Lista de obras - David MacMillan - Dominio Público Uruguay

A General Small-Scale Reactor To Enable Standardization and Acceleration of Photocatalytic Reactions

artículo científico publicado en 2017

A Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity

scientific article published on 04 August 2020

A Metallaphotoredox Strategy for the Cross-Electrophile Coupling of α-Chloro Carbonyls with Aryl Halides

scientific article published on 05 September 2019

A general and enantioselective approach to pentoses: a rapid synthesis of PSI-6130, the nucleoside core of sofosbuvir

artículo científico publicado en 2014

A general method for the enantioselective synthesis of pantolactone derivatives

artículo científico publicado en 2002

A general strategy for organocatalytic activation of C-H bonds via photoredox catalysis: direct arylation of benzylic ethers

artículo científico publicado en 2013

A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes

scientific article published on 01 June 2018

Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3-sp2 Cross-Coupling of Oxalates with Aryl Halides

artículo científico publicado en 2016

Alcohols as alkylating agents in heteroarene C-H functionalization

artículo científico publicado en 2015

Aryl amination using ligand-free Ni(II) salts and photoredox catalysis

artículo científico publicado en 2016

Carboxylic acids as a traceless activation group for conjugate additions: a three-step synthesis of (±)-pregabalin.

artículo científico publicado en 2014

Catalyst-controlled oligomerization for the collective synthesis of polypyrroloindoline natural products

artículo científico publicado en 2017

Collective synthesis of natural products by means of organocascade catalysis ⬇️

artículo científico publicado el 13 de julio de 2011

Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway

artículo científico publicado en 2010

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides

artículo científico publicado en 2019

Copper-mediated synthesis of drug-like bicyclopentanes

scientific article published on 17 February 2020

Correction to "Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling".

artículo científico publicado en 2016

Cross-Electrophile Coupling of Unactivated Alkyl Chlorides

artículo científico publicado en 2020

Cycle-specific organocascade catalysis: application to olefin hydroamination, hydro-oxidation, and amino-oxidation, and to natural product synthesis

artículo científico publicado en 2009

Decarboxylative Hydroalkylation of Alkynes.

artículo científico publicado en 2018

Decarboxylative Peptide Macrocyclization through Photoredox Catalysis.

artículo científico publicado en 2016

Decarboxylative Trifluoromethylation of Aliphatic Carboxylic Acids

artículo científico publicado en 2018

Decarboxylative alkylation for site-selective bioconjugation of native proteins via oxidation potentials.

artículo científico publicado en 2017

Decarboxylative arylation of α-amino acids via photoredox catalysis: a one-step conversion of biomass to drug pharmacophore

artículo científico publicado en 2014

Decarboxylative sp C-N coupling via dual copper and photoredox catalysis

scientific article published in Nature

Decarboxylative sp3 C–N Coupling via Dual Copper/Photoredox Catalysis

Development of a general, enantioselective organocatalytic Mukaiyama-Michael reaction with α,β-unsaturated aldehydes

artículo científico publicado en 2009

Development of a new Lewis acid-catalyzed [3,3]-sigmatropic rearrangement: the allenoate-Claisen rearrangement

artículo científico publicado en 2002

Direct Aldehyde C-H Arylation and Alkylation via the Combination of Nickel, Hydrogen Atom Transfer, and Photoredox Catalysis.

artículo científico publicado en 2017

Direct and enantioselective organocatalytic alpha-chlorination of aldehydes

artículo científico publicado en 2004

Direct and enantioselective α-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis ⬇️

artículo científico publicado el 4 de octubre de 2010

Direct arylation of strong aliphatic C-H bonds

artículo científico publicado en 2018

Direct α-arylation of ethers through the combination of photoredox-mediated C-H functionalization and the Minisci reaction.

