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1-naphthylpropargyl ether group: a readily cleaved and sterically minimal protecting system for stereoselective glycosylation

artículo científico publicado en 2006

4,6-O-[1-cyano-2-(2-iodophenyl)ethylidene] acetals. improved second-generation acetals for the stereoselective formation of beta-D-mannopyranosides and regioselective reductive radical fragmentation to beta-D-rhamnopyranosides. scope and limitations

artículo científico publicado en 2006

4,6-O-benzylidene-directed beta-mannopyranosylation and alpha-glucopyranosylation: the 2-deoxy-2-fluoro and 3-deoxy-3-fluoro series of donors and the importance of the O2-C2-C3-O3 interaction

artículo científico publicado en 2007

6-O-Benzyl- and 6-O-silyl-N-acetyl-2-amino-2-N,3-O-carbonyl-2-deoxyglucosides: effective glycosyl acceptors in the glucosamine 4-OH Series. effect of anomeric stereochemistry on the removal of the oxazolidinone group

artículo científico publicado en 2005

A Practical Method for the Removal of Organotin Residues from Reaction Mixtures

scientific article published on 01 October 1996

A practical alternative to the hunsdiecker reaction

article

A propos of glycosyl cations and the mechanism of chemical glycosylation; the current state of the art.

artículo científico publicado en 2014

A stable, commercially available sulfenyl chloride for the activation of thioglycosides in conjunction with silver trifluoromethanesulfonate

artículo científico publicado en 2008

Absence of Stereodirecting Participation by 2-O-Alkoxycarbonylmethyl Ethers in 4,6-O-Benzylidene-Directed Mannosylation

artículo científico publicado en 2015

Allylic selenosulfide rearrangement: a method for chemical ligation to cysteine and other thiols

artículo científico publicado en 2006

Alternative synthesis and antibacterial evaluation of 1,5-dideoxy-1,5-imino-L-rhamnitol

artículo científico publicado en 2015

Alternative synthesis of P-chiral phosphonite-borane complexes: application to the synthesis of phostone-phostone dimers

artículo científico publicado en 2013

Aminoglycosides: Time for the Resurrection of a Neglected Class of Antibacterials?

scientific article published on 19 December 2019

An oxyanion-hole selective serine protease inhibitor in complex with trypsin

artículo científico publicado en 2002

Anomericity of T-2 toxin-glucoside: masked mycotoxin in cereal crops

artículo científico publicado en 2015

Application of the 4-trifluoromethylbenzenepropargyl ether group as an unhindered, electron deficient protecting group for stereoselective glycosylation

artículo científico publicado en 2008

Apralogs: Apramycin 5-O-Glycosides and Ethers with Improved Antibacterial Activity and Ribosomal Selectivity and Reduced Susceptibility to the Aminoacyltranserferase (3)-IV Resistance Determinant

scientific article published on 17 December 2019

Assessing the role of dopamine in the differential neurotoxicity patterns of methamphetamine, mephedrone, methcathinone and 4-methylmethamphetamine

artículo científico publicado en 2017

Asymmetric Synthesis of Polyhydroxylated N-Alkoxypiperidines by Ring-Closing Double Reductive Amination: Facile Preparation of Isofagomine and Analogues

artículo científico publicado el 23 de diciembre de 2011

Asymmetric synthesis of highly substituted beta-nitro alcohols and enantiomerically enriched 4,4,5-trisubstituted oxazolidinones

artículo científico publicado en 2003

Bacillus anthracis o-succinylbenzoyl-CoA synthetase: reaction kinetics and a novel inhibitor mimicking its reaction intermediate

artículo científico publicado en 2008

Block synthesis of tetra- and hexasaccharides (beta-D-glycero-D-manno-Hep p-(1-->4)-[alpha-l-Rha p-(1-->3)-beta-D-glycero-D-manno-Hep p-(1-->4)]n-alpha-L-Rha p-OMe (n = 1 and 2)) corresponding to multiple repeat units of the glycan from the surface-

artículo científico publicado en 2008

Blue Light Photocatalytic Glycosylation without Electrophilic Additives

artículo científico publicado en 2017

Branched aliphatic alkanes with quaternary substituted carbon atoms in modern and ancient geologic samples

