Lista de obras - Jun Zhu - Dominio Público Uruguay

A Metallanaphthalyne Complex from Zinc Reduction of a Vinylcarbyne Complex

artículo científico publicado en 2007

Access to tetracyclic aromatics with bridgehead metals via metalla-click reactions

artículo científico publicado en 2020

Activation of the S−S Bonds of Alkyl Disulfides RSSR (R = Me, Et, Pr, Bun) by Heterodinuclear Phosphido-Bridged CpW(CO)2(μ-PPh2)Mo(CO)5

All-metal Baird aromaticity

scientific article published on 17 September 2020

An Unprecedented Ga/P Frustrated Lewis Pair: Synthesis, Characterization, and Reactivity

scientific article published on 17 October 2019

An isolable catenane consisting of two Möbius conjugated nanohoops

artículo científico publicado en 2018

An isotope (18O, 15N, and 2H) technique to investigate the metal ion interactions between the phosphoryl group and amino acid side chains by electrospray ionization mass spectrometry

artículo científico publicado en 2011

Are Hetero-metallapentalenes Aromatic or Not? A DFT Investigation

artículo científico publicado en 2020

Are Hetero-metallapentalenes Aromatic or Not? A DFT Investigation

scientific article published on 01 April 2020

Aromaticity effects on the profiles of the lowest triplet-state potential-energy surfaces for rotation about the C=C bonds of olefins with five-membered ring substituents: an example of the impact of Baird's rule

artículo científico publicado en 2013

Aromaticity-promoted C-F Bond Activation in Rhodium Complex: A Facile Tautomerization

scientific article published on 29 April 2019

Aromaticity-promoted CO2 Capture by P/N-Based Frustrated Lewis Pairs: A Theoretical Study

scientific article published on 17 December 2019

Bonded to Carbon or Nitrogen? This is a Question on the Regioselectivity in Hyperconjugative Aromaticity

artículo científico publicado en 2019

Chemoselectivity for B-O and B-H Bond Cleavage by Pincer-Type Phosphorus Compounds: Theoretical and Experimental Studies

artículo científico publicado en 2020

Concerted or stepwise mechanism? New insight into the water-mediated neutral hydrolysis of carbonyl sulfide

artículo científico publicado en 2014

Conversions of osmabenzyne and isoosmabenzene

artículo científico publicado en 2012

Cu-Catalyzed Aromatic Metamorphosis of 3-Aminoindazoles

scientific article published on 10 September 2019

Double role of the hydroxy group of phosphoryl in palladium(II)-catalyzed ortho-olefination: a combined experimental and theoretical investigation

artículo científico publicado en 2013

Dual Aromaticity in Both the T0 and S1 States: Osmapyridinium with Phosphonium Substituents

scientific article published on 28 March 2019

Evaluation of triplet aromaticity by the isomerization stabilization energy

artículo científico publicado en 2013

Facile η5-η1 ring slippage of the cycloolefin ligands in osmocene and bis(η5-indenyl)ruthenium(II).

artículo científico publicado en 2013

Formation of Iridium(III) Complexes via Selective Activation of the C-H and N-H Bonds of a Dipyridylpyrrole Ligand

artículo científico publicado en 2020

Fragmentation of pentacoordinate spirobicyclic aminoacyl-phosphoranes (P-AAs) by electrospray ionization tandem mass spectrometry concerning P-O and P-N bond cleavage

scientific article published on 01 October 2011

G2(+)M study on N-alkylamino cation affinities of neutral main-group element hydrides: trends across the periodic table

scientific article published on 29 April 2014

Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums

scientific article published on 10 December 2019

Insertion Reactions of Allenes Giving Vinyl Complexes

Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)

Isolation of an 11-Atom Polydentate Carbon Chain Chelate via Cycloaddition of Cyclic Metal Carbyne with Alkynes.

artículo científico publicado en 2018

Kinetic Control in the Synthesis of a Möbius Tris((ethynyl)[5]helicene) Macrocycle Using Alkyne Metathesis

scientific article published on 31 March 2020

Ligand Effect on the Insertion Reactions of Allenes with MHCl(CO)(PPh3)3and MHCl(PPh3)3(M = Ru, Os)

Mechanism, reactivity, and selectivity in Rh(III)-catalyzed phosphoryl-directed oxidative C-H activation/cyclization: a DFT study.

artículo científico publicado en 2014

Mechanistic insight into the CO2 capture by amidophosphoranes: interplay of the ring strain and the trans influence determines the reactivity of the frustrated Lewis pairs.

artículo científico publicado en 2013

Mechanistic insight into the copper-catalyzed phosphorylation of terminal alkynes: a combined theoretical and experimental study.

