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A Room-Temperature Stable Y(II) Aryloxide: Using Steric Saturation to Kinetically Stabilize Y(II) Complexes

artículo científico publicado en 2020

A Series of Well-Defined Metathesis Catalysts–Synthesis of[RuCl2(CHR′)(PR3)2] and Its Reactions

article

A Trapped Intermediate in the Copper(II)-Mediated Template Synthesis of an Amino Acid-Containing Ligand

artículo científico publicado en 1997

Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η5-C5Me3H(CH2)-κC]2– Tuck-over Ligands in a Tetrathorium Octahydride Complex

article

Aluminium complexes of N,N′-ethylenebis(salicylideneimine)(H2salen). X-Ray crystal structures of [{Al(salen)}2(µ-O)]·MeCN and [Al(OC6H2Me3-2,4,6)(salen)]

Analysis of uranium azide and nitride complexes by atmospheric pressure chemical ionization mass spectrometry

artículo científico publicado en 2007

Assembly and Properties of Heterobimetallic CoII/III/CaII Complexes with Aquo and Hydroxo Ligands

artículo científico publicado el 15 de octubre de 2012

C-H bond activation through steric crowding of normally inert ligands in the sterically crowded gadolinium and yttrium (C5Me5)3M complexes

artículo científico publicado en 2006

Catalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols

artículo científico publicado en 2009

Characterization of the Oxo-Alkylidyne Complex CpWOs3(CO)10(.mu.-O)(.mu.3-CCH2Tol) Resulting from Acyl Ligand C-O Bond Scission. Interconversion of Alkylidyne, Alkylidene, Vinylidene, and Alkyne Ligand Moieties in a Single Heterometallic Cluster Syst

artículo científico publicado en 1994

Chelate-Free Synthesis of the U(II) Complex, [(C5H3(SiMe3)2)3U]1–, Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs

artículo científico publicado en 2018

Comparisons of lanthanide/actinide +2 ions in a tris(aryloxide)arene coordination environment

artículo científico publicado en 2017

Completing the series of +2 ions for the lanthanide elements: synthesis of molecular complexes of Pr2+, Gd2+, Tb2+, and Lu2+.

artículo científico publicado en 2013

Coordination Chemistry of Samarium Diiodide with Ethers Including the Crystal Structure of Tetrahydrofuran-Solvated Samarium Diiodide, SmI2(THF)5

article

Differentiating Chemically Similar Lewis Acid Sites in Heterobimetallic Complexes: The Rare-Earth Bridged Hydride (C5Me5)2Ln(μ-H)2Ln′(C5Me5)2 and Tuckover Hydride (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln′(C5Me5) Systems

Dinitrogen Reduction, Sulfur Reduction, and Isoprene Polymerization via Photochemical Activation of Trivalent Bis(cyclopentadienyl) Rare-Earth-Metal Allyl Complexes

article

Electrocatalytic H2O Reduction with f-Elements: Mechanistic In-sight and Overpotential Tuning in a Series of Lanthanide Complexes

artículo científico publicado en 2018

Electrochemical studies of tris(cyclopentadienyl)thorium and uranium complexes in the +2, +3, and +4 oxidation states

artículo científico publicado en 2021

Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI2(THF)2 Precursors (Ln = Sm, Eu, Yb)

scientific article published on 10 July 2019

Heterobimetallic Complexes with M(III)-(μ-OH)-M(II) Cores (M(III) = Fe, Mn, Ga; M(II) = Ca, Sr, and Ba): Structural, Kinetic, and Redox Properties

artículo científico publicado en 2013

Isolation of a Square-Planar Th(III) Complex: Synthesis and Structure of [Th(OC6H2tBu2-2,6-Me-4)4]1

artículo científico publicado en 2019

Isolation of reactive Ln(ii) complexes with C5H4Me ligands (CpMe) using inverse sandwich countercations: synthesis and structure of [(18-crown-6)K(μ-CpMe)K(18-crown-6)][CpMe3LnII] (Ln = Tb, Ho)

artículo científico publicado en 2018

Lanthanide metallocene complexes of the 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinato Ligand, (hpp)1-.