artículo científico publicado el 9 de octubre de 2003

CD1c presentation of synthetic glycolipid antigens with foreign alkyl branching motifs

artículo científico publicado en 2007

Catalytic oxidation adjacent to carbonyl groups and at benzylic positions with a fluorous seleninic acid in the presence of iodoxybenzene

artículo científico publicado en 2005

Cation Clock Reactions for the Determination of Relative Reaction Kinetics in Glycosylation Reactions: Applications to Gluco- and Mannopyranosyl Sulfoxide and Trichloroacetimidate Type Donors

artículo científico publicado en 2015

Cation clock permits distinction between the mechanisms of α- and β-O- and β-C-glycosylation in the mannopyranose series: evidence for the existence of a mannopyranosyl oxocarbenium ion.

artículo científico publicado en 2012

Chemical diversification of sialic acid glycosides by stereospecific, chemoselective deamination

artículo científico publicado en 2013

Chemistry of 1-Alkoxy-1-glycosyl Radicals: Formation of beta-Mannopyranosides by Radical Decarboxylation and Decarbonylation of manno-Heptulosonic Acid Glycoside Derivatives

artículo científico publicado en 1996

Chemistry of 1-Alkoxy-1-glycosyl Radicals: The Manno- and Rhamnopyranosyl Series. Inversion of alpha- to beta-Pyranosides and the Fragmentation of Anomeric Radicals.

artículo científico publicado en 1996

Confirmation of the connectivity of 4,8,12,16,20-pentamethylpentacosylphoshoryl beta-D-mannopyranoside, an unusual beta-mannosyl phosphoisoprenoid from Mycobacterium avium, through synthesis

artículo científico publicado en 2002

Convergent synthesis of a beta-(1-->3)-mannohexaose

artículo científico publicado en 2007

Correction: Comparison of the reactivity of β-thiolactones and β-lactones toward ring-opening by thiols and amines

artículo científico publicado en 2015

Cyclic peptide synthesis with thioacids

artículo científico publicado en 2010

Dechalcogenative allylic selenosulfide and disulfide rearrangements: complementary methods for the formation of allylic sulfides in the absence of electrophiles. Scope, limitations, and application to the functionalization of unprotected peptides in

artículo científico publicado en 2007

Design and synthesis of highly constrained factor Xa inhibitors: amidine-substituted bis(benzoyl)--diazepan-2-ones and bis(benzylidene)-bis(gem-dimethyl)cycloketones

artículo científico publicado en 2003

Design, Multigram Synthesis, and in Vitro and in Vivo Evaluation of Propylamycin: A Semisynthetic 4,5-Deoxystreptamine Class Aminoglycoside for the Treatment of Drug-Resistant Enterobacteriaceae and Other Gram-Negative Pathogens

scientific article published on 13 March 2019

Design, synthesis, and evaluation of oxyanion-hole selective inhibitor substituents for the S1 subsite of factor Xa.

artículo científico publicado en 2004

Determination of the Influence of Side-Chain Conformation on Glycosylation Selectivity using Conformationally Restricted Donors

artículo científico publicado en 2016

Diastereoselective Cyclizations of 1,3-Dioxan-2-yl Radicals: Chiral Acyl Radical Equivalents

scientific article published on 01 May 1996

Diastereoselectivity in the cyclization of alkene radical cations generated under non-oxidizing conditions: contact ion pairs and memory effects

artículo científico publicado en 2002

Dihydro-3-(triphenylphosphoranylidene)-2,5-thiophendione: a convenient synthon for the preparation of substituted 1,4-thiazepin-5-ones and piperidinones via the intermediacy of thioacids

artículo científico publicado el 14 de agosto de 2010

Dimethylthexylsilyl 2-acetamido-3-O-allyl-2-deoxy-6-O-(4-methoxybenzyl)-beta-D-glucopyranoside, dimethylthexylsilyl 3,4,6-tri-O-benzyl-beta-D-mannopyranosyl-(1-->4)-2-acetamido-3-O-allyl-2-deoxy-6-O-(4-methoxybenzyl)-beta-D-glucopyranoside, and dime

