Lista de obras - M. Esther García - Dominio Público Uruguay

A Triply Bonded Dimolybdenum Hydride Complex with Acid, Base and Radical Activity

A Versatile and Unprecedented Triply Bonded Dimolybdenum Carbonyl Anion

A thiophosphinidene complex as a vehicle in phosphinidene transmetalation: easy formation and cleavage of a P-S bond.

artículo científico publicado en 2011

Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex

artículo científico publicado en 2018

Activation of H-H and H-O bonds at phosphorus with diiron complexes bearing pyramidal phosphinidene ligands.

artículo científico publicado en 2012

Alkenyl Derivatives of the Unsaturated Dimolybdenum Hydride Complex [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2]

C-C and C-N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives

artículo científico

C-X bond formation and cleavage in the reactions of the ditungsten hydride complex [W2(η5-C5H5)2(H)(μ-PCy2)(CO)2] with small molecules having multiple C-X bonds (X = C, N, O).

artículo científico publicado en 2011

Carbene- and Carbyne-like Behavior of the Mo−P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand

scientific article published on 04 July 2007

Chemical and Structural Effects of Bulkness on Bent-Phosphinidene Bridges: Synthesis and Reactivity of the Diiron Complex [Fe2Cp2{μ-P(2,4,6-C6H2tBu3)}(μ-CO)(CO)2]

Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)].

artículo científico publicado en 2017

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 56. Synthesis of iron–molybdenum compounds; crystal structures of [FeMo(µ-CR)(CO)6(η-C5H5)] and [FeMo2(µ3-RC2R)(CO)6(η-C5H5)2](R = C6H4Me-4)

article published in 1987

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 69. Reactions of [MoW(CC6H4Me-4)(CO)7(η-C5H5)] with but-2-yne; crystal structures of [MoW{µ-C(C6H4Me-4)C(Me)C(Me)}(CO)3(η-MeC2Me)2(η-C5H5)] and [MoW{µ-C(C

article published in 1988

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 77. Reactions of iron–molybdenum compounds with alkynes; crystal structures of [MoFe{µ-C(C6H4Me-4)C(CHMe)CH2C(Me)C(Me)}(CO)4(η-C5H5)], [MoFe{µ-C(C6H4Me-4)C(C

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

artículo científico publicado en 2010

Chemistry of the oxophosphinidene ligand. 2. Reactivity of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) toward electrophiles based on elements different from carbon.

artículo científico publicado en 2010

Chemistry of the phosphinidene oxide ligand.

artículo científico publicado en 2004

Coordination and Dehydrogenation of Diphosphine-Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative

scientific article published on 12 November 2019

Cycloaddition Reactions of the Phosphinidene-Bridged Complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)] with Diazoalkanes and Other Heterocumulenes

artículo científico publicado en 2016

Dehydrogenation, Methyl Elimination and Insertion Reactions of the Agostic Methyl-Bridged Complex [Mo2 Cp2 (μ-κ1 :η2 -CH3 )(μ-Pt Bu2 )(μ-CO)]

artículo científico publicado en 2018

Dimolybdenum cyclopentadienyl complexes with bridging chalcogenophosphinidene ligands.

artículo científico publicado en 2012

Dimolybdenum−Tin Derivatives of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] and HSnR3(R = Ph, Bu): Bridging versus Terminal Coordination of the Triorganostannyl Group

Diphosphorus-bridged heterometallic anions and hydrides derived from reactions of complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− with precursors of 16-electron metal carbonyl fragments

E-H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

artículo científico publicado en 2018

Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo-Re Complex. A Platform Combining Nucleophilic and Electrophilic Features

artículo científico publicado en 2020

Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo2(η5-C5H5)(μ-κ1:κ1,η5-PC5H4)(η6-C6H3tBu3)(CO)2(PMe3)]

artículo científico publicado en 2015

Enhanced nucleophilic behavior of a dimolybdenum phosphinidene complex: multicomponent reactions with activated alkenes and alkynes in the presence of CO or CNXyl

scientific article published on 23 May 2011

From coordinated oxophosphinidene to O,O,P-bound arylhypophosphite(2-) to build a singular Mo2Sn2O4P2 metallocycle

artículo científico publicado en 2008

Gold(I) and related heterometallic derivatives of dimolybdenum complexes with asymmetric phosphinidene bridges

artículo científico publicado en 2014

Heterometallic derivatives of [Fe2Cp2(μ-PCy)(μ-CO)(CO)2]: rational synthesis of polynuclear complexes from neutral precursors having pyramidal-phosphinidene bridges.