artículo científico publicado en 2008

Ligand Effects in the Synthesis of Ln2+ Complexes by Reduction of Tris(cyclopentadienyl) Precursors Including C–H Bond Activation of an Indenyl Anion

article

Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity

artículo científico publicado en 2018

Oxidation and hydrolysis of tris-tert-butylgallium

article

Planar trimethylenemethane dianion chemistry of lanthanide metallocenes: synthesis, structure, density functional theory analysis, and reactivity of [(C5Me5)2Ln]2[mu-eta3:eta3-C(CH2)(3] Complexes

artículo científico publicado en 2006

Preparation and Structural Properties of In(III)-H Complexes

artículo científico publicado en 2013

Rare‐Earth Metal(II) Aryloxides: Structure, Synthesis, and EPR Spectroscopy of [K(2.2.2‐cryptand)][Sc(OC 6 H 2 t Bu 2 ‐2,6‐Me‐4) 3 ]

scientific article published on 08 November 2018

Reactivity of Complexes of 4fn5d1 and 4fn+1 Ln2+ Ions with Cyclooctatetraene

article

Reactivity of Ln(II) Complexes Supported by (C5H4Me)1– Ligands with THF and PhSiH3: Isolation of Ring-Opened, Bridging Alkoxyalkyl, Hydride, and Silyl Products

Reactivity of a series of isostructural cobalt pincer complexes with CO2, CO, and H(+).

artículo científico publicado en 2014

Reduction chemistry of the mixed ligand metallocene [(C5Me5)(C8H8)U]2(μ-C8H8) with bipyridines

article

Reductive reactivity of the organolanthanide hydrides, [(C5Me5)2LnH]x, leads to ansa-allyl cyclopentadienyl (eta(5)-C5Me4CH2-C5Me4CH2-eta(3))2- and trianionic cyclooctatetraenyl (C8H7)3- ligands.

artículo científico publicado en 2008

Relative and Absolute Structure Assignments of Alkenes Using Crystalline Osmate Derivatives for X-Ray Analysis

Relative and Absolute Structure Assignments of Alkenes Using Crystalline Osmate Derivatives for X-ray Analysis

artículo científico publicado en 2019

Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media

artículo científico publicado en 1992

Solution Synthesis, Structure, and CO2 Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe3 )2 ]3 }.

artículo científico publicado en 2017

Solution Synthesis, Structure, and CO2 Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe3 )2 ]3 }−

Spectroscopic and X-ray Crystallographic Evidence for Electrostatic Effects in 4-Substituted Cyclohexanone-Derived Hydrazones, Imines, and Corresponding Salts

artículo científico publicado el 14 de septiembre de 2011

Stabilization of U(III) to Oxidation and Hydrolysis by Encapsulation Using 2.2.2-Cryptand

artículo científico publicado en 2020

Sterically crowded aryloxide compounds of aluminum: reactions with Main-Group chlorides

scholarly article by Matthew D. Healy et al published September 1992 in Organometallics

Structure, Magnetism, and Multi-electron Reduction Reactivity of the Inverse Sandwich Reduced Arene La2+ Complex [{[C5H3(SiMe3)2]2La}2(μ-η6:η6-C6H6)]1–

Structure, reactivity, and density functional theory analysis of the six-electron reductant, [(C5Me5)2U]2(mu-eta6:eta6-C6H6), synthesized via a new mode of (C5Me5)3M reactivity

artículo científico publicado en 2004

Sulfonamido tripods: tuning redox potentials via ligand modifications.

artículo científico publicado en 2015

Syntheses and activities of new single-component, ruthenium-based olefin metathesis catalysts

article

Syntheses, characterizations and thermal analyses of four novel unsymmetrical β-diketiminates

artículo científico publicado en 2013

Synthesis and Applications of RuCl2(CHR‘)(PR3)2:  The Influence of the Alkylidene Moiety on Metathesis Activity

artículo científico publicado en 1996

Synthesis and Reactivity of Organosamarium Diarylpnictide Complexes: Cleavage Reactions of Group 15 E-E and E-C Bonds by Samarium(II).

