Lista de obras - Enrique Oñate - Dominio Público Uruguay

(NHC)Palladium Complexes from Hydroxy-Functionalized Imidazolium Salts as Catalyst for the Microwave-Accelerated Fluorine-Free Hiyama Reaction

artículo científico publicado en 2011

2-Azetidinones as Precursors of Pincer Ligands: Preparation, Structure, and Spectroscopic Properties of CC'N-Osmium Complexes.

artículo científico publicado en 2015

A Capped Octahedral MHC6 Compound of a Platinum Group Metal

artículo científico publicado en 2016

Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes

artículo científico publicado en 2015

Ammonia Borane Dehydrogenation Promoted by a Pincer-Square-Planar Rhodium(I) Monohydride: A Stepwise Hydrogen Transfer from the Substrate to the Catalyst

artículo científico publicado en 2016

An Entry to Stable Mixed Phosphine-Osmium-NHC Polyhydrides

artículo científico publicado en 2016

Arene Osmium Complexes with Ethacrynic Acid-Modified Ligands: Synthesis, Characterization, and Evaluation of Intracellular Glutathione S-Transferase Inhibition and Antiproliferative Activity

scholarly article by Gabriele Agonigi et al published 25 March 2016 in Organometallics

Aromatic C−H Bond Activation of 2-Methylpyridine Promoted by an Osmium(VI) Complex: Formation of an η2(N,C)-Pyridyl Derivative

artículo científico publicado en 2008

Aromatic Osmacyclopropenefuran Bicycles and Their Relevance for the Metal-Mediated Hydration of Functionalized Allenes

scientific article published on 04 October 2016

Aromatic diosmatricyclic nitrogen-containing compounds

artículo científico publicado en 2008

Assembly of an allenylidene ligand, a terminal alkyne, and an acetonitrile molecule: formation of osmacyclopentapyrrole derivatives

scientific article published on 01 March 2006

Azole Assisted C–H Bond Activation Promoted by an Osmium-Polyhydride: Discerning between N and NH

artículo científico publicado en 2015

B-H activation and H-H formation: two consecutive heterolytic processes on an osmium-hydrogensulfide bond.

artículo científico publicado en 2013

Base-Free and Acceptorless Dehydrogenation of Alcohols Catalyzed by an Iridium Complex Stabilized by a N,N,N-Osmaligand

artículo científico publicado en 2018

Behavior of OsH2Cl2(PiPr3)2in Acetonitrile: The Importance of the Small Details

artículo científico publicado en 2009

Borinium cations as sigma-B-H ligands in osmium complexes.

artículo científico publicado en 2010

C(sp2)−H Activation of RCHE−py (E = CH, N) and RCHCHC(O)R‘ Substrates Promoted by a Highly Unsaturated Osmium−Monohydride Complex

artículo científico publicado en 2005

C-H activations at iridium(I) square-planar complexes promoted by a fifth ligand

artículo científico publicado en 2005

C-H bond activation and subsequent C-C bond formation promoted by osmium: 2-vinylpyridine-acetylene couplings

artículo científico publicado en 2006

CCC–Pincer–NHC Osmium Complexes: New Types of Blue-Green Emissive Neutral Compounds for Organic Light-Emitting Devices (OLEDs)

artículo científico publicado en 2014

Catalytic Cyclization of o-Alkynyl Phenethylamines via Osmacyclopropene Intermediates: Direct Access to Dopaminergic 3-Benzazepines

artículo científico publicado en 2015

Chelated Assisted Metal-Mediated N–H Bond Activation of β-Lactams: Preparation of Irida-, Rhoda-, Osma-, and Ruthenatrinems

artículo científico publicado en 2014

Cleavage of both C(sp3)-C(sp2) bonds of alkylidenecyclopropanes: formation of ethylene-osmium-vinylidene complexes.

