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Lista de obras de Jonathan Clayden

(S)-2-(Dibenzylamino)-3-phenylpropanal as a chiral auxiliary: a new strategy for the asymmetric synthesis of 2-substituted alcohols

(−)-Ephedrine as an auxiliary for the asymmetric synthesis of atropisomeric amides by dynamic resolution under thermodynamic control

article published in 2001

1,3,4,5-Tetrahydroazepin-2-ones by Dearomatising Anionic Cyclisation of N-Allyl-1-Naphthamides

2,2- and 2,6-Diarylpiperidines by Aryl Migration within Lithiated Urea Derivatives of Tetrahydropyridines

artículo científico publicado en 2015

2,3-Dihydroisoindolones by cyclisation and rearomatisation of lithiated benzamides

A One-Pot Synthesis of 2-Aryl-4,5-anti-diphenyloxazolines

A general synthetic approach to the amnesic shellfish toxins: total synthesis of (−)-isodomoic acid B, (−)-isodomoic acid E and (−)-isodomoic acid F

scientific article published on 24 February 2011

A tendril perversion in a helical oligomer: trapping and characterizing a mobile screw-sense reversal

artículo científico publicado en 2017

Achieving conformational control over C–C, C–N and C–O bonds in biaryls, N,N′-diarylureas and diaryl ethers: advantages of a relay axis

artículo científico publicado en 2006

Addition of Lithiated Tertiary Aromatic Amides to Epoxides and Aziridines: Asymmetric Synthesis of (S)-(+)-Mellein

article

Alkenyl oxazolidinones by stereoselective epoxidation of δ-hydroxy allylic phosphine oxides: Synthesis of any isomer (RR, RS, SR or SS; E or Z) bearing 1,4-related chiral centres across a double bond

Allylic sulfones as allyl anion equivalents: homoallylic alcohols from metal catalysed reactions of sulfones with aldehydes and ketones

Amines Bearing Tertiary Substituents by Tandem Enantioselective Carbolithiation–Rearrangement of Vinylureas

artículo científico publicado en 2013

Amines Bearing Tertiary Substituents by Tandem Enantioselective Carbolithiation–Rearrangement of Vinylureas

artículo científico publicado en 2012

Amino Acid-Derived trans- N-Chloroformylimidazolidinones: Scalable, Stereoselective Synthesis, Structure, and Utility

scientific article published on 29 May 2019

An Aliphatic Bischler-Napieralski Reaction: Dihydropyridones by Cyclocarbonylation of 3-Allylimidazolidin-4-ones

scientific article published on 17 December 2019

Anion translocation in organolithiums: A mechanism for the lithiation and cyclisation of tertiary naphthamides

Anionic cyclisations of an N-benzyl naphthamide: a route to benzo[e]isoindolones

Asymmetric Ortholithiation of Amides by Conformationally Mediated Chiral Memory: An Enantioselective Route to Naphtho- and Benzofuranones

Asymmetric and Geometry-Selective α-Alkenylation of α-Amino Acids

artículo científico publicado en 2019

Asymmetric deprotonation and dearomatising cyclisation of N-benzyl benzamides using chiral lithium amides: formal synthesis of (-)-kainic acid

artículo científico publicado en 2002

Asymmetric epoxidations and kinetic resolutions of δ-hydroxy allylic phosphine oxides

Asymmetric induction using atropisomers: Diastereoselective additions to 2-acyl-1-naphthamides

article

Asymmetric synthesis of biaryl atropisomers by dynamic resolution on condensation of biaryl aldehydes with (-)-ephedrine or a proline-derived diamine

artículo científico publicado en 2008

Asymmetric synthesis of enantiomerically enriched atropisomeric amides by desymmetrisation of N,N-dialkylmesitamides †

article by Jonathan Clayden et al published 2001 in Journal of the Chemical Society, Perkin Transactions 1

Asymmetric synthesis of tertiary thiols and thioethers

artículo científico publicado en 2011

Atropisomeric Amides as Chiral Ligands: Using (−)-Sparteine-Directed Enantioselective Silylation to Control the Conformation of a Stereogenic Axis

scientific article published on 01 October 2000

Atropisomeric benzamides and naphthamides as chiral auxiliaries †

Atropisomeric diastereoisomers from nucleophilic attack on 8-acyl-1-naphthamides

Atropisomerism

Atropisomerism about Aryl–Csp3 Bonds: The Electronic and Steric Influence of ortho-Substituents on Conformational Exchange in Cannabidiol and Linderatin Derivatives

scientific article published on 23 June 2014

Atropisomerism at CS Bonds: Asymmetric Synthesis of Diaryl Sulfones by Dynamic Resolution Under Thermodynamic Control

artículo científico publicado en 2009

Atropisomers and near-atropisomers: achieving stereoselectivity by exploiting the conformational preferences of aromatic amides

scientific article published on 14 October 2003

Atroposelective attack of nucleophiles and electrophiles on 2-acyl-1-naphthamides and their enolates

