Lista de obras - Victorio Cadierno - Dominio Público Uruguay

A new class of tethered-arene ruthenium(II) complexes with pendant P and C donor atoms: synthesis of eta6:eta1:eta1 phosphonio-azabutadienyl ruthenabicycles via allenylidene intermediates.

artículo científico publicado en 2004

Access to the first (iminophosphoranyl)(selenophosphoranyl)methane ligands Ph2P(=Se)CH2P(=NR)Ph2: coordination of their methanide and methandiide anions to ruthenium

scientific article published on 19 November 2009

Access to unusual polycyclic spiro-enones from 2,2'-bis(allyloxy)-1,1'-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence

artículo científico publicado en 2011

Allenylidene indenyl ruthenium(II) complexes as sources of highly functionalized alkynyl complexes: synthesis of the first bimetallic derivatives containing a vinylidene–carbene bridge

An Easy Entry to Dimers [{RuX(μ-X)(CO)(P⌒P)}2] (X = Cl, Br; P⌒P = 1,1‘-Bis(diphenylphosphino)ferrocene, 1,1‘-Bis(diisopropylphosphino)ferrocene) from η3-Allylruthenium(II) Derivatives [RuX(η3-2-C3H4R)(CO)(P⌒P)] (R = H, Me): Efficient Cat

article

An Unprecedented Ruthenium Allenylidene Complex Containing an Unsaturated Bicyclic System: Formal Addition of 1-Ethynyl-1-cyclohexanol to an Alkenylvinylidene Intermediate Complex

article

An efficient ruthenium(IV) catalyst for the selective hydration of nitriles to amides in water under mild conditions

artículo científico publicado en 2014

Arene-ruthenium(II) complexes with hydrophilic P-donor ligands: versatile catalysts in aqueous media

artículo científico publicado en 2014

Bis(allyl)ruthenium(IV) complexes containing water-soluble phosphane ligands: synthesis, structure, and application as catalysts in the selective hydration of organonitriles into amides.

artículo científico publicado en 2010

Bis(iminophosphorano)methane Derivatives as Precursors of Unusual Ruthenium Carbene Complexes: A Synthetic and DFT Study

article published in 2004

Catalytic synthesis of amides via aldoximes rearrangement.

artículo científico publicado en 2015

Chemistry by Nanocatalysis: First Example of a Solid‐Supported RAPTA Complex for Organic Reactions in Aqueous Medium ⬇️

artículo científico publicado el 18 de noviembre de 2010

Cycloisomerization versus hydration reactions in aqueous media: a Au(III)-NHC catalyst that makes the difference

artículo científico publicado en 2012

Dendrimers Containing Zwitterionic [Phosphonium Anionic Zirconocene(IV)] Complexes

Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV): a highly efficient catalyst for the isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media

artículo científico publicado en 2003

Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols

artículo científico publicado en 2019

Early Transition Metal alpha-Diazoalkane Complexes

artículo científico publicado en 2000

Efficient Synthetic Routes to Terminal γ-Keto−Alkynes and Unsaturated Cyclic Carbene Complexes Based on Regio- and Diastereoselective Nucleophilic Additions of Enolates on Ruthenium(II) Indenyl Allenylidenes

article

Efficient intermolecular [2 + 2 + 2] alkyne cyclotrimerization in aqueous medium using a ruthenium(IV) precatalyst

artículo científico publicado en 2006

Efficient tandem process for the catalytic deprotection of N-allyl amides and lactams in aqueous media: a novel application of the bis(allyl)-ruthenium(IV) catalysts [Ru(eta3:eta2:eta3-C12H18)Cl2] and [{Ru(eta3:eta3-C10H16)(micro-Cl)Cl}2].

artículo científico publicado en 2007

Expeditious entry to novel 2-methylene-2,3-dihydrofuro[3,2-c] chromen-2-ones from 6-chloro-4-hydroxychromen-2-one and propargylic alcohols.

artículo científico publicado en 2011

Glycerol and derived solvents: new sustainable reaction media for organic synthesis

artículo científico publicado en 2011

Gold(i)-catalyzed addition of carboxylic acids to internal alkynes in aqueous medium

artículo científico publicado en 2017

Gold-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Iodoalkynes: Access to (Z)-β-Iodoenol Esters and 1,4-Disubstituted (Z)-Enynyl Esters

artículo científico publicado en 2017

Half-sandwich ruthenium(ii) complexes with tethered arene-phosphinite ligands: synthesis, structure and application in catalytic cross dehydrogenative coupling reactions of silanes and alcohols

scientific article published on 06 December 2019

Highlights of the Most Cited Papers in the Section “Catalysis in Organic and Polymer Chemistry”

artículo científico publicado en 2020

Iminophosphine Palladium Complexes in Catalytic Stille Coupling Reactions: From Monomers to Dendrimers

