Lista de obras - Pablo J Sanz Miguel - Dominio Público Uruguay

"Directed" assembly of metallacalix[n]arenes with pyrimidine nucleobase ligands of low symmetry: interchanging metals in mixed-metal metallacalix[4]arenes and incorporating additional metals at the exocyclic groups.

artículo científico publicado en 2011

"Directed" assembly of metallacalix[n]arenes with pyrimidine nucleobase ligands of low symmetry: metallacalix[n]arene derivatives of cis-[a2M(cytosine-N3)2]2+ (M=Pt(II), Pd(II); n=4 and 6).

artículo científico publicado en 2011

(Dien)MII (M=Pd, Pt) and (NH3)3PtII complexes of 1-methylcytosine: Linkage and rotational isomerism, metal-promoted deamination, and pathways to dinuclear species

artículo científico publicado en 2006

3,5-Di-p-toluoyl-1,2-dideoxy-β-1-(imidazol-1-yl)-D-ribofuranose

7-Methylguanine: protonation, formation of linkage isomers with trans-(NH3)2PtII, and base pairing properties

artículo científico publicado en 2012

A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene))

scientific article published on 01 June 2015

A conducting coordination polymer based on assembled Cu9 cages.

artículo científico publicado en 2008

A conformationally flexible dinuclear Pt(II) complex with differential behavior of its two states toward quadruplex DNA.

artículo científico publicado en 2013

A neutral Pt3 stack unsupported by any bridging ligand

article

A synthon for a 14-electron Ir(iii) species: catalyst for highly selective β-(Z) hydrosilylation of terminal alkynes

artículo científico publicado en 2012

A “directed” approach toward a cationic molecular square containing four isonicotinamidate ligands and (4+2) (en)PtII metal entities

An alternative mechanistic paradigm for the β-Z hydrosilylation of terminal alkynes: the role of acetone as a silane shuttle.

artículo científico publicado en 2013

Analogues of Cis- and Transplatin with a Rich Solution Chemistry: cis-[PtCl2 (NH3 )(1-MeC-N3)] and trans-[PtI2 (NH3 )(1-MeC-N3)].

artículo científico publicado en 2015

Argentophilicity as essential driving force for a dynamic cation-cation host-guest system: [Ag(acetonitrile)₂]⁺⊂[Ag₂(bis-NHC)₂]²⁺ (NHC = N-heterocyclic carbene)

artículo científico publicado en 2014

C3-Symmetric Pt3Pd3 Purine Vases Based on a Metal Coordination Motif Involving the Pyrimidinic N1 and N3 Sites

scientific article published on 21 July 2011

Cationic tetrakis(nucleobase)complexes of PtII as metalloligands and potential building blocks for molecular architectures

artículo científico publicado en 2005

Coexistence of major and minor tautomers of 1-methylcytosine (1-MeC) in a single metal complex, trans-Pt(1-MeC-N3)(1-MeC-N4)X2 (X=Cl, I): metal migration N3→N4 at acidic pH

Coordination of two different metal ions as reason for N-chirality in μ-amide complexes

artículo científico publicado en 2011

Decaborane anion tautomerism: ion pairing and proton transfer control.

artículo científico publicado en 2018

Different rotamer states of cytosine nucleobases in heteronuclear PtPd-, PtPd2, and Pt2Pd2Ag complexes derived from [Pt(2,2'-bpy)(1-MeC-N3)2]2+ (1-MeC = 1-methylcytosine): first examples of species with head-head oriented 1-MeC(-) ligands

artículo científico publicado en 2012

Dimethylphosphinate bridged binuclear Rh(i) catalysts for the alkoxycarbonylation of aromatic C-H bonds.

artículo científico publicado en 2016

Diplatinum(III) complexes with four bridging 1-methylcytosinato nucleobases derived from a mononuclear trans-(NH3)2PtII complex and CuII.

artículo científico publicado en 2003

Direct X-Ray Scattering Evidence for Metal-Metal Interactions in Solution at the Molecular Level

scientific article published on 01 September 2015

Direct evidence of nanowires formation from a Cu(i) coordination polymer

article

Discrete Molecular Squares {[(en)M(CN)]4}4+ Derived from [(en)M(CN)2] (M = PtII, PdII)

Discrete and polymeric heteronuclear constructs derived from triangular 2,2′-bipyrazine complexes of cis-a2PtII (with a = NH3 or a2 = en)

artículo científico publicado en 2013

Effective Fixation of CO2by Iridium-Catalyzed Hydrosilylation

artículo científico publicado en 2012

Electrical conductivity in platinum-dimer columns.