artículo científico publicado en 2008

Direct Fmoc-Chemistry-Based Solid-Phase Synthesis of Peptidyl Thioesters

artículo científico publicado el 13 de julio de 2011

Direct chemical synthesis of the beta-D-mannans: the beta-(1-->2) and beta-(1-->4) series

artículo científico publicado en 2004

Direct chemical synthesis of the beta-mannans: linear and block syntheses of the alternating beta-(1-->3)-beta-(1-->4)-mannan common to Rhodotorula glutinis, Rhodotorula mucilaginosa, and Leptospira biflexa

artículo científico publicado en 2004

Direct stereocontrolled synthesis of 3-amino-3-deoxy-beta-mannopyranosides: importance of the nitrogen protecting group on stereoselectivity

artículo científico publicado en 2007

Direct synthesis of the beta-l-rhamnopyranosides

artículo científico publicado en 2003

Dissecting the Influence of Two Structural Substituents on the Differential Neurotoxic Effects of Acute Methamphetamine and Mephedrone Treatment on Dopamine Nerve Endings with the Use of 4-Methylmethamphetamine and Methcathinone.

artículo científico publicado en 2016

Dissecting the influence of oxazolidinones and cyclic carbonates in sialic acid chemistry

artículo científico publicado en 2012

Dissecting the mechanisms of a class of chemical glycosylation using primary ¹³C kinetic isotope effects

artículo científico publicado en 2012

Does neighboring group participation by non-vicinal esters play a role in glycosylation reactions? Effective probes for the detection of bridging intermediates

artículo científico publicado en 2008

Effects of the 1- N-(4-Amino-2 S-hydroxybutyryl) and 6'- N-(2-Hydroxyethyl) Substituents on Ribosomal Selectivity, Cochleotoxicity, and Antibacterial Activity in the Sisomicin Class of Aminoglycoside Antibiotics

artículo científico publicado en 2018

Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane

artículo científico publicado en 2006

Electrochemical generation of glycosyl triflate pools

artículo científico publicado en 2007

En Route to the Transformation of Glycoscience: A Chemist's Perspective on Internal and External Crossroads in Glycochemistry

artículo científico publicado en 2020

Endo-selective quenching of hexahydropyrrolo[2,3-b]indole-based N-acyliminium ions

artículo científico publicado en 2004

Enhanced diastereoselectivity in beta-mannopyranosylation through the use of sterically minimal propargyl ether protecting groups

artículo científico publicado en 2006

Epimerization-free block synthesis of peptides from thioacids and amines with the Sanger and Mukaiyama reagents

artículo científico publicado en 2009

Expedient synthesis of threo-beta-hydroxy-alpha-amino acid derivatives: phenylalanine, tyrosine, histidine, and tryptophan

artículo científico publicado en 2006

Exploration of the Oxazolidinthione Protecting System for the Synthesis of Sialic Acid Glycosides

artículo científico publicado en 2013

Facile dearomatizing radical arylation of furan and thiophene.

artículo científico publicado en 2005

Facile oxidative cleavage of 4-O-benzyl ethers with dichlorodicyanoquinone in rhamno- and mannopyranosides

artículo científico publicado en 2007

Fluorine-decoupled carbon spectroscopy for the determination of configuration at fully substituted, trifluoromethyl- and perfluoroalkyl-bearing carbons: comparison with 19F-1H heteronuclear Overhauser effect spectroscopy

artículo científico publicado en 2015

Formation of beta-Mannopyranosides of Primary Alcohols Using the Sulfoxide Method

artículo científico publicado en 1996

Further studies on cation clock reactions in glycosylation: observation of a configuration specific intramolecular sulfenyl transfer and isolation and characterization of a tricyclic acetal

artículo científico publicado en 2016

Generation and trapping of alkene radical cations under nonoxidizing conditions: formation of six-membered rings by exo- and endo-mode cyclizations

scientific article published on 01 July 2002

Heterobivalent library expansion by "living radical" processes: thiocarbonyl addition/elimination, and nitroxide-based reactions with fluorous deconvolution

artículo científico publicado en 2007

Highly stereoselective synthesis of alpha-D-mannopyranosyl phosphosugars

artículo científico publicado en 2009

Hydrogenolytic cleavage of naphthylmethyl ethers in the presence of sulfides.