In Search of Optically Active γ-Keto Acetylenes via Regioselective Coupling of Allenylidene Groups and Cyclic Enolates

Metal-catalyzed transformations of propargylic alcohols into alpha,beta-unsaturated carbonyl compounds: from the Meyer-Schuster and Rupe rearrangements to redox isomerizations.

artículo científico publicado en 2010

One-pot three-component catalytic synthesis of fully substituted pyrroles from readily available propargylic alcohols, 1,3-dicarbonyl compounds and primary amines

artículo científico publicado en 2007

One-pot three-component synthesis of tetrasubstituted Nâ H pyrroles from secondary propargylic alcohols, 1,3-dicarbonyl compounds andtert-butyl carbamate

Phosphinous Acid-Assisted Hydration of Nitriles: Understanding the Controversial Reactivity of Osmium and Ruthenium Catalysts.

artículo científico publicado en 2017

Reactivity of Indenyl−Ruthenium(II) Vinylidene Complexes: Selective Synthesis of Alkenyl−Phosphonio Derivatives via Nucleophilic Addition of Triphenylphosphine on Their η2-Alkyne Tautomers. Theoretical Study of the η1-Vinylidene−η2-Alkyne Ta

article

Ru(IV)-catalyzed isomerization of allylamines in water: a highly efficient procedure for the deprotection of N-allylic amines

scientific article published on 13 July 2005

Ruthenium(II) and ruthenium(IV) complexes containing kappa1-P-, kappa2-P,O-, and kappa3-P,N,O-iminophosphorane-phosphine ligands Ph2PCH2P[=NP(=O)(OR)2]Ph2 (R = Et, Ph): synthesis, reactivity, theoretical studies, and catalytic activity in transfer h

artículo científico publicado en 2003

Ruthenium(IV)-catalyzed isomerization of the C=C bond of o-allylic substrates: a theoretical and experimental study

Ruthenium-Catalyzed Isomerizations of Allylic and Propargylic Alcohols in Aqueous and Organic Media: Applications in Synthesis

Ruthenium-catalyzed reduction of allylic alcohols: an efficient isomerization/transfer hydrogenation tandem process

scientific article published on 19 March 2007

Ruthenium/TFA-catalyzed coupling of activated secondary propargylic alcohols with cyclic 1,3-diones: furan versus pyran ring formation.

artículo científico publicado en 2008

Selective Reactions of Functionalized Ruthenium(II) σ-Alkynyl Complexes with Dicobalt Octacarbonyl and Tetracobalt Dodecacarbonyl: Synthesis of Cyclopentenone DerivativesviaIntermolecular Pauson−Khand Reactions

Selective ruthenium-catalyzed hydration of nitriles to amides in pure aqueous medium under neutral conditions

artículo científico publicado en 2008

Silver(I) complexes of N-thiophosphorylated bis(iminophosphorane) ligands: from monomers to polymers

artículo científico publicado en 2007

Stereochemically Controlled Synthesis of Ruthenium(II) Complexes Containing Bis(oxazolin-2'-yl)pyridine Ligands. X-ray Crystal Structures of trans-[RuCl(2)(PPh(3)){kappa(3)-N,N,N-(S,S)-(i)Pr-pybox}] and [RuCl(=C=C=CPh(2))(PPh(3)){kappa(3)-N,N,N-(S,S

artículo científico publicado en 1999

Synthesis and reactivity studies of palladium(II) complexes containing the N-phosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=O)(OR)2}Ph2 (R=Et, Ph): application to the catalytic synthesis of 2,3-dimethylfuran.

artículo científico publicado en 2006

Synthesis of indenyl-ruthenium(II) σ-alkynyl complexes via nucleophilic addition of (1R)-(+)- and (1S)-(−)-camphor enolates on the allenylidene group of [Ru(CCCPh2)(η5-C9H7)(PPh3)2][PF6]: Efficient synthesis of novel optically pure vinyl

Synthesis, reactivity and catalytic activity in transfer hydrogenation of ketones of ruthenium(ii) and ruthenium(iv) complexes containing the novel N-thiophosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{NP(S)(OR)2}Ph2(R = Et, Ph)

scholarly article by Victorio Cadierno et al published 2003 in Dalton Transactions

