Lista de obras -

1-Alkali-metal-2-alkyl-1,2-dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

artículo científico publicado en 2017

A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide

artículo científico publicado en 2013

A μ4-oxide-containing a dimeric variant of a sodium dialkyl(amido)zincate reagent

article

Accessible heavier s-block dihydropyridines: structural elucidation and reactivity of isolable molecular hydride sources

article

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

article

Adding a Structural Context to the Deprotometalation and Trans-Metal Trapping Chemistry of Phenyl-Substituted Benzotriazole.

artículo científico publicado en 2015

After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products

article

Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates

scientific article published on 02 May 2019

Alkene Oxyamination Using Malonoyl Peroxides: Preparation of Pyrrolidines and Isoxazolidines

artículo científico publicado en 2018

Alkene Syn- and Anti-Oxyamination with Malonoyl Peroxides

artículo científico publicado en 2020

Ambient temperature zincation of N-Boc pyrrolidine and its solvent dependency

article

Atom Efficient Synthesis of Selectively Difluorinated Carbocycles through a Gold(I)-Catalyzed Cyclization

artículo científico publicado en 2018

Backbone Reactivity of Lithium β-Diketiminate (NacNac) Complexes with CO2 , tBuNCO and iPrNCO

artículo científico publicado en 2019

Chasing the "Killer" Phonon Mode for the Rational Design of Low-Disorder, High-Mobility Molecular Semiconductors

artículo científico publicado en 2019

Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes

artículo científico publicado en 2018

Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set

scientific article published on 09 July 2018

Concealed cyclotrimeric polymorph of lithium 2,2,6,6-tetramethylpiperidide unconcealed: X-ray crystallographic and NMR spectroscopic studies

artículo científico publicado en 2013

Contrasting the group 6 metal-metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies

artículo científico publicado en 2017

Developing a hetero-alkali-metal chemistry of 2,2,6,6-tetramethylpiperidide (TMP): stoichiometric and structural diversity within a series of lithium/sodium, lithium/potassium and sodium/potassium TMP compounds

artículo científico publicado en 2011

Developing lithium chemistry of 1,2-dihydropyridines: from kinetic intermediates to isolable characterized compounds

artículo científico publicado en 2015

Diverse outcomes of CO2 fixation using alkali metal amides including formation of a heterobimetallic lithium-sodium carbamato-anhydride via lithium-sodium bis-hexamethyldisilazide

scientific article published on 01 January 2019

Dizincation of a 2-substituted thiophene: constructing a cage with a [16]crown-4 zincocyclic core

artículo científico publicado en 2012

Donor-influenced Structure-Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido-Monohydrido-Dialkylaluminates

artículo científico publicado en 2018

Exploiting σ/π Coordination Isomerism to Prepare Homologous Organoalkali Metal (Li, Na, K) Monomers with Identical Ligand Sets

article

Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS).

artículo científico publicado en 2017

Exposing elusive cationic magnesium-chloro aggregates in aluminate complexes through donor control

artículo científico publicado en 2016

Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent

article

Heterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C–H bond cleavage/dimethylamino capture or intact DMPEA complex

article

Interrogating Pd(II) Anion Metathesis Using a Bifunctional Chemical Probe: A Transmetalation Switch.

artículo científico publicado en 2017

Lead(ii) coordination polymers driven by pyridine-hydrazine donors: from anion-guided self-assembly to structural features

artículo científico publicado en 2020

LiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

artículo científico publicado en 2017

Ligand-induced reactivity of β-diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C-H or C-F bond activations

artículo científico publicado en 2017

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

artículo científico publicado en 2016

Lithium and aluminium carbamato derivatives of the utility amide 2,2,6,6-tetramethylpiperidide

article

Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

artículo científico publicado en 2018

Lithium, sodium and potassium picolyl complexes: syntheses, structures and bonding

article

Lithium-Aluminate-Catalyzed Hydrophosphination Applications

artículo científico publicado en 2019

Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.