artículo científico publicado en 2010

Coordination and Rupture of Methyl C(sp3)−H Bonds in Osmium−Polyhydride Complexes with δ Agostic Interaction

artículo científico publicado en 2007

Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity

artículo científico publicado en 2019

Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands

artículo científico publicado en 2008

Cβ−H Activation of Aldehydes Promoted by an Osmium Complex

artículo científico publicado en 2004

C–H Bond Activation Reactions in Ketones and Aldehydes Promoted by POP-Pincer Osmium and Ruthenium Complexes

scholarly article by Joaquín Alós et al published 24 September 2015 in Organometallics

C−C Bond Activation of the NHC Ligand of an Osmium−Amido Complex

artículo científico publicado en 2010

Dehydrative cyclization of alkynals: vinylidene complexes with the Cβ incorporated into unsaturated five- or six-membered rings

artículo científico publicado en 2011

Dehydrogenation of Formic Acid Promoted by a Trihydride-Hydroxo-Osmium(IV) Complex: Kinetics and Mechanism

scholarly article by Miguel A. Esteruelas et al published 22 October 2018 in ACS Catalysis

Dihydride versus Elongated Dihydrogen in [H2Os(κ2-O2CCH3)L(PiPr3)2]+Complexes: Influence of the L Ligand

artículo científico publicado en 2002

Dioxygen activation by an osmium-dihydride: preparation and characterization of a d4 square-planar complex

artículo científico publicado en 2003

Direct Access to POP-Type Osmium(II) and Osmium(IV) Complexes: Osmium a Promising Alternative to Ruthenium for the Synthesis of Imines from Alcohols and Amines

artículo científico publicado en 2011

Direct C-H Borylation of Arenes Catalyzed by Saturated Hydride-Boryl-Iridium-POP Complexes: Kinetic Analysis of the Elemental Steps

scientific article published on 19 May 2020

Displacement of Phenyl and Styryl Ligands by Benzophenone Imine and 2-Vinylpyridine on Ruthenium and Osmium

artículo científico publicado en 2006

Electronic Communication in Binuclear Osmium- and Iridium-Polyhydrides

artículo científico publicado en 2021

Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes.

artículo científico publicado en 2016

Elongated σ-Borane versus σ-Borane in Pincer–POP–Osmium Complexes

scholarly article by Miguel A. Esteruelas et al published 13 June 2017 in Organometallics

Evidence for a Bis(Elongated σ)-Dihydrideborate Coordinated to Osmium.

artículo científico publicado en 2018

Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents

scientific article published on 01 August 2003

From tetrahydroborate- to aminoborylvinylidene-osmium complexes via alkynyl-aminoboryl intermediates

scientific article published on 27 January 2011

Homo- and hetero-binuclear complexes containing the anion [Rh(C5Me5){PO(OMe)2}2(pyrazolate)]–as ligand. Crystal structure of [(C5Me5)Rh{µ-PO(OMe)2}2(µ-C3H3N2)-Ru(C6H6)]ClO4·CH2Cl2

Hydride-alkenylcarbyne to alkenylcarbene transformation in bisphosphine-osmium complexes.

artículo científico publicado en 2005

Influence of the Anion of the Salt Used on the Coordination Mode of an N-Heterocyclic Carbene Ligand to Osmium

artículo científico publicado en 2007

Insertion of Unsaturated C-C Bonds into the O-H Bond of an Iridium(III)-Hydroxo Complex: Formation of Phosphorescent Emitters with an Asymmetrical β-Diketonate Ligand

scientific article published on 15 October 2020

Iridium-Promoted B-B Bond Activation: Preparation and X-ray Diffraction Analysis of a mer-Tris(boryl) Complex

scientific article published on 27 March 2019

Kinetic Analysis and Sequencing of Si-H and C-H Bond Activation Reactions: Direct Silylation of Arenes Catalyzed by an Iridium-Polyhydride

artículo científico publicado en 2020

Mechanistic Insight into the Facilitation of β-Lactam Fragmentation through Metal Assistance