artículo científico publicado en 2011

Heterometallic derivatives of the unsaturated ditungsten hydride [W2(η(5)-C5H5)2(H)(μ-PCy2)(CO)2]

artículo científico publicado en 2013

High yield synthesis and reactivity of a phosphinidene bridged dimolybdenum complex

artículo científico publicado en 2002

Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2](-).

artículo científico publicado en 2014

Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4

Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes

scientific article published on 01 March 2016

Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo₂(η⁵-C₅H₅)₂(μ-CH₂R)(μ-PCy₂)(CO)₂] (R = H, Ph) with isocyanides and secondary phosphines.

artículo científico publicado en 2014

Low-temperature N-O bond cleavage and reversible N-P bond formation processes in the reactions of the unsaturated anions [M2(η5-C5H5)2(μ-PCy2)(μ-CO)2]- (M = Mo, W) with the nitrosyl complex [Re(η5-C5H4Me)(CO)2(NO)]+.

artículo científico publicado en 2013

Low-temperature N-O bond cleavage in nitrosyl ligands induced by the unsaturated dimolybdenum anion [Mo2(eta(5)-C5H5)2(mu-PPh2)(mu-CO)2]-.

artículo científico publicado en 2009

Low-temperature N-O bond cleavage of nitrogen monoxide in heterometallic carbonyl complexes. An experimental and theoretical study.

artículo científico publicado en 2008

Methylene, oxygen, and sulphur addition to a µ-alkylidyne ligand in an iron–molybdenum complex: X-ray crystal structures of [FeMo{µ-σ,η-C(C6H4Me-4)CH2}(µ-CH2)(CO)5(η-C5H5)], [FeMo{µ-η3-C(C6H4Me-4)C(OMe)C(H)}(CO)5(η-C5H5)], and [FeMo{µ-

article

Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo2(η5-C5H5)2(μ-R)(μ-PCy2)(CO)2] (R = Me, CH2Ph, Ph) with CO and NO

Mild N–O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center

scientific article published on 03 November 2015

Mild P-P bond cleavage in the methyldiphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] to give novel phosphide-bridged trinuclear derivatives

artículo científico publicado en 2014

Mild P4Activation To Give an Anionic Diphosphorus Complex with a Dual Binding Ability at a Single P Site

artículo científico publicado en 2011

M−P versus MM Bonds as Protonation Sites in the Organophosphide-Bridged Complexes [M2Cp2(μ-PR2)(μ-PR‘2)(CO)2], (M = Mo, W; R, R‘ = Ph, Et, Cy)†

scientific article published on 01 August 2006

N-O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W)

scientific article published on 21 November 2018

Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO)2{E,P-EP(O)(2,4,6-C6H2tBu3)}]−(E = O, S)

scientific article published on 01 November 2014

One-step synthesis and P-H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

artículo científico publicado en 2019

Oxidation reactions of the phosphinidene oxide ligand.

artículo científico publicado en 2005

P-N and N-Mo Bond Formation Processes in the Reactions of a Pyramidal Phosphinidene-Bridged Dimolybdenum Complex with Diazoalkanes and Organic Azides

scientific article published on 21 May 2020

P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.

artículo científico publicado en 2015

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes)(CO)2] (Mes = 2,4,6-C6H2tBu3).

artículo científico publicado en 2018

Phosphinidene-bridged binuclear complexes

article published in 2017

Proton induced P–H and Mo–H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(µ-H)(µ-PHR)(CO)4] (R = Cy, 2,4,6-C6H2R′3; R′ = H, Me,tBu)

artículo científico publicado en 2004

Reactions between µ-alkylidyne iron–molybdenum complexes and but-2-yne: unusually facile C–C bond forming processes accompanied by hydrogen migration between carbon centres

Reactions of the Tetrafluoroborate Complex [Mo2Cp2(κ2-F2BF2)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P)

scientific article published on 20 June 2012

Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite Ligand

scientific article published on 16 April 2014

Reactions of the Unsaturated Hydroxo Complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N)

artículo científico publicado en 2012

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with electrophiles based on p-block elements

artículo científico publicado en 2012

Reactions of the unsaturated complex [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PEt(2))(2)(CO)(2)] with [Au(PR(3))](+) cations: kinetic preference of the Mo-P bonds as the site of attack of the gold(I) electrophile.

artículo científico publicado en 2009

Reactivity of the 30-electron dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]− towards β,γ-unsaturated organic halides: Alkenyl, allenyl and alkoxycarbyne derivatives

