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7-endo radical cyclizations catalyzed by titanocene(III). Straightforward synthesis of terpenoids with seven-membered carbocycles

artículo científico publicado en 2005

A heterotrimetallic Ir(III), Au(III) and Pt(II) complex incorporating cyclometallating bi- and tridentate ligands: simultaneous emission from different luminescent metal centres leads to broad-band light emission

artículo científico publicado en 2015

Advances in functional-group-tolerant metal-catalyzed alkyl-alkyl cross-coupling reactions

scientific article published on 01 January 2003

Allyl stannanes as electrophiles or nucleophiles in the palladium-catalyzed reactions with alkynes

artículo científico publicado en 2003

Approaches to segment stent area from Intravascular Optical Coherence Tomography

Aryl transfer between Pd(II) centers or Pd(IV) intermediates in Pd-catalyzed domino reactions

artículo científico publicado en 2006

Atom-Economical Ni-Catalyzed Diborylative Cyclization of Enynes: Preparation of Unsymmetrical Diboronates

artículo científico publicado en 2019

Atom-economical regioselective Ni-catalyzed hydroborylative cyclization of enynes: development and mechanism

artículo científico publicado en 2019

Borylative Cyclization Reactions

artículo científico publicado en 2016

Carbocations or Cyclopropyl Gold Carbenes in Cyclizations of Enynes

artículo científico publicado el 8 de octubre de 2010

Cationic (η1-Allyl)-palladium Complexes as Feasible Intermediates in Catalyzed Reactions

artículo científico publicado en 2006

Cationic gold(I) complexes: highly alkynophilic catalysts for the exo- and endo-cyclization of enynes

artículo científico publicado en 2004

Combining the power of Ti(III)-mediated processes for easy access to hydroxylated polycyclic terpenoids: synthesis of sesterstatin 1 and C-D rings of aspergilloxide

scientific article published on 24 August 2012

Computational Study of a Nanofuse Based on Organic Molecules

artículo científico publicado en 2009

Computational studies on the cyclization of polycyclic aromatic hydrocarbons in the synthesis of curved aromatic derivatives

scientific article published on 01 February 2006

Conductance and application of organic molecule pairs as nanofuses

artículo científico publicado en 2011

Copper-Catalyzed Borylative Aromatization of p-Quinone Methides: Enantioselective Synthesis of Dibenzylic Boronates

artículo científico publicado en 2015

Copper-catalysed cross-coupling of alkyl Grignard reagents and propargylic ammonium salts: stereospecific synthesis of allenes

artículo científico publicado en 2018

Corrigendum: Iron-Catalyzed Hydroborylative Cyclization of 1,6-Enynes

scientific article published on 22 January 2020

Cover Feature: Iron-Catalyzed Hydroborylative Cyclization of 1,6-Enynes (Chem. Eur. J. 4/2018)

artículo científico publicado en 2017

Development of a New Dual Polarity and Viscosity Probe Based on the Foldamer Concept

article

Divergent luminescence behaviour from differential interactions in dinuclear Pt, Au, and mixed Pt-Au complexes built on a xanthene scaffold

artículo científico publicado en 2012

Divergent mechanisms for the skeletal rearrangement and [2+2] cycloaddition of enynes catalyzed by gold

scientific article published on 01 September 2005

Electronic properties of nanosize GNRs: The role of the anchoring groups

artículo científico publicado en 2011

Fe-catalysed Kumada-type alkyl–alkyl cross-coupling. Evidence for the intermediacy of Fe(i) complexes

artículo científico publicado en 2013

Feasibility of associative mechanism in enyne metathesis catalyzed by grubbs complexes

scientific article published on 09 May 2007

Frontispiece: Towards Useful Boronates through Atom-Economical Catalyzed Cascade Reactions

artículo científico publicado en 2018

Gold(I)-catalyzed intramolecular [4+2] cycloadditions of arylalkynes or 1,3-enynes with alkenes: scope and mechanism

artículo científico publicado en 2007

Gold(I)-catalyzed intramolecular cyclopropanation of dienynes

artículo científico publicado en 2006

Hydroxy- and Alkoxycyclizations of Enynes Catalyzed by Platinum(II) Chloride

artículo científico publicado en 2003

Influence of Controlled Cooling in Bimodal Scaffold Fabrication Using Polymers with Different Melting Temperatures.

