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Lista de obras de Luis Oro Giral

1,2,4-Triazolate (tz) complexes of rhodium(I), iridium(I), and palladium(II). Crystal structure of [Rh3(µ3-tz)(µ-Cl)Cl(η4-tfbb)(CO)4]·0.5CH2Cl2(tfbb = tetrafluorobenzobarrelene), a trinuclear complex with extended metal–metal interactions

scholarly article by Luis Oro et al published 1986 in Dalton transactions RSC

1H-Pyrrolo[2,3-b]pyridine (HL) ligands in rhodium(I) and iridium(I) chemistry. Crystal and molecular structures of [Rh2(µ-L)2(nbd)2] and [Rh4(µ-Cl)2(µ-L)2(µ-CO)2(CO)2(nbd)2]

scholarly article by Luis Oro et al published 1985 in Dalton transactions RSC

2,2?-biimidazole, 2,2?-bibenzimidazole and imidazoles as ligands in cationic rhodium(I) complexes

scholarly article by Rafael Us�n et al published April 1981 in Transition Metal Chemistry

2,2′-Bibenzimidazolate anions as bridging ligands in cationic heteronuclear gold(I)–rhodium(I) complexes. Crystal structure of [(Ph3P)2Au2(µ-bbzim)Rh(cod)][ClO4]·CHCl3

scholarly article by Rafael Usón et al published 1983 in Dalton transactions RSC

2-Pyridonate (OPy) rhodium complexes. Crystal structure of [Rh(μ-OPy)(CO)22]; a chain-forming complex with alternate short and long metal-metal distances

2-Pyridonate (Opy) rhodium(I) carbonyl complexes. Crystal structure of the unusual tetranuclear complex [Rh4(µ-Opy)4(µ-CO)2(CO)4]

8-Oxyquinolate iridium(I) complexes and their oxidative-addition reactions

scholarly article by Rafael Usón et al published February 1981 in Journal of Organometallic Chemistry

A C-H activation-CO(2)-carboxylation reaction sequence mediated by an 'Iridium(dppm)' species. Formation of the anionic ligand (Ph(2)P)(2)C-COOH.

artículo científico publicado en 2008

A DFT and crystallographic reinvestigation of the [L2RuC2B7H9] and [L3RuC2B7H9] ‘hypercloso’ and closo systems

A Hexanuclear Iridium Chain

scholarly article by Cristina Tejel et al published 3 February 2003 in Angewandte Chemie International Edition

A Paramagnetic, Mononuclear Organometallic Iridium(II) Complex:[Ir(C6Cl5)2(cod)]

scholarly article by María P. García et al published November 1992 in Angewandte Chemie International Edition

A Trithiol Protio-Ligand and Its Fixation to the Periphery of a Carbosilane Dendrimer as Scaffolds for Polynuclear Rhodium and Iridium Complexes and Metallodendrimers

scholarly article by José A. Camerano et al published October 2005 in Organometallics

A Way to Novel Heterometallic Raft-like Clusters from Neutral Precursors

artículo científico publicado en 1997

A flexible framework obtained from oxidative additions upon the binuclear complex [Ir2(µ-pz)(µ-SBut)(CO)2{P(OMe)3}2]: preparation and X-ray structures of [Ir2(µ-pz)(µ-SBut)(µ-L)(CO)2{P(OMe)3}2] and [Ir2(µ-pz)(µ-SBut)(µ-L)I2(CO)2-{P(OMe)3}2](H

article

A highly efficient Ir-catalyst for the solventless dehydrogenation of formic acid: the key role of an N-heterocyclic olefin

A leap forward in iridium-NHC catalysis: new horizons and mechanistic insights.

artículo científico publicado en 2018

A well-defined NHC-Ir(iii) catalyst for the silylation of aromatic C-H bonds: substrate survey and mechanistic insights

artículo científico publicado en 2017

Activation of a vinyl carbon–hydrogen bond in a tris(pyrazolyl)boratoiridium complex. The X-ray crystal structure of [IrH{HB(pz)3}(σ-C8H13)(η2-C8H14)]

Addition to Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}-Thiodecaborane Fragment System

article

Alcohol activation by [Ir(COD)(tris(pyrazol-1-yl)methane)]+ and [Ir(COD) (tris(pyrazol-1-yl)ethanel+ cations: formation of alkoxycarbonyl derivatives [(tpzm)IrH(CO2R′)(CO)]+ and [(tpze)IrH(CO2R′)]+ (R′ = Me, Et, i-Pr)

Alkene C−H Activations at Dinuclear Complexes Promoted by Oxidation

artículo científico publicado en 2002

Alkene hydrogenation on an 11-vertex rhodathiaborane with full cluster participation

artículo científico publicado en 2008

Amide rhodium and iridium complexes derived from Z-N-phenyl,β-(amino)-4-methylstyryldiphenylphospha-1 λ5-azene

scholarly article by Maria J. Fernandez et al published January 1987 in Polyhedron

Amides of rhodium and iridium derived from 2-aminothiophenol and diaminonaphthalene: X-ray crystal structure of Rh2(μ-1,8-(NH)2C10H6)(CO)4

scholarly article by Maria J. Fernandez et al published March 1989 in Inorganica Chimica Acta

An alternative mechanistic paradigm for the β-Z hydrosilylation of terminal alkynes: the role of acetone as a silane shuttle.

artículo científico publicado en 2013

An iridium-mediated C-H activation/CO2-carboxylation reaction of 1,1-bisdiphenylphosphinomethane

artículo científico publicado en 2010

Arene–Ruthenium Chemistry and Brønsted Acid Catalysis of a Chiral Phosphane-Hydroxyl Ligand

Argentotropism in (Pentamethylcyclopentadienyl)iridium Complexes with Pyrazole Ligands: Multinuclear DNMR Experiments

scholarly article by Daniel Carmona et al published May 1994 in Inorganic Chemistry

Asymmetric 1,3-dipolar cycloaddition reaction of α,β-unsaturated nitriles with nitrones catalyzed by chiral-at-metal rhodium or iridium complexes

scholarly article by Daniel Carmona et al published June 2009 in Tetrahedron: Asymmetry

Asymmetric 1,3-dipolar cycloaddition reactions between enals and nitrones catalysed by half-sandwich rhodium or iridium diphosphane complexes

scholarly article by Ainara Asenjo et al published 2015 in Catalysis Science & Technology

Benzamidinatorhodium complexes. X-Ray structures of [Rh{CPh(NPh)2}(cod)] and [Rh2{µ-CPh(NPh)2}2(tfbb)2]

Benzene-1,2-dithiolate-induced assembly of reactive iridium fragments into tetranuclear octahydride complexes

scholarly article by M.Victoria Jiménez et al published April 2004 in Inorganica Chimica Acta

Benzotriazole and benzotriazolate complexes of rhodium(I)

scholarly article by Luis Oro et al published January 1985 in Journal of Organometallic Chemistry

Bi-edge condensation of imido–rhodium clusters leading to novel planar hexametallic structures

scholarly article by Cristina Tejel et al published 1999 in Chemical Communications

Bi-imidazole (H2bim) and bibenzimidazole η3-allylic complexes of palladium(II). Mono- and tetra-nuclear palladium(II) and heteronuclear palladium(II)–rhodium(I) complexes. Crystal structure of [Pd4(η3-C3H5)4(µ-bim)2]·CH2Cl2

scholarly article by Rafael Usón et al published 1983 in Dalton transactions RSC

Bimetallic Reactivity of Dirhodium Compounds Leading to Functionalized Methylene-Bridged Compounds†

Bimetallic reactivity: unusual change in the coordination mode of the bridging ligands arising from an oxidative addition process

article

Binuclear dirhodium(I) complexes with phenyl(2-pyridyl)amido ligands. Crystal and molecular structure of [{Rh(μ-N,N′-PhNPy)(nbd)}2]·H2O (nbd = 2,5-norbomadiene)

Binuclear hydroxo-, methoxo-, and pyrazolate-bridged complexes of ruthenium(II). Molecular structure of [{(p-cymene)Ru}2(μ-pz)(μ-OH)2]BF4 (p-cymene = p-MeC6H4CHMe2, pz = pyrazolate)

Binuclear pentamethylcyclopentadienyl dirhodium complexes with pyrazolato and diphenylphosphido bridging ligands

Binuclear rhodium and iridium complexes containing pentamethylcyclopentadienyl and pyrazolate ligands

scholarly article by Daniel Carmona et al published 1987 in Dalton transactions RSC

Bioorganometallic chemistry

Bis-bridged dirhodium or diiridium complexes derived from diamine- or dihydroxy-naphthalenes

Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}–Thiadecaborane Fragment System