artículo científico publicado en 2014

Mechanistic insight into the nickel-catalyzed cross-coupling of aryl phosphates with arylboronic acids: potassium phosphate is not a spectator base but is involved in the transmetalation step in the Suzuki-Miyaura reaction

artículo científico publicado en 2013

Multiyne chains chelating osmium via three metal-carbon σ bonds

artículo científico publicado en 2017

Ni(II)/Zn Catalyzed Reductive Coupling of Aryl Halides with Diphenylphosphine Oxide in Water ⬇️

artículo científico publicado el 27 de mayo de 2011

One-pot synthesis of pyrazoles through a four-step cascade sequence

artículo científico publicado en 2013

Osmabenzenes from the Reactions of a Dicationic Osmabenzyne Complex

artículo científico publicado en 2006

Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of α-fluorophosphonates.

artículo científico publicado en 2014

Predicting an Antiaromatic Benzene Ring in the Ground State Caused by Hyperconjugation

scientific article published on 06 November 2019

Predicting an unconventional facile route to metallaanthracenes.

artículo científico publicado en 2018

Probing Reaction Mechanism of [1,5]-Migration in Pyrrolium and Pyrrole Derivatives: Activation of a Stronger Bond in Electropositive Groups Becomes Easier

artículo científico publicado en 2019

Probing the Most Aromatic and Antiaromatic Pyrrolium Rings by Maximizing Hyperconjugation and Push-Pull Effect

artículo científico publicado en 2018

Probing the Origin of Adaptive Aromaticity in 16-Valence-Electron Metallapentalenes

artículo científico publicado en 2020

Probing the Origin of Challenge of Realizing Metallaphosphabenzenes: Unfavorable 1,2-Migration in Metallapyridines Becomes Feasible in Metallaphosphabenzenes

artículo científico publicado en 2016

Probing the reactivity of microhydrated α-nucleophile in the anionic gas-phase S(N)2 reaction

artículo científico publicado en 2015

Probing the tautomerization of disilenes and disilabenzenes with their isomeric silylenes: significant substituent, aromaticity and base effects

artículo científico publicado en 2020

Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity.

artículo científico publicado en 2017

Rational Design of a Carbon-Boron Frustrated Lewis Pair for Metal-free Dinitrogen Activation

scientific article published on 12 March 2019

Rational design of the nickel‐borane complex for efficient hydrogenation of styrene

artículo científico publicado en 2021

Reaction Mechanisms on Unusual 1,2-Migrations of N-Heterocyclic Carbene-Ligated Transition Metal Complexes

scientific article published on 29 August 2019

Reactions of Hydrotris(pyrazolyl)borate (Tp)-Supported Ruthenium Dihydrogen Complexes [TpRu(L2)(H2)]+(L2= dppm, dppp, (PPh3)2) with O2

Reactions of [Cp*Ru(H2O)(NBD)]+with Dihydrogen, Silanes, Olefins, Alkynes, and Allenes

Reactivity of Germylene toward Phosphorus-Containing Compounds: Nucleophilic Addition and Tautomerism.

artículo científico publicado en 2015

Redox Neutral Radical-Relay Cobalt Catalysis toward C-H Fluorination and Amination

scientific article published on 20 April 2020

Requirement for an Oxidant in Pd/Cu Co-Catalyzed Terminal Alkyne Homocoupling To Give Symmetrical 1,4-Disubstituted 1,3-Diynes

artículo científico publicado en 2005

Screening Borane Species for Dinitrogen Activation

artículo científico publicado en 2020

Silicon-containing formal 4π-electron four-membered ring systems: antiaromatic, aromatic, or nonaromatic?

artículo científico publicado en 2012

Stability, Reactivity, Selectivity, Catalysis, and Predictions of 1,3,2,5-Diazadiborinine: Computational Insight into a Boron-Boron Frustrated Lewis Pair

scientific article published on 24 August 2015

Synthesis of aromatic aza-metallapentalenes from metallabenzene via sequential ring contraction/annulation

artículo científico publicado en 2015

Synthesis of aromatic ruthenabenzothiophenes via C-H activation of thiophenes.

artículo científico publicado en 2015

Synthesis of digermylene-stabilized linear tetraboronate and boroxine.

artículo científico publicado en 2015

Synthesis of five-membered osmacycloallenes and conversion into six-membered osmacycloallenes

artículo científico publicado en 2013

Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums

artículo científico publicado en 2016

The Clar Structure in Inorganic BN Analogues of Polybenzenoid Hydrocarbons: Does it Exist or Not?

artículo científico publicado en 2015

The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions.

artículo científico publicado en 2014

Theoretical Investigation of Alkyne Metathesis Catalyzed by W/Mo Alkylidyne Complexes

