Lista de obras - Pavel Kocovsky - Dominio Público Uruguay

2H-quadrupolar coupling-based analysis of stereochemical and regiochemical memory in the Pd-catalysed allylic alkylation of iso-cinnamyl type substrates employing the chiral monophosphine ligands ‘MOP’ and ‘MAP’

A New Insight into the Stereoelectronic Control of the Pd0 -Catalyzed Allylic Substitution: Application for the Synthesis of Multisubstituted Pyran-2-ones via an Unusual 1,3-Transposition

artículo científico publicado en 2019

A modular approach to aryl-C-ribonucleosides via the allylic substitution and ring-closing metathesis sequence. a stereocontrolled synthesis of all four α-/β- and D-/L-C-nucleoside stereoisomers

artículo científico publicado en 2011

A novel bifunctional allyldisilane as a triple allylation reagent in the stereoselective synthesis of trisubstituted tetrahydrofurans

artículo científico publicado en 2011

Amino acid-derived hydroxamic acids as chiral ligands in the vanadium catalysed epoxidation.

artículo científico publicado en 2005

An Approach toward the Triquinane-Type Skeleton via Reagent-Controlled Skeletal Rearrangements. A Facile Method for Protection-Deprotection of Organomercurials, Tuning the Selectivity of Wagner-Meerwein Migrations, and a New Route to Annulated Lacto

scientific article published on 01 January 1999

Asymmetric Allylic Substitution Catalyzed byC1-Symmetrical Complexes of Molybdenum: Structural Requirements of the Ligand and the Stereochemical Course of the Reaction

artículo científico publicado en 2006

C-nucleosides: synthetic strategies and biological applications.

artículo científico publicado en 2009

Chiral 2,2'-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane

artículo científico publicado en 2002

Chiral recognition in solution and the gas phase. Experimental and theoretical studies of aromatic D- and L-amino acid-Cu(II)-chiragen complexes.

artículo científico publicado en 2004

Corner attack on cyclopropane by thallium(III) ions. A highly stereospecific cleavage and skeletal rearrangement of 3.alpha.,5-cyclo-5.alpha.-cholestan-6.alpha.-ol

scholarly article by Pavel Kocovsky et al published August 1990 in Journal of the American Chemical Society

Corner opening of cyclopropanes by mercury(II) and thallium(III) and transmetalation of the intermediate organomercurials. A novel, stereoselective approach to cyclobutanes and cyclopropanes

scholarly article by Pavel Kocovsky et al published January 1994 in Journal of the American Chemical Society

Cross-Aldol Reaction of Isatin with Acetone Catalyzed by Leucinol: A Mechanistic Investigation

artículo científico publicado en 2015

Dendron-anchored organocatalysts: the asymmetric reduction of imines with trichlorosilane, catalysed by an amino acid-derived formamide appended to a dendron.

artículo científico publicado en 2009

Desymmetrization of cyclic meso-epoxides with silicon tetrachloride catalyzed by PINDOX, a chiral bipyridine mono-N-oxide

artículo científico publicado en 2009

Dynamic kinetic resolution in the asymmetric synthesis of beta-amino acids by organocatalytic reduction of enamines with trichlorosilane

scientific article published on 01 January 2008

Electrochemical recognition of analytes using quaternary ammonium binaphthyl salts ⬇️

artículo científico publicado el 1 de marzo de 2003

Electrochemical recognition of chiral species using quaternary ammonium binaphthyl salts.

artículo científico publicado en 2002

Enantioselective Baeyer-Villiger oxidation catalyzed by palladium(II) complexes with chiral P,N-ligands.