C-H activations at iridium(I) square-planar complexes promoted by a fifth ligand

artículo científico publicado en 2005

C-NH2 bond formation mediated by iridium complexes

artículo científico publicado en 2014

CO2Activation and Catalysis Driven by Iridium Complexes

scholarly article by Francisco J. Fernández-Alvarez et al published 10 September 2013 in ChemCatChem

Carbon monoxide activation by poly(1-pyrazolyl)boratoiridium complexes

Carbon monoxide activation in [Ir(HBPz3)(CO)2]: Formation of carbamoyl complexes by direct reaction with amines

Catalytic activity of some fluorothiolate derivatives of rhodium(I). Crystal structure of [Rh(μ-SC6H4F)(CO)2]2

scholarly article by Carmen Claver et al published November 1990 in Journal of Organometallic Chemistry

Cationic Rhodium Complexes with Hemilabile Phosphine Ligands as Polymerization Catalyst for High Molecular Weight Stereoregular Poly(phenylacetylene)

Cationic complexes of rhodium(I) with phenanthroline type ligands

scholarly article by Carmen Claver et al published October 1982 in Transition Metal Chemistry

Cationic iridium(I) complexes with 1,5-cyclooctadiene and nitrogen ligands

scholarly article by Rafael Uson et al published January 1983 in Inorganica Chimica Acta

Chemical evidence of polynuclear intermediates in a ligand redistribution equilibrium between dinuclear rhodium complexes. X-ray structure of [Rh2(μ-bzta)2(CO)3(PPh3)] (bzta = benzothiazole-2-thiolate)

scholarly article by Miguel A. Ciriano et al published August 1993 in Journal of Organometallic Chemistry

Chiral Brønsted Acid Catalysts. Activation of Methyl 3,3,3-Trifluoropyruvate by Hydroxymethylpyridine-Containing Half-Sandwich Complexes

Chiral Half-Sandwich Ruthenium(II) Complexes as Catalysts in 1,3-Dipolar Cycloaddition Reactions of Nitrones with Methacrolein

Chiral Octahedral Phosphano–Oxazoline Iridium(III) Complexes as Catalysts in Asymmetric Cycloaddition Reactions

scholarly article by Daniel Carmona et al published 20 February 2013 in Organometallics

Chiral Phosphinooxazoline−Ruthenium(II) and −Osmium(II) Complexes as Catalysts in Diels−Alder Reactions

scholarly article by Daniel Carmona et al published March 2006 in Organometallics

Chiral iridium(III) α-amino acidato complexes (RIr,SN,SC)- and (SIr,SN,SC)-[(η5-C5Me5)Ir(L-prolinate)(CCCMe3)]

scholarly article by Daniel Carmona et al published July 1993 in Tetrahedron: Asymmetry

Chiral pyridylamino-ruthenium(II) complexes: synthesis, structure and catalytic properties in Diels-Alder reactions

artículo científico publicado en 2008

Chiral-at-metal ruthenium(II) complexes as catalysts in the asymmetric cyclopropanation reaction

Complete Characterization of a Chiral Lewis Acid−Product Complex for the Enantioselective Diels−Alder Reaction between Methacrolein and Cyclopentadiene: Mechanistic Considerations

Complexes of rhodium(I) with 1,8-naphthyridine and related ligands. Crystal structure of [Rh2(µ-napy)2(nbd)2][ClO4]2·H2O

scholarly article by Antonio Tiripicchio et al published 1984 in Dalton transactions RSC

Controlling the molecular architecture of low nuclearity rhodium and iridium complexes using bridging NCX (X=N, O, S) ligands

scholarly article by Luis Oro et al published October 1999 in Coordination Chemistry Reviews

Coordination features of a hybrid scorpionate/phosphane ligand exemplified with Iridium

artículo científico publicado en 2008

Corrigendum to “Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline” [J. Organomet. Chem. 691 (2006) 5560–5566]

scholarly article published in Journal of Organometallic Chemistry

Crescent-shaped rhodium(I) complexes with bis(o-carboxymethylphenyl)triazenide

artículo científico publicado en 2004

C−C Formation and C−O Cleavage Reactions on Hemilabile Arene−Phosphine Ligands in Route to η5-Cyclohexadienyl Iridium Compounds§

scholarly article by M. Victoria Jiménez et al published August 2008 in Organometallics

C−H Activation and C−C Coupling Reactions in 2-Vinylpyridine Cationic Complexes of Iridium

scholarly article by Janeth Navarro et al published April 2004 in Organometallics

C−H Bond Activations by New Labile η6-Arene Complexes of Iridium

scholarly article by Francisco Torres et al published November 1999 in Journal of the American Chemical Society

CH activation of methyl vinyl ketone in Ir(acac){η2-CH2CHC(O)CH3}(PCy3)

artículo científico publicado en 1998

Degradation and Oxidation of 1,1,1-Trichloroethane-Mediated Rhodium Compounds. A New Entry in the Synthesis of Bridging Vinylidene and .eta.1-Chlorovinyl Complexes

Dehalogenation of Polychloroarenes with HSiEt3Catalyzed by an Homogeneous Rhodium−Triphenylphosphine System

artículo científico publicado en 1999

Deprotonation of Cp2Ti(SH)2with Mononuclear Rhodium and Iridium Compounds: A New Route to Trinuclear Early−Late Heterobimetallic Complexes

scholarly article by Miguel A. Casado et al published December 1999 in Organometallics

Determination of the free activation energy for the breaking of the 31P107(109)Ag bond in [(η6-p-cymene)Ru(μ-pz)3Ag(PPh3)]

Di(μ-pyrazolate)bis(pentamethylcyclopentadienyl)rhodium complexes. Molecular structure of [{Rh(C5Me5)(pz)} 2(μ-pz = pyrazolate)

Di- and tetra-nuclear mixed-valence complexes of rhodium(III,I) and rhodium(III)–iridium(I) with the 2,2′-bi-imidazolate(2–) anion (bim) as bridging ligand. Crystal structure of [{(η-C5Me5)[P(OEt)3]Rh(bim)Rh(nbd)}2][ClO4]2

scholarly article by Luis Oro et al published 1986 in Dalton transactions RSC

Diastereoselective Synthesis of Chiral Octahedral Iridium(III) Phosphano–Oxazoline Complexes

scholarly article by Daniel Carmona et al published 20 February 2013 in Organometallics

Diastereoselective formation of chiral iridium hydrides containing the chiral P,N-chelate ligand (4S)-2-(2-(diphenylphosphino)phenyl)-4-isopropyl-1,3-oxazoline

artículo científico publicado en 2002

Dimer species in aqueous solutions of m–phenylenediamine-N,N,N′,N′-tetra-acetic acid (m-H4pdta) with copper(II) and of pyridine-2,6-diamine-N,N,N′,N′-tetra-acetic acid (2,6-H4pydta) with nickel(II). X-Ray crystal structures of Na4[Cu2(m-pdt

scholarly article by Alfredo Mederos et al published 1990 in Dalton transactions RSC

Dimetallic Dioxygen Activation Leading to a Doubly Oxygen-Bridged Dirhodium Complex

Dimethylphosphinate bridged binuclear Rh(i) catalysts for the alkoxycarbonylation of aromatic C-H bonds.

artículo científico publicado en 2016

Dinuclear pentafluorophenyl compounds of rhodium(III) with anionic bridging ligands. Molecular structures of [P(CH2Ph)Ph3]2[{Rh(C6F5)3}2(µ-SCN)2] and [P(CH2Ph)Ph3]2[{Rh(C6F5)3}2(µ-CO3)]

scholarly article by María P. García et al published 1995 in Dalton transactions RSC

Dinuclear pyridine-4-thiolate-bridged rhodium and iridium complexes as ditopic building blocks in molecular architecture

artículo científico publicado en 2014

Dinuclear rhodium and iridium complexes with mixed amido/methoxo and amido/hydroxo bridges

artículo científico publicado en 2002

Dinuclear rhodium(I) compounds containing diolefins and the 1,6-bis(2′-benzimidazolyl)-2,5-dithiahexane ligand

scholarly article by Luis Oro et al published January 1983 in Inorganica Chimica Acta

Diolefin rhodium(I) complexes with tropolone and related ligands

scholarly article by Mauricio Valderrama et al published August 1981 in Transition Metal Chemistry

Discrete Mixed-Valence Metal Chains: Iridium Pyridonate Blues The generous financial support from DGES and MCyT-PNI (Projects PB98-641 and BQU2000-1170) is gratefully acknowledged

artículo científico publicado en 2001

Discrete iridium pyridonate chains with variable metal valence: nature and energetics of the Ir-Ir bonding from DFT calculations

artículo científico publicado en 2005

Dynamic Behavior in Solution of theTrans-Hydridodihydrogen Complex [OsHCl(n2-H2)(CO)(PiPr3)2]: Ab Initio and NMR Studies

