Lista de obras - Alexander Hepp - Dominio Público Uruguay

3H-Phosphaallenes Revisited: Facile Synthesis by Hydroalumination of Alkynylphosphines and β-Elimination, Stability and Trapping of Transient Species by Coordination to Transition Metal Atoms

scientific article published on 01 March 2019

6-Substituted purines containing thienyl or furyl substituents as artificial nucleobases for metal-mediated base pairing

artículo científico publicado en 2013

A Family of Hydrazone-Based Nucleosides for Use in Metal-Mediated Base Pairs

A Family of “Click” Nucleosides for Metal-Mediated Base Pairing: Unravelling the Principles of Highly Stabilizing Metal-Mediated Base Pairs

artículo científico publicado en 2014

A P-H functionalized Al/P-based frustrated Lewis pair - hydrophosphination of nitriles, ring opening with cyclopropenones and evidence of P[double bond, length as m-dash]C double bond formation

artículo científico publicado en 2018

Activation of isocyanates and carbon dioxide by a monomeric aluminium hydrazide as an active Lewis pair.

artículo científico publicado en 2013

Al/P- and Ga/P-Based Frustrated Lewis Pairs and Electronically Unsaturated Substrates: Ring Cleavage and Ring Closure, C-C and C-N Bond Formation

artículo científico publicado en 2019

Alkynide and acetonitrile activation by strained AlPC2 heterocycles

artículo científico publicado en 2012

Alkynyl functionalized Al/P-based frustrated Lewis pairs - aluminium alkynide elimination and evidence for the formation of 3H-phosphaallenes [R-P=C=C(H)-(t)Bu].

artículo científico publicado en 2015

Aluminium Functionalized Germanes: Intramolecular Activation of Ge-H Bonds, Formation of a Dihydrogen Bond and Facile Hydrogermylation of Unsaturated Substrates

artículo científico publicado en 2019

An Al/P-based frustrated Lewis pair as an efficient ambiphilic ligand: coordination of boron trihalides, rearrangement, and formation of HBX₂ complexes (X = Br, I)

artículo científico publicado en 2014

An intermolecular FLP System derived from an NHC-coordinated trisilacyclopropylidene

artículo científico publicado en 2020

Carbanions with two N substituents: nucleophilic acyl-group-transfer reagents

artículo científico publicado en 2007

Chemoselective synthesis of heterobimetallic bis-NHC complexes

artículo científico publicado en 2020

Cooperative Activation of Isocyanates by Al-N-Based Active Lewis Pairs and the Generation of a C5 Chain by Simultaneous Formation of Two C-C Bonds

artículo científico publicado en 2016

Coordination chemistry of bisstannylenes with platinum(0)

scientific article published on 09 October 2008

Copper(ii)-mediated base pairing involving the artificial nucleobase 3H-imidazo[4,5-f]quinolin-5-ol

scientific article published on 01 July 2019

Dimeric aluminum-phosphorus compounds as masked frustrated Lewis pairs for small molecule activation

scientific article published on 12 March 2012

Efficient Synthesis of a NHC-Coordinated Trisilacyclopropylidene and Its Coordination Behavior

scientific article published on 21 June 2018

Facile Access to an NHC-Coordinated Silicon Ring Compound with a Si=N Group and a Two-Coordinate Silicon Atom

scientific article published on 27 February 2019

Facile formation of a persistent butadien-2-yl cation stabilized by hyperconjugation with an Al-C bond

scientific article published on 01 June 2006

Formation of Cationic [RP5Cl]+-Cages via Insertion of [RPCl]+-Cations into a P–P Bond of the P4 Tetrahedron