artículo científico publicado en 2014

Direct β-alkylation of aldehydes via photoredox organocatalysis

artículo científico publicado en 2014

Direct β-functionalization of cyclic ketones with aryl ketones via the merger of photoredox and organocatalysis

artículo científico publicado en 2013

Direct, enantioselective α-alkylation of aldehydes using simple olefins

artículo científico publicado en 2017

Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity ⬇️

artículo científico publicado el 25 de noviembre de 2011

Dual catalysis. Merging photoredox with nickel catalysis: coupling of α-carboxyl sp³-carbons with aryl halides

artículo científico publicado en 2014

Embryonic toxin expression in the cone snail Conus victoriae: primed to kill or divergent function?

artículo científico publicado en 2011

Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis.

artículo científico publicado en 2016

Enantioselective Organo-SOMO Cycloadditions: A Catalytic Approach to Complex Pyrrolidines from Olefins and Aldehydes ⬇️

artículo científico publicado el 10 de julio de 2012

Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene

artículo científico publicado en 1995

Enantioselective aldehyde alpha-nitroalkylation via oxidative organocatalysis.

artículo científico publicado en 2009

Enantioselective alpha-arylation of aldehydes via organo-SOMO catalysis. An ortho-selective arylation reaction based on an open-shell pathway

artículo científico publicado en 2009

Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis

artículo científico publicado en 2009

Enantioselective copper-catalyzed construction of aryl pyrroloindolines via an arylation-cyclization cascade ⬇️

artículo científico publicado el 22 de junio de 2012

Enantioselective intramolecular aldehyde α-alkylation with simple olefins: direct access to homo-ene products

artículo científico publicado en 2013

Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation.

artículo científico publicado en 2009

Enantioselective organo-SOMO cascade cycloadditions: a rapid approach to molecular complexity from simple aldehydes and olefins

artículo científico publicado en 2010

Enantioselective organo-SOMO catalysis: the alpha-vinylation of aldehydes

scientific article published on 21 December 2007

Enantioselective organo-cascade catalysis

artículo científico publicado en 2005

Enantioselective organo-singly occupied molecular orbital catalysis: the carbo-oxidation of styrenes

artículo científico publicado en 2008

Enantioselective organocatalytic amine conjugate addition

artículo científico publicado en 2006

Enantioselective organocatalytic construction of pyrroloindolines by a cascade addition-cyclization strategy: synthesis of (-)-flustramine B.

scholarly article

Enantioselective organocatalytic cyclopropanations. The identification of a new class of iminium catalyst based upon directed electrostatic activation.

artículo científico publicado en 2005

Enantioselective organocatalytic direct aldol reactions of alpha-oxyaldehydes: step one in a two-step synthesis of carbohydrates

artículo científico publicado en 2004

Enantioselective organocatalytic hydride reduction

artículo científico publicado en 2005

Enantioselective organocatalytic indole alkylations. Design of a new and highly effective chiral amine for iminium catalysis

artículo científico publicado en 2002

Enantioselective organocatalytic reductive amination

artículo científico publicado en 2006

Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes

artículo científico publicado en 2007

Enantioselective organocatalytic transfer hydrogenation reactions using Hantzsch esters

artículo científico publicado en 2007

Enantioselective organocatalytic α-fluorination of cyclic ketones

artículo científico publicado en 2011

Enantioselective α-Alkylation of Aldehydes by Photoredox Organocatalysis: Rapid Access to Pharmacophore Fragments from β-Cyanoaldehydes

artículo científico publicado en 2015

Enantioselective α-Arylation of Aldehydes via the Productive Merger of Iodonium Salts and Organocatalysis ⬇️

artículo científico publicado el 9 de marzo de 2011

Enantioselective α-Arylation of Carbonyls via Cu(I)-Bisoxazoline Catalysis ⬇️

artículo científico publicado el 17 de agosto de 2011

Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis ⬇️

artículo científico publicado el 6 de octubre de 2010

Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis

artículo científico publicado en 2012

Fragment Couplings via CO2 Extrusion-Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox

artículo científico publicado en 2015

Mechanistic complexity in organo-SOMO activation

artículo científico publicado en 2010

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids

artículo científico publicado en 2015

Merging photoredox and nickel catalysis: decarboxylative cross-coupling of carboxylic acids with vinyl halides.