Dynamic Behavior, Redistribution Reactions, and Intermetallic Distances of Dinuclear Bis(μ-pyrazolato)rhodium(I) Complexes

scholarly article by Cristina Tejel et al published January 1996 in Organometallics

Early (Ti, Zr)-late (Rh, Ir) heteronuclear complexes with bridging sulphido ligands

Early−Late Heterotetranuclear Complexes (TiRh3) with Bridging Sulfido Ligands: Ligand Replacement Reactions and Catalytic Activity in Hydroformylation of Olefins

Effect of structural differences of carbon nanotubes and graphene based iridium-NHC materials on the hydrogen transfer catalytic activity

scholarly article by Matías Blanco et al published January 2016 in Carbon

Effective Fixation of CO2by Iridium-Catalyzed Hydrosilylation

scholarly article by Ralte Lalrempuia et al published 14 September 2012 in Angewandte Chemie

Effects of the Heterocycle and Its Substituents on Structure and Fluxionality in Rhodium(I) and Iridium(I) Complexes with the Hindered Thiolates 6-tert-Butylpyridine-2-thiolate and 1-Alkyl-4-tert-butylimidazole-2-thiolate (alkyl = methyl andtert-buty

scholarly article by Valentín Miranda-Soto et al published August 2006 in Organometallics

Efficient Rhodium-Catalyzed Multicomponent Reaction for the Synthesis of Novel Propargylamines

artículo científico publicado en 2015

Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant

artículo científico publicado en 2016

En route to phosphonato iridium(i) complexes: the decisive effect of an intramolecular hydrogen bond

scholarly article by Vincenzo Passarelli et al published 2016 in Dalton Transactions

Enantioselective 1,3-dipolar cycloaddition of nitrones to methacrolein catalyzed by (eta5-C5Me5)M{(R)-prophos} containing complexes (M = Rh, Ir; (R)-prophos = 1,2-bis(diphenylphosphino)propane): on the origin of the enantioselectivity

artículo científico publicado en 2005

Enantioselective Catalytic Diels–Alder Reactions with Enones As Dienophiles

Enantioselective Diels–Alder Reactions Catalyzed by Well-Defined Arene–Ruthenium Complexes. Relationship between Catalyst Structure and Enantioselectivity

Enantioselective Friedel–Crafts alkylations catalysed by well-defined iridium and rhodium half-sandwich complexes

scholarly article by Daniel Carmona et al published April 2011 in Tetrahedron: Asymmetry

Enantioselective catalysts based on the chiral fragment (η5-C5Me5)Ir(Prophos) for Diels–Alder reactions

Encapsulation of Thallium(I) by Tetranuclear Rhodium or Iridium Complexes: Synthesis and Molecular Structure of Heterobimetallic Complexes Stabilized by s2−d8Bonding Interactions

scholarly article by Miguel A. Casado et al published May 1999 in Inorganic Chemistry

Energetics of the oxidative addition of I2 to [Ir(Μ-L)(CO)2]2 (L=S t Bu, 3,5-Me2pz,7-aza) complexes. X-ray structures of Ir(Μ-S t Bu)(I)(CO)2]2 and [Ir(Μ-3,5-Me2pz)(I)(CO)2]2

article

Enhanced Hydrogen-Transfer Catalytic Activity of Iridium N-Heterocyclic Carbenes by Covalent Attachment on Carbon Nanotubes

scholarly article by Matías Blanco et al published 15 May 2013 in ACS Catalysis

Enhancing the hydrogen transfer catalytic activity of hybrid carbon nanotube-based NHC–iridium catalysts by increasing the oxidation degree of the nanosupport

scholarly article by Matías Blanco et al published 2016 in Catalysis Science & Technology

Evidence for enhancement of catalysis by a second metal in heterobinuclear complexes: X-ray structure of [H(CO)(PPh3)2Ru(bim)Rh(cod)](bim = 2,2′-bi-imidazolato, cod = cyclo-octa-1,5-diene)

Five coordinate complexes of the type Rh(SnCl3)(NBD)L2

article published in 1983

Flexible Building Blocks for Transition Metal Early−Late Chemistry. Synthesis of Heterobimetallic Tetranuclear Metallomacrocycles

Formation of Diiridium(II) Complexes by Photoassisted Oxidative-Addition Reactions: Structure of a Stable Binuclear Iodo(iodomethyl)iridium(II) Complex

article

From Platinum Blues to Rhodium and Iridium Blues

scholarly article by Cristina Tejel et al published 1 April 1999 in Chemistry—A European Journal

Grafting of Copper(I)-NHC Species on MCM-41: Homogeneous versus Heterogeneous Catalysis

Graphene–NHC–iridium hybrid catalysts built through –OH covalent linkage

scholarly article by Matías Blanco et al published March 2015 in Carbon

Half-Sandwich Complexes of Osmium(II) with l-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity

scholarly article by Daniel Carmona et al published 22 March 2012 in Organometallics

Half-sandwich organometallic complexes with stereogenic metal centres: Synthesis and characterization of diastereomeric [(ηn-ring)M(Aa)X] (Aa = α-amino carboxylate) compounds

Half-sandwich rhodium (and iridium) complexes as enantioselective catalysts for the 1,3-dipolar cycloaddition of 3,4-dihydroisoquinoline N-oxide to methacrylonitrile

artículo científico publicado en 2007

Heterobinuclear IrRh, RuRh and Rulr complexes with pyrazolate bridging ligands: reactivity towards chelating diphosphines; crystal structure of [(C5Me5)Ir(µ-pz)2(µ-CO)-Ir(CO)(dppen)]BPh4·0.5MeOH [pz = pyrazolate, dppen =cis-1,2-bis(diphenylphosphi

Heterodinuclear Iridium Cyclooctadiene Complexes with the [(η5-C5H5)Fe(η6-(1,1-di(2-propenyl)-3-butenyl)benzene)]+Ligand

scholarly article by Silvia Marcén et al published January 2002 in Organometallics

Heterogeneous catalysts based on supported Rh–NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation

Heteronuclear and heterovalent diphenylphosphido-bridged complexes of rhodium, iridium and ruthenium. Crystal structure of [(C5Me5)ClRh(μ-Cl)(μ-PPh2)Rh(COD)] · Et2O (COD = 1,5-cyclooctadiene)

scholarly article by Montserrat Esteban et al published January 1991 in Journal of Organometallic Chemistry

Heteronuclear rhodium, palladium, platinum, and gold organoimido complexes from dinuclear organoamido rhodium precursors

artículo científico publicado en 2004

Heterotrinuclear angular aggregates of rhodium, iridium, palladium and Group 11 metals. X-Ray structure of the complex [(cod)2Rh2(µ3-C7H4NS2)2Ag(O2ClO2)](cod = cycloocta-1,5-diene)

scholarly article by Miguel A. Ciriano et al published 1991 in Dalton transactions RSC

Homo- and hetero-binuclear complexes containing the anion [Rh(C5Me5){PO(OMe)2}2(pyrazolate)]–as ligand. Crystal structure of [(C5Me5)Rh{µ-PO(OMe)2}2(µ-C3H3N2)-Ru(C6H6)]ClO4·CH2Cl2

Homogeneous catalytic reduction of CO2 with hydrosilanes

Homogeneous hydrogenation of tetrasubstituted alkene moieties in prochiral didehydro amino acid derivatives catalysed by iridium complexes

scholarly article by Javier A. Cabeza et al published 1988 in Journal of the Chemical Society. Perkin transactions 1

Hydride Exchange Processes in the Coordination Sphere of Transition Metal Complexes: The OsH3(BH4)(PR3)2System

artículo científico publicado en 1996

Hydridorhodathiaboranes: Synthesis, Characterization, and Reactivity

Hydroformylation catalysis by a [Rh(NBD)Cl]2/PPh3 system

Hydroformylation of 1-heptene by a [Rh(NBD)Cl]2/PPh3 system. A kinetic approach

Hydroformylation of 1-hexene under mild conditions catalyzed by various μ-pyrazolato dirhodium(I) complexes

Hydroformylation of Hex-1-ene by a Dinuclear gem-Dithiolato-bridged Rhodium Catalyst Under CO/H2O Conditions

Hydroformylation of Synthetic Naphtha Catalyzed by a Dinuclear gem-Dithiolato-Bridged Rhodium(I) Complex~!2009-09-28~!2009-12-18~!2010-04-23~!

