Lista de obras - Gerd-Volker Röschenthaler

A Selectfluor-promoted oxidative reaction of disulfides and amines: access to sulfinamides

artículo científico publicado en 2020

A novel type of formation of zwitterionic compounds, containing two phosphorus atoms of opposite charge and different coordination number.

artículo científico publicado en 2002

Are intramolecular frustrated Lewis pairs also intramolecular catalysts? A theoretical study on H2 activation

artículo científico publicado en 2015

Asymmetric Synthesis of 4,4-(Difluoro)glutamic Acid via Chiral Ni(II)-Complexes of Dehydroalanine Schiff Bases. Effect of the Chiral Ligands Structure on the Stereochemical Outcome

artículo científico publicado en 2020

Asymmetric synthesis of phosphonotrifluoroalanine and its derivatives using N-tert-butanesulfinyl imine derived from fluoral

CF2-Containing acetylenephosphonates in heterocyclization reactions: the first synthesis of 2-difluoromethyl azaxanth-3-ylphosphonates ⬇️

artículo científico publicado el 19 de octubre de 2011

Carbamoylphosphonate-based matrix metalloproteinase inhibitor metal complexes: solution studies and stability constants. Towards a zinc-selective binding group

artículo científico publicado en 2004

Carbamoylphosphonates, a new class of in vivo active matrix metalloproteinase inhibitors. 1. Alkyl- and cycloalkylcarbamoylphosphonic acids

artículo científico publicado en 2004

Carbene complexes of phosphorus(V) fluorides substituted with perfluoroalkyl-groups synthesized by oxidative addition. Cleavage of the complexes reveals a new synthetic protocol for ionic liquids.

artículo científico publicado en 2014

Click-chemistry approach to isoxazole-containing α-CF3-substituted α-aminocarboxylates and α-aminophosphonates

scientific article published on 02 September 2011

Complementary bonding analysis of the N-Si interaction in pentacoordinated silicon compounds using quantum crystallography

scientific article published on 17 October 2019

Complexes of Ge(IV)- and Sn(IV)-fluorides with cyclic and acyclic carbenes: bis(dialkylamino)-difluoromethylenes as carbene sources

scientific article published on 03 January 2012

Control of Regio- and Enantioselectivity in the Asymmetric Organocatalytic Addition of Acetone to 4-(Trifluoromethyl)pyrimidin-2(1H)-ones

article

Convenient synthesis of ethyl 4-aryl-6-(trifluoromethyl)-2-oxo-2H-pyran-3-carboxylates and 4-aryl-6-(trifluoromethyl)-2H-pyran-2-ones: novel highly reactive CF3-containing building blocks

scientific article published on 07 June 2008

Copper-catalyzed trifluoromethylation of aryl iodides with potassium (trifluoromethyl)trimethoxyborate.

artículo científico publicado en 2011

Darstellung und Struktur von Dispiro-diazaphosphetidinen

Darstellung und Strukturbestimmung von Ammoniak-Phosphorpentafluorid (1/1)

article published in 1983

Darstellung von 2-Amino-1.3.2λ3(λ5)-dioxaphospholanen / Synthesis of 2-Amino-1,3,2λ3 (λ5)-dioxaphospholanes

Design, cytotoxic and fluorescent properties of novel N-phosphorylalkyl substituted E,E-3,5-bis(arylidene)piperid-4-ones.

artículo científico publicado en 2008

Different fluoride anion sources and (trifluoromethyl)trimethylsilane: molecular structure of tris(dimethylamino)sulfonium bis(trifluoromethyl)trimethylsiliconate, the first isolated pentacoordinate silicon species with five Si–C bonds

article

Diphosphates and diphosphonates in polyoxometalate chemistry.

artículo científico

Elemental F2 with transannular dienes: regioselectivities and mechanisms

artículo científico publicado en 2014

Fluorinated Cyclic Phosphorus(III)-Based Electrolyte Additives for High Voltage Application in Lithium-Ion Batteries: Impact of Structure-Reactivity Relationships on CEI Formation and Cell Performance

scientific article published on 26 April 2019

Fluorine and Lithium: Ideal Partners for High-Performance Rechargeable Battery Electrolytes

artículo científico publicado en 2019

Guanidinophosphazenes: design, synthesis, and basicity in THF and in the gas phase

artículo científico publicado en 2005

Heterocyclization of N-(1-chloro-2,2,2-trifluoroethylidene)carbamates with β-enaminoesters—a novel synthetic strategy to functionalized trifluoromethylated pyrimidines