artículo científico publicado en 1996

Synthesis and Structure of Asymmetric Bis(sulfonamide) Based Copper(II) Complexes: Influence of Diastereomeric Interactions in the Solid State

artículo científico publicado en 1999

Synthesis and Structure of the First Molecular Thulium(II) Complex:[TmI2(MeOCH2CH2OMe)3]

article

Synthesis and characterization of mesitylgallium chloride compounds including the crystal and molecular structure of dichloromesitylgallium(III), an inorganic polymer

Synthesis and reductive chemistry of bimetallic and trimetallic rare-earth metallocene hydrides with (C 5 H 4 SiMe 3 ) 1− ligands

article

Synthesis of (C5Me5)2(C5Me4H)UMe, (C5Me5)2(C5H5)UMe, and (C5Me5)2UMe[CH(SiMe3)2] from cationic metallocenes for the evaluation of sterically induced reduction.

artículo científico publicado en 2008

Synthesis of 1,3-diphenyltriazenide complexes of aluminium, gallium and indium: Crystal structure of tris(1,3-diphenyltriazenido)aluminium(III)

article

Synthesis of Zirconium Aryloxide Complexes Containing Pendent Vinyl Groups

artículo científico publicado en 1999

Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2.

artículo científico publicado en 2017

Synthesis of uranium-in-cryptand complexes

article

Synthesis, crystal structure, and stereoisomerism of the alkylidene complex (.eta.5-C5H5)WOs3(CO)9(.mu.-O)(.mu.-Cl)(.mu.-CHCH2C6H4Me-4) and related complexes

artículo científico publicado en 1987

Synthesis, structure, and physical properties for a series of trigonal bipyramidal M(II)-Cl complexes with intramolecular hydrogen bonds

artículo científico publicado en 2012

Synthesis, structure, and reactivity of heterometallic polyhydride complexes of rhenium with yttrium and lutetium

article

Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C5Me4H)3Ln] Complexes

Thallium-Stabilized Silsesquioxides: Versatile Reagents for the Synthesis of Metallasilsesquioxanes, Including High-Valent Molybdenum-Containing Silsesquioxanes

scholarly article by Frank J. Feher et al published August 1995 in Organometallics

Thermal carbon-oxygen bond scission in a .mu.3-.eta.2-coordinated acyl. Structural characterization of a doubly bridging four-electron oxo ligand

scientific article published in 1984

Thorium Metallocene Cation Chemistry: Synthesis and Characterization of the Bent [(C5Me5)2Th(C6H5)(THF)][BPh4] and the Parallel Ring [(C5Me5)2Th(NCR)5][BPh4]2 (R = Me, Ph) Complexes

scholarly article by Ryan R. Langeslay et al published 31 January 2018 in Organometallics

Titanium(IV) Neopentoxides. X-ray Structures of Ti(3)(&mgr;(3)-O)(&mgr;(3)-Cl)(&mgr;-OCH(2)CMe(3))(3)(OCH(2)CMe(3))(6) and [Ti(&mgr;-OCH(2)CMe(3))(OCH(2)CMe(3))(3)](2).

artículo científico publicado en 1997

Trimethylsilyl versus Bis(trimethylsilyl) Substitution in Tris(cyclopentadienyl) Complexes of La, Ce, and Pr: Comparison of Structure, Magnetic Properties, and Reactivity

Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons

Trivalent [(C5Me5)2(THF)Ln]2(mu-eta2:eta2-N2) complexes as reducing agents including the reductive homologation of CO to a ketene carboxylate, (mu-eta4-O2C-C=C=O)2-.

artículo científico publicado en 2006

Uranium metallocene complexes of the 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinato ligand, (hpp)(-).

artículo científico publicado en 2010

Using Diamagnetic Yttrium and Lanthanum Complexes to Explore Ligand Reduction and C–H Bond Activation in a Tris(aryloxide)mesitylene Ligand System

scientific article published on 24 September 2018

Utility of Arylamido Ligands in Yttrium and Lanthanide Chemistry(1).

artículo científico publicado en 1996

Utility of Lithium in Rare-Earth Metal Reduction Reactions to Form Nontraditional Ln2+ Complexes and Unusual [Li(2.2.2-cryptand)]1+ Cations

artículo científico publicado en 2018

Utilizing tautomerization of 2-amino-oxazoline in hydrogen bonding tripodal ligands

artículo científico publicado en 2010