Hydroformylation of oct-1-ene catalyzed by dinuclear gem-dithiolato-bridged rhodium(I) complexes and phosphorus donor ligands

Hydroformylation of styrene using thiolato–pyrazolate bridge rhodium catalysts modified with phosphorous ligands

Hydrogenation catalysts based on pentamethylcyclopentadienyl rhodium complexes with pyrazole-type ligands

scholarly article by Luis Oro et al published March 1987 in Journal of molecular catalysis

Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis-N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups

scholarly article by Mélanie Aliaga-Lavrijsen et al published 23 December 2014 in Organometallics

Hydrosilylation of Terminal Alkynes Catalyzed by a ONO-Pincer Iridium(III) Hydride Compound: Mechanistic Insights into the Hydrosilylation and Dehydrogenative Silylation Catalysis

scholarly article by Jesús J Pérez-Torrente et al published 6 July 2016 in Organometallics

Hydroxo–Rhodium–N-Heterocyclic Carbene Complexes as Efficient Catalyst Precursors for Alkyne Hydrothiolation

Impact of Protic Ligands in the Ir-Catalyzed Dehydrogenation of Formic Acid in Water

Indenyl complexes of ruthenium(II). Crystal structure of [Ru(CO)(PPh3)2(η5-C9H7)]ClO4·CH2Cl2

scholarly article by Luis Oro et al published July 1985 in Journal of Organometallic Chemistry

Indolylgold(I) derivatives and indole as π-arene ligands in cationic rhodium(I) complexes

Intermolecular hydroamination versus stereoregular polymerization of phenylacetylene by rhodium catalysts based on N–O bidentate ligands

Intramolecular C–H Oxidative Addition to Iridium(I) in Complexes Containing a N,N′-Diphosphanosilanediamine Ligand

article

Intramolecular C–H oxidative addition to iridium(i) triggered by trimethyl phosphite in N,N′-diphosphanesilanediamine complexes

article

IrCl2H(PiPr3)2 as catalyst precursor for the reduction of unsaturated substrates

Iridium Complexes withN-Allyl-Substituted Benzimidazol-2-ylidene Ligands and Their Application in Catalytic Transfer Hydrogenation

scholarly article by F. Ekkehardt Hahn et al published April 2005 in Organometallics

Iridium and rhodium complexes with tetrafluorobenzobarrelene diolefins

scholarly article by Miguel A. Esteruelas & Luis Oro published October 1999 in Coordination Chemistry Reviews

Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts

scholarly article by M. Victoria Jiménez et al published 24 October 2011 in Organometallics

Iridium(I) complexes with tetrafluorobenzobarrelene

scholarly article by Rafael Usón et al published February 1984 in Journal of Organometallic Chemistry

Iridium-Catalyzed 1,3-Dipolar Cycloadditions

scholarly article by Daniel Carmona & Luis Oro published 13 November 2010 in Topics in Organometallic Chemistry

Iridium-Catalyzed Hydrogen Production from Hydrosilanes and Water

scholarly article by Karin Garcés et al published 11 April 2014 in ChemCatChem

Iridium-catalysed homogeneous hydrogenation of prochiral enamides containing tetrasubstituted alkene moieties

scholarly article by Luis Oro et al published 1983 in Journal of the Chemical Society. Chemical communications

Iridium-catalyzed hydrosilylation of hex-1-yne: the unusual formation of 1-triethylsilylhex-1-yne

scholarly article by Maria J. Fernandez et al published April 1988 in Journal of molecular catalysis

Iridium–NSiN catalyzed formation of silylphosphinecarboxylates from the reaction of CO2 with P(SiMe3)R2 (R = Ph, Cy)

scholarly article by Alejandro Julián et al published 2017 in Catalysis Science & Technology

Kinetic and spectroscopic study of the hydrogen-transfer reaction from 2-propanol to cyclohexanone catalyzed by [IrH2(pz)(Hpz)(PPh3)2] (Hpzpyrazole)

Labile Rhodium(I)–N-Heterocyclic Carbene Complexes

Mechanistic Insights into Transfer Hydrogenation Catalysis by [Ir(cod)(NHC)2]+ Complexes with Functionalized N-Heterocyclic Carbene Ligands

Mechanistic Insights on the Reduction of CO2 to Silylformates Catalyzed by Ir-NSiN Species.

artículo científico publicado en 2017

Mechanistic Investigation on the Polymerization of Phenylacetylene by 2-Diphenylphosphinopyridine Rhodium(I) Catalysts: Understanding the Role of the Cocatalyst and Alkynyl Intermediates

Mechanistic Studies on the Catalytic Oxidative Amination of Alkenes by Rhodium(I) Complexes with Hemilabile Phosphines

Mechanistic considerations on catalytic H/D exchange mediated by organometallic transition metal complexes

Mechanistic investigations of imine hydrogenation catalyzed by cationic iridium complexes

artículo científico publicado en 2006

Mechanistic investigations of imine hydrogenation catalyzed by dinuclear iridium complexes

artículo científico publicado en 2006

Mechanistic studies on the N-alkylation of amines with alcohols catalysed by iridium(i) complexes with functionalised N-heterocyclic carbene ligands

scholarly article by M. Victoria Jiménez et al published 2018 in Catalysis Science & Technology

Metal Basicity of Dirhodium and Diiridium Complexes Induced by Isocyanide Ligands. Model for the Oxidative-Addition Reaction of Methyl Iodide with Dinuclear Complexes

article

Metal–Nitroalkene and aci-Nitro Intermediates in Catalytic Enantioselective Friedel–Crafts Reactions of Indoles with trans-β-Nitrostyrenes

Methylene- and diamidonaphthalene-bridged diiridium(III) complexes

Mixed-bridged bimetallic d8 complexes. Crystal and molecular structure of (η3-C3H5)Pd(μ-pz)(μ-N3)Rh(CO)2, heterobinuclear complex with extended Rh⋯Rh interactions

Mixed-valence pyrazolate rhodium complexes. Molecular structure of [(C5Me5)ClRhCl(pz)Rh(tfb)]·CH2Cl2(Hpz = pyrazole; tbf = tetrafluorobenzobarrelene)

Modification of [8,8,8-(H)(PPh3)2-9-(Py)-nido-8,7-RhSB9H9], Py = NC5H5, with Monodentate Phosphines: Reactivity and Mechanistic Insights

Mono- and dinuclear rhodium(I) complexes containing the ligand 3,5-bis(pyridin-2-yl)-1,2,4-triazole

scholarly article by Maria P. Garcia et al published January 1992 in Inorganica Chimica Acta

Mononuclear and dinuclear bromo bridged iridium(I) complexes with N-allyl substituted imidazolin-2-ylidene ligands

scholarly article by F. Ekkehardt Hahn et al published December 2006 in Inorganica Chimica Acta

Mononuclear rhodium and iridium compounds with pyridyl-pyrazole ligands

scholarly article by Ana P. Martínez et al published March 2005 in Inorganica Chimica Acta

Mononuclear rhodium(I) complexes of 4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole. Crystal structure of [Rh(CO)2(NH2bpt)]ClO4

scholarly article by Maria P. Garcia et al published December 1986 in Inorganica Chimica Acta

N-Substituted imidazole derivatives of rhodium(I) and iridium(I) with and without metal-metal interaction. Crystal structure of cis-(CO)2RhCl(N-methylimidazole)

scholarly article by Flavio Bonati et al published June 1989 in Journal of Organometallic Chemistry

N-substituted imidazole derivatives of rhodium(I) and iridium(I). Crystal structure of the head-to-head dinuclear compound [Ir2(μ-N-benzylimidazolato-N3,C2)2(CO)4]

scholarly article by Flavio Bonati et al published February 1994 in Journal of Organometallic Chemistry

NH3-promoted ligand lability in eleven-vertex rhodathiaboranes

artículo científico publicado en 2014

New Dihydride− and Alkene−η6-Arene Complexes of Iridium

artículo científico publicado en 2001

New Perspective on the Formation and Reactivity of Metal−Metal-Bonded Dinuclear Rhodium and Iridium Complexes

scholarly article by Cristina Tejel et al published October 1997 in Organometallics

New biimidazole and bibenzimidazole derivatives: mono and binuclear palladium(II) or platinum(II) complexes and heterobinuclear palladium(II)-rhodium(I) or platinum(II)-rhodium(I) complexes

scholarly article by Rafael Usón et al published January 1983 in Polyhedron

New methoxo-, hydroxo-, and pyrazolate-bridged complexes of rhodium(III). Crystal structures of [{Rh(C5Me5)}2(mpz)(OMe)2][ClO4](mpz = 3-methylpyrazolate), [{Rh(C5Me5)}2(Hdmpz)2(OH)2][BF4]2(Hdmpz = 3,5-dimethylpyrazole), and [{Rh(C5Me5)}2(pz)2(OH)]-[C

New thiocarbonyl iridium and rhodium complexes with azolate type ligands

scholarly article by Josefa Reyes et al published 1985 in Transition Metal Chemistry