Unexpected coupling between an η5-indenyl ligand and alkenyl-vinylidene fragments: synthesis of unprecedented (η6-indene)ruthenium(ii) metallacyclesElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/s

artículo científico publicado en 2003

Unexpected formal [1+3] cycloadditions between azides and alpha-zirconated phosphanes: a route to unprecedented phosphazide and iminophosphorane complexes

scientific article published on 01 January 2000

Unmasking the Action of Phosphinous Acid Ligands in Nitrile Hydration Reactions Catalyzed by Arene-Ruthenium(II) Complexes

artículo científico publicado en 2015

Lista de obras de Victorio Cadierno

A new class of tethered-arene ruthenium(II) complexes with pendant P and C donor atoms: synthesis of eta6:eta1:eta1 phosphonio-azabutadienyl ruthenabicycles via allenylidene intermediates.

Access to the first (iminophosphoranyl)(selenophosphoranyl)methane ligands Ph2P(=Se)CH2P(=NR)Ph2: coordination of their methanide and methandiide anions to ruthenium

Access to unusual polycyclic spiro-enones from 2,2'-bis(allyloxy)-1,1'-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence

Allenylidene indenyl ruthenium(II) complexes as sources of highly functionalized alkynyl complexes: synthesis of the first bimetallic derivatives containing a vinylidene–carbene bridge

An Easy Entry to Dimers [{RuX(μ-X)(CO)(P⌒P)}2] (X = Cl, Br; P⌒P = 1,1‘-Bis(diphenylphosphino)ferrocene, 1,1‘-Bis(diisopropylphosphino)ferrocene) from η3-Allylruthenium(II) Derivatives [RuX(η3-2-C3H4R)(CO)(P⌒P)] (R = H, Me): Efficient Cat

An Unprecedented Ruthenium Allenylidene Complex Containing an Unsaturated Bicyclic System: Formal Addition of 1-Ethynyl-1-cyclohexanol to an Alkenylvinylidene Intermediate Complex

An efficient ruthenium(IV) catalyst for the selective hydration of nitriles to amides in water under mild conditions

Arene-ruthenium(II) complexes with hydrophilic P-donor ligands: versatile catalysts in aqueous media

Bis(allyl)ruthenium(IV) complexes containing water-soluble phosphane ligands: synthesis, structure, and application as catalysts in the selective hydration of organonitriles into amides.

Bis(iminophosphorano)methane Derivatives as Precursors of Unusual Ruthenium Carbene Complexes: A Synthetic and DFT Study

Catalytic synthesis of amides via aldoximes rearrangement.

Chemistry by Nanocatalysis: First Example of a Solid‐Supported RAPTA Complex for Organic Reactions in Aqueous Medium ⬇️

Cycloisomerization versus hydration reactions in aqueous media: a Au(III)-NHC catalyst that makes the difference

Dendrimers Containing Zwitterionic [Phosphonium Anionic Zirconocene(IV)] Complexes

Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV): a highly efficient catalyst for the isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media

Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols

Early Transition Metal alpha-Diazoalkane Complexes

Efficient Synthetic Routes to Terminal γ-Keto−Alkynes and Unsaturated Cyclic Carbene Complexes Based on Regio- and Diastereoselective Nucleophilic Additions of Enolates on Ruthenium(II) Indenyl Allenylidenes

Efficient intermolecular [2 + 2 + 2] alkyne cyclotrimerization in aqueous medium using a ruthenium(IV) precatalyst

Efficient tandem process for the catalytic deprotection of N-allyl amides and lactams in aqueous media: a novel application of the bis(allyl)-ruthenium(IV) catalysts [Ru(eta3:eta2:eta3-C12H18)Cl2] and [{Ru(eta3:eta3-C10H16)(micro-Cl)Cl}2].

Expeditious entry to novel 2-methylene-2,3-dihydrofuro[3,2-c] chromen-2-ones from 6-chloro-4-hydroxychromen-2-one and propargylic alcohols.

