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"Nanoobjects" by Self-Assembly Concomitant with Modifications under Alterable Boundary Conditions: Incorporation of Paramagnetic Metal Centers (Cu(2+)) in Ring-Shaped Molybdenum-Oxide Based Clusters

artículo científico publicado en 2001

(PPh4)4[Ag2S20]·S8, an unusual very sulfur-rich compound

A Comprehensive Study on Triplesalen-Based [MnIII6FeIII]3+and [MnIII6FeII]2+Complexes: Redox-Induced Variation of Molecular Magnetic Properties

A Mixed-Valence Fluorido-Bridged FeIIFeIII Complex

artículo científico publicado en 2017

A Mn(III) triplesalen-based 1D pearl necklace: exchange interactions and zero-field splittings in a C3-symmetric Mn(III)6 complex

artículo científico publicado en 2009

A Small Cavity with Reactive Internal Shell Atoms Spanned by Four {As(W/V)9}-Type Building Blocks Allows Host-Guest Chemistry under Confined Conditions

artículo científico publicado en 2005

A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

artículo científico publicado en 2012

A potassium selective ‘nanosponge’ with well defined pores

artículo científico publicado en 2002

A spherical 24 butyrate aggregate with a hydrophobic cavity in a capsule with flexible pores: confinement effects and uptake-release equilibria at elevated temperatures

artículo científico publicado en 2009

A tailor-made ligand to mimic the active site of diiron enzymes: an air-oxidized high-valent FeIIIh.s.(μ-O)2FeIVh.s. species ⬇️

artículo científico publicado el 19 de noviembre de 2010

A unique fluoride nanocontainer: porous molecular capsules can accommodate an unusually high number of "rather labile" fluoride anions

artículo científico publicado en 2015

Additions and corrections

An inverted triplesalen ligand by a convergent synthesis and its influence on trinuclear FeIII 3 complexes

Archimedean Synthesis and Magic Numbers: “Sizing” Giant Molybdenum-Oxide-Based Molecular Spheres of the Keplerate Type

artículo científico publicado en 1999

Artificial Cells: Temperature-Dependent, Reversible Li+-Ion Uptake/Release Equilibrium at Metal Oxide Nanocontainer Pores

artículo científico publicado en 2004

Building blocks as disposition in solution: [{MoVIO3(H2O)}10{VIVO(H2O)}20{(MoVI/MoVI5O21)(H2O)3}10({MoVIO2(H2O)2}5/2)2 ({NaSO4}5)2]20−, a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry?

Cation behavior at an artificial cell interface: binding distinguished by ion hydration energetics and size.

artículo científico publicado en 2008

Chameleon water: assemblies confined in nanocapsules

Changeable Pore Sizes Allowing Effective and Specific Recognition by a Molybdenum-Oxide Based “Nanosponge”: En Route to Sphere-Surface and Nanoporous-Cluster Chemistry

artículo científico publicado en 2002

Chemical adaptability: the integration of different kinds of matter into giant molecular metal oxides

artículo científico publicado en 2012

Coordination chemistry under confined conditions: a simplified illustrative view

Countercation Transport Modeled by Porous Spherical Molybdenum Oxide Based Nanocapsules

article

Cover Picture: Angew. Chem. Int. Ed. 19/2002

Cross-linking nanostructured spherical capsules as building units by crystal engineering: related chemistry

article published in 2000

Crystal and molecular structure of ((C6H5)3P)2CuS2MoS2CuP(C6H5)3·0.8CH2Cl2, a compound with a doubly bridging MoS2-4-ligand between Cu-Centers

Darstellung und Kristallstruktur von (PPh3)3Ag2WS4, einem neuartigen Dreikern-Komplex mit tetraedrisch und trigonal planar koordinierten Ag-Atomen / Preparation and Crystal Structure of (PPh3)3Ag2WS4, a Novel Trinuclear Complex with Tetrahedral and T