Atroposelective attack of nucleophiles on 2-formyl-1-naphthamides and their derivatives: chelation and non-chelation control

Atroposelectivity in the Reactions of Laterally Lithiated Tertiary Amides

article by Jonathan Clayden & Jennifer H. Pink published April 1997 in Tetrahedron Letters

Atroposelectivity in the electrophilic substitution reactions of laterally lithiated and silylated tertiary amides

article by Jonathan Clayden et al published 6 March 2002 in Journal of the Chemical Society, Perkin Transactions 1

Atroposelectivity in the reactions of ortholithiated aromatic tertiary amides with aldehydes

article published in 1997

Attack on fluorinated 2-aryloxazolines by organolithiums: dearomatisation, lithiation or substitution

Automated solid-phase concatenation of Aib residues to form long, water-soluble, helical peptides

artículo científico publicado en 2020

Axial chirality in xanthene-4,5-dicarboxamides: 1,9-stereocontrol mediated by remote interactions between conformationally constrained amide groups

article by Jonathan Clayden et al published July 2000 in Tetrahedron Letters

Azabicyclic Amino Acids by Stereoselective Dearomatizing Cyclization of the Enolates ofN-Nicotinoyl Glycine Derivatives

scientific article published on 01 November 2006

Barriers to rotation about the chiral axis of tertiary aromatic amides

article by Anjum Ahmed et al published October 1998 in Tetrahedron

Beilstein Journal of Organic Chemistry

artículo científico publicado en 2005

Biocatalytic Dynamic Kinetic Resolution for the Synthesis of Atropisomeric Biaryl N-Oxide Lewis Base Catalysts

Biocatalytic Dynamic Kinetic Resolution for the Synthesis of Atropisomeric Biaryl N-Oxide Lewis Base Catalysts.

artículo científico publicado en 2016

Biocatalytic desymmetrization of an atropisomer with both an enantioselective oxidase and ketoreductases.

artículo científico publicado en 2010

Bis-pyrene probes of foldamer conformation in solution and in phospholipid bilayers

artículo científico publicado en 2018

Bonded peri-interactions govern the rate of racemisation of atropisomeric 8-substituted 1-naphthamides†

Can relief of ring-strain in a cyclopropylmethyllithium drive the Brook rearrangement?

Carbamate-directed benzylic lithiation for the diastereo- and enantioselective synthesis of diaryl ether atropisomers

artículo científico publicado en 2011

Carbolithiation of N-alkenyl ureas and N-alkenyl carbamates

artículo científico publicado en 2013

Carbolithiation of S-alkenyl-N-aryl thiocarbamates: carbanion arylation in a connective route to tertiary thiols

artículo científico publicado en 2013

Carbolithiation of aromatic rings: cyclohexadienes from N-aroyl-2,2,6,6-tetramethylpiperidines

artículo científico publicado en 2002

Chemical communication: conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains

artículo científico publicado en 2012

Chemistry of domoic acid, isodomoic acids, and their analogues

Chemoenzymatic Synthesis of Substituted Azepanes by Sequential Biocatalytic Reduction and Organolithium-Mediated Rearrangement

artículo científico publicado en 2018

Communicating chirality ⬇️

artículo científico publicado el 24 de octubre de 2011

Competing Hydrogen-Bond Polarities in a Dynamic Oligourea Foldamer: A Molecular Spring Torsion Balance

article

Conformation and stereodynamics of 2,2'-disubstituted N,N'-diaryl ureas

artículo científico publicado en 2008

Conformational Preference and Remote (1,10) Stereocontrol in Biphenyl-2,2‘-dicarboxamides

artículo científico publicado en 2001

Conformational Preferences of a Polar Biaryl: A Phase- and Enantiomeric Purity-Dependent Molecular Hinge

artículo científico publicado en 2009

Conformational Switching of a Foldamer in a Multicomponent System by pH-Filtered Selection between Competing Noncovalent Interactions

artículo científico publicado en 2015

Conformational analysis of helical aminoisobutyric acid (Aib) oligomers bearing C-terminal ester Schellman motifs