Notes. Nuclear magnetic resonance evidence for three different isomers of [Ru3(µ-H)(µ-bzim)(CO)9(PPh3)](bzim = benzimidazolate). Crystal structure of [Ru3(µ-H)(µ-bzim)(CO)10]·Me2CO

article

Novel Neutral and Anionic Rhodium Complexes Containing Imido Ligands

scholarly article by Cristina Tejel et al published 1 April 1996 in Angewandte Chemie International Edition

Novelgem-Dithiolato-Bridged Rhodium Hydroformylation Catalysts: Bridging the Gap in Dinuclear Rhodium Thiolate Chemistry

scholarly article by Marc A. F. Hernandez-Gruel et al published December 2007 in European Journal of Inorganic Chemistry

ONO Dianionic Pincer-Type Ligand Precursors for the Synthesis of σ,π-Cyclooctenyl Iridium(III) Complexes: Formation Mechanism and Coordination Chemistry

scholarly article by Duc Hanh Nguyen et al published 8 November 2013 in Organometallics

Optically active pseudoctahedral rhodium(III), iridium(III), and ruthenium(II) complexes with α-amino acidato ligands. Crystal structures of RIrSCSN- and SIrSCSN-[(C5Me5)Ir(pro)Cl] · H2O (Hpro = l-proline)

scholarly article by Daniel Carmona et al published October 1990 in Journal of Organometallic Chemistry

Orthometallation of N-substituents at the NHC ligand of [Rh(Cl)(COD)(NHC)] complexes: its role in the catalytic hydrosilylation of ketones

Outer-Sphere Ionic Hydrosilylation Catalysis

Oxidation and β-Alkylation of Alcohols Catalysed by Iridium(I) Complexes with Functionalised N-Heterocyclic Carbene Ligands.

artículo científico publicado en 2015

Oxidation of Substrates by an Iridium Dioxygen Complex: Intramolecular Oxidation of Carbon Monoxide and Activation of a Carbonyl Group by Attack of a Heterocyclic Nitrogen

scholarly article by Miguel A. Ciriano et al published October 1995 in Organometallics

Oxidative addition of I2, MeI, and CH2I2to the naphthalene-1,8-diamide bridged complex [Ir2{µ-1,8-(NH)2C10H6}(CO)2(PPh3)2]. X-Ray crystal structure of [Ir2I2(µ-CH2){µ-1,8-(NH)2C10H6}(CO)2(PPh3)2]·CH2Cl2

article

Oxidative-Addition of Organic Monochloro Derivatives to Dinuclear Iridium Complexes: The Detection of Tautomeric Equilibria and Their Implications on the Reactivity

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Oxidative-Addition of Organic Monochloro Derivatives to Dinuclear Rhodium Complexes: Mechanistic Considerations

article

Oxidative-addition reactions of Mel or CH2I2to [M2(µ-pz)(µ-SBut)(CO)2{P(OMe)3}2](M = Rh or Ir) complexes. X-Ray structure of [Ir2(µ-pz)(µ-SBut)(µ-CH2)I2(CO)2{P(OMe)3}2](pz = pyrazolate)

article

Oxo Sulfido Heteronuclear Titanium−Rhodium Clusters with an Incomplete Doubly-Fused Cubane Structure

scholarly article by Miguel A. Casado et al published August 1998 in Organometallics

P-H activation of secondary phosphanes on a parent amido diiridium complex

artículo científico publicado en 2014

Paramagnetic mononuclear rhodium(II) organometallic complexes. X-ray structure of [Rh(C6Cl5)2[P(OPh)3]2]

scholarly article by Maria P. Garcia et al published August 1993 in Organometallics

Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands

Pentafluorophenyl compounds of rhodium(III) with bidentate phosphorus or nitrogen ligands

scholarly article by María P. Garćia et al published October 1992 in Journal of Organometallic Chemistry

Pentamethylcyclopentadienyl-iridium(iii) complexes with pyridylamino ligands: synthesis and applications as asymmetric catalysts for Diels–Alder reactions

artículo científico publicado en 2007

Pentamethylcyclopentadienylrhodium complexes with the pyridazine ligand. Molecular structure of [{Rh(C5Me5)}2(µ-Cl)2(µ-pydz)][ClO4]2·H2O (pydz = pyridazine)

Peripheral SH-functionalisation of carbosilane dendrimers including the synthesis of the model compound dimethylbis(propanethiol)silane and their interaction with rhodium complexes

artículo científico publicado en 2005

Poly(1-pyrazolyl)boratoiridium and tris(1-pyrazolylmethyl)aminoiridium and -rhodium complexes

Polynuclear rhodium(I) complexes with 3,3?,5,5?-tetramethyl-4,4?-bipyrazole and 4,4?-methylen-bis(3,5-dimethylpyrazole)

scholarly article by Rafael Us�n et al published August 1982 in Transition Metal Chemistry

Postsynthetic modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis bases: cluster modular tuning

artículo científico publicado en 2016

Preferential α-Hydrosilylation of Terminal Alkynes by Bis-N-Heterocyclic Carbene Rhodium(III) Catalysts

Preparation and X-ray structure of a trinuclear rhodium complex with the polydentate 1,8-naphthyridine-2-one (onapy) ligand: [Rh3(μ3-onapy)2(CO)2(cod)2](ClO4)·1.5C2H4Cl2

scholarly article by Antonio Tiripicchio et al published January 1986 in Inorganica Chimica Acta

Preparation and properties of some cationic norbornadiene rhodium(I) complexes with triarylphosphines

scholarly article by Luis Oro et al published February 1981 in Transition Metal Chemistry

Preparation and reactivity of dinuclear complexes having the M2(μ-Pz)(μ-SBut)(μ-dppm) core (M=Rh, Ir; Pz=pyrazolate)

Preparation and structural studies of diphenylthiophosphinito rhodium(III) complexes. X-ray structure analysis of [{(C5Me5)Rh}2(µ-Cl)2(µ-Ph2PS)][BPh4]

Preparation of IrH(diene)L2 compounds via methoxyiridium complexes: Catalysts for hydrogen transfer reactions

article published in 1986

Proton-assisted hydrogen activation on polyhedral cations

artículo científico publicado en 2013

Protonation reactions of dinuclear pyrazolato iridium(I) complexes

artículo científico publicado en 2003

Pyrazolate A-frame rhodium complexes. Crystal structures of [Rh2(µ-dmpz)(CO)2(µ-dppm)2][ClO4] and [Rh2(µ-dmpz)I2(CO)2(µ-dppm)2][ClO4]

scholarly article by Luis Oro et al published 1985 in Dalton transactions RSC

Pyrazolate bridged ruthenium(I) complexes. A convenient synthesis of ruthenium(I) compounds. The X-ray structure of bis-μ-(3,5-dimethylpyrazolate)bis(tricarbonyl-ruthenium(I)) (RuRu)

scholarly article by Javier A. Cabeza et al published March 1987 in Journal of Organometallic Chemistry

Pyrazolate rhodium complexes as hydroformylation catalyst precursors

scholarly article by Rafael Uson et al published March 1982 in Journal of molecular catalysis

Pyrazolato-iridium(III) complexes

scholarly article by María P. Garcá et al published March 1994 in Journal of Organometallic Chemistry

Pyridine-enhanced head-to-tail dimerization of terminal alkynes by a rhodium-N-heterocyclic-carbene catalyst

artículo científico publicado en 2013

Pyridinethiolate Titanocene Metalloligands and Their Self-Assembly Reactions To Yield Early–Late Metallamacrocycles

Rational design of efficient rhodium catalysts for the anti-Markovnikov oxidative amination of styrene

artículo científico publicado en 2010

Reaction of [Rh2{µ-1,8-(NH)2C10H6}(CO)2(PPh3)2] with [M(PPh3)]+(M = Au, Ag, or Cu): formation of unusual 44-electron Rh2M clusters. Crystal structure of [Rh2{µ-Au(PPh3)}{µ-1,8-(NH)2C10H6}(CO)2(PPh3)2]ClO4·2CH2Cl2

Reactions of 11-vertex rhodathiaboranes with HCl: synthesis and reactivity of new Cl-ligated clusters

artículo científico publicado en 2012

Reactions of Diamidonaphthalene-Bridged Diiridium Tetrahydrides with Alkynes: Hydrogenation, Vinylidene Formation, and Catalytic C−C Coupling

Reactions of IrXL2(PR3)(X = Cl, OTf; L2= TFB, 2CO) with HSnR3(R = Ph, nBu)

artículo científico publicado en 1997

Reactions of Phosphine Ligands with Iridium Complexes Leading to C(sp3)−H Bond Activation

scholarly article by Cristina Tejel et al published March 2005 in Organometallics