Monocationic trihydride and dicationic dihydride-dihydrogen and bis(dihydrogen) osmium complexes containing cyclic and acyclic triamine ligands: influence of the N-Os-N angles on the hydrogen-hydrogen interactions.

artículo científico publicado en 2009

Multiple C−H Bond Activation of Phenyl-Substituted Pyrimidines and Triazines Promoted by an Osmium Polyhydride: Formation of Osmapolycycles with Three, Five, and Eight Fused Rings

artículo científico publicado en 2010

N-h and N-C bond activation of pyrimidinic nucleobases and nucleosides promoted by an osmium polyhydride

artículo científico publicado en 2012

NH-Tautomerization of Quinolines and 2-Methylpyridine Promoted by a Hydride-Iridium(III) Complex: Importance of the Hydride Ligand

artículo científico publicado en 2009

Nazarov type cyclization on an osmium-dienylcarbene complex

artículo científico publicado en 2009

One-Pot Dehydrogenative Addition of Isopropyl to Alkynes Promoted by Osmium: Formation of γ-(η3-Allyl)-α-Alkenylphosphine Derivatives Starting from a Dihydride−Dihydrogen−Triisopropylphosphine Complex

artículo científico publicado en 2007

Osmium Hydride Acetylacetonate Complexes and Their Application in Acceptorless Dehydrogenative Coupling of Alcohols and Amines and for the Dehydrogenation of Cyclic Amines

artículo científico publicado en 2017

Osmium NHC Complexes from Alcohol-Functionalized Imidazoles and Imidazolium Salts

artículo científico publicado en 2011

Osmium(II) Complexes Containing a Dianionic CCCC-Donor Tetradentate Ligand

artículo científico publicado en 2016

Osmium-Catalyzed Allylic Alkylation

scholarly article by Miguel A. Esteruelas et al published 13 October 2008 in Organometallics

Osmium-Centered Oxetylidene: Formation and Cleavage

scholarly article by María Batuecas et al published 28 November 2012 in Organometallics

Osmium−Allenylidene Complexes Containing an N-Heterocyclic Carbene Ligand

artículo científico publicado en 2008

Oxidative Addition of Group 14 Element Hydrido Compounds to OsH(2)(eta(2)-CH(2)=CHEt)(CO)(P(i)Pr(3))(2): Synthesis and Characterization of the First Trihydrido-Silyl, Trihydrido-Germyl, and Trihydrido-Stannyl Derivatives of Osmium(IV)

scientific article published on 01 February 1996

POP-pincer osmium-polyhydrides: head-to-head (Z)-dimerization of terminal alkynes

artículo científico publicado en 2013

POP-pincer ruthenium complexes: d(6) counterparts of osmium d(4) species.

artículo científico publicado en 2014

Phosphorescent Iridium(III) Complexes with a Dianionic C,C',N,N'-Tetradentate Ligand

artículo científico publicado en 2020

Preparation and Photophysical Properties of Bis(tridentate) Iridium(III) Emitters: Pincer Coordination of 2,6-Di(2-pyridyl)phenyl

artículo científico publicado en 2020

Preparation and characterization of novel Os-diolefin dimers: new entry to Os-cyclooctadiene complexes

artículo científico publicado en 2006

Preparation of Half-Sandwich Osmium-Allyl Complexes by Consecutive C−C Bond Formation and C−H Bond Activation Reactions

artículo científico publicado en 2006

Preparation of Phosphorescent Iridium(III) Complexes with a Dianionic C,C,C,C-Tetradentate Ligand.