artículo científico publicado en 2017

Influence of the number of anchoring groups on the electronic and mechanical properties of benzene-, anthracene- and pentacene-based molecular devices

artículo científico publicado en 2012

Intramolecular coupling of allyl carboxylates with allyl stannanes and allyl silanes: a new type of reductive elimination reaction?

artículo científico publicado en 2002

Intramolecular reactions of alkynes with furans and electron rich arenes catalyzed by PtCl2: the role of platinum carbenes as intermediates.

artículo científico publicado en 2003

Iron-Catalyzed Coupling of Propargyl Bromides and Alkyl Grignard Reagents

artículo científico publicado en 2018

Iron-Catalyzed Hydroborylative Cyclization of 1,6-Enynes.

artículo científico publicado en 2017

Ligand-Controlled Electron Structure of Catalytically Active Ni Complexes.

artículo científico publicado en 2018

Ligand-controlled divergent formation of alkenyl- or allylboronates catalyzed by Pd, and synthetic applications

artículo científico publicado en 2014

Mechanistic study on the palladium-catalyzed (3 + 2) intramolecular cycloaddition of alk-5-enylidenecyclopropanes

artículo científico publicado en 2012

Metal cyclopropyl carbenes in the reactions of alkynes with alkenes and furans

artículo científico publicado en 2004

New Building Blocks Based on Truxene Cores: Synthesis of Functionalizedsyn-Tri- and -Hexasubstituted Derivatives

Ni-Catalyzed Cyclization of Enynes and Alkynylboronates: Atom-Economical Synthesis of Boryl-1,4-dienes

scientific article published on 18 October 2019

Ni-Catalyzed Reductive Dicarbofunctionalization of Nonactivated Alkenes: Scope and Mechanistic Insights

scientific article published on 21 August 2019

Ni-catalyzed cascade cyclization-Kumada alkyl-alkyl cross-coupling

artículo científico publicado en 2013

Ni-catalyzed cascade formation of C(sp3)--C(sp3) bonds by cyclization and cross-coupling reactions of iodoalkanes with alkyl zinc halides

scientific article published on 01 January 2007

NiI Catalyzes the Regioselective Cross-Coupling of Alkylzinc Halides and Propargyl Bromides to Allenes.

artículo científico publicado en 2016

Nickel-catalysed Negishi cross-coupling reactions: scope and mechanisms

artículo científico publicado en 2009

Nickel-catalyzed cross-coupling of alkyl zinc halides for the formation of C(sp(2))-C(sp(3)) bonds: scope and mechanism

artículo científico publicado en 2009

Nonafluorobutanesulfonyl azide as a shelf-stable highly reactive oxidant for the copper-catalyzed synthesis of 1,3-diynes from terminal alkynes

artículo científico publicado en 2015

Novel ortho-OPE metallofoldamers: binding-induced folding promoted by nucleating Ag(i)–alkyne interactions

O-H and (CO)N-H bond weakening by coordination to Fe(ii)

scientific article published on 01 February 2019

On the Mechanism of the Puzzling “Endocyclic” Skeletal Rearrangement of 1,6-Enynes

artículo científico publicado en 2007

On the mechanism of the formation of alkyl-Ni(i) catalysts

artículo científico publicado en 2021

On/off electrochemical switches based on quinone-bisketals

artículo científico publicado en 2010

Palladium-catalysed [3+2] cycloaddition of alk-5-ynylidenecyclopropanes to alkynes: a mechanistic DFT study.

artículo científico publicado en 2008

Pd-catalyzed borylative cyclisation of 1,7-enynes

scientific article published on 01 November 2012

Pd-catalyzed borylative cyclization of 1,6-enynes

scientific article published on 30 January 2007

Pd-catalyzed borylative cyclization of allenynes and enallenes

artículo científico publicado en 2009

Pd-catalyzed borylative polycyclization of enediynes to alkylboronates

scientific article published on 30 January 2011

Pd-catalyzed borylative polycyclization of enediynes to allylboronates

artículo científico publicado en 2008

Preparation of allylboronates by Pd-catalysed borylative cyclisation of dienynes

artículo científico publicado en 2013

Pt(II)-Catalyzed Intramolecular Reaction of Furans with Alkynes This work was supported by the DGICYT (project PB97-0002) and the MCyT (predoctoral fellowship to B.M.-M.). We also acknowledge Johnson Matthey PLC for a generous loan of PtCl(2)