artículo científico publicado en 2015

Merging photoredox catalysis with organocatalysis: the direct asymmetric alkylation of aldehydes

artículo científico publicado en 2008

Metallaphotoredox Difluoromethylation of Aryl Bromides

artículo científico publicado en 2018

Metallaphotoredox Perfluoroalkylation of Organobromides

artículo científico publicado en 2020

Metallaphotoredox aryl and alkyl radiomethylation for PET ligand discovery

scientific article published on 25 November 2020

Metallaphotoredox-Catalyzed Cross-Electrophile Csp3-Csp3 Coupling of Aliphatic Bromides

scientific article published on 10 December 2018

Metallaphotoredox-catalysed sp(3)-sp(3) cross-coupling of carboxylic acids with alkyl halides.

artículo científico publicado en 2016

Microenvironment mapping via Dexter energy transfer on immune cells

artículo científico publicado en 2020

Native functionality in triple catalytic cross-coupling: sp³ C-H bonds as latent nucleophiles

scientific article published on 28 April 2016

Nature of intermediates in organo-SOMO catalysis of alpha-arylation of aldehydes

artículo científico publicado en 2010

New Strategies for Organic Catalysis: The First Highly Enantioselective Organocatalytic Diels−Alder Reaction

article

Nine-step enantioselective total synthesis of (+)-minfiensine

artículo científico publicado en 2009

Nine-step enantioselective total synthesis of (-)-vincorine

artículo científico publicado en 2013

O-H hydrogen bonding promotes H-atom transfer from α C-H bonds for C-alkylation of alcohols

artículo científico publicado en 2015

Open-Shell Fluorination of Alkyl Bromides: Unexpected Selectivity in a Silyl Radical-Mediated Chain Process

artículo científico publicado en 2019

Organocatalysis ⬇️

artículo científico publicado el 30 de noviembre de 2010

Organocatalytic transfer hydrogenation of cyclic enones

artículo científico publicado en 2006

Organocatalytic vinyl and Friedel-Crafts alkylations with trifluoroborate salts

artículo científico publicado en 2007

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling

artículo científico publicado en 2015

Oxy-Allyl Cation Catalysis: An Enantioselective Electrophilic Activation Mode

artículo científico publicado en 2016

Photoredox Catalysis in Organic Chemistry

artículo científico publicado en 2016

Photoredox activation for the direct β-arylation of ketones and aldehydes

artículo científico publicado en 2013

Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.

artículo científico publicado en 2011

Photoredox α-vinylation of α-amino acids and N-aryl amines

artículo científico publicado en 2014

Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor®

artículo científico publicado en 2019

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds

artículo científico publicado en 2017

Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II).

artículo científico publicado en 2017

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis.

artículo científico publicado en 2018

Selective Radical-Radical Cross-Couplings: Design of a Formal β-Mannich Reaction

artículo científico publicado en 2015

Selective sp3 C-H alkylation via polarity-match-based cross-coupling

artículo científico publicado en 2017

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling

artículo científico publicado en 2016

Simple catalytic mechanism for the direct coupling of α-carbonyls with functionalized amines: a one-step synthesis of Plavix.

artículo científico publicado en 2013

Site-Selective Functionalization of Methionine Residues via Photoredox Catalysis

scientific article published on 08 December 2020

Site-selective tyrosine bioconjugation via photoredox catalysis for native-to-bioorthogonal protein transformation

artículo científico publicado en 2021

Spin-Center Shift-Enabled Direct Enantioselective a-Benzylation of Aldehydes with Alcohols.