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]− Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Donor Ability and Dynamics of the P2 Ligand

artículo científico publicado en 2012

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− toward Phosphorus- and Transition Metal-Based Electrophiles

artículo científico publicado en 2013

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward 17- and 16-Electron Metal Carbonyl Fragments: Rational Synthesis of Electron-Deficient Heterometallic Clusters

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward P-Donor Bidentate Ligands and Unsaturated N-Containing Organic Molecules

Reactivity of the unsaturated dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]− towards electrophiles based on p- and d-block elements

Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(CO)2]: Migratory Behavior and Methylidyne Derivatives

Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

artículo científico publicado en 2013

Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands.

artículo científico publicado en 2017

Structure and Bonding in the Unsaturated Hydride- and Hydrocarbyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-X)(μ-PCy2)(CO)2] (X = H, CH3, CH2Ph, Ph). Evidence for the Presence of α-Agostic and π-Bonding Interactions†

Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity

scientific article published on 06 December 2011

Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex

artículo científico publicado en 2016

Synthesis and Decarbonylation Reactions of Diiron Cyclopentadienyl Complexes with Bent-Phosphinidene Bridges

article published in 2011

Synthesis and Decarbonylation Reactions of the Triiron Phosphinidene Complex [Fe3Cp3(μ-H)(μ3-PPh)(CO)4]: Easy Cleavage and Formation of P–H and Fe–Fe Bonds

artículo científico publicado en 2011

Synthesis of the triply-bonded dimolybdenum anions [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PA(2))(mu-CO)(2)](-) (A = Cy, Et, Ph, OEt): unsaturated hydride and carbyne derivatives.

artículo científico publicado en 2009

Ten-electron coordination and reactivity of an arylphosphinidene ligand.

artículo científico publicado en 2003

Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study.

artículo científico publicado en 2017

Tetranuclear phosphide- and phosphinidene-bridged derivatives of the diphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2].

artículo científico publicado en 2015

The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2](-): an entry to the chemistry of unsaturated nitrosyl complexes.

artículo científico publicado en 2016

Trapping of hemiquinone radicals at Mo and P sites by phosphide-bridged dimolybdenum species: chemistry of complexes [Mo2(eta5-C5H5)2(OC6H4OH)(mu-PR2)(CO)4] and [Mo2(eta5-C5H5)2{mu-PR(OC6H4OH)}(CO)4]- (R = Cy, Ph)

artículo científico publicado en 2006

Lista de obras de M. Esther García

A Triply Bonded Dimolybdenum Hydride Complex with Acid, Base and Radical Activity

A Versatile and Unprecedented Triply Bonded Dimolybdenum Carbonyl Anion

A thiophosphinidene complex as a vehicle in phosphinidene transmetalation: easy formation and cleavage of a P-S bond.

Acetonitrile Adduct [MoReCp(μ-H)(μ-PCy2)(CO)5(NCMe)]: A Surrogate of an Unsaturated Heterometallic Hydride Complex

Activation of H-H and H-O bonds at phosphorus with diiron complexes bearing pyramidal phosphinidene ligands.

Alkenyl Derivatives of the Unsaturated Dimolybdenum Hydride Complex [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2]

C-C and C-N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives

C-X bond formation and cleavage in the reactions of the ditungsten hydride complex [W2(η5-C5H5)2(H)(μ-PCy2)(CO)2] with small molecules having multiple C-X bonds (X = C, N, O).

Carbene- and Carbyne-like Behavior of the Mo−P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal-Pyramidal Coordination of a Phosphinidene Ligand

Chemical and Structural Effects of Bulkness on Bent-Phosphinidene Bridges: Synthesis and Reactivity of the Diiron Complex [Fe2Cp2{μ-P(2,4,6-C6H2tBu3)}(μ-CO)(CO)2]

Chemistry of CS2- and SCNPh-adducts of the pyramidal phosphinidene-bridged complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)(PMe3)].

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 56. Synthesis of iron–molybdenum compounds; crystal structures of [FeMo(µ-CR)(CO)6(η-C5H5)] and [FeMo2(µ3-RC2R)(CO)6(η-C5H5)2](R = C6H4Me-4)

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 69. Reactions of [MoW(CC6H4Me-4)(CO)7(η-C5H5)] with but-2-yne; crystal structures of [MoW{µ-C(C6H4Me-4)C(Me)C(Me)}(CO)3(η-MeC2Me)2(η-C5H5)] and [MoW{µ-C(C

Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 77. Reactions of iron–molybdenum compounds with alkynes; crystal structures of [MoFe{µ-C(C6H4Me-4)C(CHMe)CH2C(Me)C(Me)}(CO)4(η-C5H5)], [MoFe{µ-C(C6H4Me-4)C(C

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R*}(CO)(2)](-) (M = Mo, W; R* = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

Chemistry of the oxophosphinidene ligand. 2. Reactivity of the anionic complexes [MCp{P(O)R*}(CO)(2)](-) (M = Mo, W; R* = 2,4,6-C(6)H(2)(t)Bu(3)) toward electrophiles based on elements different from carbon.