Design and synthesis of a dinucleating ligand system with varying terminal donor functions that provides no bridging donor and its application to the synthesis of a series of Fe(III)-μ-O-Fe(III) complexes

artículo científico publicado en 2016

Do trinuclear triplesalen complexes exhibit cooperative effects? Synthesis, characterization, and enantioselective catalytic sulfoxidation by chiral trinuclear Fe(III) triplesalen complexes

artículo científico publicado en 2010

Drawing Small Cations into Highly Charged Porous Nanocontainers Reveals “Water” Assembly and Related Interaction Problems

scientific article published on 01 May 2003

En route to coordination chemistry under confined conditions in a porous capsule: Pr3+with different coordination shells

scientific article published on 13 August 2004

Environmental influence on the single-molecule magnet behavior of [Mn(III)6Cr(III)]3+: molecular symmetry versus solid-state effects

artículo científico publicado en 2012

Exchange interactions and zero-field splittings in C3-symmetric Mn(III)6Fe(III): using molecular recognition for the construction of a series of high spin complexes based on the triplesalen ligand

artículo científico publicado en 2009

Expanding the Hierarchy of Metal-Oxide Building Blocks from Fragments via Clusters to Networks: A ∞ 2 [({Mo17(NO)2}3{MoV 2}3{FeIII}6)(FeII 1.5)]-Type Layer Compound

Extending the {(Mo)Mo5}12M30 Capsule Keplerate Sequence: A {Cr30} Cluster ofS=3/2 Metal Centers with a {Na(H2O)12} Encapsulate

artículo científico publicado en 2007

Formation of a “less stable” polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}2−⊂{Movi72Feiii30O252(ac)20(H2O)92}]4−

artículo científico publicado en 2006

Gated and differently functionalized (new) porous capsules direct encapsulates' structures: higher and lower density water

artículo científico publicado en 2009

Generating Structural Motifs between Three-Dimensional Solids and Discrete Species Based on the {CuNCS} Unit: (PPh4)[(ReS4)Cu2(NCS)2], (NEt4)2[(ReS4)Cu3(NCS)4], and (PPh4)2[(ReS4)2Cu2(NCS)2]

Guests on Different Internal Capsule Sites Exchange with Each Other and with the Outside

artículo científico publicado en 2011

Hydrophobic interactions and clustering in a porous capsule: option to remove hydrophobic materials from water

artículo científico publicado en 2011

Hysteresis in the ground and excited spin state up to 10 T of a [MnIII6MnIII]3+ triplesalen single-molecule magnet

Inelastic Neutron Scattering on Three Mixed-Valence Dodecanuclear Polyoxovanadate Clusters†

artículo científico publicado en 2002

Infinite octamolybdate chains cross-linked by paramagnetic iron (II) centers

Inorganic chemistry goes protein size: a Mo368 nano-hedgehog initiating nanochemistry by symmetry breaking

artículo científico publicado en 2002

Inorganic cluster compounds as models for the structure of active sites in promoted hydrodesulphurization catalysts

article published in 1987

Isopoly- und Heteropoly-Thioanionen. Kristall- und Molekülstrukturen von (PPh4)2[(WS4)WS(WS4)],CS2[(WS4)WO(WS4)H2O]·2H2O und (AsPh4)2[(WS4)Ni(WS4)]/Isopoly- and Heteropoly-Thioanions. Crystal and Molecular Structures of (PPh4)2[(WS4)WS(WS4)], Cs2[(

Linking Icosahedral, Strong Molecular Magnets {MoFe} to Layers—A Solid-State Reaction at Room Temperature

Metal-Oxide-Based Nucleation Process under Confined Conditions: Two Mixed-Valence V6-Type Aggregates Closing the W48 Wheel-Type Cluster Cavities

artículo científico publicado en 2007

Mimicking Biological Cation-Transport Based on Sphere-Surface Supramolecular Chemistry: Simultaneous Interaction of Porous Capsules with Molecular Plugs and Passing Cations

scientific article published on 01 January 2007

Molecular and Electronic Structures of Dinuclear Iron Complexes Incorporating Strongly Electron-Donating Ligands: Implications for the Generation of the One- and Two-Electron Oxidized Forms

artículo científico publicado en 2010

Molecular and electronic structures of mononuclear iron complexes using strongly electron-donating ligands and their oxidized forms

artículo científico publicado en 2008

Molecular recognition of Ca2+cations by internal and external receptors/interfaces in a spherical porous molybdenum-oxide capsule: unusual coordination scenarios

article published in 2014

Multiply bridgehead- and periphery-substituted tribenzotriquinacenes—highly versatile rigid molecular building blocks with C3v or C3 symmetry

Nanometer-Sized Molybdenum–Iron Oxide Capsule-Surface Modifications: External and Internal

artículo científico publicado en 2007

New homo- and heteronuclear tetrathiometalato complexes, specific to the FeII/WS42− system: the novel tetranuclear [S2WS2FeS2FeS2WS2]4− complex with linear metal atom array

