROC6H4)-4,2′:6′,4′′-tpy)}n] polymers to discrete [Zn2(OAc)4(4′-(4-ROC6H4)-4,2′:6′,4′′-tpy)2] complexes

Green-emitting iridium(III) complexes containing sulfanyl- or sulfone-functionalized cyclometallating 2-phenylpyridine ligands

artículo científico publicado en 2014

Half a grid is better than no grid: competition between 2,2':6',2''-terpyridine and 3,6-di(pyrid-2-yl)pyridazine for copper(II).

artículo científico publicado en 2010

Heteroleptic chromium(III) tris(diimine) [Cr(N^N)2(N′^N′)]3+ complexes

Homoleptic and heteroleptic complexes of chromium(III) containing 4′-diphenylamino-2,2′:6′,2″-terpyridine ligands

Host–guest chemistry of a chiral Schiff base copper(ii) complex: can chiral information be transferred to the guest cation?

Improving the photoresponse of copper(I) dyes in dye-sensitized solar cells by tuning ancillary and anchoring ligand modules.

artículo científico publicado en 2013

Investigating the effects of supramolecularly caging ligands in [Ru(bpy)2L]2+ complexes

Ligand-Based Charge-Transfer Luminescence in Ionic Cyclometalated Iridium(III) Complexes Bearing a Pyrene-Functionalized Bipyridine Ligand: A Joint Theoretical and Experimental Study

artículo científico publicado en 2012

Metallohexacycles containing 4′-aryl-4,2′:6′,4′′-terpyridines: conformational preferences and fullerene capture

article published in 2014

Metallohosts with a Heart of Carbon

artículo científico publicado en 2011

Metallomacrocycles with a difference: macrocyclic complexes with exocyclic ruthenium(II)-containing domains

artículo científico publicado en 2009

Mix and match: templating chiral Schiff base ligands to suit the needs of the metal ion.

artículo científico publicado en 2010

Molecular recognition between 4′-(4-biphenylyl)-4,2′:6′,4″-terpyridine domains in the assembly of d9 and d10 metal ion-containing one-dimensional coordination polymers

Monomer, dimer or cyclic helicate? Coordination diversity with hard–soft P,N-donor ligands

artículo científico publicado en 2013

Multinuclear zinc(II) complexes with {Zn6(μ-O)6(μ3-O)2}- and {Zn5(μ-O)3(μ3-O)3}-cluster cores

Novel grafting procedure of ruthenium 2,2':6',2"-terpyridine complexes with phosphonate ligands to titania for water splitting applications

artículo científico publicado en 2010

Phosphonate-functionalized heteroleptic ruthenium(II) bis(2,2′:6′,2″-terpyridine) complexes

Photoactive building blocks for coordination complexes: Gilding 2,2′:6′,2″-terpyridine

Red emitting [Ir(C^N)2(N^N)]+ complexes employing bidentate 2,2':6',2''-terpyridine ligands for light-emitting electrochemical cells.

artículo científico publicado en 2014

Redox addressable ligands in copper(i) coordination chemistry: thione and oligosulfide-bridged 6-methyl-2,2′-bipyridines

Restricting the geometrical relaxation in four-coordinate copper(i) complexes using face-to-face and edge-to-face π-interactions

Same head, different scaffold: a plethora of structural motifs assembled from silver(i) and ditopic 2,2′-bipyridine ligands

Sheet, ladder or chain? Small substituents in 4′-phenyl-4,2′:6′,4″-terpyridines control dimensionality in cadmium(ii) coordination polymers

Softening the donor set for light-emitting electrochemical cells: [Ir(ppy)2(N^N)]+, [Ir(ppy)2(P^P)]+ and [Ir(ppy)2(P^S)]+ salts

Solution, structural and photophysical aspects of substituent effects in the N^N ligand in [Ir(C^N)2(N^N)]+ complexes

artículo científico publicado en 2013

Stereochemistry controlled by an asymmetric sulfur atom, and a rare example of a kryptoracemate

artículo científico publicado en 2012

Sticking and patching: tuning and anchoring cyclometallated ruthenium(ii) complexes

artículo científico publicado en 2015

Structural and Photophysical Properties of (Phosphane)gold(I)-Decorated 4,4′-Diethynyl-2,2′-bipyridine Ligands

Structural diversity in the reactions of 4′-(pyridyl)-2,2′:6′,2″-terpyridine ligands and bis{4′-(4-pyridyl)-2,2′:6′,2″-terpyridine}iron(II) with copper(II) salts

Substituent effects in homoleptic iron(II) and ruthenium(II) complexes of 4′-hydrazone derivatives of 2,2′:6′,2″-terpyridine

The intramolecular aryl embrace: from light emission to light absorption

scientific article published on 13 October 2011

The mononuclear–dinuclear dance: Twisting the backbone in metalloligands operates a coordination switch

The surprising lability of bis(2,2′:6′,2′′-terpyridine)chromium(iii) complexes

artículo científico publicado en 2014

Thienylpyridine-based cyclometallated iridium(III) complexes and their use in solid state light-emitting electrochemical cells

artículo científico publicado en 2013

Towards catenanes using π-stacking interactions and their influence on the spin-state of a bis(2,2':6',2"terpyridine)iron(II) domain

artículo científico publicado en 2010

Tuning Coordination Environments Through Ligand Redox Chemistry: the Thiol - Disulfide Reaction

Tuning the photophysical properties of cationic iridium(III) complexes containing cyclometallated 1-(2,4-difluorophenyl)-1H-pyrazole through functionalized 2,2'-bipyridine ligands: blue but not blue enough

artículo científico publicado en 2013

Turning {M(tpy)2}n+ embraces and CH⋯π interactions on and off in homoleptic cobalt(ii) and cobalt(iii) bis(2,2′:6′,2″-terpyridine) complexes

scholarly article by Edwin C. Constable et al published 2010 in CrystEngComm

Water-soluble alkylated bis{4'-(4-pyridyl)-2,2':6',2''-terpyridine}ruthenium(II) complexes for use as photosensitizers in water oxidation: a complementary experimental and TD-DFT investigation

artículo científico publicado en 2011

Water-soluble bis(4′-[2,2,2-tris(hydroxymethyl)ethoxy]-2,2′:6′,2″-terpyridine)metal complexes

When five are six: the myth of five-coordinate copper(ii) in supramolecular chemistry

Wiring terpyridine: approaches to alkynylthienyl 2,2':6',2''-terpyridines

artículo científico publicado en 2008

Zinc(ii) coordination polymers, metallohexacycles and metallocapsules—do we understand self-assembly in metallosupramolecular chemistry: algorithms or serendipity?

pi-Stacking and hydrogen bonding direct diastereoselectivity in one-pot syntheses of octahedral iron(II) complexes

artículo científico publicado en 2010

‘Surfaces-as-ligands, surfaces-as-complexes’ strategies for copper(I) dye-sensitized solar cells