artículo científico publicado en 2008

Electrostatics Plus O-π Interactions Rather Than “Directed” Hydrogen Bonding Keep SO42−in a Triangular Pt3Pd3-Tris(2,2′-bipyrazine) Host

artículo científico publicado en 2010

Enhanced Metallophilicity in Metal-Carbene Systems: Stronger Character of Aurophilic Interactions in Solution

scientific article published on 09 January 2020

Expanding the pH range of metal-nucleobase complexes for acid-base chemistry: properties of bis(guanine) complexes of (bpy)Pt(II) with either two major or major and minor tautomers bonded simultaneously.

artículo científico publicado en 2009

Expected and Unconventional Ag+ Binding Modes in Heteronuclear Pt,Ag Coordination Polymers Derived from trans-[Pt(methylamine)2(pyrazole)2]2+

Exploring the Metal Coordination Properties of the Pyrimidine Part of Purine Nucleobases: Isomerization Reactions in Heteronuclear PtII/PdIIof 9-Methyladenine

artículo científico publicado en 2011

Flat vs. Folded Chelate Rings incis-PtIIa2(a = NH3, a2= en, a2= 2, 2′-bpy) Complexes of Twofold Substituted Diazine Ligands

Hirshfeld and DFT analysis of the N-heterocyclic carbene proligand methylenebis(N-butylimidazolium) as the acetonitrile-solvated diiodide salt.

artículo científico publicado en 2016

Hybrids between classical and metallacalix[4]arenes based on uracil and cis-Pt(II)L2 entities (L = P(Ph)3 or L2 = 2,2'-bipyridine).

artículo científico publicado en 2009

Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis-N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups

scholarly article by Mélanie Aliaga-Lavrijsen et al published 23 December 2014 in Organometallics

Influence of PtII and PdII coordination on the equilibrium of 2,2′-dipyridylketone (dpk) with its hydrated gem-diol form (dpk·H2O)

Interguanine hydrogen-bonding patterns in adducts with water and Zn–purine complexes (purine is 9-methyladenine and 9-methylguanine). Unexpected preference of Zn(II) for adenine-N7 over guanine-N7

artículo científico publicado en 2007

Isolation of an Intermediate in the Platination ofp-Nitroacetophenone 4-Methylthiosemicarbazone: Potential Application as an Antitumor Drug

Isomerism with metallacalix[4]arenes of the nonsymmetrical pyrimidine nucleobase cytosine: how connectivity and rotamer state determine the topology of multinuclear derivatives

artículo científico publicado en 2010

Metal-mediated deamination of cytosine: experiment and DFT calculations

artículo científico publicado en 2004

Metallatriangles and metallasquares: the diversity behind structurally characterized examples and the crucial role of ligand symmetry

artículo científico publicado en 2011

Mixed adenine/guanine quartets with three trans-a2 Pt(II) (a=NH(3) or MeNH(2)) cross-links: linkage and rotational isomerism, base pairing, and loss of NH(3).

artículo científico publicado en 2014

Models of putative (AH)G(AH)G nucleobase quartets

artículo científico publicado en 2005

Molecular Architectures Derived from Metal Ions and the Flexible 3,3'-Bipyridine Ligand: Unexpected Dimer with Hg(II).

artículo científico publicado en 2010

Multiple Condensation Reactions Involving Pt(II) /Pd(II) -OH2 , Pt-NH3 , and Cytosine-NH2 Groups: New Twists in Cisplatin-Nucleobase Chemistry.

artículo científico publicado en 2016

Multiple Metal Binding to the 9-Methyladenine Model Nucleobase Involving N1, N6, and N7: Discrete Di- and Trinuclear Species with Different Combinations of Monofunctional PdII and PtII Entities

artículo científico publicado en 2012

N-Heterocyclic olefins as ancillary ligands in catalysis: a study of their behaviour in transfer hydrogenation reactions

artículo científico publicado en 2016

On the many roles of NH3 ligands in mono- and multinuclear complexes of platinum

artículo científico publicado en 2009

Organocatalytic enantioselective hydrophosphonylation of aldehydes

artículo científico publicado en 2014

PdII-Catalyzed Condensation of a Mononuclear Pt-Nucleobase Complex to Its Head-Tail Dimer: Characterization of a Key Intermediate and an End Product

artículo científico publicado en 2009

Preferential α-Hydrosilylation of Terminal Alkynes by Bis-N-Heterocyclic Carbene Rhodium(III) Catalysts

PtII Coordination to N1 of 9-Methylguanine: Why it Facilitates Binding of Additional Metal Ions to the Purine Ring

artículo científico publicado en 2011

Pyrazine as a building block for molecular architectures with PtII.

