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1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes as strong salt-free reductants for generating low-valent early transition metals with electron-donating ligands.

artículo científico publicado en 2014

2,2'-Bipyridyl formation from 2-arylpyridines through bimetallic diyttrium intermediate

artículo científico publicado en 2015

4,4'-Bipyridyl-Catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron

artículo científico publicado en 2019

A New Protocol to Generate Catalytically Active Species of Group 4-6 Metals by Organosilicon-Based Salt-Free Reductants

artículo científico publicado en 2018

Aminomethylation reaction of ortho-pyridyl C-H bonds catalyzed by group 3 metal triamido complexes.

artículo científico publicado en 2015

Arylimido-Bridged Dinuclear Ti(μ-NAr)2 Ti Scaffold for Alkyne Insertion into the ortho-C-H Bond of Arylimido Ligands.

artículo científico publicado en 2016

Bis(imido)vanadium(V)-Catalyzed [2+2+1] Coupling of Alkynes and Azobenzenes Giving Multisubstituted Pyrroles

artículo científico publicado en 2019

Cerium(IV) Carboxylate Photocatalyst for Catalytic Radical Formation from Carboxylic Acids: Decarboxylative Oxygenation of Aliphatic Carboxylic Acids and Lactonization of Aromatic Carboxylic Acids

artículo científico publicado en 2020

Cerium-Complex-Catalyzed Oxidation of Arylmethanols under Atmospheric Pressure of Dioxygen and Its Mechanism through a Side-On μ-Peroxo Dicerium(IV) Complex.

artículo científico publicado en 2016

Chemo- and Regioselective Reduction of 5,15-Diazaporphyrins Providing Antiaromatic Azaporphyrinoids

artículo científico publicado en 2016

Cobalt-Catalyzed E-Selective Cross-Dimerization of Terminal Alkynes: A Mechanism Involving Cobalt(0/II) Redox Cycles

scientific article published on 12 December 2019

Dehalogenation of vicinal dihalo compounds by 1,1'-bis(trimethylsilyl)-1H,1'H-4,4'-bipyridinylidene for giving alkenes and alkynes in a salt-free manner.

artículo científico publicado en 2017

Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex

artículo científico publicado en 2018

Direct functionalization of unactivated C-H bonds catalyzed by group 3-5 metal alkyl complexes.

artículo científico

Direct ortho-C-H Aminoalkylation of 2-Substituted Pyridine Derivatives Catalyzed by Yttrium Complexes with N,N'-Diarylethylenediamido Ligands

artículo científico publicado en 2018

Hemilabile N-Xylyl-N′-methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage

artículo científico publicado el 23 de agosto de 2013

Hydrodehalogenation of alkyl halides catalyzed by a trichloroniobium complex with a redox active α-diimine ligand

scientific article published on 05 June 2019

In Situ Catalyst Generation and Benchtop-Compatible Entry Points for TiII/TiIV Redox Catalytic Reactions

artículo científico publicado en 2018

Lanthanide Complexes Supported by a Trizinc-crown Ether as Catalysts for Alternating Copolymerization of Epoxide and CO₂: Telomerization Controlled by Carboxylate Anions.

artículo científico publicado en 2018

Low Temperature Activation of Supported Metathesis Catalysts by Organosilicon Reducing Agents

artículo científico publicado en 2016

Mechanistic understanding of alkyne cyclotrimerization on mononuclear and dinuclear scaffolds: [4 + 2] cycloaddition of the third alkyne onto metallacyclopentadienes and dimetallacyclopentadienes.

artículo científico publicado en 2016

Metal-Free Deoxygenation and Reductive Disilylation of Nitroarenes by Organosilicon Reducing Reagents

artículo científico publicado en 2018

Metathesis cleavage of an N[double bond, length as m-dash]N bond in benzo[c]cinnolines and azobenzenes by triply-bonded ditungsten complexes

artículo científico publicado en 2018

Mixed Ligated Tris(amidinate)dimolybdenum Complexes as Catalysts for Radical Addition of CCl4 to 1-Hexene: Leaving Ligand Lability Controls Catalyst Activity.

artículo científico publicado en 2016

Mixed-ligand complexes of paddlewheel dinuclear molybdenum as hydrodehalogenation catalysts for polyhaloalkanes.

artículo científico publicado en 2015

Nickel-catalyzed cyanation of aryl halides and triflates using acetonitrile via C-CN bond cleavage assisted by 1,4-bis(trimethylsilyl)-2,3,5,6-tetramethyl-1,4-dihydropyrazine

artículo científico publicado en 2018

Organomagnesium-catalyzed isomerization of terminal alkynes to allenes and internal alkynes.

artículo científico publicado en 2015

Organosilicon Reducing Reagents for Stereoselective Formations of Silyl Enol Ethers from α-Halo Carbonyl Compounds

artículo científico publicado en 2018

Salt-Free Reduction of Nonprecious Transition-Metal Compounds: Generation of Amorphous Ni Nanoparticles for Catalytic C-C Bond Formation

artículo científico publicado en 2015

Salt-Free Reduction of Transition Metal Complexes by Bis(trimethylsilyl)cyclohexadiene, -dihydropyrazine, and -4,4'-bipyridinylidene Derivatives

artículo científico publicado en 2019

Salt-free reducing reagent of bis(trimethylsilyl)cyclohexadiene mediates multielectron reduction of chloride complexes of W(VI) and W(IV)

artículo científico publicado en 2013

Self-Assembled Multilayer Iron(0) Nanoparticle Catalyst for Ligand-Free Carbon-Carbon/Carbon-Nitrogen Bond-Forming Reactions

artículo científico publicado en 2020

Silica-supported isolated molybdenum di-oxo species: formation and activation with organosilicon agent for olefin metathesis

scientific article published on 01 April 2018

Structural and Electronic Noninnocence of α-Diimine Ligands on Niobium for Reductive C-Cl Bond Activation and Catalytic Radical Addition Reactions

artículo científico publicado en 2017

Synthesis and Characterization of Alkoxide-Bridged Heterometallic Clusters of Cerium and Copper

artículo científico publicado en 2019

Synthesis and Characterization of Paramagnetic Tungsten Imido Complexes Bearing α-Diimine Ligands

artículo científico publicado en 2016

Synthesis of Pyridylimido Complexes of Tantalum and Niobium by Reductive Cleavage of the N═N Bond of 2,2'-Azopyridine: Precursors for Early-Late Heterobimetallic Complexes

artículo científico publicado en 2019

Tantallacyclopentadiene as a unique metal-containing diene ligand coordinated to nickel for preparing tantalum-nickel heterobimetallic complexes.

artículo científico publicado en 2017

Tetraplatinum cluster complexes bearing hydrophilic anchors as precursors for γ-Al2O3-supported platinum nanoparticles.

artículo científico publicado en 2013

α-Diimine-Niobium Complex-Catalyzed Deoxychlorination of Benzyl Ethers with Silicon Tetrachloride

artículo científico publicado en 2019