Novel soluble cyclic and polycyclic polysulfido species: [Au2S8]2-, [Cu4Sx]2- (x = 13−15) and other copper clusters

Nucleation process in the cavity of a 48-tungstophosphate wheel resulting in a 16-metal-centre iron oxide nanocluster

artículo científico publicado en 2008

On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation

Paramagnetic Keplerate “Necklaces” Synthesized by a Novel Room-Temperature Solid-State Reaction: Controlled Linking of Metal-Oxide-Based Nanoparticles

Picking up 30 CO2 molecules by a porous metal oxide capsule based on the same number of receptors

artículo científico publicado en 2012

Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M5}12V30 Keplerates (M = Mo, W)

artículo científico publicado en 2009

Polyoxovanadates: High-Nuclearity Spin Clusters with Interesting Host−Guest Systems and Different Electron Populations. Synthesis, Spin Organization, Magnetochemistry, and Spectroscopic Studies

Porous Capsules Allow Pore Opening and Closing That Results in Cation Uptake

artículo científico publicado en 2005

Porous Capsules {(M)M5}12FeIII30 (M=MoVI, WVI): Sphere Surface Supramolecular Chemistry with 20 Ammonium Ions, Related Solution Properties, and Tuning of Magnetic Exchange Interactions

scientific article published on 01 January 2010

Probing the radialene-character in triplesalophen ligands by spectroscopic and structural analysis

artículo científico publicado en 2012

Protonation of decamethylsilicocene [bis(pentamethylcyclopentadienyl)silicon]

Rational design of a cytotoxic dinuclear Cu2 complex that binds by molecular recognition at two neighboring phosphates of the DNA backbone

artículo científico publicado en 2015

Reaction of Decamethylsilicocene with Sulfur, Selenium, and Tellurium : From a pπpπSystem to New Heterocycles

scholarly article by Peter Jutzi et al published November 1989 in Angewandte Chemie. International edition in English

Reactions inside a porous nanocapsule/artificial cell: encapsulates' structuring directed by internal surface deprotonations

scientific article published on 05 July 2006

Reduced molybenum-oxide-based core-shell hybrids: "blue" electrons are delocalized on the shell

artículo científico publicado en 2011

Reversible Carboxylate Shift in a μ-Oxo Diferric Complex in Solution by Acid-/Base-Addition

artículo científico publicado en 2018

Self-Association Based on Interfacial Structured Water Leads to {Mo154}≈1165 Super Clusters: A Dielectric Study

artículo científico publicado en 2007

Softening of Pore and Interior Properties of a Metal-Oxide-Based Capsule: Substituting 60 Oxide by 60 Sulfide Ligands

artículo científico publicado en 2011

Strong and anisotropic superexchange in the single-molecule magnet (SMM) [MnIII(6)OsIII]3+: promoting SMM behavior through 3d-5d transition metal substitution

artículo científico publicado en 2013

Structural influences on the exchange coupling and zero-field splitting in the single-molecule magnet [Mn(III)6Mn(III)]3+.

artículo científico publicado en 2012

Structure of a cavity-encapsulated nanodrop of water

Structure of a cavity-encapsulated nanodrop of water [Inorg. Chem. Commun. 6 (2003) 52]

Supramolecular Chemistry on a Cluster Surface: Fixation/Complexation of Potassium and Ammonium Ions with Crown-Ether-Like Rings

artículo científico publicado en 2009

Switching from antiferromagnetic to ferromagnetic coupling in heptanuclear [M(t)6M(c)](n+) complexes by going from an achiral to a chiral triplesalen ligand

artículo científico publicado en 2014

Synergetic activation of “silent receptor” sites leading to a new type of inclusion complex: integration of a 64-membered ring comprising K+and SO42−ions into a molybdenum oxide-based nanoobject

scientific article published on 01 August 2003

Synthesis and characterization of a trinuclear CuII3 complex bridged by an extended phloroglucinol-ligand: implications for a rational enhancement of ferromagnetic interactions ⬇️

artículo científico publicado el 5 de noviembre de 2010

Synthesis, Fragmentation, and Rearrangement Reactions of Annelated Cyclobutylcarbinols

Synthesis, structure, and magnetic characterization of a C3-symmetric Mn(III)3Cr(III) assembly: molecular recognition between a trinuclear Mn(III) triplesalen complex and a fac-triscyano Cr(III) complex

artículo científico publicado en 2009

Synthetic, spectroscopic, and X-ray crystallographic studies on binuclear copper(II) complexes with a tridentate NNS-bonding 2-formylpyridine thiosemicarbazone ligand. The characterization of both neutral and deprotonated co-ordinated ligand structur