Hexaalkylguanidinium and 2-(dialkylamino)-1,3-dimethylimidazolinium trimethyldifluorosiliconates and perfluoroalkoxides. Accidental isolation and molecular structure of [C(NMe2)3]+F-*6CH2Cl2.

artículo científico publicado en 2002

Hypervalent-iodine mediated one-pot synthesis of isoxazolines and isoxazoles bearing a difluoromethyl phosphonate moiety

artículo científico publicado en 2021

Janus face all-cis 1,2,4,5-tetrakis(trifluoromethyl)- and all-cis 1,2,3,4,5,6-hexakis(trifluoromethyl)- cyclohexanes

artículo científico publicado en 2020

Methylenebisphosphonates with Dienone Pharmacophore: Synthesis, Structure, Antitumor and Fluorescent Properties ⬇️

artículo científico publicado el 2 de enero de 2012

Methyltrifluoropyruvate imines possessing N-oxalyl and N-phosphonoformyl groups--precursors to a variety of alpha-CF3-alpha-amino acid derivatives

artículo científico publicado en 2006

NHC→SiCl4 : an ambivalent carbene-transfer reagent.

artículo científico publicado en 2014

New Chiral Reagent for Installation of Pharmacophoric (S)- or (R)-2-(Alkoxyphosphono)-1-amino-2,2-difluoroethyl Groups

artículo científico publicado en 2016

Noncyclic [10-S-5] Sulfuranide Dioxide Salts with Three S−C Bonds: A New Class of Stable Hypervalent Compounds ⬇️

artículo científico publicado el 15 de octubre de 2003

On the mechanism of hydrogen activation by frustrated Lewis pairs

artículo científico publicado en 2013

Pentakis(trifluoromethyl)phenyl, a sterically crowded and electron-withdrawing group: synthesis and acidity of pentakis(trifluoromethyl)benzene, -toluene, -phenol, and -aniline

artículo científico publicado en 2008

Phosphorus(V) Complexes with Acyclic Monoaminocarbene Ligands via Oxidative Addition ⬇️

artículo científico publicado el 26 de abril de 2013

Polytrifluoromethylation versus polyfluorination of the isomers of Kekulé benzene and phenol: a theoretical study

artículo científico publicado en 2010

Preparations of SF(5)- and CF(3)-substituted arenes utilizing the 7-oxabicyclo[2.2.1]hept-2-ene synthones.

artículo científico publicado en 2013

Propargyl-Substituted Phosphonocarboxylates: Efficient Synthesis and Application to Click Chemistry

artículo científico publicado en 2009

Regioselective nucleophilic 1,4-trifluoromethylation of 2-polyfluoroalkylchromones with (trifluoromethyl)trimethylsilane. Synthesis of fluorinated analogs of natural 2,2-dimethylchroman-4-ones and 2,2-dimethylchromenes.

artículo científico publicado en 2003

SF5-Enolates in Ti(IV)-Mediated Aldol Reactions

artículo científico publicado en 2016

Selective synthesis of cis- and trans-[(NHC(Me))2PtCl2] and [NHC(Me)Pt(cod)Cl][NHC(Me)PtCl3] using NHC(Me)SiCl4

artículo científico publicado en 2014

Struktur und Synthese eines spirocyclischen Phosphoranid-Anions: Modell für einen Zwischenzustand bei einer SN2(P)-Reaktion

article published in 1983

Synthesis and Characterization of Oxazaborinin Phosphonate for Blue OLED Emitter Applications

artículo científico publicado en 2019

Synthesis and reactivity of new functionalized perfluoroalkylfluorophosphates

scientific article published on 14 May 2014

Synthesis of (α,α-Difluoropropargyl)phosphonates via Aldehyde-to-Alkyne Homologation ⬇️