artículo científico publicado en 2014

Conformational arm-wrestling: battles for stereochemical control in benzamides bearing matched and mismatched chiral 2- and 6-substituents

artículo científico publicado en 2005

Conformational communication between the Ar–CO and Ar–N axes in 2,2′-disubstituted benzanilides and their derivatives

artículo científico publicado en 2006

Conformational cooperativity between helical domains of differing geometry in oligoamide–oligourea foldamer chimeras

artículo científico publicado en 2015

Conformational photoswitching of a synthetic peptide foldamer bound within a phospholipid bilayer

artículo científico publicado en 2016

Conformational preference in aromatic amides bearing chiral ortho substituents: its origin and application to relayed stereocontrol

artículo científico publicado en 2005

Conformational studies of tertiary oligo-m-benzanilides and oligo-p-benzanilides in solution

Conformational switching between diastereoisomeric atropisomers of arenedicarboxamides induced by complexation with Lewis acids

artículo científico publicado en 2007

Conformationally Interlocked Amides: Remote Asymmetric Induction by Mechanical Transfer of Stereochemical Information

article by Jonathan Clayden et al published January 1998 in Tetrahedron Letters

Connective synthesis of 5,5-disubstituted hydantoins by tandem α-amination and α-arylation of silyl ketene acetals

artículo científico publicado en 2019

Consecutive Ring Expansion and Contraction for the Synthesis of 1-Aryl Tetrahydroisoquinolines and Tetrahydrobenzazepines from Readily Available Heterocyclic Precursors

Consecutive Ring Expansion and Contraction for the Synthesis of 1-Aryl Tetrahydroisoquinolines and Tetrahydrobenzazepines from Readily Available Heterocyclic Precursors

artículo científico publicado en 2018

Contra-Friedel–Crafts tert-butylation of substituted aromatic rings via directed metallation and sulfinylation

artículo científico publicado en 2006

Control of stereochemistry with phosphine oxides: asymmetric synthesis of 4-alkenyloxazolidin-2-ones with 1,4-related stereogenic centres across a double bond

Controlling Chemoselectivity in the Lithiation of Substituted Aromatic Tertiary Amides

scientific article published on 01 April 2004

Controlling axial conformation in 2-arylpyridines and 1-arylisoquinolines: application to the asymmetric synthesis of QUINAP by dynamic thermodynamic resolution.

artículo científico publicado en 2009

Controlling the regioselectivity of lithiation using kinetic isotope effects: Deuterium as a protecting group for carbon

article by Jonathan Clayden et al published November 1998 in Tetrahedron Letters

Controlling the sign and magnitude of screw-sense preference from the C-terminus of an achiral helical foldamer

artículo científico publicado en 2014

Cyclisations of Organolithiums onto Aromatic Rings

Cyclization of Lithiated Pyridine and Quinoline Carboxamides:  Synthesis of Partially Saturated Pyrrolopyridines and Spirocyclic β-Lactams

artículo científico publicado en 2005

Dearomatising cyclisation of lithiated 1-naphthamides with a phenylglycinol-derived chiral auxiliary: asymmetric synthesis of an arylkainoid and a kainoid-like pyroglutamate

Dearomatising cyclisation of lithiated allyl phenyl ethers: the role of an oxazoline substituent

Dearomatising cyclisations of lithiated N-benzylbenzamides

Dearomatising rearrangements of lithiated thiophenecarboxamides

artículo científico publicado en 2004

Dearomatization and Aryl Migration in Organolithium Chemistry

Dearomatizing Cyclization of Arylsulfonylalkoxymethyl Lithiums: A Route to the Podophyllotoxin Skeleton

scientific article published on 01 March 2003

Dearomatizing Disrotatory Electrocyclic Ring Closure of Lithiated N-Benzoyloxazolidines

artículo científico publicado en 2002

Designing foldamer-foldamer interactions in solution: the roles of helix length and terminus functionality in promoting the self-association of aminoisobutyric acid oligomers

artículo científico publicado en 2014

Diastereoisomeric atropisomers from the addition of lithiated N,N-dialkyl-l-naphthamides to aldehydes

article

Diastereoisomeric atropisomers of peri-substituted naphthamides: synthesis, stereoselectivity and stability

Diastereomeric ratio determination by high sensitivity band-selective pure shift NMR spectroscopy

artículo científico publicado en 2014

Diastereoselective ortholithiation and conformational control in stereospecific dearomatising anionic cyclisations

Diastereoselective protonation of extended pyrrol-3-en-2-one enolates: an attempted ‘de-epimerisation’