Chemistry of the phosphinidene oxide ligand.

Coordination and Dehydrogenation of Diphosphine-Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative

Cycloaddition Reactions of the Phosphinidene-Bridged Complex [Mo2Cp(μ-κ1:κ1,η5-PC5H4)(CO)2(η6-HMes*)] with Diazoalkanes and Other Heterocumulenes

Dehydrogenation, Methyl Elimination and Insertion Reactions of the Agostic Methyl-Bridged Complex [Mo2 Cp2 (μ-κ1 :η2 -CH3 )(μ-Pt Bu2 )(μ-CO)]

Dimolybdenum cyclopentadienyl complexes with bridging chalcogenophosphinidene ligands.

Dimolybdenum−Tin Derivatives of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] and HSnR3(R = Ph, Bu): Bridging versus Terminal Coordination of the Triorganostannyl Group

Diphosphorus-bridged heterometallic anions and hydrides derived from reactions of complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− with precursors of 16-electron metal carbonyl fragments

E-H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2].

Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo-Re Complex. A Platform Combining Nucleophilic and Electrophilic Features

Electronic Structure and Multisite Basicity of the Pyramidal Phosphinidene-Bridged Dimolybdenum Complex [Mo2(η5-C5H5)(μ-κ1:κ1,η5-PC5H4)(η6-C6H3tBu3)(CO)2(PMe3)]

Enhanced nucleophilic behavior of a dimolybdenum phosphinidene complex: multicomponent reactions with activated alkenes and alkynes in the presence of CO or CNXyl

From coordinated oxophosphinidene to O,O,P-bound arylhypophosphite(2-) to build a singular Mo2Sn2O4P2 metallocycle

Gold(I) and related heterometallic derivatives of dimolybdenum complexes with asymmetric phosphinidene bridges

Heterometallic derivatives of [Fe2Cp2(μ-PCy)(μ-CO)(CO)2]: rational synthesis of polynuclear complexes from neutral precursors having pyramidal-phosphinidene bridges.

Heterometallic derivatives of the unsaturated ditungsten hydride [W2(η(5)-C5H5)2(H)(μ-PCy2)(CO)2]

High yield synthesis and reactivity of a phosphinidene bridged dimolybdenum complex

Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2](-).

Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4

Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes

Insertion, coupling and elimination processes in the reactions of the unsaturated alkyl-bridged complexes [Mo₂(η⁵-C₅H₅)₂(μ-CH₂R)(μ-PCy₂)(CO)₂] (R = H, Ph) with isocyanides and secondary phosphines.

Low-temperature N-O bond cleavage and reversible N-P bond formation processes in the reactions of the unsaturated anions [M2(η5-C5H5)2(μ-PCy2)(μ-CO)2]- (M = Mo, W) with the nitrosyl complex [Re(η5-C5H4Me)(CO)2(NO)]+.

Low-temperature N-O bond cleavage in nitrosyl ligands induced by the unsaturated dimolybdenum anion [Mo2(eta(5)-C5H5)2(mu-PPh2)(mu-CO)2]-.

Low-temperature N-O bond cleavage of nitrogen monoxide in heterometallic carbonyl complexes. An experimental and theoretical study.

Methylene, oxygen, and sulphur addition to a µ-alkylidyne ligand in an iron–molybdenum complex: X-ray crystal structures of [FeMo{µ-σ,η-C(C6H4Me-4)CH2}(µ-CH2)(CO)5(η-C5H5)], [FeMo{µ-η3-C(C6H4Me-4)C(OMe)C(H)}(CO)5(η-C5H5)], and [FeMo{µ-

Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo2(η5-C5H5)2(μ-R)(μ-PCy2)(CO)2] (R = Me, CH2Ph, Ph) with CO and NO

Mild N–O Bond Cleavage Reactions of a Pyramidalized Nitrosyl Ligand Bridging a Dimolybdenum Center

Mild P-P bond cleavage in the methyldiphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2] to give novel phosphide-bridged trinuclear derivatives

Mild P4Activation To Give an Anionic Diphosphorus Complex with a Dual Binding Ability at a Single P Site

M−P versus MM Bonds as Protonation Sites in the Organophosphide-Bridged Complexes [M2Cp2(μ-PR2)(μ-PR‘2)(CO)2], (M = Mo, W; R, R‘ = Ph, Et, Cy)†

N-O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W)

Nucleophilic behaviour of dioxo- and thiooxophosphorane complexes [MoCp(CO)2{E,P-EP(O)(2,4,6-C6H2tBu3)}]−(E = O, S)

One-step synthesis and P-H bond cleavage reactions of the phosphanyl complex syn-[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

Oxidation reactions of the phosphinidene oxide ligand.