Reactions of [IrH2(Me2CO)(Hpz)(PPh3)2]BF4 with alkynes: synthesis of new hydride-vinyl iridium(III) complexes

scholarly article by Miguel A. Esteruelas et al published February 1994 in Journal of Organometallic Chemistry

Reactions of chloroform and gem-dichlorocarbons with binuclear rhodium complexes leading to functionalized methylene-bridged compounds

scholarly article by Miguel A. Ciriano et al published 1992 in Dalton transactions RSC

Reactivity of Ir-NSiN Complexes: Ir-Catalyzed Dehydrogenative Silylation of Carboxylic Acids

article published in 2018

Reactivity of [TiM 2 ] (M = Rh, Ir) and [TiIr 3 ] early-late heterobimetallic sulfido-bridged clusters

Reactivity of binuclear heterobridged iridium complexes with SnCl2

scholarly article by M. Teresa Pinillos et al published 1992 in Dalton transactions RSC

Reactivity of binuclear pyrazolate-bridged rhodium complexes with isocyanides. Molecular structure of [Rh2(µ-pz)I2(CNBut)2–(µ-Ph2PCH2PPh2)2]BF4(pz = pyrazolate)

scholarly article by Daniel Carmona et al published 1989 in Dalton transactions RSC

Reactivity of rhodium(III) complexes containing chelating pentachlorophenyl ligands. Molecular structures of fac-[Rh(C6Cl5)3(py)] and mer-[Rh(C6Cl5)3(tBuNC)3]

Reactivity of the Chiral Metallic Brønsted Acid [(η6-p-MeC6H4iPr)Ru(κ3P,O,O′-POH)][SbF6]2 (POH = (SC1,RC2)-Ph2PC(Ph)HC(OH)HCH2OMe) toward Aldimines

Reactivity of the parent amido complexes of iridium with olefins: C-NH2 bond formation versus C-H activation

artículo científico publicado en 2017

Recent advances in homogeneous enantioselective Diels–Alder reactions catalyzed by chiral transition-metal complexes

Reductive Elimination of [Ph2CCCHPR3]BF4from the Rhodium(III)−Allenyl Derivatives [Rh(acac){CHCCPh2}(PR3)2]BF4(PR3= PCy3, PiPr3)

artículo científico publicado en 1997

Reversible CO2Fixation by Iridium(I) Complexes Containing Me2PhP as Ligand

scholarly article by Jens Langer et al published 12 April 2010 in Organometallics

Reversible C−H Bond Activation of a Bifunctional Phosphine Bridging Ligand across Two Unbonded Metal Centers

Reversible Formation of Raftlike Organoimidotetrarhodium Clusters by the Migration of RhLn+ Fragments

Reversible Opening of the Triangular Structure of a Sulfido-Bridged ZrRh2Early−Late Heterobimetallic Complex Induced by Bis-(diphenylphosphino)methane

Reversible Small-Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters

Rhodium and iridium complexes containing the anion of 1-phenyl-3-methyl-4-benzoyl- pyrazolone-5, a sophisticated analogue of β-diketones

scholarly article by Flavio Bonati et al published January 1985 in Polyhedron

Rhodium carbonyl complexes with tropolones, salicylaldehyde and salicylaldimine schiff bases

scholarly article by Mauricio Valderrama & Luis Oro published September 1981 in Journal of Organometallic Chemistry

Rhodium complexes of 4,5-dicyano-1,2,3-triazole

scholarly article by M.Teresa Pinillos et al published January 1988 in Journal of Organometallic Chemistry

Rhodium complexes of the binucleating ligands pyridine-2-thiolate and benzothiazole-2-thiolate. Crystal structures of [{Rh(µ-SC5H4N)(CO)2}2] and [{Rh(µ-SC5H4N)(tfbb)}2]·Me2CO (tfbb = tetrafluorobenzobarrelene)

scholarly article by Miguel A. Ciriano et al published 1989 in Dalton transactions RSC

Rhodium wires based on binuclear acetate-bridged complexes

scholarly article by Florian P. Pruchnik et al published January 2001 in Inorganic Chemistry Communications

Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts

Rhodium(I) Complexes with Hemilabile Phosphines: Rational Design for Efficient Oxidative Amination Catalysts

Rhodium(I) and iridium(I) complexes of 2,2′-dipyridylamine and its deprotonated form

scholarly article by Luis Oro et al published May 1986 in Inorganica Chimica Acta

Rhodium(I) complexes containing triphenylphosphite ligands

Rhodium(I) complexes with pyridine-2-aldehyde and related Schiff-base ligands

Rhodium(I) complexes with the 2,2′-bipyrimidine ligand

scholarly article by Maria P. Garcia et al published January 1987 in Polyhedron

Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling of N-Vinylpyrazoles with Alkynes via C–H Activation

article

Rhodium, iridium and gold complexes of the short-bite ligand 1-benzyl-2-imidazolyldiphenylphosphine

scholarly article by Cristina Tejel et al published April 2003 in Inorganica Chimica Acta

Rhodium-Catalyzed Polymerization of Phenylacetylene and its Derivatives

scholarly article by Miguel A. Casado et al published 29 May 2013 in Arabian Journal for Science and Engineering

Rhodium-Rhodium Bonds in Edge-Sharing Coplanar Dinuclear Complexes

scholarly article by Cristina Tejel et al published 3 July 2000 in Angewandte Chemie

Rhodium?tetranuclear complexes as building blocks for the construction of coordination polymers: chiroselectivity in the formation of [ClCuRh4(µ-PyS2)2(cod)4]n (H2PyS2= 2,6-dimercaptopyridine)

Rhodium–N-Heterocyclic Carbene Catalyzed Hydroalkenylation Reactions with 2-Vinylpyridine and 2-Vinylpyrazine: Preparation of Nitrogen-Bridgehead Heterocycles

Selective CH Bond Functionalization of 2-(2-Thienyl)pyridine by a Rhodium N-Heterocyclic Carbene Catalyst

Sequential C-H activation and dinuclear insertion of ethylene promoted by a diiridium complex

artículo científico publicado en 2002

Solvent-free iridium-catalyzed CO2 hydrosilylation: experiments and kinetic modeling

scholarly article by E. A. Jaseer et al published 2015 in Catalysis Science & Technology

Spectroscopic and electrochemical properties of Rh(I) complexes containing diene (norbornadiene or cyclooctadiene) and diimine (bipyrimidine) type ligands

article published in 1990

Square-planar rhodium(I) complexes partnered with [arachno-6-SB(9)H(12)]- : a route toward the synthesis of new rhodathiaboranes and organometallic/thiaborane salts

artículo científico publicado en 2007

Stereoselective oxidative additions of iodoalkanes and activated alkynes to a sulfido-bridged heterotrinuclear early-late (TiIr2) complex

artículo científico publicado en 2003

Stereoselective oxidative-addition reaction of molecular iodine and mercury(II) halides to rhodium dithiolate compounds. Crystal structure of [Rh2{µ-S(CH2)2S}Cl2(CO)2(PPh3)2]

article

Steric Effects in the Oxidative Addition of MeI to a Sulfido-Bridged ZrRh2 Early–Late Heterobimetallic Compound

Structural and dynamic studies on amido-bridged rhodium and iridium complexes

artículo científico publicado en 2002

Sulfido-Bridged Tetranuclear Titanium−Iridium Complexes with an Unconventional Tetrahedral Iridium Center

scholarly article by Miguel A. Casado et al published August 1999 in Organometallics

Syntheses and Reactivity of Functionalized (η5-Tetramethylcyclopentadienyl) Rhenium Complexes: Molecular Structures of (η5:η2-C5Me4CH2CH2CHCH2)Re(CO)2and (η5-C5Me4CH2-2-C4H3S)Re(CO)2(PMe3)

scholarly article by Fernando Godoy et al published November 2003 in Organometallics

Synthesis and Characterisation of New Iridium Complexes with the (4S)-2-[2-(Diphenylphosphanyl)phenyl]-4-isopropyl-1,3-oxazoline Ligand That Catalyse Asymmetric Michael Reactions

scholarly article by Daniel Carmona et al published May 2005 in European Journal of Inorganic Chemistry

Synthesis and Characterization of New Hydridoiridium Complexes Containing Carboxylate Ligands

artículo científico publicado en 1994

Synthesis and Oxidation of a Paddlewheel-Shaped Rhodium/Antimony Complex Featuring Pyridine-2-Thiolate Ligands

artículo científico publicado en 2017

Synthesis and Reactivity of Mononuclear (Pentachlorophenyl)rhodium(II) Complexes. Structural Relevance of Rhodium−o-Chlorine Secondary Bonding

scholarly article by María P. García et al published March 1997 in Organometallics