Diastereoselective reactions of optically active γ-substituted vinyl phosphine oxides

Diastereoselective synthesis of atropisomers containing two non-biaryl stereogenic axes: stereochemical relay through stereogenic centres in dihydrostilbene-2,2'-dicarboxamides

artículo científico publicado en 2005

Diastereotopic fluorine substituents as 19F NMR probes of screw-sense preference in helical foldamers

artículo científico publicado en 2013

Dibenzazepinyl ureas as dual NMR and CD probes of helical screw-sense preference in conformationally equilibrating dynamic foldamers

artículo científico publicado en 2017

Dihydrothiophenes containing quaternary stereogenic centres by sequential stereospecific rearrangements and ring-closing metathesis

artículo científico publicado en 2014

Direct synthesis of sulfonated azacalixarenes in water

artículo científico publicado en 2009

Directed Lithiation of Pentadienylsilanes

Doubly dearomatising intramolecular coupling of a nucleophilic and an electrophilic heterocycle

artículo científico publicado en 2009

Dynamic foldamer chemistry

artículo científico publicado en 2016

Dynamic resolution of atropisomeric amides using proline-derived imidazolines and ephedrine-derived oxazolidines

Dynamically resolved peri-substituted 2-formyl naphthamides: a new class of atropisomeric chiral auxiliary

Electrophile-induced dearomatizing spirocyclization of N-arylisonicotinamides: a route to spirocyclic piperidines

artículo científico publicado en 2008

Enantiomerically enriched atropisomeric N,N′-diaryl ureas by oxidative kinetic resolution of their 2-sulfanyl derivatives

Enantioselective Synthesis of Atropisomeric Amides by Dynamic Resolution: Thermodynamic Control with a Proline-Derived Diamine Resolving Agent

scientific article published on 01 September 1999

Enantioselective Synthesis of an Atropisomeric Diaryl Ether

artículo científico publicado en 2008

Enantioselective carbolithiation of S-alkenyl-N-aryl thiocarbamates: kinetic and thermodynamic control

artículo científico publicado en 2015

Enantioselective synthesis of tertiary thiols by intramolecular arylation of lithiated thiocarbamates

artículo científico publicado en 2011

Enantioselectively functionalised phenytoin derivatives by auxiliary-directed N to C aryl migration in lithiated α-amino nitriles

artículo científico publicado en 2018

End-to-end conformational communication through a synthetic purinergic receptor by ligand-induced helicity switching

scientific article published on 15 September 2013

Engineering the structure of an N-terminal β-turn to maximize screw-sense preference in achiral helical peptide chains

artículo científico publicado en 2014

Enzymatic desymmetrising redox reactions for the asymmetric synthesis of biaryl atropisomers

artículo científico publicado en 2014

Extended Diethylglycine Homopeptides Formed by Desulfurization of Their Tetrahydrothiopyran Analogues

artículo científico publicado en 2019

Fast racemisation and slow epimerisation of laterally lithiated amides: stereochemical evidence for the mechanism of inversion of amide-substituted benzyllithiums

article

Flaws in foldamers: conformational uniformity and signal decay in achiral helical peptide oligomers

artículo científico publicado en 2015

Foldamer-Mediated Remote Stereocontrol: >1,60 Asymmetric Induction

artículo científico publicado en 2013

Foreword

Formation of water-soluble sulfonated azacalix[4]arenes from cyanuric chloride

Fused bicyclic piperidines and dihydropyridines by dearomatising cyclisation of the enolates of nicotinyl-substituted esters and ketones

artículo científico publicado en 2010

Geometry-Retentive C-Alkenylation of Lithiated α-Aminonitriles: Quaternary α-Alkenyl Amino Acids and Hydantoins

artículo científico publicado en 2017

Geometry-Retentive C-Alkenylation of Lithiated α-Aminonitriles: Quaternary α-Alkenyl Amino Acids and Hydantoins

Geometry-Selective Synthesis ofEorZN-Vinyl Ureas (N-Carbamoyl Enamines)

artículo científico publicado en 2010

Geometry-selective synthesis of the unsaturated side chains of the isodomoic acids

Heavily Substituted Atropisomeric Diarylamines by Unactivated Smiles Rearrangement of N -Aryl Anthranilamides