artículo científico publicado en 2017

IMPROVED SYNTHESIS OF 1-BENZENESULFINYL PIPERIDINE AND ANALOGS FOR THE ACTIVATION OF THIOGLYCOSIDES IN CONJUNCTION WITH TRIFLUOROMETHANESULFONIC ANHYDRIDE.

artículo científico publicado en 2005

Identification and evaluation of improved 4'-O-(alkyl) 4,5-disubstituted 2-deoxystreptamines as next-generation aminoglycoside antibiotics

artículo científico publicado en 2014

Importance of the 6'-hydroxy group and its configuration for apramycin activity

artículo científico publicado en 2014

Imposing the trans/gauche conformation on a sialic acid donor with a 5-N,7-O-oxazinanone group: effect on glycosylation stereoselectivity

artículo científico publicado en 2008

Influence of 4'-O-Glycoside Constitution and Configuration on Ribosomal Selectivity of Paromomycin

artículo científico publicado en 2015

Influence of Protecting Groups on the Reactivity and Selectivity of Glycosylation: Chemistry of the 4,6-O-Benzylidene Protected Mannopyranosyl Donors and Related Species

artículo científico publicado el 1 de enero de 2011

Influence of protecting groups on the anomeric equilibrium; case of the 4,6-O-benzylidene acetal in the mannopyranose series

artículo científico publicado en 2012

Influence of side chain conformation and configuration on glycosyl donor reactivity and selectivity as illustrated by sialic acid donors epimeric at the 7-position

artículo científico publicado en 2013

Influence of the 4,6-O-benzylidene, 4,6-O-phenylboronate, and 4,6-O-polystyrylboronate protecting groups on the stereochemical outcome of thioglycoside-based glycosylations mediated by 1-benzenesulfinyl piperidine/triflic anhydride and N-iodosuccini

artículo científico publicado en 2003

Influence of the O3 protecting group on stereoselectivity in the preparation of C-mannopyranosides with 4,6-O-benzylidene protected donors

artículo científico publicado en 2010

Interplay of Protecting Groups and Side Chain Conformation in Glycopyranosides. Modulation of the Influence of Remote Substituents on Glycosylation?

artículo científico publicado en 2018

Intramolecular Homolytic Aromatic Substitution of Alkyl 2-Benzimidazolyl Sulfones as a Means of Entry into Alkyl Radicals for Organic Synthesis

artículo científico publicado en 2008

Is donor-acceptor hydrogen bonding necessary for 4,6-O-benzylidene-directed beta-mannopyranosylation? Stereoselective synthesis of beta-C-mannopyranosides and alpha-C-glucopyranosides

artículo científico publicado en 2008

Is there a homolytic substitution chemistry (SH2) of sulfones?

artículo científico publicado en 2005

Mechanism of 4,6-O-benzylidene-directed beta-mannosylation as determined by alpha-deuterium kinetic isotope effects

artículo científico publicado en 2004

Mechanism of a chemical glycosylation reaction

artículo científico publicado en 2010

Mechanisms of Stereodirecting Participation and Ester Migration from Near and Far in Glycosylation and Related Reactions

artículo científico publicado en 2020

Methodology Development and Physical Organic Chemistry: A Powerful Combination for the Advancement of Glycochemistry

artículo científico publicado el 4 de octubre de 2011

Modification at the 2'-Position of the 4,5-Series of 2-Deoxystreptamine Aminoglycoside Antibiotics To Resist Aminoglycoside Modifying Enzymes and Increase Ribosomal Target Selectivity

scientific article published on 13 September 2019

N-O bond as a glycosidic-bond surrogate: synthetic studies toward polyhydroxylated N-alkoxypiperidines

artículo científico publicado en 2012

N6', N6''', and O4' Modifications to Neomycin Affect Ribosomal Selectivity without Compromising Antibacterial Activity

artículo científico publicado en 2017

New and improved methods for the radical decarboxylation of acids

article

O-sialylation with N-acetyl-5-n,4-o-carbonyl-protected thiosialoside donors in dichloromethane: facile and selective cleavage of the oxazolidinone ring