P-N and N-Mo Bond Formation Processes in the Reactions of a Pyramidal Phosphinidene-Bridged Dimolybdenum Complex with Diazoalkanes and Organic Azides

P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives.

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes*)(CO)2] (Mes* = 2,4,6-C6H2tBu3).

Phosphinidene-bridged binuclear complexes

Proton induced P–H and Mo–H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(µ-H)(µ-PHR)(CO)4] (R = Cy, 2,4,6-C6H2R′3; R′ = H, Me,tBu)

Reactions between µ-alkylidyne iron–molybdenum complexes and but-2-yne: unusually facile C–C bond forming processes accompanied by hydrogen migration between carbon centres

Reactions of the Tetrafluoroborate Complex [Mo2Cp2(κ2-F2BF2)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, Se, N, P)

Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite Ligand

Reactions of the Unsaturated Hydroxo Complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with Mono- and Bidentate Ligands Having E–H bonds (E = O, S, N)

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with electrophiles based on p-block elements

Reactions of the unsaturated complex [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PEt(2))(2)(CO)(2)] with [Au(PR(3))](+) cations: kinetic preference of the Mo-P bonds as the site of attack of the gold(I) electrophile.

Reactivity of the 30-electron dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]− towards β,γ-unsaturated organic halides: Alkenyl, allenyl and alkoxycarbyne derivatives

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]− Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Donor Ability and Dynamics of the P2 Ligand

Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]− toward Phosphorus- and Transition Metal-Based Electrophiles

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward 17- and 16-Electron Metal Carbonyl Fragments: Rational Synthesis of Electron-Deficient Heterometallic Clusters

Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward P-Donor Bidentate Ligands and Unsaturated N-Containing Organic Molecules

Reactivity of the unsaturated dimolybdenum anion [Mo2(η5-C5H5)2(μ-PCy2)(μ-CO)2]− towards electrophiles based on p- and d-block elements

Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(CO)2]: Migratory Behavior and Methylidyne Derivatives

Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

Structural and Chemical Effects of the PtBu2 Bridge at Unsaturated Dimolybdenum Complexes Having Hydride and Hydrocarbyl Ligands.

Structure and Bonding in the Unsaturated Hydride- and Hydrocarbyl-Bridged Complexes [Mo2(η5-C5H5)2(μ-X)(μ-PCy2)(CO)2] (X = H, CH3, CH2Ph, Ph). Evidence for the Presence of α-Agostic and π-Bonding Interactions†

Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity

Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex

Synthesis and Decarbonylation Reactions of Diiron Cyclopentadienyl Complexes with Bent-Phosphinidene Bridges

Synthesis and Decarbonylation Reactions of the Triiron Phosphinidene Complex [Fe3Cp3(μ-H)(μ3-PPh)(CO)4]: Easy Cleavage and Formation of P–H and Fe–Fe Bonds

Synthesis of the triply-bonded dimolybdenum anions [Mo(2)(eta(5)-C(5)H(5))(2)(mu-PA(2))(mu-CO)(2)](-) (A = Cy, Et, Ph, OEt): unsaturated hydride and carbyne derivatives.

Ten-electron coordination and reactivity of an arylphosphinidene ligand.

Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study.

Tetranuclear phosphide- and phosphinidene-bridged derivatives of the diphosphenyl complex [Mo2Cp2(μ-PCy2)(μ-κ(2):κ(2)-P2Me)(CO)2].

The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2](-): an entry to the chemistry of unsaturated nitrosyl complexes.

Chemistry of the oxophosphinidene ligand. 1. Electronic structure of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) and their reactions with H(+) and C-based electrophiles.

Chemistry of the oxophosphinidene ligand. 2. Reactivity of the anionic complexes [MCp{P(O)R}(CO)(2)](-) (M = Mo, W; R = 2,4,6-C(6)H(2)(t)Bu(3)) toward electrophiles based on elements different from carbon.

Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes)(CO)2] (Mes = 2,4,6-C6H2tBu3).