Heavily Substituted Atropisomeric Diarylamines by Unactivated Smiles Rearrangement of N-Aryl Anthranilamides

artículo científico publicado en 2017

Helical Foldamers Incorporating Photoswitchable Residues for Light-Mediated Modulation of Conformational Preference

scientific article published on 16 June 2016

Helical peptaibol mimics are better ionophores when racemic than when enantiopure

scientific article published on 01 October 2015

Helix persistence and breakdown in oligoureas of metaphenylenediamine: apparent diastereotopicity as a spectroscopic marker of helix length in solution

artículo científico publicado en 2008

Hindered diarylether and diarylsulfone bisphosphine ligands: atropisomerism and palladium complexes

Homoallylic alcohols from samarium diiodide-mediated coupling of allylic sulfones with carbonyl compounds

article published in 1994

Inducing achiral aliphatic oligoureas to fold into helical conformations

article

Induction of Unexpected Left-Handed Helicity by an N-Terminal L-Amino Acid in an Otherwise Achiral Peptide Chain

artículo científico publicado en 2012

Influence of achiral units with gem-dimethyl substituents on the helical character of aliphatic oligourea foldamers

artículo científico publicado en 2013

Interruption of a 310-helix by a single Gly residue in a poly-Aib motif: A crystallographic study

artículo científico publicado en 2011

Intramolecular Vinylation of Secondary and Tertiary Organolithiums

artículo científico publicado en 2012

Intramolecular arylation of amino acid enolates

scientific article published on 01 October 2013

Intramolecular vinylation of carbanions using N -acyl benzomorpholines as masked vinylureas and vinylcarbamates

Is nevirapine atropisomeric? Experimental and computational evidence for rapid conformational inversion

article

Kinetic and thermodynamic stereocontrol in the atroposelective formation of sulfoxides by oxidation of 2-sulfanyl-1-naphthamides

artículo científico publicado en 2005

Lateral lithiation of N,N′-diaryl ureas

Left-handed helical preference in an achiral peptide chain is induced by an L-amino acid in an N-terminal type II β-turn

artículo científico publicado en 2013

Length-Dependent Formation of Transmembrane Pores by 310-Helical α-Aminoisobutyric Acid Foldamers

artículo científico publicado en 2015

Ligand Effects in the Formation of Tertiary Carbanions from Substituted Tertiary Aromatic Amides

artículo científico publicado en 2011

Ligand-modulated conformational switching in a fully synthetic membrane-bound receptor

Lithiated Tertiary Carbanions Display Variable Coordination Modes: Evidence from DFT and NMR Studies

artículo científico publicado en 2012

Lithiation and Stereoselective Transformations of 3-Aroyl-2,2,4,4-tetramethyloxazolidines (TMO Amides), a New Class of Acid-labile Atropisomeric Amides

Lithium Choreography Determines Contrasting Stereochemical Outcomes of Aryl Migrations in Benzylic Carbamates, Ureas and Thiocarbamates

Lithium Choreography: Intramolecular Arylations of Carbamate-Stabilised Carbanions and Their Mechanisms Probed by In Situ IR Spectroscopy and DFT Calculations

scientific article published on 23 October 2012

Lithium-sulfoxide-lithium exchange for the asymmetric synthesis of atropisomers under thermodynamic control

artículo científico publicado en 2002

Looking forward to volume six.

artículo científico publicado en 2010

Manipulating the Diastereoselectivity of Ortholithiation in Planar Chiral Ferrocenes

artículo científico publicado en 2013

Measuring Screw-Sense Preference in a Helical Oligomer by Comparison of13C NMR Signal Separation at Slow and Fast Exchange

artículo científico publicado en 2011

Mechanism of Stabilization of Helix Secondary Structure by Constrained Cα-Tetrasubstituted α-Amino Acids

scientific article published on 12 January 2015

Medium-Ring Nitrogen Heterocycles through Migratory Ring Expansion of Metalated Ureas

artículo científico publicado en 2016

Medium-Ring Nitrogen Heterocycles through Migratory Ring Expansion of Metalated Ureas

Medium-Sized-Ring Analogues of Dibenzodiazepines by a Conformationally Induced Smiles Ring Expansion

artículo científico publicado en 2017

Medium-Sized-Ring Analogues of Dibenzodiazepines by a Conformationally Induced Smiles Ring Expansion

N to C aryl migration in lithiated carbamates: alpha-arylation of benzylic alcohols.

artículo científico publicado en 2009

N,N'-diarylureas: a new family of atropisomers exhibiting highly diastereoselective reactivity

artículo científico publicado en 2008

N-Chloroformylimidazolidinone Enolates as 1,3-Dipolar Reagents for the Stereoselective Synthesis of 3,4-Dihydroisoquinolones

scientific article published on 25 February 2019

N-versus C-terminal control over the screw-sense preference of the configurationally achiral, conformationally helical peptide motif Aib(8)GlyAib(8).