artículo científico publicado en 2007

On the influence of the C2-O2 and C3-O3 bonds in 4,6-O-benzylidene-directed beta-mannopyranosylation and alpha-glucopyranosylation

artículo científico publicado en 2006

On the nitrile effect in L-rhamnopyranosylation

artículo científico publicado en 2006

On the regioselectivity of the Hanessian-Hullar reaction in 4,6-O-benzylidene protected galactopyranosides

artículo científico publicado en 2006

On the use of 3,5-O-benzylidene and 3,5-O-(di-tert-butylsilylene)-2-O-benzylarabinothiofuranosides and their sulfoxides as glycosyl donors for the synthesis of beta-arabinofuranosides: importance of the activation method

artículo científico publicado en 2007

One-Pot Formation of Piperidine- and Pyrrolidine-Substituted Pyridinium Salts via Addition of 5-Alkylaminopenta-2,4-dienals to N-Acyliminium Ions: Application to the Synthesis of (±)-Nicotine and Analogs

artículo científico publicado el 5 de noviembre de 2010

One-pot syntheses of dissymmetric diamides based on the chemistry of cyclic monothioanhydrides. Scope and limitations and application to the synthesis of glycodipeptides

artículo científico publicado en 2009

Oxazolidinone Protection of N-Acetylglucosamine Confers High Reactivity on the 4-Hydroxy Group in Glycosylation

artículo científico publicado el 17 de abril de 2003

Oxidative Deamination of N-Acetyl Neuraminic Acid: Substituent Effects and Mechanism

artículo científico publicado en 2016

Phenylthiomethyl glycosides: convenient synthons for the formation of azidomethyl and glycosylmethyl glycosides and their derivatives

artículo científico publicado en 2009

Practical Synthesis of 2-Keto-3-deoxy-d-glycero-d-galactononulosonic Acid (KDN)

artículo científico publicado el 9 de noviembre de 2011

Probing the influence of a 4,6-O-acetal on the reactivity of galactopyranosyl donors: verification of the disarming influence of the trans-gauche conformation of C5-C6 bonds

artículo científico publicado en 2013

Probing the influence of protecting groups on the anomeric equilibrium in sialic acid glycosides with the persistent radical effect

artículo científico publicado en 2014

Protecting Group-Free Glycoligation by the Desulfurative Rearrangement of Allylic Disulfides as a Means of Assembly of Oligosaccharide Mimetics

artículo científico publicado el 23 de marzo de 2011

Radical chemistry associated with the thiocarbonyl group

artículo científico publicado en 1989

Radical contraction of 1,3,2-dioxaphosphepanes to 1,3,2-dioxaphosphorinanes: a kinetic and (17)O NMR spectroscopic study

artículo científico publicado en 2002

Reaction of thioacids with isocyanates and isothiocyanates: a convenient amide ligation process

artículo científico publicado en 2009

Revisiting the armed-disarmed concept: the importance of anomeric configuration in the activation of S-benzoxazolyl glycosides

artículo científico publicado en 2007

S(N)2-type nucleophilic opening of beta-thiolactones (thietan-2-ones) as a source of thioacids for coupling reactions

artículo científico publicado en 2009

Selective Protection of Secondary Amines as the N-Phenyltriazenes. Application to Aminoglycoside Antibiotics

artículo científico publicado en 2015

Sigmatropic rearrangements as tools for amino acid and peptide modification: application of the allylic sulfur ylide rearrangement to the preparation of neoglycoconjugates and other conjugates

artículo científico publicado en 2006

Silver-mediated allylic disulfide rearrangement for conjugation of thiols in protic media

artículo científico publicado en 2009

Solid-phase synthesis of beta-mannosides

artículo científico publicado en 2002

Solid-phase synthesis of peptidyl thioacids employing a 9-fluorenylmethyl thioester-based linker in conjunction with Boc chemistry

artículo científico publicado en 2009

Stereochemical memory effects in alkene radical cation/anion contact ion pairs: effect of substituents, and models for diastereoselectivity

artículo científico publicado en 2005

Stereocontrolled Synthesis of the Equatorial Glycosides of 3-Deoxy-d-manno-oct-2-ulosonic Acid: Role of Side Chain Conformation

