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Lista de obras de Raghavan B. Sunoj

2,5-Dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: different oxidation state distributions in complexes [{(bpy)2Ru}2(mu-H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(mu-H2L)]m (m=

artículo científico publicado en 2005

A computational insight into a metal mediated pathway for the ring-opening polymerization (ROP) of lactides by an ionic {(NHC)2Ag}(+)X(-) (X = halide) type N-heterocyclic carbene (NHC) complex

artículo científico publicado en 2011

A new approach to evaluating the extent of Michael adduct formation to PAH quinones: tetramethylammonium hydroxide (TMAH) thermochemolysis with GC/MS.

artículo científico publicado en 2003

A new coordination mode of the photometric reagent glyoxalbis(2-hydroxyanil) (H2gbha): bis-bidentate bridging by gbha2- in the redox series [(mu-gbha)[Ru(acac)2]2]n (n = -2, -1, 0, +1, +2), including a radical-bridged diruthenium(III) and a Ru(III)/

artículo científico publicado en 2005

A phosphomide based PNP ligand, 2,6-{Ph2PC(O)}2(C5H3N), showing PP, PNP and PNO coordination modes

artículo científico publicado en 2015

A quantification scheme for non-covalent interactions in the enantio-controlling transition states in asymmetric catalysis

artículo científico publicado en 2018

A unified machine-learning protocol for asymmetric catalysis as a proof of concept demonstration using asymmetric hydrogenation

artículo científico publicado en 2020

Ab initio and density functional theory evidence on the rate-limiting step in the Morita-Baylis-Hillman reaction

scientific article published on 09 October 2007

Aliphatic C(sp3)-H Bond Activation Using Nickel Catalysis: Mechanistic Insights on Regioselective Arylation

artículo científico publicado en 2017

Anomalous excited-state dynamics of lucifer yellow CH in solvents of high polarity: evidence for an intramolecular proton transfer

scientific article published on 01 May 2006

Asymmetric Cooperative Catalysis in a Three-Component Reaction: Mechanism and Origin of Enantio- and Diastereoselectivities

artículo científico publicado en 2016

Axial coordination dichotomy in dirhodium carbenoid catalysis: a curious case of cooperative asymmetric dual-catalytic approach toward amino esters

artículo científico publicado en 2015

Axially chiral imidodiphosphoric Acid catalyst for asymmetric sulfoxidation reaction: insights on asymmetric induction

artículo científico publicado en 2014

Bicyclic proline analogues as organocatalysts for stereoselective aldol reactions: an in silico DFT study

artículo científico publicado en 2007

Chemo-, regio-, and diastereoselectivity preferences in the reaction of a sulfur ylide with a dienal and an enone

artículo científico publicado el 21 de enero de 2011

Computational investigations on the general reaction profile and diastereoselectivity in sulfur ylide promoted aziridination

artículo científico publicado en 2007

Conformational and isomeric preferences of six-membered inorganic heterocycles [EtNP(E)(OR)]3 (E = Lone Pair, O, S, or Se): a synthetic, spectroscopic, structural, and computational study

artículo científico publicado en 2009

Conformational mapping and energetics of saccharide-aromatic residue interactions: implications for the discrimination of anomers and epimers and in protein engineering

artículo científico publicado en 2012

Cooperativity and serial ligand catalysis in an allylic amination reaction by Pd(ii)-bis-sulfoxide and Brønsted acids

scientific article published on 06 August 2019

Cyclopalladation of dimesityl selenide: synthesis, reactivity, structural characterization, isolation of an intermediate complex with C-H···Pd intra-molecular interaction and computational studies

artículo científico publicado en 2013

Deciphering the Origin of Stereoinduction in Cooperative Asymmetric Catalysis Involving Pd(II) and a Chiral Brønsted Acid

scientific article published on 09 June 2015

Deciphering the origin of cooperative catalysis by dirhodium acetate and chiral spiro phosphoric acid in an asymmetric amination reaction

scientific article published on 14 October 2014

Density functional theory and atoms-in-molecule study on the role of two-electron stabilizing interactions in retro Diels-Alder reaction of cycloadducts derived from substituted cyclopentadiene and p-benzoquinone

scientific article published on 27 September 2006

Density functional theory investigations on sulfur ylide promoted cyclopropanation reactions: insights on mechanism and diastereoselection issues

artículo científico publicado en 2007

Directing group assisted meta-hydroxylation by C-H activation

artículo científico publicado en 2016

Enamine versus oxazolidinone: what controls stereoselectivity in proline-catalyzed asymmetric aldol reactions?

artículo científico publicado en 2010

Enantio- and diastereoselectivities in chiral sulfur ylide promoted asymmetric aziridination reactions

artículo científico publicado en 2008

Enhanced diastereoselectivity via confinement: diastereoselective photoisomerization of 2,3-diphenyl-1-benzoylcyclopropane derivatives within zeolites.

artículo científico publicado en 2004

Enhanced diastereoselectivity via confinement: photoisomerization of 2,3-diphenylcyclopropane-1-carboxylic acid derivatives within zeolites.