artículo científico publicado en 2008

Enantioselective allylation of α,β-unsaturated aldehydes with allyltrichlorosilane catalyzed by METHOX

artículo científico publicado en 2011

Enantioselective and catalytic method for alpha-crotylation of aldehydes with a kinetic self-refinement of stereochemistry

scientific article published on 01 January 2009

Enantioselective synthesis of 1,2-diarylaziridines by the organocatalytic reductive amination of alpha-chloroketones

scientific article published on 01 January 2007

METHOX: a new pyridine N-oxide organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilanes

scientific article published on 01 July 2005

Mapping lipid and detergent molecules at the surface of membrane proteins

scientific article published on 01 June 2011

Mechanistic dichotomy in the asymmetric allylation of aldehydes with allyltrichlorosilanes catalyzed by chiral pyridine N-oxides

artículo científico publicado en 2013

Molybdenum(II)- and Tungsten(II)-Catalyzed Allylic Substitution

artículo científico publicado en 1999

Molybdenum(II)-Catalyzed Allylation of Electron-Rich Aromatics and Heteroaromatics

scientific article published on 01 April 1999

Molybdenum(V)-Mediated Skeletal Rearrangement of an Organomercury Steroid. Stereoelectronic Control and Mechanism

New Lewis-Acidic Molybdenum(II) and Tungsten(II) Catalysts for Intramolecular Carbonyl Ene and Prins Reactions. Reversal of the Stereoselectivity of Cyclization of Citronellal

artículo científico publicado en 1999

Non-symmetrically substituted 1,1'-binaphthyls in enantioselective catalysis

artículo científico publicado en 2003

On the selective N-methylation of BOC-protected amino acids.

artículo científico publicado en 2009

Organocatalysis with a fluorous tag: asymmetric reduction of imines with trichlorosilane catalyzed by amino acid-derived formamides

scientific article published on 01 February 2007

Organocatalysts immobilised onto gold nanoparticles: application in the asymmetric reduction of imines with trichlorosilane.

artículo científico publicado en 2009

PINDY: A novel, pinene-derived bipyridine ligand and its application in asymmetric, Copper(I)-catalyzed allylic oxidation

scientific article published on 01 October 2000

Palladium(II) Complexes of 2-Dimethylamino-2‘- diphenylphosphino-1,1‘-binaphthyl (MAP) with Unique P,Cσ-Coordination and Their Catalytic Activity in Allylic Substitution, Hartwig−Buchwald Amination, and Suzuki Coupling

artículo científico publicado en 1999

Palladium-catalyzed alkoxycarbonylation of terminal alkenes to produce α,β-unsaturated esters: the key role of acetonitrile as a ligand

artículo científico publicado en 2014

Palladium-catalyzed stereoselective intramolecular oxidative amidation of alkenes in the synthesis of 1,3- and 1,4-amino alcohols and 1,3-diamines

artículo científico publicado en 2014

Polymer-supported organocatalysts: asymmetric reduction of imines with trichlorosilane catalyzed by an amino acid-derived formamide anchored to a polymer.

artículo científico publicado en 2008

Quinox, a quinoline-type N-oxide, as organocatalyst in the asymmetric allylation of aromatic aldehydes with allyltrichlorosilanes: the role of arene-arene interactions

artículo científico publicado en 2003

Remote chiral induction in the organocatalytic hydrosilylation of aromatic ketones and ketimines

artículo científico publicado en 2006

Role of noncovalent interactions in the enantioselective reduction of aromatic ketimines with trichlorosilane

scientific article published on 01 June 2004

Ruthenium-Catalyzed Oppenauer-Type Oxidation of 3beta-Hydroxy Steroids. A Highly Efficient Entry into the Steroidal Hormones with 4-En-3-one Functionality

artículo científico publicado en 1996

Soluble polymer-supported organocatalysts: asymmetric reduction of imines with trichlorosilane catalyzed by an amino acid derived formamide anchored to a soluble polymer.

artículo científico publicado en 2009

Stereoselective palladium-catalyzed functionalization of homoallylic alcohols: a convenient synthesis of di- and trisubstituted isoxazolidines and β-amino-δ-hydroxy esters

artículo científico publicado en 2012

Steroids with modified ring A or B: screening for potential antiandrogenic and synandrogenic activity

scientific article published on 01 April 1980

Structural requirements for the thallium(III)-mediated cyclisation of unsaturated alcohols. A novel fragmentation reaction producing 19-norsteroids

scholarly article by Pavel Kocovsky et al published 1990 in Journal of the Chemical Society. Chemical communications

Synthesis of alpha-amino acids via asymmetric phase transfer-catalyzed alkylation of achiral nickel(II) complexes of glycine-derived Schiff bases.