artículo científico publicado en 2018

Preparation of Phosphorescent Osmium(IV) Complexes with N,N′,C- and C,N,C′-Pincer Ligands

artículo científico publicado en 2017

Preparation of Tris-Heteroleptic Iridium(III) Complexes Containing a Cyclometalated Aryl-N-Heterocyclic Carbene Ligand

artículo científico publicado en 2018

Preparation, Spectroscopic Characterization, X-ray Structure, and Theoretical Investigation of Hydride−, Dihydrogen−, and Acetone−OsTp Complexes: A Hydridotris(pyrazolyl)borate−Cyclopentadienyl Comparison

artículo científico publicado en 2007

Reaction of a Cationic Osmium(IV) Dihydride with Ethylene: Formation and Structure of the Novel Tetraethylene Dimer Complex [{(PiPr3)(η2-C2H4)2Os}2(μ-OH)2(μ-O2CCH3)]BF4

artículo científico publicado en 2000

Reactions of New Osmium−Dihydride Complexes with Terminal Alkynes: Metallacyclopropene versus Metal−Carbyne. Influence of the Alkyne Substituent

scholarly article by María L. Buil et al published November 1999 in Organometallics

Reactions of an Osmium(IV)-Hydroxo Complex with Amino-Boranes: Formation of Boroxide Derivatives

scholarly article by Antonio Antiñolo et al published 21 November 2018 in Organometallics

Redox Isomerization of Allylic Alcohols Catalyzed by Osmium and Ruthenium Complexes Containing a Cyclopentadienyl Ligand with a Pendant Amine or Phosphoramidite Group: X-ray Structure of an η3-1-Hydroxyallyl-Metal-Hydride Intermediate

scholarly article by María Batuecas et al published 10 May 2010 in Organometallics

Reduction and C(sp2)−H Bond Activation of Ketones Promoted by a Cyclopentadienyl-Osmium- Dihydride-Dihydrogen Complex

artículo científico publicado en 2005

Reduction of Benzonitriles via Osmium-Azavinylidene Intermediates Bearing Nucleophilic and Electrophilic Centers

artículo científico publicado en 2019

Ruthenium Hydroxycarbenes as Key Intermediates in Cycloisomerization and Decarbonylative Cyclization of Terminal Alkynals

Ruthenium-catalyzed (2 + 2) intramolecular cycloaddition of allenenes

artículo científico publicado en 2011

Sequential and selective hydrogenation of the C(alpha)-C(beta) and M-C(alpha) double bonds of an allenylidene ligand coordinated to osmium: new reaction patterns between an allenylidene complex and alcohols

artículo científico publicado en 2007

Sequential protonation and methylation of a hydride-osmium complex containing a cyclopentadienyl ligand with a pendant amine group.

artículo científico publicado en 2005

Seven-Coordinate Dihydrido Complex OsH2(κ2-O2CCH3){κ1-OC(O)CH3}(PiPr3)2as Precursor of New Organometallic Compounds Containing Unsaturated η1-Carbon Ligands

artículo científico publicado en 1998

Square-Planar Alkylidyne-Osmium and Five-Coordinate Alkylidene-Osmium Complexes: Controlling the Transformation from Hydride-Alkylidyne to Alkylidene

artículo científico publicado en 2016

Stoichiometric and Catalytic Deuteration of Pyridine and Methylpyridines by H/D Exchange with Benzene-d6Promoted by an Unsaturated Osmium Tetrahydride Species

artículo científico publicado en 2009

Synthesis of Hydrido−Vinylidene and Hydrido−Carbyne Osmium Complexes Containing Pyrazole: New Examples of N−H···Y (Y = N, F, Cl) Hydrogen Bonds

artículo científico publicado en 1999

The Allenylidene Complex [Ru(η5-C5H5)(CCCPh2)(CO)(PiPr3)]BF4as a Precursor of Novel Pyrido[1,2-a]pyrimidinyl and 1,3-Thiazinyl Complexes

artículo científico publicado en 2000

The Dihydride−Osmium(IV) Complex [OsH2(κ2-O2CCH3)(H2O)(PiPr3)2]BF4 as a Precursor for Carbon−Carbon Coupling Reactions

artículo científico publicado en 2000

Thermally Activated Site Exchange and Quantum Exchange Coupling Processes in Unsymmetrical Trihydride Osmium Compounds