artículo científico publicado en 2010

Nanometer-Range Communication of Stereochemical Information by Reversible Switching of Molecular Helicity

artículo científico publicado en 2010

Nickel-catalysed substitutions of aryl tert-butyl sulfones with organometallic reagents: synthesis of ortho-substituted unsymmetrical biaryls

scholarly article by Jonathan Clayden et al published 1995 in Journal of the Chemical Society. Perkin transactions 1

No turning back for motorized molecules

artículo científico publicado en 2016

Non-Biaryl Atropisomers: New Classes of Chiral Reagents, Auxiliaries and Ligands?

Non-Biaryl Atropisomers: New Classes of Chiral Reagents, Auxiliaries and Ligands?

Non-Biaryl Atropisomers: New Classes of Chiral Reagents, Auxiliaries, and Ligands?

Nucleophilic addition to electron-rich heteroaromatics: dearomatizing anionic cyclizations of pyrrolecarboxamides

artículo científico publicado en 2004

On the control of secondary carbanion structure utilising ligand effects during directed metallation

artículo científico publicado en 2012

Optically Active Vibrational Spectroscopy of α-Aminoisobutyric Acid Foldamers in Organic Solvents and Phospholipid Bilayers

Organometallic reagents: deconstructing THF.

artículo científico publicado en 2010

Origin of Helical Screw Sense Selectivity Induced by Chiral Constrained Cα-Tetrasubstituted α-Amino Acids in Aib-based Peptides

artículo científico publicado en 2015

Oxidative fragmentation of bicyclic hydroxy silanes and stannanes: a strategy for the stereoselective synthesis of kainoids

article published in 2007

Palladium Catalyzed C-Arylation of Amino Acid Derived Hydantoins

artículo científico publicado en 2015

Participation of non-aminoisobutyric acid (Aib) residues in the 310 helical conformation of Aib-rich foldamers: a solid state study

Pathways for decomposition of THF by organolithiums: the role of HMPA

Perilithiation and the synthesis of 8-substituted-1-naphthamides

Polycyclic Indoline Derivatives by Dearomatizing Anionic Cyclization of Indole and Tryptamine-Derived Ureas

artículo científico publicado en 2018

Pseudoephedrine-Directed Asymmetric α-Arylation of α-Amino Acid Derivatives

artículo científico publicado en 2015

Pyrrolidinone-fused Cyclohexenones by Regioselective Dearomatising Anionic Cyclisation of 2-, 3- or 4-Methoxybenzamides

Quantifying End-to-End Conformational Communication of Chirality through an Achiral Peptide Chain

artículo científico publicado en 2009

Quaternary centres bearing nitrogen (α-tertiary amines) as products of molecular rearrangements.

scientific article published on 07 March 2011

Refoldable Foldamers: Global Conformational Switching by Deletion or Insertion of a Single Hydrogen Bond

artículo científico

Refoldable Foldamers: Global Conformational Switching by Deletion or Insertion of a Single Hydrogen Bond

Relaying stereochemistry through aromatic ureas: 1,9 and 1,15 remote stereocontrol

artículo científico publicado en 2008

Remote conformational responses to enantiomeric excess in carboxylate-binding dynamic foldamers

scientific article published on 17 July 2019

Remote stereocontrol using rotationally restricted amides: (1,5)-asymmetric induction

article by Jonathan Clayden et al published December 1997 in Tetrahedron Letters

Reproducibility of tract segmentation between sessions using an unsupervised modelling-based approach

artículo científico publicado en 2008

Reversible aryl migrations in metallated ureas: controlled inversion of configuration at a quaternary carbon atom.

artículo científico publicado en 2013

Ring-Selective Functionalization ofN,N‘-Diarylureas by Regioselective N-Alkylation and Directed Ortho Metalation

scientific article published on 01 July 2005

S-Allyl Thiocarbamates from Allylic Alcohols by in situ [3,3]-Sigmatropic Rearrangement of a Thiocarbonyldiimidazole Adduct

Screw sense alone can govern enantioselective extension of a helical peptide by kinetic resolution of a racemic amino acid

scientific article published on 01 July 2015

Sequential double α-arylation of N-allylureas by asymmetric deprotonation and N→C aryl migration.

artículo científico publicado en 2010

Signal transduction in oligoamide foldamers by selective non-covalent binding of chiral phosphates at a urea binding site

artículo científico publicado en 2017

Slow interconversion of enantiomeric conformers or atropisomers of anilide and urea derivatives of 2-substituted anilines.