artículo científico publicado en 2006

Rationalizing the Structural Variability of the Exocyclic Amino Groups in Nucleobases and Their Metal Complexes: Cytosine and Adenine

artículo científico publicado en 2014

Rationalizing the formation and versatility of multinuclear metal complexes of bis(1-methyluracil-5-yl)methane as hybrids between classical calix[n]arenes and metallacalixaromatics

Reactivity of ammonia ligands of the antitumor agent cisplatin: a unique dodecanuclear Pt4,Pd4,Ag4 platform for four cytosine model nucleobases

artículo científico publicado en 2008

S-S bond reactivity in metal-perthiocarboxylato compounds.

artículo científico publicado en 2009

Single layers of a multifunctional laminar Cu(I,II) coordination polymer.

artículo científico publicado en 2010

Stepwise Coordination of PtII-180° and PdII-90° Metal Fragments to the Purine Nucleobase 9-Methylhypoxanthine Affords a Closed Octadecanuclear Pt6Pd12Cluster

artículo científico publicado en 2013

Steroid-AuI -NHC Complexes: Synthesis and Antibacterial Activity.

artículo científico publicado en 2017

Supramolecular assembly of diplatinum species through weak Pt(II)⋅⋅⋅Pt(II) intermolecular interactions: a combined experimental and computational study

artículo científico publicado en 2012

Supramolecular isomerism of 2,2'-bipyrazine complexes with cis-(NH(3))(2)Pt(II): ligand rotational state and sequential orientation determine the 3D shape of metallacycles

artículo científico publicado en 2011

Synthesis, structural characterisation and quadruplex DNA binding studies of a new gold(III) pyrazolylpyridine complex

artículo científico publicado en 2010

The Renaissance of Metal-Pyrimidine Nucleobase Coordination Chemistry.

artículo científico publicado en 2016

The challenge of deciphering linkage isomers in mixtures of oligomeric complexes derived from 9-methyladenine and trans-(NH3)2Pt(II) units.

artículo científico publicado en 2015

The exocyclic amino group of adenine in PtII and PdII complexes: a critical comparison of the X-ray crystallographic structural data and gas phase calculations.

artículo científico publicado en 2017

The preparation and characterization of trans-platinum(IV) complexes with unusually high cytotoxicity

artículo científico publicado en 2010

The role of intramolecular hydrogen bonding on nucleobase acidification following metal coordination: possible implications of an "indirect" role of metals in acid-base catalysis of nucleic acids

artículo científico publicado en 2005

Tuning PCP–Ir complexes: the impact of an N-heterocyclic olefin

artículo científico publicado en 2015

Unique Pt5 metallacycle: [Pt(II)Cl(pyrrolidinedithiocarbamate)]5

artículo científico publicado en 2011

Unsupported single-walled water cluster nanotube: A novel hydrogen bonding pattern for water organization

Unusual dimeric Zn(II)-cytosine complexes: new models of the interaction of Zn(II) with DNA and RNA

scientific article published on 07 August 2007

[NO3[symbol: see text]{(en)Pt(2,2'-bpz)}3]NO3(SO4)2: snapshot of nitrate insertion into a cationic Pt3 metallacycle or simply a packing effect?

artículo científico publicado en 2010

Lista de obras de Pablo J Sanz Miguel

"Directed" assembly of metallacalix[n]arenes with pyrimidine nucleobase ligands of low symmetry: interchanging metals in mixed-metal metallacalix[4]arenes and incorporating additional metals at the exocyclic groups.

"Directed" assembly of metallacalix[n]arenes with pyrimidine nucleobase ligands of low symmetry: metallacalix[n]arene derivatives of cis-[a2M(cytosine-N3)2]2+ (M=Pt(II), Pd(II); n=4 and 6).

(Dien)MII (M=Pd, Pt) and (NH3)3PtII complexes of 1-methylcytosine: Linkage and rotational isomerism, metal-promoted deamination, and pathways to dinuclear species

3,5-Di-p-toluoyl-1,2-dideoxy-β-1-(imidazol-1-yl)-D-ribofuranose

7-Methylguanine: protonation, formation of linkage isomers with trans-(NH3)2PtII, and base pairing properties

A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene))

A conducting coordination polymer based on assembled Cu9 cages.

A conformationally flexible dinuclear Pt(II) complex with differential behavior of its two states toward quadruplex DNA.