scientific article published on 01 April 1999

Tuning the Nature and Formation of Bis(dihydrogen)–Osmium Species

artículo científico publicado en 2018

Understanding the formation of N-H tautomers from alpha-substituted pyridines: tautomerization of 2-ethylpyridine promoted by osmium

scientific article published on 16 August 2007

[H(EtOH)2][{OsCl(η4-COD)}2(μ-H)(μ-Cl)2] as an Intermediate for the Preparation of [OsCl2(COD)]xand Its Activity as an Ionic Hydrogenation and Etherification Catalyst

mer, fac, and Bidentate Coordination of an Alkyl-POP Ligand in the Chemistry of Nonclassical Osmium Hydrides.

artículo científico publicado en 2016

β-Borylalkenyl Z–E Isomerization in Rhodium-Mediated Diboration of Nonfunctionalized Internal Alkynes

artículo científico publicado en 2018

η1 -Arene Complexes as Intermediates in the Preparation of Molecular Phosphorescent Iridium(III) Complexes.

artículo científico publicado en 2017

Lista de obras de Enrique Oñate

(NHC)Palladium Complexes from Hydroxy-Functionalized Imidazolium Salts as Catalyst for the Microwave-Accelerated Fluorine-Free Hiyama Reaction

2-Azetidinones as Precursors of Pincer Ligands: Preparation, Structure, and Spectroscopic Properties of CC'N-Osmium Complexes.

A Capped Octahedral MHC6 Compound of a Platinum Group Metal

Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes

Ammonia Borane Dehydrogenation Promoted by a Pincer-Square-Planar Rhodium(I) Monohydride: A Stepwise Hydrogen Transfer from the Substrate to the Catalyst

An Entry to Stable Mixed Phosphine-Osmium-NHC Polyhydrides

Arene Osmium Complexes with Ethacrynic Acid-Modified Ligands: Synthesis, Characterization, and Evaluation of Intracellular Glutathione S-Transferase Inhibition and Antiproliferative Activity

Aromatic C−H Bond Activation of 2-Methylpyridine Promoted by an Osmium(VI) Complex: Formation of an η2(N,C)-Pyridyl Derivative

Aromatic Osmacyclopropenefuran Bicycles and Their Relevance for the Metal-Mediated Hydration of Functionalized Allenes

Aromatic diosmatricyclic nitrogen-containing compounds

Assembly of an allenylidene ligand, a terminal alkyne, and an acetonitrile molecule: formation of osmacyclopentapyrrole derivatives

Azole Assisted C–H Bond Activation Promoted by an Osmium-Polyhydride: Discerning between N and NH

B-H activation and H-H formation: two consecutive heterolytic processes on an osmium-hydrogensulfide bond.

Base-Free and Acceptorless Dehydrogenation of Alcohols Catalyzed by an Iridium Complex Stabilized by a N,N,N-Osmaligand

Behavior of OsH2Cl2(PiPr3)2in Acetonitrile: The Importance of the Small Details

Borinium cations as sigma-B-H ligands in osmium complexes.

C(sp2)−H Activation of RCHE−py (E = CH, N) and RCHCHC(O)R‘ Substrates Promoted by a Highly Unsaturated Osmium−Monohydride Complex

C-H activations at iridium(I) square-planar complexes promoted by a fifth ligand

C-H bond activation and subsequent C-C bond formation promoted by osmium: 2-vinylpyridine-acetylene couplings

CCC–Pincer–NHC Osmium Complexes: New Types of Blue-Green Emissive Neutral Compounds for Organic Light-Emitting Devices (OLEDs)

Catalytic Cyclization of o-Alkynyl Phenethylamines via Osmacyclopropene Intermediates: Direct Access to Dopaminergic 3-Benzazepines

Chelated Assisted Metal-Mediated N–H Bond Activation of β-Lactams: Preparation of Irida-, Rhoda-, Osma-, and Ruthenatrinems

Cleavage of both C(sp3)-C(sp2) bonds of alkylidenecyclopropanes: formation of ethylene-osmium-vinylidene complexes.