artículo científico publicado el 19 de abril de 2013

Synthesis of 2-perfluoroalkyl 4H- and 2H-chromenylphosphonates mediated by amines and phosphines

scientific article published on 01 December 2010

Synthesis of functionalized bisphosphonates via click chemistry

artículo científico publicado en 2007

The conformational analysis of push-pull enaminones using Fourier transform IR and NMR spectroscopy, and quantum chemical calculations. V. α-Methyl-, fluorine-β-N,N-dimethylaminovinyl trifluoromethyl ketones

artículo científico publicado en 2014

The self-disproportionation of enantiomers (SDE) via column chromatography of β-amino-α,α-difluorophosphonic acid derivatives

scientific article published on 29 August 2019

The tris(trifluoromethyl)methyl phosphonium ion, P(CF(3))(3)CH(3)(+), preparation and structure

artículo científico publicado en 2009

Lista de obras de Gerd-Volker Röschenthaler

A Selectfluor-promoted oxidative reaction of disulfides and amines: access to sulfinamides

A novel type of formation of zwitterionic compounds, containing two phosphorus atoms of opposite charge and different coordination number.

Are intramolecular frustrated Lewis pairs also intramolecular catalysts? A theoretical study on H2 activation

Asymmetric Synthesis of 4,4-(Difluoro)glutamic Acid via Chiral Ni(II)-Complexes of Dehydroalanine Schiff Bases. Effect of the Chiral Ligands Structure on the Stereochemical Outcome

Asymmetric synthesis of phosphonotrifluoroalanine and its derivatives using N-tert-butanesulfinyl imine derived from fluoral

CF2-Containing acetylenephosphonates in heterocyclization reactions: the first synthesis of 2-difluoromethyl azaxanth-3-ylphosphonates ⬇️

Carbamoylphosphonate-based matrix metalloproteinase inhibitor metal complexes: solution studies and stability constants. Towards a zinc-selective binding group

Carbamoylphosphonates, a new class of in vivo active matrix metalloproteinase inhibitors. 1. Alkyl- and cycloalkylcarbamoylphosphonic acids

Carbene complexes of phosphorus(V) fluorides substituted with perfluoroalkyl-groups synthesized by oxidative addition. Cleavage of the complexes reveals a new synthetic protocol for ionic liquids.

Click-chemistry approach to isoxazole-containing α-CF3-substituted α-aminocarboxylates and α-aminophosphonates

Complementary bonding analysis of the N-Si interaction in pentacoordinated silicon compounds using quantum crystallography

Complexes of Ge(IV)- and Sn(IV)-fluorides with cyclic and acyclic carbenes: bis(dialkylamino)-difluoromethylenes as carbene sources

Control of Regio- and Enantioselectivity in the Asymmetric Organocatalytic Addition of Acetone to 4-(Trifluoromethyl)pyrimidin-2(1H)-ones

Convenient synthesis of ethyl 4-aryl-6-(trifluoromethyl)-2-oxo-2H-pyran-3-carboxylates and 4-aryl-6-(trifluoromethyl)-2H-pyran-2-ones: novel highly reactive CF3-containing building blocks

Copper-catalyzed trifluoromethylation of aryl iodides with potassium (trifluoromethyl)trimethoxyborate.

Darstellung und Struktur von Dispiro-diazaphosphetidinen

Darstellung und Strukturbestimmung von Ammoniak-Phosphorpentafluorid (1/1)

Darstellung von 2-Amino-1.3.2λ3(λ5)-dioxaphospholanen / Synthesis of 2-Amino-1,3,2λ3 (λ5)-dioxaphospholanes

Design, cytotoxic and fluorescent properties of novel N-phosphorylalkyl substituted E,E-3,5-bis(arylidene)piperid-4-ones.

Different fluoride anion sources and (trifluoromethyl)trimethylsilane: molecular structure of tris(dimethylamino)sulfonium bis(trifluoromethyl)trimethylsiliconate, the first isolated pentacoordinate silicon species with five Si–C bonds

Diphosphates and diphosphonates in polyoxometalate chemistry.