A neutral Pt3 stack unsupported by any bridging ligand

A synthon for a 14-electron Ir(iii) species: catalyst for highly selective β-(Z) hydrosilylation of terminal alkynes

A “directed” approach toward a cationic molecular square containing four isonicotinamidate ligands and (4+2) (en)PtII metal entities

An alternative mechanistic paradigm for the β-Z hydrosilylation of terminal alkynes: the role of acetone as a silane shuttle.

Analogues of Cis- and Transplatin with a Rich Solution Chemistry: cis-[PtCl2 (NH3 )(1-MeC-N3)] and trans-[PtI2 (NH3 )(1-MeC-N3)].

Argentophilicity as essential driving force for a dynamic cation-cation host-guest system: [Ag(acetonitrile)₂]⁺⊂[Ag₂(bis-NHC)₂]²⁺ (NHC = N-heterocyclic carbene)

C3-Symmetric Pt3Pd3 Purine Vases Based on a Metal Coordination Motif Involving the Pyrimidinic N1 and N3 Sites

Cationic tetrakis(nucleobase)complexes of PtII as metalloligands and potential building blocks for molecular architectures

Coexistence of major and minor tautomers of 1-methylcytosine (1-MeC) in a single metal complex, trans-Pt(1-MeC-N3)(1-MeC-N4)X2 (X=Cl, I): metal migration N3→N4 at acidic pH

Coordination of two different metal ions as reason for N-chirality in μ-amide complexes

Decaborane anion tautomerism: ion pairing and proton transfer control.

Different rotamer states of cytosine nucleobases in heteronuclear PtPd-, PtPd2, and Pt2Pd2Ag complexes derived from [Pt(2,2'-bpy)(1-MeC-N3)2]2+ (1-MeC = 1-methylcytosine): first examples of species with head-head oriented 1-MeC(-) ligands

Dimethylphosphinate bridged binuclear Rh(i) catalysts for the alkoxycarbonylation of aromatic C-H bonds.

Diplatinum(III) complexes with four bridging 1-methylcytosinato nucleobases derived from a mononuclear trans-(NH3)2PtII complex and CuII.

Direct X-Ray Scattering Evidence for Metal-Metal Interactions in Solution at the Molecular Level

Direct evidence of nanowires formation from a Cu(i) coordination polymer

Discrete Molecular Squares {[(en)M(CN)]4}4+ Derived from [(en)M(CN)2] (M = PtII, PdII)

Discrete and polymeric heteronuclear constructs derived from triangular 2,2′-bipyrazine complexes of cis-a2PtII (with a = NH3 or a2 = en)

Effective Fixation of CO2by Iridium-Catalyzed Hydrosilylation

Electrical conductivity in platinum-dimer columns.

Electrostatics Plus O-π Interactions Rather Than “Directed” Hydrogen Bonding Keep SO42−in a Triangular Pt3Pd3-Tris(2,2′-bipyrazine) Host

Enhanced Metallophilicity in Metal-Carbene Systems: Stronger Character of Aurophilic Interactions in Solution

Expanding the pH range of metal-nucleobase complexes for acid-base chemistry: properties of bis(guanine) complexes of (bpy)Pt(II) with either two major or major and minor tautomers bonded simultaneously.

Expected and Unconventional Ag+ Binding Modes in Heteronuclear Pt,Ag Coordination Polymers Derived from trans-[Pt(methylamine)2(pyrazole)2]2+

Exploring the Metal Coordination Properties of the Pyrimidine Part of Purine Nucleobases: Isomerization Reactions in Heteronuclear PtII/PdIIof 9-Methyladenine

Flat vs. Folded Chelate Rings incis-PtIIa2(a = NH3, a2= en, a2= 2, 2′-bpy) Complexes of Twofold Substituted Diazine Ligands

Hirshfeld and DFT analysis of the N-heterocyclic carbene proligand methylenebis(N-butylimidazolium) as the acetonitrile-solvated diiodide salt.

Hybrids between classical and metallacalix[4]arenes based on uracil and cis-Pt(II)L2 entities (L = P(Ph)3 or L2 = 2,2'-bipyridine).

Hydrolysis and Methanolysis of Silanes Catalyzed by Iridium(III) Bis-N-Heterocyclic Carbene Complexes: Influence of the Wingtip Groups

Influence of PtII and PdII coordination on the equilibrium of 2,2′-dipyridylketone (dpk) with its hydrated gem-diol form (dpk·H2O)

Interguanine hydrogen-bonding patterns in adducts with water and Zn–purine complexes (purine is 9-methyladenine and 9-methylguanine). Unexpected preference of Zn(II) for adenine-N7 over guanine-N7

Isolation of an Intermediate in the Platination ofp-Nitroacetophenone 4-Methylthiosemicarbazone: Potential Application as an Antitumor Drug

Isomerism with metallacalix[4]arenes of the nonsymmetrical pyrimidine nucleobase cytosine: how connectivity and rotamer state determine the topology of multinuclear derivatives

Metal-mediated deamination of cytosine: experiment and DFT calculations

Metallatriangles and metallasquares: the diversity behind structurally characterized examples and the crucial role of ligand symmetry

Mixed adenine/guanine quartets with three trans-a2 Pt(II) (a=NH(3) or MeNH(2)) cross-links: linkage and rotational isomerism, base pairing, and loss of NH(3).

