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A Biochemical Nickel(I) State Supports Nucleophilic Alkyl Addition: A Roadmap for Methyl Reactivity in Acetyl Coenzyme A Synthase

scientific article published on 21 February 2019

A Novel, Modified Human Butyrylcholinesterase Catalytically Degrades the Chemical Warfare Nerve Agent, Sarin

artículo científico publicado en 2020

A functional [NiFe]-hydrogenase model compound that undergoes biologically relevant reversible thiolate protonation

artículo científico publicado en 2012

A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO2 reduction in water.

artículo científico publicado en 2018

Addition to Metalloglycosidase Mimics: Oxidative Cleavage of Saccharides Promoted by Multinuclear Copper Complexes under Physiological Conditions

artículo científico publicado en 2020

An internal electron reservoir enhances catalytic CO2 reduction by a semisynthetic enzyme

artículo científico publicado en 2016

Applications of a rapid endospore viability assay for monitoring UV inactivation and characterizing arctic ice cores

artículo científico publicado en 2006

Azurin as a Protein Scaffold for a Low-coordinate Nonheme Iron Site with a Small-molecule Binding Pocket

artículo científico publicado en 2012

Bacterial diversity in hyperarid Atacama Desert soils

scientific article published in 2007

Characterization of Oxygen Bridged Manganese Model Complexes Using Multifrequency (17)O-Hyperfine EPR Spectroscopies and Density Functional Theory.

artículo científico publicado en 2015

Corrigendum to: "A Novel, Modified Human Butyrylcholinesterase Catalytically Degrades the Chemical Warfare Nerve Agent, Sarin"

scientific article published on 26 May 2020

Direct observation of structurally encoded metal discrimination and ether bond formation in a heterodinuclear metalloprotein

artículo científico publicado en 2013

Divergent assembly mechanisms of the manganese/iron cofactors in R2lox and R2c proteins

artículo científico publicado en 2016

Driving protein conformational changes with light: Photoinduced structural rearrangement in a heterobimetallic oxidase.

artículo científico publicado en 2017

Electrochemical, Spectroscopic, and Density Functional Theory Characterization of Redox Activity in Nickel-Substituted Azurin: A Model for Acetyl-CoA Synthase

artículo científico publicado en 2015

Electronic structural flexibility of heterobimetallic Mn/Fe cofactors: R2lox and R2c proteins

artículo científico publicado en 2014

Experimental and DFT Investigations Reveal the Influence of the Outer Coordination Sphere on the Vibrational Spectra of Nickel-Substituted Rubredoxin, a Model Hydrogenase Enzyme.

artículo científico publicado en 2017

Going beyond Structure: Nickel-Substituted Rubredoxin as a Mechanistic Model for the [NiFe] Hydrogenases

scientific article published on 01 August 2018

Hydrogen bonding of tryptophan radicals revealed by EPR at 700 GHz

artículo científico publicado en 2011

In search of metal hydrides: an X-ray absorption and emission study of [NiFe] hydrogenase model complexes

artículo científico publicado en 2016

Intramolecular Electron Transfer Governs Photoinduced Hydrogen Evolution by Nickel-Substituted Rubredoxin: Resolving Elementary Steps in Solar Fuel Generation

artículo científico publicado en 2019

Key Hydride Vibrational Modes in [NiFe] Hydrogenase Model Compounds Studied by Resonance Raman Spectroscopy and Density Functional Calculations

article

Key Structural Motifs Balance Metal Binding and Oxidative Reactivity in a Heterobimetallic Mn/Fe Protein

artículo científico publicado en 2020

Ligand Field Inversion as a Mechanism to Gate Bioorganometallic Reactivity: Investigating a Biochemical Model of Acetyl CoA Synthase Using Spectroscopy and Computation

artículo científico publicado en 2021

Light-Driven Hydrogen Evolution by Nickel-Substituted Rubredoxin.

artículo científico publicado en 2017

Metalloglycosidase Mimics: Oxidative Cleavage of Saccharides Promoted by Multinuclear Copper Complexes under Physiological Conditions

artículo científico publicado en 2020

Multielectron Chemistry within a Model Nickel Metalloprotein: Mechanistic Implications for Acetyl-CoA Synthase.

artículo científico publicado en 2017

NiFe hydrogenases: A common active site for hydrogen metabolism under diverse conditions

artículo científico publicado el 8 de febrero de 2013

Nickel-Substituted Rubredoxin as a Minimal Enzyme Model for Hydrogenase

artículo científico publicado en 2015

Photogeneration and Quenching of Tryptophan Radical in Azurin

artículo científico publicado en 2015

Quantification of viable endospores from a Greenland ice core.

artículo científico publicado en 2007

Raman and Quantum Yield Studies of Trp48-d5 in Azurin: Closed-Shell and Neutral Radical Species

scientific article published on 17 July 2019

Rational Ligand Design Enables pH Control over Aqueous Iron Magnetostructural Dynamics and Relaxometric Properties

artículo científico publicado en 2020

Resonance Raman Analysis of the Tryptophan Cation Radical.

artículo científico publicado en 2014

Resonance Raman characterization of a stable tryptophan radical in an azurin mutant

artículo científico publicado en 2009

Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO and H reduction

artículo científico publicado en 2018

Spectroscopic and electrochemical characterization of the [NiFeSe] hydrogenase from Desulfovibrio vulgaris Miyazaki F: reversible redox behavior and interactions between electron transfer centers

artículo científico publicado en 2013

Spectroscopic comparison of photogenerated tryptophan radicals in azurin: effects of local environment and structure

artículo científico publicado en 2010

The good, the neutral, and the positive: buffer identity impacts CO2 reduction activity by nickel(ii) cyclam

scientific article published on 27 September 2019

Time-Resolved Investigations of Heterobimetallic Cofactor Assembly in R2lox Reveal Distinct Mn/Fe Intermediates.

artículo científico publicado en 2017