Systematic Study of the Interaction Between VIV Centres and LnIII Ions in Well Defined {V 2 IV LnIII}{AsIIIW9O33}2 Sandwich-Type Clusters: Part 2

The behaviour of in a water nanodrop encapsulated within a highly charged porous metal–oxide nanocontainer: A thermoanalytical study

Thirty Electrons “Trapped” in a Spherical Matrix: A Molybdenum Oxide-Based Nanostructured Keplerate Reduced by 36 Electrons

artículo científico publicado en 2000

Titelbild: Angew. Chem. 19/2002

Transition Metal Thiometalates: Properties and Significance in Complex and Bioinorganic Chemistry

scientific article (publication date: November 1981)

Trapping Cations in Specific Positions in Tuneable“Artificial Cell” Channels: New Nanochemistry Perspectives

artículo científico publicado en 2003

Trapping Cations in Specific Positions in Tuneable“Artificial Cell” Channels: New Nanochemistry Perspectives

Triangular Geometrical and Magnetic Motifs Uniquely Linked on a Spherical Capsule Surface

artículo científico publicado en 2005

Trinuclear C3-symmetric extension of Jacobsen's catalyst: synthesis, characterization, and catalytic properties of a chiral trinuclear Mn(III) triplesalen complex

artículo científico publicado en 2009

Trinuclear Fragments as Nucleation Centres: New Polyoxoalkoxyvanadates by (Induced) Self-Assembly

Trinuclear copper complexes with triplesalen ligands: geometric and electronic effects on ferromagnetic coupling via the spin-polarization mechanism

artículo científico publicado en 2007

Unprecedented and differently applicable pentagonal units in a dynamic library: a keplerate of the type {(W)W5}12{Mo2}30.

artículo científico publicado en 2009

Unusual Stepwise Assembly and Molecular Growth: [H14Mo37O112]14− and [H3Mo57V6(NO)6O189(H2O)12(MoO)6]21−

Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel

artículo científico publicado en 2010

Urea as 'deus ex machina' in giant molybdenum blue type cluster synthesis: an unusual hybrid compound with perspectives for related nano, supramolecular and extended structures

artículo científico publicado en 2002

Vanadium(IV) and mixed-valence vanadium(IV/V) oxygen clusters with novel electronic properties, including the examples [V12As8O40(HCO2)]n–(n= 3 or 5)

scholarly article by Achim Müller et al published 1991 in Journal of the Chemical Society. Chemical communications

Vectorial growth/regulations in a {P8W48}-type polyoxotungstate compartment: trapped unusual molybdenum oxide acts as a handle

artículo científico publicado en 2009

X-Ray crystal and molecular structure of [W2S8Ag4(PPh3)4], a compound having a novel metal–sulphur cage fused by two connected six-membered WS3Ag2rings

article published in 1978

[Cu6S17]2–, a novel binary discrete polynuclear CuIcomplex with several interesting structural features: the arrangement of the metal atoms and co-ordination of ligands

[Fe2S2(MoS4)2]4−: The first complex with two MoS42− ions coordinated to a ferredoxin type central unit

[Fe4S4(SH)4]2–, the simplest synthetic analogue for a ferredoxin

[Mo154(NO)14O420(OH)28(H2O)70](25± 5)−: A Water-Soluble Big Wheel with More than 700 Atoms and a Relative Molecular Mass of About 24000

[Ni(S4)2]2⊖, a Homoleptic Tetrasulfido-Nickel(II) Complex

scholarly article by Achim Müller et al published December 1983 in Angewandte Chemie. International edition in English

Übergangsmetall-substituierte Diphosphene, XXIV [1] Cheletrope [1+4]-Cycloaddition von Azodicarbonsäureestern und -amiden an das metallsubstituierte Diphosphen ( η5-C5Me5)(CO)2Fe - P = P - Mes* (Mes* = 2,4,6-tBu3C6H2). Struktur von Transition Meta

“Gating” the Pores of a Metal Oxide Based Capsule: After Initial Cation Uptake Subsequent Cations Are Found Hydrated and Supramolecularly Fixed above the Pores

artículo científico publicado en 2006

“Molecular Symmetry Breakers” Generating Metal-Oxide-Based Nanoobject Fragments as Synthons for Complex Structures: [{Mo128Eu4O388H10(H2O)81}2]20, a Giant-Cluster Dimer

artículo científico publicado en 2002

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