Glycerol and derived solvents: new sustainable reaction media for organic synthesis

Gold(i)-catalyzed addition of carboxylic acids to internal alkynes in aqueous medium

Gold-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Iodoalkynes: Access to (Z)-β-Iodoenol Esters and 1,4-Disubstituted (Z)-Enynyl Esters

Half-sandwich ruthenium(ii) complexes with tethered arene-phosphinite ligands: synthesis, structure and application in catalytic cross dehydrogenative coupling reactions of silanes and alcohols

Highlights of the Most Cited Papers in the Section “Catalysis in Organic and Polymer Chemistry”

Iminophosphine Palladium Complexes in Catalytic Stille Coupling Reactions: From Monomers to Dendrimers

In Search of Optically Active γ-Keto Acetylenes via Regioselective Coupling of Allenylidene Groups and Cyclic Enolates

Metal-catalyzed transformations of propargylic alcohols into alpha,beta-unsaturated carbonyl compounds: from the Meyer-Schuster and Rupe rearrangements to redox isomerizations.

One-pot three-component catalytic synthesis of fully substituted pyrroles from readily available propargylic alcohols, 1,3-dicarbonyl compounds and primary amines

One-pot three-component synthesis of tetrasubstituted Nâ H pyrroles from secondary propargylic alcohols, 1,3-dicarbonyl compounds andtert-butyl carbamate

Phosphinous Acid-Assisted Hydration of Nitriles: Understanding the Controversial Reactivity of Osmium and Ruthenium Catalysts.

Reactivity of Indenyl−Ruthenium(II) Vinylidene Complexes: Selective Synthesis of Alkenyl−Phosphonio Derivatives via Nucleophilic Addition of Triphenylphosphine on Their η2-Alkyne Tautomers. Theoretical Study of the η1-Vinylidene−η2-Alkyne Ta

Ru(IV)-catalyzed isomerization of allylamines in water: a highly efficient procedure for the deprotection of N-allylic amines

Ruthenium(II) and ruthenium(IV) complexes containing kappa1-P-, kappa2-P,O-, and kappa3-P,N,O-iminophosphorane-phosphine ligands Ph2PCH2P[=NP(=O)(OR)2]Ph2 (R = Et, Ph): synthesis, reactivity, theoretical studies, and catalytic activity in transfer h

Ruthenium(IV)-catalyzed isomerization of the C=C bond of o-allylic substrates: a theoretical and experimental study

Ruthenium-Catalyzed Isomerizations of Allylic and Propargylic Alcohols in Aqueous and Organic Media: Applications in Synthesis

Ruthenium-catalyzed reduction of allylic alcohols: an efficient isomerization/transfer hydrogenation tandem process

Ruthenium/TFA-catalyzed coupling of activated secondary propargylic alcohols with cyclic 1,3-diones: furan versus pyran ring formation.

Selective Reactions of Functionalized Ruthenium(II) σ-Alkynyl Complexes with Dicobalt Octacarbonyl and Tetracobalt Dodecacarbonyl: Synthesis of Cyclopentenone DerivativesviaIntermolecular Pauson−Khand Reactions

Selective ruthenium-catalyzed hydration of nitriles to amides in pure aqueous medium under neutral conditions

Silver(I) complexes of N-thiophosphorylated bis(iminophosphorane) ligands: from monomers to polymers

Stereochemically Controlled Synthesis of Ruthenium(II) Complexes Containing Bis(oxazolin-2'-yl)pyridine Ligands. X-ray Crystal Structures of trans-[RuCl(2)(PPh(3)){kappa(3)-N,N,N-(S,S)-(i)Pr-pybox}] and [RuCl(=C=C=CPh(2))(PPh(3)){kappa(3)-N,N,N-(S,S

Synthesis and reactivity studies of palladium(II) complexes containing the N-phosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=O)(OR)2}Ph2 (R=Et, Ph): application to the catalytic synthesis of 2,3-dimethylfuran.

Synthesis of indenyl-ruthenium(II) σ-alkynyl complexes via nucleophilic addition of (1R)-(+)- and (1S)-(−)-camphor enolates on the allenylidene group of [Ru(CCCPh2)(η5-C9H7)(PPh3)2][PF6]: Efficient synthesis of novel optically pure vinyl

Synthesis, reactivity and catalytic activity in transfer hydrogenation of ketones of ruthenium(ii) and ruthenium(iv) complexes containing the novel N-thiophosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{NP(S)(OR)2}Ph2(R = Et, Ph)

Unexpected coupling between an η5-indenyl ligand and alkenyl-vinylidene fragments: synthesis of unprecedented (η6-indene)ruthenium(ii) metallacyclesElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/s

Unexpected formal [1+3] cycloadditions between azides and alpha-zirconated phosphanes: a route to unprecedented phosphazide and iminophosphorane complexes

Unmasking the Action of Phosphinous Acid Ligands in Nitrile Hydration Reactions Catalyzed by Arene-Ruthenium(II) Complexes