artículo científico publicado en 2005

Spirocyclic Dihydropyridines by Electrophile-Induced Dearomatizing Cyclization of N-Alkenyl Pyridinecarboxamides

scientific article published on 03 April 2013

Stabilizers cause instability

artículo científico publicado en 2012

Stereochemical relays: communication via conformation

artículo científico publicado en 2006

Stereocontrol in Organic Synthesis Using the Diphenylphosphoryl Group

article

Stereocontrol with Rotationally Restricted Amides

Stereocontrolled synthesis of R or S E or Z unsaturated α—amino acids by enantio- and diastereoselective epoxidation of δ-hydroxy allylic phosphine oxides

Stereodynamics of bond rotation in tertiary aromatic amides

artículo científico publicado en 2002

Stereoselective dearomatizing addition of nucleophiles to uncomplexed benzene rings: a route to carbocyclic sugar analogues

artículo científico publicado en 2008

Stereospecific DearomatisingCyclisation of Tertiary α-Amidoorganolithiums

Stereospecific Intramolecular Arylation of 2- and 3-Pyridyl Substituted Alkylamines via Configurationally Stable α-Pyridyl Organolithiums

artículo científico publicado en 2017

Stereospecific formation of tetrasubstituted centres from trisubstituted centres during dearomatising anionic cyclisations

Stereospecific photochemical ring expansion of lithiated benzamides

artículo científico publicado en 2003

Stereospecificity and Stereoselectivity in Electrophilic Substitution Reactions of Non-α-Heterosubstituted Organolithiums and Stannanes: A Rotationally Restricted Amide as an Internal Stereochemical Marker

artículo científico publicado en 2001

Structural Influences in Lithium Pentadienylsilane Complexes

Stuart Warren (24 Dec 1938-22 Mar 2020)

scientific article published on 16 September 2020

Substituent effects on axial chirality in 1-aryl-3,4-dihydroisoquinolines: controlling the rate of bond rotation

Substituted Diarylmethylamines by Stereospecific Intramolecular Electrophilic Arylation of Lithiated Ureas

artículo científico publicado en 2007

Substituted Dihydroisoquinolinones by Iodide-Promoted Cyclocarbonylation of Aromatic α-Amino Acids

artículo científico publicado en 2018

Sulfoxides as ‘traceless’ resolving agents for the synthesis of atropisomers by dynamic or classical resolution

Supramolecular chemistry: Host in translation

scientific article published on 13 March 2017

Switchable foldamer ion channels with antibacterial activity

scientific article published on 04 June 2020

Synthesis and Stacked Conformations of Symmetrical and Unsymmetrical Oligo-ureas of Metaphenylenediamine

artículo científico publicado en 2007

Synthesis of (-)-(S,S)-clemastine by invertive N --> C aryl migration in a lithiated carbamate

artículo científico publicado en 2010

Synthesis of (±)-kainic acid by dearomatising cyclisation of a lithiated N-benzyl p-anisamide

Synthesis of (−)-kainic acid using chiral lithium amides in an asymmetric dearomatizing cyclization

Synthesis of 1-Arylcycloalkenamines by Intramolecular Arylation of Lithiated Ureas

Synthesis of 2,2′,6-Trisubstituted and 2,2′,6,6′-Tetrasubstituted Diaryl Sulfides and Diaryl Sulfones by Copper-Promoted Coupling and/or Ortholithiation

Synthesis of Multiplyortho-Substituted Diaryl Ethers via Lithiation and Oxidation of a Dibenzosiloxane (Phenoxasilin)

Synthesis of a potent (±)-4-(2-hydroxyphenyl) analogue of the acromelic acids by dearomatising cyclisation of a lithiated N-p-methoxybenzyl-4-methoxy-1-naphthamide

Synthesis of atropisomeric 2-(1-aminoalkyl)-1-naphthamides by stereoselective addition of organolithiums to a 2-imino-1-naphthamide

Synthesis of atropisomeric diamides with remotely related stereogenic axes by stereoselective additions to imines

article

Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions

artículo científico publicado en 2007

Synthesis of enantiomerically enriched (R)-C-labelled 2-aminoisobutyric acid (Aib) by conformational memory in the alkylation of a derivative of L-alanine

artículo científico publicado en 2011

Synthesis of enantiomerically enriched isotopically-labelled anilines by (−)-sparteine directed lithiation