Theoretical study on the stability and aromaticity in silapentafulvenes towards triplet ground state species

scientific article published on 01 February 2020

Theoretical study on the stability of osmasilabenzynes

artículo científico publicado en 2014

Trans Influence of Boryl Ligands and Comparison with C, Si, and Sn Ligands

scientific article published on 01 December 2005

Tuning the Properties of Corannulene-Based Polycyclic Aromatic Hydrocarbons by Varying the Fusing Positions of Corannulene

artículo científico publicado en 2020

Unconventional Aromaticity in Organometallics: The Power of Transition Metals

scientific article published on 07 May 2019

Understanding Nonplanarity in Metallabenzene Complexes

Unexpected 1,2-migration in metallasilabenzenes: theoretical evidence for reluctance of silicon to participate in π bonding

artículo científico publicado en 2014

Unexpected higher stabilisation of two classical antiaromatic frameworks with a ruthenium fragment compared to the osmium counterpart: origin probed by DFT calculations

artículo científico publicado en 2015

β-Hydrogen Elimination of Five-Membered-Ring Metallacycles. Is It Possible?

σ Aromaticity Dominates in the Unsaturated Three-Membered Ring of Cyclopropametallapentalenes from Groups 7-9: A DFT Study.

artículo científico publicado en 2015

σ-Aromaticity in a Fully Unsaturated Ring

scientific article published on 31 October 2018

Lista de obras de Jun Zhu

A Metallanaphthalyne Complex from Zinc Reduction of a Vinylcarbyne Complex

Access to tetracyclic aromatics with bridgehead metals via metalla-click reactions

Activation of the S−S Bonds of Alkyl Disulfides RSSR (R = Me, Et, Pr, Bun) by Heterodinuclear Phosphido-Bridged CpW(CO)2(μ-PPh2)Mo(CO)5

All-metal Baird aromaticity

An Unprecedented Ga/P Frustrated Lewis Pair: Synthesis, Characterization, and Reactivity

An isolable catenane consisting of two Möbius conjugated nanohoops

An isotope (18O, 15N, and 2H) technique to investigate the metal ion interactions between the phosphoryl group and amino acid side chains by electrospray ionization mass spectrometry

Are Hetero-metallapentalenes Aromatic or Not? A DFT Investigation

Are Hetero-metallapentalenes Aromatic or Not? A DFT Investigation

Aromaticity effects on the profiles of the lowest triplet-state potential-energy surfaces for rotation about the C=C bonds of olefins with five-membered ring substituents: an example of the impact of Baird's rule

Aromaticity-promoted C-F Bond Activation in Rhodium Complex: A Facile Tautomerization

Aromaticity-promoted CO2 Capture by P/N-Based Frustrated Lewis Pairs: A Theoretical Study

Bonded to Carbon or Nitrogen? This is a Question on the Regioselectivity in Hyperconjugative Aromaticity

Chemoselectivity for B-O and B-H Bond Cleavage by Pincer-Type Phosphorus Compounds: Theoretical and Experimental Studies

Concerted or stepwise mechanism? New insight into the water-mediated neutral hydrolysis of carbonyl sulfide

Conversions of osmabenzyne and isoosmabenzene

Cu-Catalyzed Aromatic Metamorphosis of 3-Aminoindazoles

Double role of the hydroxy group of phosphoryl in palladium(II)-catalyzed ortho-olefination: a combined experimental and theoretical investigation

Dual Aromaticity in Both the T0 and S1 States: Osmapyridinium with Phosphonium Substituents

Evaluation of triplet aromaticity by the isomerization stabilization energy

Facile η5-η1 ring slippage of the cycloolefin ligands in osmocene and bis(η5-indenyl)ruthenium(II).

Formation of Iridium(III) Complexes via Selective Activation of the C-H and N-H Bonds of a Dipyridylpyrrole Ligand

Fragmentation of pentacoordinate spirobicyclic aminoacyl-phosphoranes (P-AAs) by electrospray ionization tandem mass spectrometry concerning P-O and P-N bond cleavage

G2(+)M study on N-alkylamino cation affinities of neutral main-group element hydrides: trends across the periodic table

Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums

Insertion Reactions of Allenes Giving Vinyl Complexes

Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)

Isolation of an 11-Atom Polydentate Carbon Chain Chelate via Cycloaddition of Cyclic Metal Carbyne with Alkynes.

Kinetic Control in the Synthesis of a Möbius Tris((ethynyl)[5]helicene) Macrocycle Using Alkyne Metathesis

Ligand Effect on the Insertion Reactions of Allenes with MHCl(CO)(PPh3)3and MHCl(PPh3)3(M = Ru, Os)

Mechanism, reactivity, and selectivity in Rh(III)-catalyzed phosphoryl-directed oxidative C-H activation/cyclization: a DFT study.

Mechanistic insight into the CO2 capture by amidophosphoranes: interplay of the ring strain and the trans influence determines the reactivity of the frustrated Lewis pairs.