artículo científico publicado en 2018

Static to inducibly dynamic stereocontrol: The convergent use of racemic β-substituted ketones

artículo científico publicado en 2020

Sulfonamidation of Aryl and Heteroaryl Halides via Photosensitized Nickel Catalysis

artículo científico publicado en 2018

Switching on elusive organometallic mechanisms with photoredox catalysis

artículo científico publicado en 2015

The advent and development of organocatalysis

artículo científico publicado en 2008

The direct and enantioselective organocatalytic alpha-oxidation of aldehydes

artículo científico publicado en 2003

The direct arylation of allylic sp(3) C-H bonds via organic and photoredox catalysis

artículo científico publicado en 2015

The enantioselective organocatalytic 1,4-addition of electron-rich benzenes to alpha,beta-unsaturated aldehydes

artículo científico publicado en 2002

The first Suzuki cross-couplings of aryltrimethylammonium salts

artículo científico publicado en 2003

The first direct and enantioselective cross-aldol reaction of aldehydes

artículo científico publicado en 2002

The first enantioselective organocatalytic Mukaiyama-Michael reaction: a direct method for the synthesis of enantioenriched gamma-butenolide architecture

artículo científico publicado en 2003

The first general enantioselective catalytic Diels-Alder reaction with simple alpha,beta-unsaturated ketones

artículo científico publicado en 2002

The importance of iminium geometry control in enamine catalysis: identification of a new catalyst architecture for aldehyde-aldehyde couplings

artículo científico publicado en 2004

The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)-H trifluoromethylation

artículo científico publicado en 2020

Total synthesis and structural revision of callipeltoside C.

artículo científico publicado en 2008

Total synthesis of brasoside and littoralisone

artículo científico publicado en 2005

Transient Absorption Spectroscopy Offers Mechanistic Insights for an Iridium/Nickel-Catalyzed C-O Coupling

artículo científico publicado en 2020

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis.

artículo científico publicado en 2011

Two-step synthesis of carbohydrates by selective aldol reactions

artículo científico publicado en 2004

Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis

artículo científico publicado en 2013

Lista de obras de David MacMillan

A General Small-Scale Reactor To Enable Standardization and Acceleration of Photocatalytic Reactions

A Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity

A Metallaphotoredox Strategy for the Cross-Electrophile Coupling of α-Chloro Carbonyls with Aryl Halides

A general and enantioselective approach to pentoses: a rapid synthesis of PSI-6130, the nucleoside core of sofosbuvir

A general method for the enantioselective synthesis of pantolactone derivatives

A general strategy for organocatalytic activation of C-H bonds via photoredox catalysis: direct arylation of benzylic ethers

A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes

Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3-sp2 Cross-Coupling of Oxalates with Aryl Halides

Alcohols as alkylating agents in heteroarene C-H functionalization

Aryl amination using ligand-free Ni(II) salts and photoredox catalysis

Carboxylic acids as a traceless activation group for conjugate additions: a three-step synthesis of (±)-pregabalin.

Catalyst-controlled oligomerization for the collective synthesis of polypyrroloindoline natural products

Collective synthesis of natural products by means of organocascade catalysis ⬇️

Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides

Copper-mediated synthesis of drug-like bicyclopentanes

Correction to "Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling".

Cross-Electrophile Coupling of Unactivated Alkyl Chlorides

Cycle-specific organocascade catalysis: application to olefin hydroamination, hydro-oxidation, and amino-oxidation, and to natural product synthesis

Decarboxylative Hydroalkylation of Alkynes.

Decarboxylative Peptide Macrocyclization through Photoredox Catalysis.

Decarboxylative Trifluoromethylation of Aliphatic Carboxylic Acids

Decarboxylative alkylation for site-selective bioconjugation of native proteins via oxidation potentials.

Decarboxylative arylation of α-amino acids via photoredox catalysis: a one-step conversion of biomass to drug pharmacophore

Decarboxylative sp C-N coupling via dual copper and photoredox catalysis

Decarboxylative sp3 C–N Coupling via Dual Copper/Photoredox Catalysis

Decarboxylative sp3 C–N Coupling via Dual Copper/Photoredox Catalysis

Development of a general, enantioselective organocatalytic Mukaiyama-Michael reaction with α,β-unsaturated aldehydes

Development of a new Lewis acid-catalyzed [3,3]-sigmatropic rearrangement: the allenoate-Claisen rearrangement

Direct Aldehyde C-H Arylation and Alkylation via the Combination of Nickel, Hydrogen Atom Transfer, and Photoredox Catalysis.