Formation of an NHC-stabilized heterocyclic housane and its isomerization into a cyclopentenyl anion analogue

scientific article published on 01 October 2019

Functionalized alkynyl-chlorogermanes: hydrometallation, Ge-Cl bond activation, Ge-H bond formation and chlorine-tert-butyl exchange via a transient germyl cation

scientific article published on 27 November 2015

Gold(III)-mediated cyclization of 2-hydrazinylquinolines

Heterobimetallic Carbene Complexes by a Single-Step Site-Selective Metalation of a Tricarbene Ligand ⬇️

artículo científico publicado el 26 de marzo de 2013

Hydroalumination of alkynyl-aminophosphines as a promising tool for the synthesis of unusual phosphines: P-N bond activation, a transient phosphaallene, a zwitterionic AlP2C2 heterocycle and a masked Al/P-based frustrated Lewis pair

artículo científico publicado en 2015

Hydrometallation of amino-trialkynylsilanes--intramolecular M-N interactions (M = Al, Ga) and potential activation of Si-N bonds

artículo científico publicado en 2014

Hydroxylaminato yttrate and samarate complexes

artículo científico publicado en 2007

Metal complexes of 6-pyrazolylpurine derivatives as models for metal-mediated base pairs

artículo científico publicado en 2015

Metal-mediated base pairing in DNA involving the artificial nucleobase imidazole-4-carboxylate

scientific article published on 06 November 2018

Molybdenum and tungsten eta2-alkyne-1-thio complexes acting as sulfur donors in homoleptic Werner type complexes with nickel(II) and palladium(II).

artículo científico publicado en 2006

Mononuclear and dinuclear bromo bridged iridium(I) complexes with N-allyl substituted imidazolin-2-ylidene ligands

scholarly article by F. Ekkehardt Hahn et al published December 2006 in Inorganica Chimica Acta

Naphthalonitriles featuring efficient emission in solution and in the solid state

artículo científico publicado en 2020

Neutral and Cationic Hydridoruthenium Tetrakiscarbene Complexes

article

Oligonuclear gallium nitrogen cage compounds: molecular intermediates on the way from gallium hydrazides to gallium nitride

artículo científico publicado en 2010

Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands

artículo científico publicado en 2008

Palladium and platinum complexes of a benzannulated N-heterocyclic plumbylene with an unusual bonding mode

artículo científico publicado en 2011

Platinum(II) and palladium(II) complexes of tridentate hydrazone-based ligands as selective guanine quadruplex binders.

artículo científico

Reactions of a Silicon-Based Cyclic Silylone with Chalcogens

artículo científico publicado en 2019

Reactions of an Al/P Frustrated Lewis Pair with α,β-Unsaturated Carbonyl Compounds - FLPs as Efficient 2e Reductants with the Formation of Enolates, a cis-Enediolate and an Allene

artículo científico publicado en 2018

Regioselectivity of the C-metalation of 6-furylpurine: importance of directing effects

artículo científico publicado en 2015

Silver(I) and Mercury(II) Complexes with 1-Methyl-1,2,4-triazole as Models for Metal-Mediated Base Pairs - Formation of Discrete Complexes in Solution vs. One- and Two-Dimensional Coordination Polymers in the Solid State

Single-Step Synthesis of Organometallic Molecular Squares from NR,NR',NR'',NR'''-Substituted Benzobiscarbenes

artículo científico publicado en 2016

Small Molecule Activation with N,NR-MIC Platinum Complexes

artículo científico publicado en 2017

Structural diversity in bishydroxylamine complexes of gallium

artículo científico publicado en 2008

Synthesis and Reactivity of Intramolecularly NHC-Stabilized Germylenes and Stannylenes