Coordination and Rupture of Methyl C(sp3)−H Bonds in Osmium−Polyhydride Complexes with δ Agostic Interaction

Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity

Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands

Cβ−H Activation of Aldehydes Promoted by an Osmium Complex

C–H Bond Activation Reactions in Ketones and Aldehydes Promoted by POP-Pincer Osmium and Ruthenium Complexes

C−C Bond Activation of the NHC Ligand of an Osmium−Amido Complex

Dehydrative cyclization of alkynals: vinylidene complexes with the Cβ incorporated into unsaturated five- or six-membered rings

Dehydrogenation of Formic Acid Promoted by a Trihydride-Hydroxo-Osmium(IV) Complex: Kinetics and Mechanism

Dihydride versus Elongated Dihydrogen in [H2Os(κ2-O2CCH3)L(PiPr3)2]+Complexes: Influence of the L Ligand

Dioxygen activation by an osmium-dihydride: preparation and characterization of a d4 square-planar complex

Direct Access to POP-Type Osmium(II) and Osmium(IV) Complexes: Osmium a Promising Alternative to Ruthenium for the Synthesis of Imines from Alcohols and Amines

Direct C-H Borylation of Arenes Catalyzed by Saturated Hydride-Boryl-Iridium-POP Complexes: Kinetic Analysis of the Elemental Steps

Displacement of Phenyl and Styryl Ligands by Benzophenone Imine and 2-Vinylpyridine on Ruthenium and Osmium

Electronic Communication in Binuclear Osmium- and Iridium-Polyhydrides

Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes.

Elongated σ-Borane versus σ-Borane in Pincer–POP–Osmium Complexes

Evidence for a Bis(Elongated σ)-Dihydrideborate Coordinated to Osmium.

Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents

From tetrahydroborate- to aminoborylvinylidene-osmium complexes via alkynyl-aminoboryl intermediates

Homo- and hetero-binuclear complexes containing the anion [Rh(C5Me5){PO(OMe)2}2(pyrazolate)]–as ligand. Crystal structure of [(C5Me5)Rh{µ-PO(OMe)2}2(µ-C3H3N2)-Ru(C6H6)]ClO4·CH2Cl2

Hydride-alkenylcarbyne to alkenylcarbene transformation in bisphosphine-osmium complexes.

Influence of the Anion of the Salt Used on the Coordination Mode of an N-Heterocyclic Carbene Ligand to Osmium

Insertion of Unsaturated C-C Bonds into the O-H Bond of an Iridium(III)-Hydroxo Complex: Formation of Phosphorescent Emitters with an Asymmetrical β-Diketonate Ligand

Iridium-Promoted B-B Bond Activation: Preparation and X-ray Diffraction Analysis of a mer-Tris(boryl) Complex

Kinetic Analysis and Sequencing of Si-H and C-H Bond Activation Reactions: Direct Silylation of Arenes Catalyzed by an Iridium-Polyhydride

Mechanistic Insight into the Facilitation of β-Lactam Fragmentation through Metal Assistance

Monocationic trihydride and dicationic dihydride-dihydrogen and bis(dihydrogen) osmium complexes containing cyclic and acyclic triamine ligands: influence of the N-Os-N angles on the hydrogen-hydrogen interactions.