Reaction of enol ethers with alkynes catalyzed by transition metals: 5-exo-dig versus 6-endo-dig cyclizations via cyclopropyl platinum or gold carbene complexes

scientific article published on 01 June 2003

Regiocontrolled Cu(I)-catalyzed borylation of propargylic-functionalized internal alkynes

artículo científico publicado en 2012

Stapled helical -OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity

artículo científico publicado en 2016

Sulfoxide-Induced Homochiral Folding of ortho-Phenylene Ethynylenes (o-OPEs) by Silver(I) Templating: Structure and Chiroptical Properties.

artículo científico publicado en 2017

Synthesis ofC3 Benzo[1,2-e:3,4-e′:5,6-e′′]tribenzo[l]acephenanthrylenes (“Crushed Fullerene” Derivatives) by Intramolecular Palladium-Catalyzed Arylation

artículo científico publicado en 2004

Synthesis, X-ray Structure, and Electrochemical and Excited-State Properties of Multicomponent Complexes Made of a [Ru(Tpy)2]2+Unit Covalently Linked to a [2]-Catenate Moiety. Controlling the Energy-Transfer Direction by Changing the Catenate Metal I

scientific article published in 1999

Templating and Clipping Coordination Reactions Leading to Heteronuclear Trimetallic Complexes Containing Interlocking Rings

scientific article published on 01 June 1997

The final steps of the Oppolzer cyclization: mechanism of the insertion of alkenes into allylpalladium(II) complexes

artículo científico publicado en 2003

The role of water-based hydrogen atom wires in long-range electron-transfer reactions in aqueous media for the FeII-FeIII self-exchange and related systems

artículo científico publicado en 2013

Thermally driven nanofuses based on organometallic rotors

artículo científico publicado en 2012

Titanocene(III)-catalyzed 6-exo versus 7-endo cyclizations of epoxypolyprenes: efficient control and synthesis of versatile terpenic building blocks

artículo científico publicado en 2013

Titanocene-catalyzed cascade cyclization of epoxypolyprenes: straightforward synthesis of terpenoids by free-radical chemistry

artículo científico publicado en 2004

Toward Multiple Conductance Pathways with Heterocycle-Based Oligo(phenyleneethynylene) Derivatives.

artículo científico publicado en 2015

Towards Useful Boronates through Atom-Economical Catalyzed Cascade Reactions

artículo científico publicado en 2018

Triflyl-assisted reductive Pd-catalyzed Tsuji-Trost type reaction

scientific article published on 29 April 2020

Two-dimensional carbon-based conductive materials with dynamically controlled asymmetric Dirac cones.

artículo científico publicado en 2015

Understanding the exceptional hydrogen-atom donor characteristics of water in Ti(III)-mediated free-radical chemistry

artículo científico publicado en 2010

Unprecedented H-atom transfer from water to ketyl radicals mediated by Cp(2)TiCl

scientific article published on 12 August 2010

Unprecedented hydrogen transfer from water to alkenes and alkynes mediated by TiIII and late transition metals

scientific article published on 05 May 2007

Versatile Bottom-up Approach to Stapled π-Conjugated Helical Scaffolds: Synthesis and Chiroptical Properties of Cyclico-Phenylene Ethynylene Oligomers

artículo científico publicado en 2012

Water: the ideal hydrogen-atom source in free-radical chemistry mediated by Ti(III) and other single-electron-transfer metals?

artículo científico publicado en 2006

Water‐Based Hydrogen‐Atom Wires as Mediators in Long‐Range Proton‐Coupled Electron Transfer in Enzymes: A New Twist on Water Reactivity

artículo científico publicado el 10 de junio de 2011

cis-Selective single-cleavage skeletal rearrangement of 1,6-enynes reveals the multifaceted character of the intermediates in metal-catalyzed cycloisomerizations

artículo científico publicado en 2008