Synthesis of cationic R2P5(+) cages and subsequent chalcogenation reactions

artículo científico publicado en 2013

Synthesis of silver(I) and gold(I) complexes with cyclic tetra- and hexacarbene ligands

scientific article published on 01 January 2008

The missing link in the coordination chemistry of hydrazines--a hydrazinetriide [N-N(Me)](3-) anion coordinated to five Al atoms

scientific article published on 04 January 2012

The reactions of dialkylgallium hydrides with tert-butylethynylbenzenes--a systematic investigation into the course of hydrogallation reactions

artículo científico publicado en 2006

The role of amines in the growth of terbium(III)-doped cerium phosphate nanoparticles

artículo científico publicado en 2008

Trapping of tin(II) and lead(II) homologues of carbon monoxide by a benzannulated lutidine-bridged bisstannylene

artículo científico publicado en 2008

Unprecedented dinuclear silver(i)-mediated base pair involving the DNA lesion 1,N6-ethenoadenine

scientific article published on 01 February 2015

Vinylgallium and alkyllithium compounds: transmetalation and generation of oligolithium cages

scientific article published on 21 October 2011

Zwitterionic and cationic P5-clusters from four-membered phosphorus–nitrogen–metal heterocycles

scientific article published on 23 August 2010

π-Bonding in Complexes of Benzannulated Biscarbenes, -germylenes, and -stannylenes: An Experimental and Theoretical Study

scientific article published on 01 January 2008

Lista de obras de Alexander Hepp

3H-Phosphaallenes Revisited: Facile Synthesis by Hydroalumination of Alkynylphosphines and β-Elimination, Stability and Trapping of Transient Species by Coordination to Transition Metal Atoms

6-Substituted purines containing thienyl or furyl substituents as artificial nucleobases for metal-mediated base pairing

A Family of Hydrazone-Based Nucleosides for Use in Metal-Mediated Base Pairs

A Family of “Click” Nucleosides for Metal-Mediated Base Pairing: Unravelling the Principles of Highly Stabilizing Metal-Mediated Base Pairs

A P-H functionalized Al/P-based frustrated Lewis pair - hydrophosphination of nitriles, ring opening with cyclopropenones and evidence of P[double bond, length as m-dash]C double bond formation

Activation of isocyanates and carbon dioxide by a monomeric aluminium hydrazide as an active Lewis pair.

Al/P- and Ga/P-Based Frustrated Lewis Pairs and Electronically Unsaturated Substrates: Ring Cleavage and Ring Closure, C-C and C-N Bond Formation

Alkynide and acetonitrile activation by strained AlPC2 heterocycles

Alkynyl functionalized Al/P-based frustrated Lewis pairs - aluminium alkynide elimination and evidence for the formation of 3H-phosphaallenes [R-P=C=C(H)-(t)Bu].

Aluminium Functionalized Germanes: Intramolecular Activation of Ge-H Bonds, Formation of a Dihydrogen Bond and Facile Hydrogermylation of Unsaturated Substrates

An Al/P-based frustrated Lewis pair as an efficient ambiphilic ligand: coordination of boron trihalides, rearrangement, and formation of HBX₂ complexes (X = Br, I)

An intermolecular FLP System derived from an NHC-coordinated trisilacyclopropylidene

Carbanions with two N substituents: nucleophilic acyl-group-transfer reagents

Chemoselective synthesis of heterobimetallic bis-NHC complexes

Cooperative Activation of Isocyanates by Al-N-Based Active Lewis Pairs and the Generation of a C5 Chain by Simultaneous Formation of Two C-C Bonds

Coordination chemistry of bisstannylenes with platinum(0)

Copper(ii)-mediated base pairing involving the artificial nucleobase 3H-imidazo[4,5-f]quinolin-5-ol

Dimeric aluminum-phosphorus compounds as masked frustrated Lewis pairs for small molecule activation

Efficient Synthesis of a NHC-Coordinated Trisilacyclopropylidene and Its Coordination Behavior

Facile Access to an NHC-Coordinated Silicon Ring Compound with a Si=N Group and a Two-Coordinate Silicon Atom

Facile formation of a persistent butadien-2-yl cation stabilized by hyperconjugation with an Al-C bond

Formation of Cationic [RP5Cl]+-Cages via Insertion of [RPCl]+-Cations into a P–P Bond of the P4 Tetrahedron

Formation of an NHC-stabilized heterocyclic housane and its isomerization into a cyclopentenyl anion analogue