artículo científico publicado en 2003

Synthesis of enantiopure 1-arylprop-2-en-1-ols and their tert-butyl carbonates

scientific article published on 08 October 2008

Synthesis of new chiral 2,2'-bipyridine ligands and their application in copper-catalyzed asymmetric allylic oxidation and cyclopropanation.

artículo científico publicado en 2003

The syn/anti-dichotomy in the palladium-catalyzed addition of nucleophiles to alkenes.

artículo científico publicado en 2014

Transmetallation with palladium(II) of an organomercurial arising from mercury(II)-mediated cyclopropane cleavage. Tuning of the palladium reactivity and a novel, intramolecular redox reaction

scholarly article by Pavel Kocovsky et al published 1992 in Journal of the Chemical Society. Chemical communications

Vicinal Amino Alcohols as Organocatalysts in Asymmetric Cross-Aldol Reaction of Ketones: Application in the Synthesis of Convolutamydine A†

artículo científico publicado en 2007

Lista de obras de Pavel Kocovsky

2H-quadrupolar coupling-based analysis of stereochemical and regiochemical memory in the Pd-catalysed allylic alkylation of iso-cinnamyl type substrates employing the chiral monophosphine ligands ‘MOP’ and ‘MAP’

A New Insight into the Stereoelectronic Control of the Pd0 -Catalyzed Allylic Substitution: Application for the Synthesis of Multisubstituted Pyran-2-ones via an Unusual 1,3-Transposition

A modular approach to aryl-C-ribonucleosides via the allylic substitution and ring-closing metathesis sequence. a stereocontrolled synthesis of all four α-/β- and D-/L-C-nucleoside stereoisomers

A novel bifunctional allyldisilane as a triple allylation reagent in the stereoselective synthesis of trisubstituted tetrahydrofurans

Amino acid-derived hydroxamic acids as chiral ligands in the vanadium catalysed epoxidation.

An Approach toward the Triquinane-Type Skeleton via Reagent-Controlled Skeletal Rearrangements. A Facile Method for Protection-Deprotection of Organomercurials, Tuning the Selectivity of Wagner-Meerwein Migrations, and a New Route to Annulated Lacto

Asymmetric Allylic Substitution Catalyzed byC1-Symmetrical Complexes of Molybdenum: Structural Requirements of the Ligand and the Stereochemical Course of the Reaction

C-nucleosides: synthetic strategies and biological applications.

Chiral 2,2'-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane

Chiral recognition in solution and the gas phase. Experimental and theoretical studies of aromatic D- and L-amino acid-Cu(II)-chiragen complexes.

Corner attack on cyclopropane by thallium(III) ions. A highly stereospecific cleavage and skeletal rearrangement of 3.alpha.,5-cyclo-5.alpha.-cholestan-6.alpha.-ol

Corner opening of cyclopropanes by mercury(II) and thallium(III) and transmetalation of the intermediate organomercurials. A novel, stereoselective approach to cyclobutanes and cyclopropanes

Cross-Aldol Reaction of Isatin with Acetone Catalyzed by Leucinol: A Mechanistic Investigation

Dendron-anchored organocatalysts: the asymmetric reduction of imines with trichlorosilane, catalysed by an amino acid-derived formamide appended to a dendron.

Desymmetrization of cyclic meso-epoxides with silicon tetrachloride catalyzed by PINDOX, a chiral bipyridine mono-N-oxide

Dynamic kinetic resolution in the asymmetric synthesis of beta-amino acids by organocatalytic reduction of enamines with trichlorosilane

Electrochemical recognition of analytes using quaternary ammonium binaphthyl salts ⬇️

Electrochemical recognition of chiral species using quaternary ammonium binaphthyl salts.

Enantioselective Baeyer-Villiger oxidation catalyzed by palladium(II) complexes with chiral P,N-ligands.