Synthesis of α-methyl kainic acid by stereospecific lithiation–dearomatizing cyclization of a chiral benzamide

article published in 2003

Tandem beta-alkylation-alpha-arylation of amines by carbolithiation and rearrangement of N-carbamoyl enamines (vinyl ureas).

artículo científico publicado en 2010

Tertiary Alcohols by Tandem β-Carbolithiation and N→C Aryl Migration in Enol Carbamates

scientific article published on 29 November 2011

Tertiary Thiols from Allylic Thiocarbamates by Tandem Enantioselective [3,3]-Sigmatropic Rearrangement and Stereospecific Arylation

artículo científico publicado en 2014

The First Crystallographic Evidence for the Structures ofortho-Lithiated Aromatic Tertiary Amides

article

The Mechanism of the Stereospecific Intramolecular Arylation of Lithiated Ureas: The Role of Li+ Probed by Electronic Structure Calculations, and by NMR and IR Spectroscopy

The N-terminal nonapeptide of cephaibols A and C: a naturally occurring example of mismatched helical screw-sense control

artículo científico publicado en 2013

The Role of Terminal Functionality in the Membrane and Antibacterial Activity of Peptaibol-Mimetic Aib Foldamers

artículo científico publicado en 2017

The Twisted Amide 2-Quinuclidone: 60 Years in the Making

artículo científico publicado en 2006

The Urea Renaissance

artículo científico publicado en 2011

The challenge of atropisomerism in drug discovery

artículo científico publicado en 2009

The meso Helix: Symmetry and Symmetry-Breaking in Dynamic Oligourea Foldamers with Reversible Hydrogen-Bond Polarity

artículo científico publicado en 2016

The meso Helix: Symmetry and Symmetry-Breaking in Dynamic Oligourea Foldamers with Reversible Hydrogen-Bond Polarity

The origin of the conformational preference of N,N'-diaryl-N,N'-dimethyl ureas

artículo científico publicado en 2010

The synthesis of (-)-isodomoic acid C.

artículo científico publicado en 2005

The synthesis of δ-hydroxy allylic phosphine oxides by palladium(II)-catalysed allylic transposition

scholarly article by Jonathan Clayden et al published November 1992 in Tetrahedron Letters

Thionoglycine as a multifunctional spectroscopic reporter of screw-sense preference in helical foldamers

artículo científico publicado en 2013

Three groups good, four groups bad? Atropisomerism in ortho-substituted diaryl ethers

Total Synthesis of Kainoids by Dearomatizing Anionic Cyclization

Transition Metal Free Cycloamination of Prenyl Carbamates and Ureas Promoted by Aryldiazonium Salts

Transition Metal Free Cycloamination of Prenyl Carbamates and Ureas Promoted by Aryldiazonium Salts

article published in 2018

Transmission of stereochemical information over nanometre distances in chemical reactions

scientific article published on 08 December 2008

Transmitting information along oligo-para-phenylenes: 1,12-stereochemical control in a terphenyl tetracarboxamide

artículo científico publicado en 2007

Ultra-remote stereocontrol by conformational communication of information along a carbon chain

artículo científico publicado en 2004

Using Dipoles to Control the Directionality of Functional Groups:Syn- andAnti-Oriented Benzene-1,3-dicarboxamides

artículo científico publicado en 2005

Using Symmetry to Monitor Geared Bond Rotation in Aromatic Amides by Dynamic NMR

scientific article published on 01 October 2000

Using amide conformation to ‘project’ the stereochemistry of an (−)-ephedrine-derived oxazolidine: a pair of pseudoenantiomeric chiral amido-phosphine ligands

Variations in the solid-state, solution and theoretical structures of a laterally deprotonated aromatic tertiary amide

ortho-Substituted unsymmetrical biaryls from aryl tert-butyl sulfones

α-Arylation of Cyclic Amines by Aryl Transfer in Lithiated Ureas

α-Methyl phenylglycines by asymmetric α-arylation of alanine and their effect on the conformational preference of helical Aib foldamers

artículo científico publicado en 2018

α-Pyridylation of Chiral Amines via Urea Coupling, Lithiation and Rearrangement

artículo científico publicado en 2008

α-Quaternary Proline Derivatives by Intramolecular Diastereoselective Arylation of N-Carboxamido Proline Ester Enolates

artículo científico publicado en 2015

β-Lactams or γ-lactams by 4-exo-trig or 5-endo-trig anionic cyclisation of lithiated acrylamide derivatives ⬇️

artículo científico publicado el 21 de octubre de 2003

‘meso-Selective’ functionalisation of N-benzyl-α-methylbenzylamine derivatives by α-lithiation and alkylation

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