Functionalized alkynyl-chlorogermanes: hydrometallation, Ge-Cl bond activation, Ge-H bond formation and chlorine-tert-butyl exchange via a transient germyl cation

Gold(III)-mediated cyclization of 2-hydrazinylquinolines

Heterobimetallic Carbene Complexes by a Single-Step Site-Selective Metalation of a Tricarbene Ligand ⬇️

Hydroalumination of alkynyl-aminophosphines as a promising tool for the synthesis of unusual phosphines: P-N bond activation, a transient phosphaallene, a zwitterionic AlP2C2 heterocycle and a masked Al/P-based frustrated Lewis pair

Hydrometallation of amino-trialkynylsilanes--intramolecular M-N interactions (M = Al, Ga) and potential activation of Si-N bonds

Hydroxylaminato yttrate and samarate complexes

Metal complexes of 6-pyrazolylpurine derivatives as models for metal-mediated base pairs

Metal-mediated base pairing in DNA involving the artificial nucleobase imidazole-4-carboxylate

Molybdenum and tungsten eta2-alkyne-1-thio complexes acting as sulfur donors in homoleptic Werner type complexes with nickel(II) and palladium(II).

Mononuclear and dinuclear bromo bridged iridium(I) complexes with N-allyl substituted imidazolin-2-ylidene ligands

Naphthalonitriles featuring efficient emission in solution and in the solid state

Neutral and Cationic Hydridoruthenium Tetrakiscarbene Complexes

Oligonuclear gallium nitrogen cage compounds: molecular intermediates on the way from gallium hydrazides to gallium nitride

Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands

Palladium and platinum complexes of a benzannulated N-heterocyclic plumbylene with an unusual bonding mode

Platinum(II) and palladium(II) complexes of tridentate hydrazone-based ligands as selective guanine quadruplex binders.

Reactions of a Silicon-Based Cyclic Silylone with Chalcogens

Reactions of an Al/P Frustrated Lewis Pair with α,β-Unsaturated Carbonyl Compounds - FLPs as Efficient 2e Reductants with the Formation of Enolates, a cis-Enediolate and an Allene

Regioselectivity of the C-metalation of 6-furylpurine: importance of directing effects

Silver(I) and Mercury(II) Complexes with 1-Methyl-1,2,4-triazole as Models for Metal-Mediated Base Pairs - Formation of Discrete Complexes in Solution vs. One- and Two-Dimensional Coordination Polymers in the Solid State

Single-Step Synthesis of Organometallic Molecular Squares from NR,NR',NR'',NR'''-Substituted Benzobiscarbenes

Small Molecule Activation with N,NR-MIC Platinum Complexes

Structural diversity in bishydroxylamine complexes of gallium

Synthesis and Reactivity of Intramolecularly NHC-Stabilized Germylenes and Stannylenes

Synthesis of cationic R2P5(+) cages and subsequent chalcogenation reactions

Synthesis of silver(I) and gold(I) complexes with cyclic tetra- and hexacarbene ligands

The missing link in the coordination chemistry of hydrazines--a hydrazinetriide [N-N(Me)](3-) anion coordinated to five Al atoms

The reactions of dialkylgallium hydrides with tert-butylethynylbenzenes--a systematic investigation into the course of hydrogallation reactions

The role of amines in the growth of terbium(III)-doped cerium phosphate nanoparticles

Trapping of tin(II) and lead(II) homologues of carbon monoxide by a benzannulated lutidine-bridged bisstannylene

Unprecedented dinuclear silver(i)-mediated base pair involving the DNA lesion 1,N6-ethenoadenine

Vinylgallium and alkyllithium compounds: transmetalation and generation of oligolithium cages

Zwitterionic and cationic P5-clusters from four-membered phosphorus–nitrogen–metal heterocycles

π-Bonding in Complexes of Benzannulated Biscarbenes, -germylenes, and -stannylenes: An Experimental and Theoretical Study