Multiple C−H Bond Activation of Phenyl-Substituted Pyrimidines and Triazines Promoted by an Osmium Polyhydride: Formation of Osmapolycycles with Three, Five, and Eight Fused Rings

N-h and N-C bond activation of pyrimidinic nucleobases and nucleosides promoted by an osmium polyhydride

NH-Tautomerization of Quinolines and 2-Methylpyridine Promoted by a Hydride-Iridium(III) Complex: Importance of the Hydride Ligand

Nazarov type cyclization on an osmium-dienylcarbene complex

One-Pot Dehydrogenative Addition of Isopropyl to Alkynes Promoted by Osmium: Formation of γ-(η3-Allyl)-α-Alkenylphosphine Derivatives Starting from a Dihydride−Dihydrogen−Triisopropylphosphine Complex

Osmium Hydride Acetylacetonate Complexes and Their Application in Acceptorless Dehydrogenative Coupling of Alcohols and Amines and for the Dehydrogenation of Cyclic Amines

Osmium NHC Complexes from Alcohol-Functionalized Imidazoles and Imidazolium Salts

Osmium(II) Complexes Containing a Dianionic CCCC-Donor Tetradentate Ligand

Osmium-Catalyzed Allylic Alkylation

Osmium-Centered Oxetylidene: Formation and Cleavage

Osmium−Allenylidene Complexes Containing an N-Heterocyclic Carbene Ligand

Oxidative Addition of Group 14 Element Hydrido Compounds to OsH(2)(eta(2)-CH(2)=CHEt)(CO)(P(i)Pr(3))(2): Synthesis and Characterization of the First Trihydrido-Silyl, Trihydrido-Germyl, and Trihydrido-Stannyl Derivatives of Osmium(IV)

POP-pincer osmium-polyhydrides: head-to-head (Z)-dimerization of terminal alkynes

POP-pincer ruthenium complexes: d(6) counterparts of osmium d(4) species.

Phosphorescent Iridium(III) Complexes with a Dianionic C,C',N,N'-Tetradentate Ligand

Preparation and Photophysical Properties of Bis(tridentate) Iridium(III) Emitters: Pincer Coordination of 2,6-Di(2-pyridyl)phenyl

Preparation and characterization of novel Os-diolefin dimers: new entry to Os-cyclooctadiene complexes

Preparation of Half-Sandwich Osmium-Allyl Complexes by Consecutive C−C Bond Formation and C−H Bond Activation Reactions

Preparation of Phosphorescent Iridium(III) Complexes with a Dianionic C,C,C,C-Tetradentate Ligand.

Preparation of Phosphorescent Osmium(IV) Complexes with N,N′,C- and C,N,C′-Pincer Ligands

Preparation of Tris-Heteroleptic Iridium(III) Complexes Containing a Cyclometalated Aryl-N-Heterocyclic Carbene Ligand

Preparation, Spectroscopic Characterization, X-ray Structure, and Theoretical Investigation of Hydride−, Dihydrogen−, and Acetone−OsTp Complexes: A Hydridotris(pyrazolyl)borate−Cyclopentadienyl Comparison

Reaction of a Cationic Osmium(IV) Dihydride with Ethylene: Formation and Structure of the Novel Tetraethylene Dimer Complex [{(PiPr3)(η2-C2H4)2Os}2(μ-OH)2(μ-O2CCH3)]BF4

Reactions of New Osmium−Dihydride Complexes with Terminal Alkynes: Metallacyclopropene versus Metal−Carbyne. Influence of the Alkyne Substituent

Reactions of an Osmium(IV)-Hydroxo Complex with Amino-Boranes: Formation of Boroxide Derivatives

Redox Isomerization of Allylic Alcohols Catalyzed by Osmium and Ruthenium Complexes Containing a Cyclopentadienyl Ligand with a Pendant Amine or Phosphoramidite Group: X-ray Structure of an η3-1-Hydroxyallyl-Metal-Hydride Intermediate

Reduction and C(sp2)−H Bond Activation of Ketones Promoted by a Cyclopentadienyl-Osmium- Dihydride-Dihydrogen Complex

Reduction of Benzonitriles via Osmium-Azavinylidene Intermediates Bearing Nucleophilic and Electrophilic Centers

Ruthenium Hydroxycarbenes as Key Intermediates in Cycloisomerization and Decarbonylative Cyclization of Terminal Alkynals