artículo científico publicado en 2011

Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

artículo científico

Mixed lithium amide-lithium halide compounds: unusual halide-deficient amido metal anionic crowns

artículo científico publicado en 2011

Modifying alkylzinc reactivity with 2,2'-dipyridylamide: activation of tBu-Zn bonds for para-alkylation of benzophenone

artículo científico publicado en 2013

Molecular Structures of THF-Solvated Alkali-Metal 2,2,6,6-Tetramethylpiperidides Finally Revealed: X-ray Crystallographic, DFT, and NMR (including DOSY) Spectroscopic Studies

article

Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): structural and bonding implications

artículo científico publicado en 2013

N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: trapping oligomeric organo s-block fragments with NHCs

article

Neutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or four pyrrolyl ligands

article

Oxygenated Cyclopentenones via the Pauson–Khand Reaction of Silyl Enol Ether Substrates

scientific article published in 2022

Regioselective Reaction of Heterocyclic N-Oxides, an Acyl Chloride, and Cyclic Thioethers.

artículo científico publicado en 2018

Regioselective Three-Component Reaction of Pyridine N-Oxides, Acyl Chlorides, and Cyclic Ethers.

artículo científico publicado en 2017

Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations

article

Role of H-Optimization in the Computed Intermolecular Interactions and Charge-Transfer Integrals in Diketopyrrolopyrroles

scientific article published on 29 March 2019

Selective mono- and dimetallation of a group 3 sandwich complex

artículo científico publicado en 2019

Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilino Ligand.

artículo científico publicado en 2016

Structural and metal-halogen exchange reactivity studies of sodium magnesiate biphenolate complexes

scientific article published on 03 April 2020

Structural tracking of the potassium-mediated magnesiation of anisole

artículo científico publicado en 2009

Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures

artículo científico publicado en 2010

Structurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations

artículo científico publicado en 2011

Structurally stimulated deprotonation/alumination of the TMP anion

artículo científico publicado en 2010

Synthetic Approaches to Phosphasugars (2-oxo-1,2-oxaphosphacyclanes) Using the Anomeric Alkoxyl Radical β-Fragmentation Reaction as the Key Step

artículo científico publicado en 2020

The Electrophilic Fluorination of Enol Esters Using SelectFluor: A Polar Two-Electron Process

artículo científico publicado en 2019

Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C-H Functionalizations.

artículo científico publicado en 2017

Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping

artículo científico publicado en 2016

Ultrafast amidation of esters using lithium amides under aerobic ambient temperature conditions in sustainable solvents

artículo científico publicado en 2020

catena-Poly[sodium-μ2-(N,N,N',N'-tetra-methyl-ethane-1,2-diamine)-κ(2) N:N'-sodium-bis-[μ2-bis-(trimethyl-sil-yl)aza-nido-κ(2) N:N]]

artículo científico publicado en 2012

Lista de obras de

1-Alkali-metal-2-alkyl-1,2-dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide

A μ4-oxide-containing a dimeric variant of a sodium dialkyl(amido)zincate reagent

Accessible heavier s-block dihydropyridines: structural elucidation and reactivity of isolable molecular hydride sources

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

Adding a Structural Context to the Deprotometalation and Trans-Metal Trapping Chemistry of Phenyl-Substituted Benzotriazole.

After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products

Alkali metal and stoichiometric effects in intermolecular hydroamination catalysed by lithium, sodium and potassium magnesiates

Alkene Oxyamination Using Malonoyl Peroxides: Preparation of Pyrrolidines and Isoxazolidines

Alkene Syn- and Anti-Oxyamination with Malonoyl Peroxides

Ambient temperature zincation of N-Boc pyrrolidine and its solvent dependency

Atom Efficient Synthesis of Selectively Difluorinated Carbocycles through a Gold(I)-Catalyzed Cyclization

Backbone Reactivity of Lithium β-Diketiminate (NacNac) Complexes with CO2 , tBuNCO and iPrNCO

Chasing the "Killer" Phonon Mode for the Rational Design of Low-Disorder, High-Mobility Molecular Semiconductors

Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes

Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set

Concealed cyclotrimeric polymorph of lithium 2,2,6,6-tetramethylpiperidide unconcealed: X-ray crystallographic and NMR spectroscopic studies