Direct and enantioselective organocatalytic alpha-chlorination of aldehydes

Direct and enantioselective α-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis ⬇️

Direct arylation of strong aliphatic C-H bonds

Direct α-arylation of ethers through the combination of photoredox-mediated C-H functionalization and the Minisci reaction.

Direct β-alkylation of aldehydes via photoredox organocatalysis

Direct β-functionalization of cyclic ketones with aryl ketones via the merger of photoredox and organocatalysis

Direct, enantioselective α-alkylation of aldehydes using simple olefins

Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity ⬇️

Dual catalysis. Merging photoredox with nickel catalysis: coupling of α-carboxyl sp³-carbons with aryl halides

Embryonic toxin expression in the cone snail Conus victoriae: primed to kill or divergent function?

Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis.

Enantioselective Organo-SOMO Cycloadditions: A Catalytic Approach to Complex Pyrrolidines from Olefins and Aldehydes ⬇️

Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene

Enantioselective aldehyde alpha-nitroalkylation via oxidative organocatalysis.

Enantioselective alpha-arylation of aldehydes via organo-SOMO catalysis. An ortho-selective arylation reaction based on an open-shell pathway

Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis

Enantioselective copper-catalyzed construction of aryl pyrroloindolines via an arylation-cyclization cascade ⬇️

Enantioselective intramolecular aldehyde α-alkylation with simple olefins: direct access to homo-ene products

Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation.

Enantioselective organo-SOMO cascade cycloadditions: a rapid approach to molecular complexity from simple aldehydes and olefins

Enantioselective organo-SOMO catalysis: the alpha-vinylation of aldehydes

Enantioselective organo-cascade catalysis

Enantioselective organo-singly occupied molecular orbital catalysis: the carbo-oxidation of styrenes

Enantioselective organocatalytic amine conjugate addition

Enantioselective organocatalytic construction of pyrroloindolines by a cascade addition-cyclization strategy: synthesis of (-)-flustramine B.

Enantioselective organocatalytic cyclopropanations. The identification of a new class of iminium catalyst based upon directed electrostatic activation.

Enantioselective organocatalytic direct aldol reactions of alpha-oxyaldehydes: step one in a two-step synthesis of carbohydrates

Enantioselective organocatalytic hydride reduction

Enantioselective organocatalytic indole alkylations. Design of a new and highly effective chiral amine for iminium catalysis

Enantioselective organocatalytic reductive amination

Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes

Enantioselective organocatalytic transfer hydrogenation reactions using Hantzsch esters

Enantioselective organocatalytic α-fluorination of cyclic ketones

Enantioselective α-Alkylation of Aldehydes by Photoredox Organocatalysis: Rapid Access to Pharmacophore Fragments from β-Cyanoaldehydes

Enantioselective α-Arylation of Aldehydes via the Productive Merger of Iodonium Salts and Organocatalysis ⬇️

Enantioselective α-Arylation of Carbonyls via Cu(I)-Bisoxazoline Catalysis ⬇️

Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis ⬇️

Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis

Fragment Couplings via CO2 Extrusion-Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox

Mechanistic complexity in organo-SOMO activation

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids

Merging photoredox and nickel catalysis: decarboxylative cross-coupling of carboxylic acids with vinyl halides.

Merging photoredox catalysis with organocatalysis: the direct asymmetric alkylation of aldehydes

Metallaphotoredox Difluoromethylation of Aryl Bromides

Metallaphotoredox Perfluoroalkylation of Organobromides

Metallaphotoredox aryl and alkyl radiomethylation for PET ligand discovery

Metallaphotoredox-Catalyzed Cross-Electrophile Csp3-Csp3 Coupling of Aliphatic Bromides

Metallaphotoredox-catalysed sp(3)-sp(3) cross-coupling of carboxylic acids with alkyl halides.

Microenvironment mapping via Dexter energy transfer on immune cells