Elemental F2 with transannular dienes: regioselectivities and mechanisms

Fluorinated Cyclic Phosphorus(III)-Based Electrolyte Additives for High Voltage Application in Lithium-Ion Batteries: Impact of Structure-Reactivity Relationships on CEI Formation and Cell Performance

Fluorine and Lithium: Ideal Partners for High-Performance Rechargeable Battery Electrolytes

Guanidinophosphazenes: design, synthesis, and basicity in THF and in the gas phase

Heterocyclization of N-(1-chloro-2,2,2-trifluoroethylidene)carbamates with β-enaminoesters—a novel synthetic strategy to functionalized trifluoromethylated pyrimidines

Hexaalkylguanidinium and 2-(dialkylamino)-1,3-dimethylimidazolinium trimethyldifluorosiliconates and perfluoroalkoxides. Accidental isolation and molecular structure of [C(NMe2)3]+F-*6CH2Cl2.

Hypervalent-iodine mediated one-pot synthesis of isoxazolines and isoxazoles bearing a difluoromethyl phosphonate moiety

Janus face all-cis 1,2,4,5-tetrakis(trifluoromethyl)- and all-cis 1,2,3,4,5,6-hexakis(trifluoromethyl)- cyclohexanes

Methylenebisphosphonates with Dienone Pharmacophore: Synthesis, Structure, Antitumor and Fluorescent Properties ⬇️

Methyltrifluoropyruvate imines possessing N-oxalyl and N-phosphonoformyl groups--precursors to a variety of alpha-CF3-alpha-amino acid derivatives

NHC→SiCl4 : an ambivalent carbene-transfer reagent.

New Chiral Reagent for Installation of Pharmacophoric (S)- or (R)-2-(Alkoxyphosphono)-1-amino-2,2-difluoroethyl Groups

Noncyclic [10-S-5] Sulfuranide Dioxide Salts with Three S−C Bonds: A New Class of Stable Hypervalent Compounds ⬇️

On the mechanism of hydrogen activation by frustrated Lewis pairs

Pentakis(trifluoromethyl)phenyl, a sterically crowded and electron-withdrawing group: synthesis and acidity of pentakis(trifluoromethyl)benzene, -toluene, -phenol, and -aniline

Phosphorus(V) Complexes with Acyclic Monoaminocarbene Ligands via Oxidative Addition ⬇️

Polytrifluoromethylation versus polyfluorination of the isomers of Kekulé benzene and phenol: a theoretical study

Preparations of SF(5)- and CF(3)-substituted arenes utilizing the 7-oxabicyclo[2.2.1]hept-2-ene synthones.

Propargyl-Substituted Phosphonocarboxylates: Efficient Synthesis and Application to Click Chemistry

Regioselective nucleophilic 1,4-trifluoromethylation of 2-polyfluoroalkylchromones with (trifluoromethyl)trimethylsilane. Synthesis of fluorinated analogs of natural 2,2-dimethylchroman-4-ones and 2,2-dimethylchromenes.

SF5-Enolates in Ti(IV)-Mediated Aldol Reactions

Selective synthesis of cis- and trans-[(NHC(Me))2PtCl2] and [NHC(Me)Pt(cod)Cl][NHC(Me)PtCl3] using NHC(Me)SiCl4

Struktur und Synthese eines spirocyclischen Phosphoranid-Anions: Modell für einen Zwischenzustand bei einer SN2(P)-Reaktion

Synthesis and Characterization of Oxazaborinin Phosphonate for Blue OLED Emitter Applications

Synthesis and reactivity of new functionalized perfluoroalkylfluorophosphates

Synthesis of (α,α-Difluoropropargyl)phosphonates via Aldehyde-to-Alkyne Homologation ⬇️

Synthesis of 2-perfluoroalkyl 4H- and 2H-chromenylphosphonates mediated by amines and phosphines

Synthesis of functionalized bisphosphonates via click chemistry

The conformational analysis of push-pull enaminones using Fourier transform IR and NMR spectroscopy, and quantum chemical calculations. V. α-Methyl-, fluorine-β-N,N-dimethylaminovinyl trifluoromethyl ketones

The self-disproportionation of enantiomers (SDE) via column chromatography of β-amino-α,α-difluorophosphonic acid derivatives

The tris(trifluoromethyl)methyl phosphonium ion, P(CF(3))(3)CH(3)(+), preparation and structure