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A novel {FeI-FeII-FeII-FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

artículo científico publicado en 2004

An electrochemical and DFT study on selected beta-diketiminato metal complexes.

artículo científico publicado en 2006

Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

artículo científico publicado en 2010

Biochemistry. Making the H-cluster from scratch

artículo científico publicado en 2014

Chemistry and the hydrogenases.

artículo científico publicado en 2003

Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site

artículo científico publicado en 2007

Correction: EPR detection and characterisation of a paramagnetic Mo(iii) dihydride intermediate involved in electrocatalytic hydrogen evolution

artículo científico publicado en 2016

Coulomb- and antiferromagnetic-induced fission in doubly charged cubelike fe-s clusters

artículo científico publicado en 2002

Determination of the photolysis products of [FeFe]hydrogenase enzyme model systems using ultrafast multidimensional infrared spectroscopy

artículo científico publicado en 2010

Dissecting the intimate mechanism of cyanation of {2Fe3S} complexes related to the active site of all-iron hydrogenases by DFT analysis of energetics, transition states, intermediates and products in the carbonyl substitution pathway.

artículo científico publicado en 2005

EPR detection and characterisation of a paramagnetic Mo(iii) dihydride intermediate involved in electrocatalytic hydrogen evolution

artículo científico publicado en 2016

Electron transfer at a dithiolate-bridged diiron assembly: electrocatalytic hydrogen evolution

scientific article published on 01 December 2004

Electron-transfer chemistry of the iron-molybdenum cofactor of nitrogenase: delocalized and localized reduced states of FeMoco which allow binding of carbon monoxide to iron and molybdenum

artículo científico publicado en 2003

Electronic control of the protonation rates of Fe-Fe bonds

artículo científico publicado en 2014

Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies

artículo científico publicado en 2007

Encapsulating [FeFe]-hydrogenase model compounds in peptide hydrogels dramatically modifies stability and photochemistry

artículo científico publicado en 2012

Femtosecond to microsecond photochemistry of a [FeFe]hydrogenase enzyme model compound.

artículo científico publicado en 2010

Ferracyclic carbamoyl complexes related to the active site of [Fe]-hydrogenase

artículo científico publicado en 2013

Mechanistic aspects of the protonation of [FeFe]-hydrogenase subsite analogues

artículo científico publicado en 2010

Modeling [Fe-Fe] hydrogenase: evidence for bridging carbonyl and distal iron coordination vacancy in an electrocatalytically competent proton reduction by an iron thiolate assembly that operates through Fe(0)-Fe(II) levels

scientific article published on 18 August 2007

Multiple-Timescale Photoreactivity of a Model Compound Related to the Active Site of [FeFe]-Hydrogenase

article

Nuclear inelastic scattering spectroscopy of iron-sulfur cubane compounds

artículo científico publicado en 2003

On the Use of pH Titration to Quantitatively Characterize Colloidal Nanoparticles

artículo científico publicado en 2012

On the electronic structure of the hydrogenase H-cluster

artículo científico publicado en 2006

On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase

artículo científico publicado en 2007

Paramagnetic bridging hydrides of relevance to catalytic hydrogen evolution at metallosulfur centers

artículo científico publicado en 2011

Probing the Intrinsic Electronic Structure of the Cubane [4Fe−4S] Cluster: Nature's Favorite Cluster for Electron Transfer and Storage

artículo científico publicado el 19 de noviembre de 2003

Protonation of [FeFe]-hydrogenase sub-site analogues: revealing mechanism using FTIR stopped-flow techniques

scientific article published on 01 January 2011

Protonation of a subsite analogue of [FeFe]-hydrogenase: mechanism of a deceptively simple reaction revealed by time-resolved IR spectroscopy

artículo científico publicado en 2009

Solar Fuels: Photoelectrosynthesis of CO from CO2 at p‐Type Si using Fe Porphyrin Electrocatalysts

artículo científico publicado el 14 de agosto de 2013

Solution-phase photochemistry of a [FeFe]hydrogenase model compound: evidence of photoinduced isomerisation.

artículo científico publicado en 2012

Structural and functional analogues of the active sites of the [Fe]-, [NiFe]-, and [FeFe]-hydrogenases

artículo científico publicado en 2009

Structure and vibrational dynamics of model compounds of the [FeFe]-hydrogenase enzyme system via ultrafast two-dimensional infrared spectroscopy.

artículo científico publicado en 2008

Synergic binding of carbon monoxide and cyanide to the FeMo cofactor of nitrogenase: relic chemistry of an ancient enzyme?

artículo científico publicado en 2004

Synthesis of the H-cluster framework of iron-only hydrogenase.

artículo científico publicado en 2005

The mixed diol–dithiol 2,2-bis(sulfanylmethyl)propane-1,3-diol: characterization of key intermediates on a new synthetic pathway

artículo científico publicado en 2010

The role of CN and CO ligands in the vibrational relaxation dynamics of model compounds of the [FeFe]-hydrogenase enzyme

scientific article published on 03 May 2011

The third hydrogenase: a ferracyclic carbamoyl with close structural analogy to the active site of Hmd

artículo científico publicado en 2010

Towards alternatives to anodic water oxidation: basket-handle thiolate Fe(III) porphyrins for electrocatalytic hydrocarbon oxidation

artículo científico publicado en 2012

Transient FTIR spectroelectrochemical and stopped-flow detection of a mixed valence (Fe(I)-Fe(II)) bridging carbonyl intermediate with structural elements and spectroscopic characteristics of the di-iron sub-site of all-iron hydrogenase.

artículo científico publicado en 2002

Water splitting by visible light: a nanophotocathode for hydrogen production.

artículo científico publicado en 2010

[FeFe] hydrogenase: protonation of {2Fe3S} systems and formation of super-reduced hydride states

artículo científico publicado en 2014