scientific article published on 10 April 2020

Stereocontrolled formation of beta-glucosides and related linkages in the absence of neighboring group participation: influence of a trans-fused 2,3-O-carbonate group

artículo científico publicado en 2005

Stereocontrolled glycoside and glycosyl ester synthesis. neighboring group participation and hydrogenolysis of 3-(2'-benzyloxyphenyl)-3,3-dimethylpropanoates

artículo científico publicado en 2007

Stereocontrolled synthesis of D- and L-beta-rhamnopyranosides with 4-O-6-S-alpha-cyanobenzylidene-protected 6-thiorhamnopyranosyl thioglycosides

artículo científico publicado en 2009

Stereocontrolled synthesis of mannans and rhamnans

artículo científico publicado en 2009

Stereocontrolled synthesis of the D- and L-glycero-beta-D-manno-heptopyranosides and their 6-deoxy analogues. Synthesis of methyl alpha-l-rhamno-pyranosyl-(1-->3)-D-glycero-beta-D-manno-heptopyranosyl- (1-->3)-6-deoxy-glycero-beta-D-manno-heptopyran

artículo científico publicado en 2006

Stereoselective C-glycoside formation with 2-O-benzyl-4,6-O-benzylidene protected 3-deoxy gluco- and mannopyranoside donors: comparison with O-glycoside formation

artículo científico publicado en 2012

Stereoselective Synthesis of 5-epi-α-Sialosides Related to the Pseudaminic Acid Glycosides. Reassessment of the Stereoselectivity of the 5-Azido-5-deacetamidosialyl Thioglycosides and Use of Triflate as Nucleophile in the Zbiral Deamination of Siali

artículo científico publicado en 2016

Stereoselective Synthesis of the Equatorial Glycosides of Legionaminic Acid

artículo científico publicado en 2017

Stereoselective formation of glycosyl sulfoxides and their subsequent equilibration: ring inversion of an alpha-xylopyranosyl sulfoxide dependent on the configuration at sulfur.

artículo científico publicado en 2002

Stereoselective iterative one-pot synthesis of N-glycolylneuraminic acid-containing oligosaccharides

artículo científico publicado en 2008

Stereoselective synthesis of alpha-keto-deoxy-D-glycero-D-galacto-nonulosonic acid glycosides by means of the 4,5-O-carbonate protecting group

artículo científico publicado en 2010

Structure-Based Design and Synthesis of Apramycin-Paromomycin Analogues: Importance of the Configuration at the 6'-Position and Differences between the 6'-Amino and Hydroxy Series

artículo científico publicado en 2017

Synthesis and Evaluation of 1,5-Dithia-d-laminaribiose, Triose, and Tetraose as Truncated β-(1→3)-Glucan Mimetics

scientific article published on 04 December 2018

Synthesis and Evaluation of Oligomeric Thioether-Linked Carbacyclic β-(1→3)-Glucan Mimetics

artículo científico publicado en 2019

Synthesis and Stereocontrolled Equatorially Selective Glycosylation Reactions of a Pseudaminic Acid Donor: Importance of the Side-Chain Conformation and Regioselective Reduction of Azide Protecting Groups

artículo científico publicado en 2018

Synthesis and biological investigation of the β-thiolactone and β-lactam analogs of tetrahydrolipstatin

artículo científico publicado el 21 de febrero de 2012

Synthesis and evaluation of 3-deoxy and 3-deoxy-3-fluoro derivatives of gluco- and manno-configured tetrahydropyridoimidazole glycosidase inhibitors

artículo científico publicado en 2013

Synthesis and structural verification of the xylomannan antifreeze substance from the freeze-tolerant Alaskan beetle Upis ceramboides

artículo científico publicado en 2011

Synthesis of Bradyrhizose from d-Glucose

artículo científico publicado en 2019

Synthesis of Conformationally-Locked cis- and trans-Bicyclo[4.4.0] Mono-, Di-, and Trioxadecane Modifications of Galacto- and Glucopyranose; Experimental Limiting 3JH,H Coupling Constants for the Estimation of Carbohydrate Side Chain Populations and

artículo científico publicado en 2017

Synthesis of Gentamicin Minor Components: Gentamicin B1 and Gentamicin X2

artículo científico publicado en 2020

Synthesis of N,N,O-Trisubstituted Hydroxylamines by Stepwise Reduction and Substitution of O-Acyl N,N-Disubstituted Hydroxylamines.