Mechanistic insight into the copper-catalyzed phosphorylation of terminal alkynes: a combined theoretical and experimental study.

Mechanistic insight into the nickel-catalyzed cross-coupling of aryl phosphates with arylboronic acids: potassium phosphate is not a spectator base but is involved in the transmetalation step in the Suzuki-Miyaura reaction

Multiyne chains chelating osmium via three metal-carbon σ bonds

Ni(II)/Zn Catalyzed Reductive Coupling of Aryl Halides with Diphenylphosphine Oxide in Water ⬇️

One-pot synthesis of pyrazoles through a four-step cascade sequence

Osmabenzenes from the Reactions of a Dicationic Osmabenzyne Complex

Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of α-fluorophosphonates.

Predicting an Antiaromatic Benzene Ring in the Ground State Caused by Hyperconjugation

Predicting an unconventional facile route to metallaanthracenes.

Probing Reaction Mechanism of [1,5]-Migration in Pyrrolium and Pyrrole Derivatives: Activation of a Stronger Bond in Electropositive Groups Becomes Easier

Probing the Most Aromatic and Antiaromatic Pyrrolium Rings by Maximizing Hyperconjugation and Push-Pull Effect

Probing the Origin of Adaptive Aromaticity in 16-Valence-Electron Metallapentalenes

Probing the Origin of Challenge of Realizing Metallaphosphabenzenes: Unfavorable 1,2-Migration in Metallapyridines Becomes Feasible in Metallaphosphabenzenes

Probing the reactivity of microhydrated α-nucleophile in the anionic gas-phase S(N)2 reaction

Probing the tautomerization of disilenes and disilabenzenes with their isomeric silylenes: significant substituent, aromaticity and base effects

Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity.

Rational Design of a Carbon-Boron Frustrated Lewis Pair for Metal-free Dinitrogen Activation

Rational design of the nickel‐borane complex for efficient hydrogenation of styrene

Reaction Mechanisms on Unusual 1,2-Migrations of N-Heterocyclic Carbene-Ligated Transition Metal Complexes

Reactions of Hydrotris(pyrazolyl)borate (Tp)-Supported Ruthenium Dihydrogen Complexes [TpRu(L2)(H2)]+(L2= dppm, dppp, (PPh3)2) with O2

Reactions of [Cp*Ru(H2O)(NBD)]+with Dihydrogen, Silanes, Olefins, Alkynes, and Allenes

Reactivity of Germylene toward Phosphorus-Containing Compounds: Nucleophilic Addition and Tautomerism.

Redox Neutral Radical-Relay Cobalt Catalysis toward C-H Fluorination and Amination

Requirement for an Oxidant in Pd/Cu Co-Catalyzed Terminal Alkyne Homocoupling To Give Symmetrical 1,4-Disubstituted 1,3-Diynes

Screening Borane Species for Dinitrogen Activation

Silicon-containing formal 4π-electron four-membered ring systems: antiaromatic, aromatic, or nonaromatic?

Stability, Reactivity, Selectivity, Catalysis, and Predictions of 1,3,2,5-Diazadiborinine: Computational Insight into a Boron-Boron Frustrated Lewis Pair

Synthesis of aromatic aza-metallapentalenes from metallabenzene via sequential ring contraction/annulation

Synthesis of aromatic ruthenabenzothiophenes via C-H activation of thiophenes.

Synthesis of digermylene-stabilized linear tetraboronate and boroxine.

Synthesis of five-membered osmacycloallenes and conversion into six-membered osmacycloallenes

Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums

The Clar Structure in Inorganic BN Analogues of Polybenzenoid Hydrocarbons: Does it Exist or Not?

The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions.

Theoretical Investigation of Alkyne Metathesis Catalyzed by W/Mo Alkylidyne Complexes

Theoretical study on the stability and aromaticity in silapentafulvenes towards triplet ground state species

Theoretical study on the stability of osmasilabenzynes

Trans Influence of Boryl Ligands and Comparison with C, Si, and Sn Ligands

Tuning the Properties of Corannulene-Based Polycyclic Aromatic Hydrocarbons by Varying the Fusing Positions of Corannulene

Unconventional Aromaticity in Organometallics: The Power of Transition Metals

Understanding Nonplanarity in Metallabenzene Complexes

Unexpected 1,2-migration in metallasilabenzenes: theoretical evidence for reluctance of silicon to participate in π bonding

Unexpected higher stabilisation of two classical antiaromatic frameworks with a ruthenium fragment compared to the osmium counterpart: origin probed by DFT calculations

β-Hydrogen Elimination of Five-Membered-Ring Metallacycles. Is It Possible?

σ Aromaticity Dominates in the Unsaturated Three-Membered Ring of Cyclopropametallapentalenes from Groups 7-9: A DFT Study.

σ-Aromaticity in a Fully Unsaturated Ring