Enantioselective allylation of α,β-unsaturated aldehydes with allyltrichlorosilane catalyzed by METHOX

Enantioselective and catalytic method for alpha-crotylation of aldehydes with a kinetic self-refinement of stereochemistry

Enantioselective synthesis of 1,2-diarylaziridines by the organocatalytic reductive amination of alpha-chloroketones

METHOX: a new pyridine N-oxide organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilanes

Mapping lipid and detergent molecules at the surface of membrane proteins

Mechanistic dichotomy in the asymmetric allylation of aldehydes with allyltrichlorosilanes catalyzed by chiral pyridine N-oxides

Molybdenum(II)- and Tungsten(II)-Catalyzed Allylic Substitution

Molybdenum(II)-Catalyzed Allylation of Electron-Rich Aromatics and Heteroaromatics

Molybdenum(V)-Mediated Skeletal Rearrangement of an Organomercury Steroid. Stereoelectronic Control and Mechanism

New Lewis-Acidic Molybdenum(II) and Tungsten(II) Catalysts for Intramolecular Carbonyl Ene and Prins Reactions. Reversal of the Stereoselectivity of Cyclization of Citronellal

Non-symmetrically substituted 1,1'-binaphthyls in enantioselective catalysis

On the selective N-methylation of BOC-protected amino acids.

Organocatalysis with a fluorous tag: asymmetric reduction of imines with trichlorosilane catalyzed by amino acid-derived formamides

Organocatalysts immobilised onto gold nanoparticles: application in the asymmetric reduction of imines with trichlorosilane.

PINDY: A novel, pinene-derived bipyridine ligand and its application in asymmetric, Copper(I)-catalyzed allylic oxidation

Palladium(II) Complexes of 2-Dimethylamino-2‘- diphenylphosphino-1,1‘-binaphthyl (MAP) with Unique P,Cσ-Coordination and Their Catalytic Activity in Allylic Substitution, Hartwig−Buchwald Amination, and Suzuki Coupling

Palladium-catalyzed alkoxycarbonylation of terminal alkenes to produce α,β-unsaturated esters: the key role of acetonitrile as a ligand

Palladium-catalyzed stereoselective intramolecular oxidative amidation of alkenes in the synthesis of 1,3- and 1,4-amino alcohols and 1,3-diamines

Polymer-supported organocatalysts: asymmetric reduction of imines with trichlorosilane catalyzed by an amino acid-derived formamide anchored to a polymer.

Quinox, a quinoline-type N-oxide, as organocatalyst in the asymmetric allylation of aromatic aldehydes with allyltrichlorosilanes: the role of arene-arene interactions

Remote chiral induction in the organocatalytic hydrosilylation of aromatic ketones and ketimines

Role of noncovalent interactions in the enantioselective reduction of aromatic ketimines with trichlorosilane

Ruthenium-Catalyzed Oppenauer-Type Oxidation of 3beta-Hydroxy Steroids. A Highly Efficient Entry into the Steroidal Hormones with 4-En-3-one Functionality

Soluble polymer-supported organocatalysts: asymmetric reduction of imines with trichlorosilane catalyzed by an amino acid derived formamide anchored to a soluble polymer.

Stereoselective palladium-catalyzed functionalization of homoallylic alcohols: a convenient synthesis of di- and trisubstituted isoxazolidines and β-amino-δ-hydroxy esters

Steroids with modified ring A or B: screening for potential antiandrogenic and synandrogenic activity

Structural requirements for the thallium(III)-mediated cyclisation of unsaturated alcohols. A novel fragmentation reaction producing 19-norsteroids

Synthesis of alpha-amino acids via asymmetric phase transfer-catalyzed alkylation of achiral nickel(II) complexes of glycine-derived Schiff bases.

Synthesis of enantiopure 1-arylprop-2-en-1-ols and their tert-butyl carbonates

Synthesis of new chiral 2,2'-bipyridine ligands and their application in copper-catalyzed asymmetric allylic oxidation and cyclopropanation.

The syn/anti-dichotomy in the palladium-catalyzed addition of nucleophiles to alkenes.

Transmetallation with palladium(II) of an organomercurial arising from mercury(II)-mediated cyclopropane cleavage. Tuning of the palladium reactivity and a novel, intramolecular redox reaction

Vicinal Amino Alcohols as Organocatalysts in Asymmetric Cross-Aldol Reaction of Ketones: Application in the Synthesis of Convolutamydine A†