artículo científico publicado en 2016

Synthesis of N-acyl-5-aminopenta-2,4-dienals via base-induced ring-opening of N-acylated furfurylamines: scope and limitations

artículo científico publicado en 2010

Synthesis of Trialkylhydroxylamines by Stepwise Reduction of O-Acyl N,N-Disubstituted Hydroxylamines: Substituent Effects on the Reduction of O-(1-Acyloxyalkyl)hydroxylamines and on the Conformational Dynamics of N-Alkoxypiperidines

artículo científico publicado en 2017

Synthesis of a 4,6-disubstituted dibenzofuran beta-sheet initiator by reductive radical arylation of benzene

artículo científico publicado en 2005

Synthesis of a beta-(1-->3)-D-rhamnotetraose by a one-pot, multiple radical fragmentation

artículo científico publicado en 2006

Synthesis of neoglycoconjugates by the desulfurative rearrangement of allylic disulfides

artículo científico publicado en 2008

Synthesis of saccharocin from apramycin and evaluation of its ribosomal selectivity

scientific article published on 13 March 2019

Synthesis of the ?-Rhamnopyranosides and the 6-Deoxy-?-mannoheptopyranosides

artículo científico publicado el 1 de enero de 2011

Synthesis of the Salmonella type E(1) core trisaccharide as a probe for the generality of 1-(benzenesulfinyl)piperidine/triflic anhydride combination for glycosidic bond formation from thioglycosides

artículo científico publicado en 2002

Synthesis of the antigenic tetrasaccharide side chain from the major glycoprotein of Bacillus anthracis exosporium

artículo científico publicado en 2007

Synthesis of the taxol AB-system by olefination of an A-ring C1 ketone and direct B-ring closure

artículo científico publicado en 1997

Synthesis, Cytotoxicity, and Genotoxicity of 10-Aza-9-oxakalkitoxin, an N,N,O-Trisubstituted Hydroxylamine Analog, or Hydroxalog, of a Marine Natural Product

artículo científico publicado en 2020

Synthesis, ribosomal selectivity, and antibacterial activity of netilmicin 4'-derivatives

artículo científico publicado en 2019

Tandem polar/radical crossover sequences for the formation of fused and bridged bicyclic nitrogen heterocycles involving radical ionic chain reactions, and alkene radical cation intermediates, performed under reducing conditions: scope and limitatio

artículo científico publicado en 2003

The 3,4-O-Carbonate Protecting Group as a β-Directing Group in Rhamnopyranosylation in Both Homogeneous and Heterogeneous Glycosylations As Compared to the Chameleon-like 2,3-O-Carbonates

artículo científico publicado el 31 de octubre de 2003

The 4,6-O-[alpha-(2-(2- iodophenyl)ethylthiocarbonyl)benzylidene] protecting group: stereoselective glycosylation, reductive radical fragmentation, and synthesis of beta-D-rhamnopyranosides and other deoxy sugars

artículo científico publicado en 2003

The 4-(tert-butyldiphenylsiloxy)-3-fluorobenzyl group: a new alcohol protecting group, fully orthogonal with the p-methoxybenzyl group and removable under desilylation conditions

artículo científico publicado en 2009

The Experimental Evidence in Support of Glycosylation Mechanisms at the SN1-SN2 Interface

artículo científico publicado en 2018

The intramolecular asymmetric Pauson-Khand cyclization as a novel and general stereoselective route to benzindene prostacyclins: synthesis of UT-15 (treprostinil).

artículo científico publicado en 2004

The invention of new radical chain reactions. Part VIII. Radical chemistry of thiohydroxamic esters; A new method for the generation of carbon radicals from carboxylic acids

article

The isothiocyanato moiety: an ideal protecting group for the stereoselective synthesis of sialic acid glycosides and subsequent diversification

artículo científico publicado en 2014

Thiomaleic anhydride: a convenient building block for the synthesis of alpha-substituted gamma- and delta-lactones through free-radical addition, nucleophilic ring opening, and subsequent thiocarboxylate manipulation

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