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A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates.

artículo científico publicado en 2017

Aryl-Fluoride Bond-Forming Reductive Elimination from Nickel(IV) Centers

artículo científico publicado en 2019

Binuclear intermediates in oxidation reactions: [(Me(3)SiC[triple bond]C)Me(2)(bipy)Pt-PtMe(2)(bipy)](+) in the oxidation of Pt(II)Me(2)(bipy) (bipy = 2,2'-bipyridine) by IPh(C[triple bond]CSiMe(3))(OTf) (OTf = triflate).

artículo científico publicado en 2009

British anti-Lewisite and organomercury poisoning

artículo científico publicado el 10 de enero de 1975

Carbon-Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) Complexes

artículo científico publicado en 2016

Cluster transformation of [Cu3(μ3-H)(μ3-BH4)((PPh2)2NH)3](BF4) to [Cu3(μ3-H)(μ2,μ1-S2CH)((PPh2)2NH)3](BF4) via reaction with CS2. X-ray structural characterisation and reactivity of cationic clusters explored by multistage mass spectrometry and comp

artículo científico publicado en 2017

Computational study of C(sp3)-O bond formation at a PdIV centre

artículo científico publicado en 2017

Computational study of selectivity in the [PtIICl4]2--catalysed arylation of arenes by diaryliodonium reagents: arene activation at PtIV centres

artículo científico publicado en 2017

Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage

scientific article published on 17 July 2012

Cu-catalyzed fluorination of diaryliodonium salts with KF.

artículo científico publicado en 2013

DFT studies of two-electron oxidation, photochemistry, and radical transfer between metal centres in the formation of platinum(IV) and palladium(IV) selenolates from diphenyldiselenide and metal(II) reactants

scientific article published on 24 September 2020

Decarboxylative-Coupling of Allyl Acetate Catalyzed by Group 10 Organometallics, [(phen)M(CH3)]+

article

Formation and reactions of the 1, 8-naphthyridine (napy) ligated geminally dimetallated phenyl complexes [(napy)Cu2(Ph)]+, [(napy)Ag2(Ph)]+ and [(napy)CuAg(Ph)]

scientific article published on 01 February 2019

Formation of ethane from mono-methyl palladium(II) complexes.

artículo científico publicado en 2014

Gas-Phase Ion-Molecule Reactions of Copper Hydride Anions [CuH2]- and [Cu2H3].

artículo científico publicado en 2017

Gas-Phase Synthesis and Reactivity of Ligated Group 10 Ions in the Formal +1 Oxidation State

artículo científico publicado en 2019

Gas-Phase and Computational Study of Identical Nickel- and Palladium-Mediated Organic Transformations Where Mechanisms Proceeding via M(II) or M(IV) Oxidation States Are Determined by Ancillary Ligands

artículo científico publicado en 2015

Identification of the Side Products That Diminish the Yields of the Monoamidated Product in Metal-Catalyzed C-H Amidation of 2-Phenylpyridine with Arylisocyanates

artículo científico publicado en 2020

Ligand effects in bimetallic high oxidation state palladium systems

artículo científico publicado en 2010

Ligand-induced decarbonylation in diphosphine-ligated palladium acetates [CH3CO2Pd((PR2)2CH2)]+ (R = Me and Ph).

artículo científico publicado en 2017

Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the Cu(I)/Cu(III) Manifold in Copper Catalysis

artículo científico publicado en 2014

Microtubule-dependent processes precede pathological calcium influx in excitotoxin-induced axon degeneration

scientific article published on 05 December 2019

Nickel(II/IV) Manifold Enables Room-Temperature C(sp3)-H Functionalization

scientific article published on 26 November 2019

Nickel(IV)-Catalyzed C-H Trifluoromethylation of (Hetero)arenes

artículo científico publicado en 2019

Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium

scientific article published on 28 August 2009

Oxidatively Induced C-H Activation at High Valent Nickel

artículo científico publicado en 2017

Reduction of a platinum(iv) prodrug model by sulfur containing biological reductants: computational mechanistic elucidation

scientific article published on 01 September 2018

Stoichiometric and Catalytic Aryl-Perfluoroalkyl Coupling at Tri-tert-butylphosphine Palladium(II) Complexes

artículo científico publicado en 2017

Substituent effects in the decarboxylation reactions of coordinated arylcarboxylates in dinuclear copper complexes, [(napy)Cu2(O2CC6H4X)]+ †.

artículo científico publicado en 2017

Synthesis, structure and gas-phase reactivity of the mixed silver hydride borohydride nanocluster [Ag3(μ3-H)(μ3-BH4)L(Ph)3]BF4 (L(Ph) = bis(diphenylphosphino)methane)

artículo científico publicado en 2015

Synthesis, structure, and condensed-phase reactivity of [Ag(μ-H)(μ-BH)L](BF) (L = bis(diphenylphosphino)amine) with CS

artículo científico publicado en 2018

Theoretical investigation into the mechanism of 3'-dGMP oxidation by [Pt(IV)Cl4(dach)]

scientific article published on 27 December 2012

Theoretical investigation into the mechanism of reductive elimination from bimetallic palladium complexes

artículo científico publicado en 2011

Using electrospray ionization-tandem mass spectrometry to explore formation and gas-phase chemistry of silver nanoclusters generated from the reaction of silver salts with NaBH4 in the presence of bis(diphenylarsino)methane

artículo científico publicado en 2020