Synthesis and Stereochemistry of Half-Sandwich Alkynyl Amino Acidate Complexes of Rhodium(III), Iridium(III), and Ruthenium(II)

scholarly article by Daniel Carmona et al published June 2000 in Organometallics

Synthesis and catalytic activity of heterodinuclear Ru-Ir and Ru-Rh complexes. Crystal structure of [H(CO)(PPh3)2Ru(μ-Cl)(μ-pz)Ir(TFB)] (pz = pyrazolate, TFB = tetrafluorobenzobarrelene)

Synthesis and catalytic activity of some cationic complexes of rhodium(I) with norbornadiene and group Vb ligands

Synthesis and catalytic activity of some cationic rhodium(I) complexes with substituted quinolines

scholarly article by Rafael Us�n et al published October 1982 in Transition Metal Chemistry

Synthesis and characterization of Ru(II), Rh(III) and Ir(III) complexes of the “Daniphos” ligands and their application in the hydrogen transfer catalysis

Synthesis and characterization of an unusual heterobridged di-rhodium complex. X-ray molecular structure of [Rh2(μ-pz)2I2(CO)2(μ-dppm)]

scholarly article by Luis Oro et al published April 1985 in Inorganica Chimica Acta

Synthesis and characterization of an unusual tetranuclear rhodium complex; X-ray molecular structure of [Rh4(µ-Cl)2(µ-az)2(µ-CO)2(CO)2(nbd)2](az = 7-azaindolate; nbd = norborna-2,5-diene)

scholarly article by Luis Oro et al published 1984 in Journal of the Chemical Society. Chemical communications

Synthesis and characterization of new 10- and 12-vertex CO-ligated metallathiaboranes

Synthesis and characterization of the alkoxycarbonyl complexes [(C5Me5)M(µ-pz)(µ-I)2Rhl(CO2R)(CO)](M = Rh, R = Me or Et; M = Ir, R = Me; pz = pyrazolate). Molecular structure of [(C5Me5)Ir(µ-pz)(µ-I)2Rhl(CO2Me)(CO)]

article published in 1990

Synthesis and hydroformylation reaction of dinuclear rhodium(I) complexes with mixed bridging ligands. X-Ray structure of [Rh2(µ-pz)(µ-SBut)(CO)2{P(OMe)3}2]

scholarly article by Carmen Claver et al published 1988 in Dalton transactions RSC

Synthesis and molecular structure of [[(HBpz(3))Rh(PPh(3))(mu-Cl)(2)](2)Ag]BF(4) (Hpz = pyrazole), a heterotrinuclear Rh(2)Ag compound with square-planar silver(I).

artículo científico publicado en 2002

Synthesis and nuclear magnetic resonance studies of some ethylene and ethyltris(pyrazolyl)boratoiridium complexes

Synthesis and properties of rhodium(I) chloranilate and 2,5-dihydroxy-1,4-benzoquinonate complexes. Crystal structures of the binuclear [Rh2(.mu.-CA)(cod)2] and tetranuclear [Rh4(.mu.-CA)2(cod)4] complexes (CA = chloranilate anion)

scholarly article by Miguel A. Calvo et al published March 1993 in Inorganic Chemistry

Synthesis and reactions of phenylacetylide iridium(I) and rhodium(I) complexes

scholarly article by María J. Fernández et al published January 1990 in Journal of Organometallic Chemistry

Synthesis and reactivity at the Ir-MeTpm platform: from κ1-N coordination to κ3-N-based organometallic chemistry

scientific article published on 01 May 2019

Synthesis and reactivity of binuclear 7-azaindolate complexes of iridium

scholarly article by Miguel A. Ciriano et al published February 1993 in Journal of Organometallic Chemistry

Synthesis and reactivity of binuclear 7-azaindolate complexes of iridium

Synthesis and reactivity of binuclear complexes having the Rh(μ-pz)(μ-SR)Rh framework (pz = pyrazolate, R = But, Ph)

Synthesis and reactivity of binuclear pyrazolate-bridged ruthenium(I) complexes. Crystal structures of bis[µ-(3,5-dimethylpyrazolato-NN′)-tricarbonylruthenium(I)](Ru–Ru) and bis[µ-(3,5-dimethylpyrazolato-NN′)]-µ-iodo-bis[tricarbonylruthenium

Synthesis and reactivity of mono- and hetero-nuclear rhodium(I) or iridium(I) complexes with 2-(2′-pyridyl)benzimidazole

scholarly article by Rafael Uson et al published May 1983 in Journal of Organometallic Chemistry

Synthesis and reactivity of new benzophenone imine derivatives containing the Ru(CO)(PiPr3)2 unit

Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline

Synthesis and x-ray structural characterization of heterobimetallic rhodium-platinum and rhodium-palladium benzothiazole-2-thiolate compounds. The first binuclear complexes having two short-bite anionic bridging ligands in a trans disposition

scholarly article by Miguel A. Ciriano et al published March 1992 in Inorganic Chemistry

Synthesis and x-ray structure of the heterotrinuclear complex [Pd{(μ-Cl)(η2-μ-P(O)(OMe)2)Rh(cod)}2]. An unusual bridging coordination mode involving phosphonate ligands

Synthesis of Poly(silyl ether)s by Rhodium(I)-NHC Catalyzed Hydrosilylation: Homogeneous versus Heterogeneous Catalysis

Synthesis of Rhodium, Iridium, and Palladium Tetranuclear Complexes Directed by 2,6-Dimercaptopyridine. X-ray Crystal Structure of [Rh4(μ-PyS2)2(cod)4] (cod = 1,5-Cyclooctadiene)

scholarly article by Jesús J. Pérez-Torrente et al published January 1996 in Inorganic Chemistry

Synthesis of [M(η2-C2Ph2)(CO)(PiPr3)2] (MOs or Ru) and X-ray crystal structure of the osmium derivative

scholarly article by Jesús Espuelas et al published April 1994 in Journal of Organometallic Chemistry

Synthesis of a Square-Planar Rhodium Alkylidene N-Heterocyclic Carbene Complex and Its Reactivity Toward Alkenes

Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh2(µ3-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H4NS2= benzothiazole-2-thiolate)

Synthesis of mononuclear complexes of Ru and Os and heterobimetallic M–M′(M = Ru or Os; M′= Rh, Ir, or Au) compounds with pyrazolate or imidazolate type ligands. X-Ray crystal structure of [(Ph3P)2(OC)HRu(µ-bim)Rh(cod)](bim = dianion of 2,2′

Synthesis of tetranuclear rhodium and iridium complexes directed by 6-mercaptopyridin-2-ol: electrochemical behavior, chemical oxidation, and coordination chemistry

artículo científico publicado en 2009

Synthesis of transition-metal complexes with heterodifunctional ligands derived of NH(PPh2)2. Crystal structure of [(η5-C5Me5)RhCl{η2-P,Se-Ph2PNP(Se)Ph2}]·CH2Cl2

Synthesis of trinuclear complexes with mixed bridging ligands. X-Ray structure of [Pd{Rh(µ-pz)(µ-SBut)(CO)2}2](pz = pyrazolate)

Synthesis, Characterization, Properties, and Asymmetric Catalytic Diels−Alder Reactions of Chiral-at-Metal Phosphinooxazoline-Rhodium(III) and −Iridium(III) Complexes§

scholarly article by Daniel Carmona et al published November 2002 in Organometallics

Synthesis, Molecular Structure and Catalytic Activity of Six-Coordinate Chloro(hydrido)- and Dihydridoruthenium(II) and -osmium(II) Complexes with the Chiral Ligands PiPr2NH(Me)Ph, (S,S)-Chiraphos and (S,S,)-Diop

scholarly article by Christoph Schlünken et al published June 2004 in European Journal of Inorganic Chemistry

Synthesis, Molecular Structure, and Reactivity of Iridium(I) and Iridium(III) Complexes Formed by Coordination and C−H Activation of the Substituted Arenes C6H5CH2CH2PiPr2and C6H5OCH2CH2PtBu2

scholarly article by Giuseppe Canepa et al published May 2003 in Organometallics

Synthesis, Reactivity, and Catalytic Activity of Triangular ZrM2(M = Rh, Ir) Early−Late Heterobimetallic Complexes

Synthesis, X-ray Structure, and Catalytic Activity of the Unusual Complex [Ir(TFB)(PiPr3)2]BF4(TFB = Tetrafluorobenzobarrelene)

artículo científico publicado en 1997

Synthesis, X-ray structure, and nuclear magnetic resonance (1H and 13C) studies of ruthenium(II) complexes containing pyrazolyl ligands

Synthesis, characterization and molecular structure of the hydroperoxo complex [(η5C5Me5)Ir(µ-pz)3Rh(OOH)(dppe)][BF4]; Hpz = pyrazole, dppe β 1,2-bis(diphenylphosphino)ethane