Models of putative (AH)G(AH)G nucleobase quartets

Molecular Architectures Derived from Metal Ions and the Flexible 3,3'-Bipyridine Ligand: Unexpected Dimer with Hg(II).

Multiple Condensation Reactions Involving Pt(II) /Pd(II) -OH2 , Pt-NH3 , and Cytosine-NH2 Groups: New Twists in Cisplatin-Nucleobase Chemistry.

Multiple Metal Binding to the 9-Methyladenine Model Nucleobase Involving N1, N6, and N7: Discrete Di- and Trinuclear Species with Different Combinations of Monofunctional PdII and PtII Entities

N-Heterocyclic olefins as ancillary ligands in catalysis: a study of their behaviour in transfer hydrogenation reactions

On the many roles of NH3 ligands in mono- and multinuclear complexes of platinum

Organocatalytic enantioselective hydrophosphonylation of aldehydes

PdII-Catalyzed Condensation of a Mononuclear Pt-Nucleobase Complex to Its Head-Tail Dimer: Characterization of a Key Intermediate and an End Product

Preferential α-Hydrosilylation of Terminal Alkynes by Bis-N-Heterocyclic Carbene Rhodium(III) Catalysts

PtII Coordination to N1 of 9-Methylguanine: Why it Facilitates Binding of Additional Metal Ions to the Purine Ring

Pyrazine as a building block for molecular architectures with PtII.

Rationalizing the Structural Variability of the Exocyclic Amino Groups in Nucleobases and Their Metal Complexes: Cytosine and Adenine

Rationalizing the formation and versatility of multinuclear metal complexes of bis(1-methyluracil-5-yl)methane as hybrids between classical calix[n]arenes and metallacalixaromatics

Reactivity of ammonia ligands of the antitumor agent cisplatin: a unique dodecanuclear Pt4,Pd4,Ag4 platform for four cytosine model nucleobases

S-S bond reactivity in metal-perthiocarboxylato compounds.

Single layers of a multifunctional laminar Cu(I,II) coordination polymer.

Stepwise Coordination of PtII-180° and PdII-90° Metal Fragments to the Purine Nucleobase 9-Methylhypoxanthine Affords a Closed Octadecanuclear Pt6Pd12Cluster

Steroid-AuI -NHC Complexes: Synthesis and Antibacterial Activity.

Supramolecular assembly of diplatinum species through weak Pt(II)⋅⋅⋅Pt(II) intermolecular interactions: a combined experimental and computational study

Supramolecular isomerism of 2,2'-bipyrazine complexes with cis-(NH(3))(2)Pt(II): ligand rotational state and sequential orientation determine the 3D shape of metallacycles

Synthesis, structural characterisation and quadruplex DNA binding studies of a new gold(III) pyrazolylpyridine complex

The Renaissance of Metal-Pyrimidine Nucleobase Coordination Chemistry.

The challenge of deciphering linkage isomers in mixtures of oligomeric complexes derived from 9-methyladenine and trans-(NH3)2Pt(II) units.

The exocyclic amino group of adenine in PtII and PdII complexes: a critical comparison of the X-ray crystallographic structural data and gas phase calculations.

The preparation and characterization of trans-platinum(IV) complexes with unusually high cytotoxicity

The role of intramolecular hydrogen bonding on nucleobase acidification following metal coordination: possible implications of an "indirect" role of metals in acid-base catalysis of nucleic acids

Tuning PCP–Ir complexes: the impact of an N-heterocyclic olefin

Unique Pt5 metallacycle: [Pt(II)Cl(pyrrolidinedithiocarbamate)]5

Unsupported single-walled water cluster nanotube: A novel hydrogen bonding pattern for water organization

Unusual dimeric Zn(II)-cytosine complexes: new models of the interaction of Zn(II) with DNA and RNA

[NO3[symbol: see text]{(en)Pt(2,2'-bpz)}3]NO3(SO4)2: snapshot of nitrate insertion into a cationic Pt3 metallacycle or simply a packing effect?