Contrasting the group 6 metal-metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies

Developing a hetero-alkali-metal chemistry of 2,2,6,6-tetramethylpiperidide (TMP): stoichiometric and structural diversity within a series of lithium/sodium, lithium/potassium and sodium/potassium TMP compounds

Developing lithium chemistry of 1,2-dihydropyridines: from kinetic intermediates to isolable characterized compounds

Diverse outcomes of CO2 fixation using alkali metal amides including formation of a heterobimetallic lithium-sodium carbamato-anhydride via lithium-sodium bis-hexamethyldisilazide

Dizincation of a 2-substituted thiophene: constructing a cage with a [16]crown-4 zincocyclic core

Donor-influenced Structure-Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido-Monohydrido-Dialkylaluminates

Exploiting σ/π Coordination Isomerism to Prepare Homologous Organoalkali Metal (Li, Na, K) Monomers with Identical Ligand Sets

Exploring the solid state and solution structural chemistry of the utility amide potassium hexamethyldisilazide (KHMDS).

Exposing elusive cationic magnesium-chloro aggregates in aluminate complexes through donor control

Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent

Heterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C–H bond cleavage/dimethylamino capture or intact DMPEA complex

Interrogating Pd(II) Anion Metathesis Using a Bifunctional Chemical Probe: A Transmetalation Switch.

Lead(ii) coordination polymers driven by pyridine-hydrazine donors: from anion-guided self-assembly to structural features

LiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

Ligand-induced reactivity of β-diketiminate magnesium complexes for regioselective functionalization of fluoroarenes via C-H or C-F bond activations

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

Lithium and aluminium carbamato derivatives of the utility amide 2,2,6,6-tetramethylpiperidide

Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

Lithium, sodium and potassium picolyl complexes: syntheses, structures and bonding

Lithium-Aluminate-Catalyzed Hydrophosphination Applications

Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.

Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

Mixed lithium amide-lithium halide compounds: unusual halide-deficient amido metal anionic crowns

Modifying alkylzinc reactivity with 2,2'-dipyridylamide: activation of tBu-Zn bonds for para-alkylation of benzophenone

Molecular Structures of THF-Solvated Alkali-Metal 2,2,6,6-Tetramethylpiperidides Finally Revealed: X-ray Crystallographic, DFT, and NMR (including DOSY) Spectroscopic Studies

Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): structural and bonding implications

N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: trapping oligomeric organo s-block fragments with NHCs

Neutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or four pyrrolyl ligands

Oxygenated Cyclopentenones via the Pauson–Khand Reaction of Silyl Enol Ether Substrates

Regioselective Reaction of Heterocyclic N-Oxides, an Acyl Chloride, and Cyclic Thioethers.

Regioselective Three-Component Reaction of Pyridine N-Oxides, Acyl Chlorides, and Cyclic Ethers.

Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations

Role of H-Optimization in the Computed Intermolecular Interactions and Charge-Transfer Integrals in Diketopyrrolopyrroles

Selective mono- and dimetallation of a group 3 sandwich complex

Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilino Ligand.

Structural and metal-halogen exchange reactivity studies of sodium magnesiate biphenolate complexes

Structural tracking of the potassium-mediated magnesiation of anisole

Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures

Structurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations

Structurally stimulated deprotonation/alumination of the TMP anion

Synthetic Approaches to Phosphasugars (2-oxo-1,2-oxaphosphacyclanes) Using the Anomeric Alkoxyl Radical β-Fragmentation Reaction as the Key Step

The Electrophilic Fluorination of Enol Esters Using SelectFluor: A Polar Two-Electron Process

Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C-H Functionalizations.

Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping

Ultrafast amidation of esters using lithium amides under aerobic ambient temperature conditions in sustainable solvents

catena-Poly[sodium-μ2-(N,N,N',N'-tetra-methyl-ethane-1,2-diamine)-κ(2) N:N'-sodium-bis-[μ2-bis-(trimethyl-sil-yl)aza-nido-κ(2) N:N]]