Synthesis, reactivity and catalytic activity of [RuH(η1-OCMe2)(CO)2(PPri3)2]BF4

Synthesis, structural characterization, and ligand replacement reactions of gem-dithiolato-bridged rhodium and iridium complexes

artículo científico publicado en 2008

Synthesis, structure, and kinetic studies on [RuCl2(NCCH3)2(cod)]

Tetra- and tri-nuclear rhodiumpalladium complexes with the 1,2,4-triazolate ligand. Crystal structure of (η3-C3H5)2Pd2Rh2(μ3-tz)2Cl2(CO)4

scholarly article by Antonio Tiripicchio et al published June 1985 in Inorganica Chimica Acta

Tetranuclear Complexes as Intermediates in Transannular Oxidative-Addition Reactions. Structure of the First Tetrairidium Linear Cluster

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Tetranuclear [Rh4(mu-PyS2)2(diolefin)4] complexes as building blocks for new inorganic architectures: synthesis of coordination polymers and heteropolynuclear complexes with electrophilic d8 and d10 metal fragments

artículo científico publicado en 2004

Tetrazolate rhodium(I) complexes. Crystal structures of the trinuclear complexes [Rh3(µ3-ttz)(µ-Cl)Cl(cod)2(CO)2](ttz = tetrazolate, cod = cyclo-octa-1,5-diene) and [Rh3(µ3-ttz)(µ-Cl)Cl(CO)6], an unusual example of metal–metal interactions

scholarly article by Luis Oro et al published 1988 in Dalton transactions RSC

The (NHEt3)[Rh(C6Cl2O4)(CO)2] complex: an example of the adverse counterion influence in the formation of metallic stacks

The Anions [Cptt2Zr(μ-S)2M(CO)2]-(M = Rh, Ir) as Versatile Precursors for the Synthesis of Sulfido-Bridged Early−Late Heterotrimetallic (ELHT) Compounds†

The chemical and electrochemical one-electron oxidation of diamidonaphthalene-bridged complexes; paramagnetic [Rh2]3+-containing A-frames

The complete characterization of a rhodium Lewis acid-dipolarophile complex as an intermediate for the enantioselective catalytic 1,3-dipolar cycloaddition of C,N-diphenylnitrone to methacrolein

artículo científico publicado en 2004

The emergence of transition-metal-mediated hydrothiolation of unsaturated carbon-carbon bonds: a mechanistic outlook

artículo científico

The influence of various azolate bridging ligands on the catalytic activity of dinuclear rhodium(I) precursors in the hydroformylation reaction

scholarly article by Carmen Claver et al published November 1987 in Journal of molecular catalysis

The reactions of [Ru3(CO)12] with nitrogen-containing heterocycles. Crystal structures of [Ru3(µ-H)(µ3-ppy)(CO)9] and [Ru3(µ-napy)(µ-CO)3(CO)7]

The rhodium and iridium co-ordination chemistry of the hemilabile hybrid ligand 1-(2′-pyridyl)-3-dimethylamino-2-propen-1-one

scholarly article by Ana P Martı́nez et al published April 2003 in Inorganica Chimica Acta

The synthesis and structure determination of a novel η6-arenerhodium(III) complex, [(Me2SiC6H5)4Rh2H2], and the synthesis of [(Me2SiC6H5)4Ir2H2]

The unexpected formal insertion of a carbonyl group into a heterocyclic NIr bond

The unexpected synthesis of rhodium(I) complexes with the 1-(2′-pyridyl)-3-oxo-1-propenoxide anionic ligand

scholarly article by Ana P. Martı́nez et al published April 2002 in Inorganic Chemistry Communications

The π-(Hydroxyalkenyl)germane Complexes Rh(acac){η2-(E)-Et3GeCHCHC(OH)R2}(PCy3) (R = Me, Ph) as Intermediates in the Hydrogermylation of Alkynols Catalyzed by Rh(acac)(cyclooctene)(PCy3)

artículo científico publicado en 1999

Theoretical Studies on the Mechanism of Iridium-Catalyzed Alkene Hydrogenation by the Cationic Complex [IrH2(NCMe)3(PiPr3)]+

scholarly article by Victor Polo et al published 5 September 2014 in Organometallics

Thiocarbonyl rhodium complexes with tricyclohexylphosphine and other nitrogen and phosphorus donor ligands

scholarly article by Rafael Usón et al published December 1980 in Transition Metal Chemistry

Trans Additions of Silanes to 1-Alkynes Catalyzed by Ruthenium Complexes: Role of in Situ Formed Polynuclear Aggregates

article

Tri-, bi- and mononuclear rhodium complexes with the anionic polydentate ligands 1,8-naphthyridine-2-one and 5,7-dimethyl-1,8-naphthyridine-2-one

scholarly article by Miguel A. Ciriano et al published October 1986 in Inorganica Chimica Acta

Trinuclear aggregates of rhodium and iridium supported by thiolate bridges: synthesis and crystal structure

scholarly article by Miguel A. Ciriano et al published 1992 in Dalton transactions RSC

Trinuclear angular aggregates of rhodium: synthesis and crystal structures of [Rh3(µ3-SC5H4N)2(CO)6][ClO4](SC5H4N = pyridine-2-thiolate) and [Rh3(µ3-C7H4NS2)2(CO)2(PPh3)2(tfbb)][ClO4](C7H4NS2= benzothiazole-2-thiolate, tfbb = tetrafluorobenzobarrel

scholarly article by Miguel A. Ciriano et al published 1990 in Dalton transactions RSC

Trinuclear iridium and rhodium complexes: the solution to a puzzle involving the multiple coordination possibilities of 1,8-naphthyridine-2-one ligands

scholarly article by B.Eva Villaroya et al published September 1996 in Inorganica Chimica Acta

Trinuclear mixed-valence complexes with the linear [Rh3]4+ core

Trinuclear pyrazolate complexes. Crystal structure of [(OC)2Rh(µ-pz)2Pd(µ-pz)2Rh(CO)2]

article

Tris(pentafluorophenyl) neutral and anionic five-co-ordinate complexes of rhodium(III). Crystal structures of [Rh(C6F5)3(PEt3)2] and [Rh(C6F5)3(AsPh3)2]

Tris(pyrazol-1-yl)methane-rhodium(I) and -iridium(I) complexes; cyrstal structure of [Rh(COD)(tpzm)][RhCl2(COD)]·3CHCl3

scholarly article by Miguel A. Esteruelas et al published April 1988 in Journal of Organometallic Chemistry

Tris(pyrazolyl)borate carbosilane dendrimers and metallodendrimers

Unprecedented hybrid scorpionate/phosphine ligand able to be anchored to carbosilane dendrimers

artículo científico publicado en 2005

Unsaturated Iridium(III) Complexes Supported by a Quinolato–Carboxylato ONO Pincer-Type Ligand: Synthesis, Reactivity, and Catalytic C–H Functionalization

scholarly article by Duc Hanh Nguyen et al published 8 November 2013 in Organometallics

Unusual Tautomers in Dinuclear Metal Chemistry and Their Role in Oxidative-Addition Reactions of Chlorocarbons

article

Versatility of Cyclooctadiene Ligands in Iridium Chemistry and Catalysis

scholarly article by Marta Martín et al published December 2003 in Organometallics

Vinylidene-based polymers by Rh(i)-NHC catalyzed thiol–yne click polymerization: synthesis, characterization and post-polymerization modification

Weak intermetallic bonding in unusual trinuclear complexes: crystal structure of [Rh3(µ3-tz)(µ2-Cl)Cl(η4-tfb)(CO)4]·½CH2Cl2and [Rh3(µ3-tz)(µ2-Cl)Cl(η3-C3H5)2(CO)4]·½C2H4Cl2(Htz = 1,2,4-triazole; tfb = tetrafluorobenzonarrelene: 5,6,7,8-tetr

[CpTi(μ3-S)3{Rh(tfbb)}3]: An early-late heterometallic complex as molecular model for the deactivation of metal sulphide catalysts

[RhCl(CO)(PPh3)]2. A precursor for the synthesis of cationic rhodium complexes with nitrogen donor ligands

gem-Selective Cross-Dimerization and Cross-Trimerization of Alkynes with Silylacetylenes Promoted by a Rhodium-Pyridine-N-Heterocyclic Carbene Catalyst

η3-Allyl rhodium complexes with azolate ligands. Crystal structures of the trinuclear 1,2,4-triazolate (tz) complexes [Rh3(µ-tz)3(η3-C3H5)6] and [Rh3(µ3-tz)(µ-Cl)Cl(η3-C3H5)2(CO)4]·0.5C2H4Cl2

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