artículo científico publicado en 2004

Exploration of CH···π mediated stacking interactions in saccharide: aromatic residue complexes through conformational sampling

artículo científico publicado en 2012

Exploring the Mechanism and Stereoselectivity in Chiral Cinchona-Catalyzed Heterodimerization of Ketenes

artículo científico publicado en 2017

Face-selective Diels-Alder reactions between unsymmetrical cyclohexadienes and symmetric trans-dienophile: an experimental and computational investigation

artículo científico publicado en 2007

Harnessing Noncovalent Interactions in Dual-Catalytic Enantioselective Heck-Matsuda Arylation

artículo científico publicado en 2018

Hypercoordinate iodine for catalytic asymmetric diamination of styrene: insights into the mechanism, role of solvent, and stereoinduction

artículo científico publicado en 2019

Importance of ligand exchanges in Pd(II)-Brønsted acid cooperative catalytic approach to spirocyclic rings

artículo científico publicado en 2014

Importance of the nature of α-substituents in pyrrolidine organocatalysts in asymmetric Michael additions.

artículo científico publicado en 2010

Insights on co-catalyst-promoted enamine formation between dimethylamine and propanal through ab initio and density functional theory study

artículo científico publicado en 2007

Intramolecular interactions between chalcogen atoms: organoseleniums derived from 1-bromo-4-tert-butyl-2,6-di(formyl)benzene

artículo científico publicado en 2005

Is silver a mere terminal oxidant in palladium catalyzed C-H bond activation reactions?

artículo científico publicado en 2019

Isomeric ruthenium terpyridine complexes [Ru(trpy)(L)Cl]n+ containing the unsymmetrically bidentate acceptor L=3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine. Synthesis, structures, electrochemistry, spectroscopy and DFT calculations

artículo científico publicado en 2005

Keto-Enol Thermodynamics of Breslow Intermediates

artículo científico publicado en 2016

Light-induced geometric isomerization of 1,2-diphenylcyclopropanes included within Y zeolites: role of cation-guest binding

artículo científico publicado en 2002

Machine learning for predicting product distributions in catalytic regioselective reactions

artículo científico publicado en 2018

Mechanism and Origin of Enantioselectivity in Nickel-Catalyzed Alkyl-Alkyl Suzuki Coupling Reaction

artículo científico publicado en 2019

Mechanism and Stereoselectivity in an Asymmetric N-Heterocyclic Carbene-Catalyzed Carbon-Carbon Bond Activation Reaction

scientific article published on 09 November 2016

Mechanism and electronic effects in nitrogen ylide-promoted asymmetric aziridination reaction

scientific article published on 02 February 2011

Mechanism and reactivity in the Morita-Baylis-Hillman reaction: the challenge of accurate computations

artículo científico publicado en 2017

Mechanism and stereoselectivity of biologically important oxygenation reactions of the 7-dehydrocholesterol radical

artículo científico publicado en 2013

Mechanism of catalytic functionalization of primary C-H bonds using a silylation strategy

artículo científico publicado en 2013

Mechanism of cooperative catalysis in a Lewis acid promoted nickel-catalyzed dual C-H activation reaction

artículo científico publicado en 2012

Mechanistic insights and the role of cocatalysts in Aza-Morita-Baylis-hillman and Morita-Baylis-Hillman reactions

artículo científico publicado en 2009

Mechanistic insights into the role of chiral ligands in asymmetric diamination reactions

artículo científico publicado en 2012

Mechanistic insights on N-heterocyclic carbene-catalyzed annulations: the role of base-assisted proton transfers

scientific article published on 13 June 2011

Mechanistic insights on cooperative asymmetric multicatalysis using chiral counterions

artículo científico publicado en 2014

Mechanistic insights on iodine(III) promoted metal-free dual C-H activation involved in the formation of a spirocyclic bis-oxindole

artículo científico publicado en 2014

Mechanistic insights on organocatalytic enantioselective decarboxylative protonation by epicinchona-thiourea hybrid derivatives

artículo científico publicado en 2012

Mechanistic insights on platinum- and palladium-pincer catalyzed coupling and cyclopropanation reactions between olefins

artículo científico publicado en 2012

Microsolvated transition state models for improved insight into chemical properties and reaction mechanisms

artículo científico publicado en 2012

Mixed-valent metals bridged by a radical ligand: fact or fiction based on structure-oxidation state correlations

artículo científico publicado en 2008

Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino[2,3-a:2′,3′-c]phenazine ligands

artículo científico publicado en 2007

N-heterocyclic carbene catalyzed asymmetric intermolecular Stetter reaction: origin of enantioselectivity and role of counterions

artículo científico publicado en 2013

NaI/CuI–II heterometallic cages interconnected by unusual linear 2-coordinate OCN-Cu(I)-NCO links: synthesis, structural, magnetostructural correlation and computational studies

artículo científico publicado en 2009

New bisphosphomide ligands, 1,3-phenylenebis((diphenylphosphino)methanone) and (2-bromo-1,3-phenylene)bis((diphenylphosphino)methanone): synthesis, coordination behavior, DFT calculations and catalytic studies

scientific article published on 01 July 2013

Non-innocent additives in a palladium(II)-catalyzed C-H bond activation reaction: insights into multimetallic active catalysts

artículo científico publicado en 2014

Noninnocent role of N-methyl pyrrolidinone in thiazolidinethione-promoted asymmetric aldol reactions

artículo científico publicado en 2012

On the activation of hypercoordinate iodine(iii) compounds for reactions of current interest

scientific article published on 01 March 2019

On the mechanism of the dehydroaromatization of hexane to benzene by an iridium pincer catalyst

artículo científico publicado en 2013

On the origin of regio- and stereoselectivity in singlet oxygen addition to enecarbamates

artículo científico publicado en 2012

On the origin of reversible hydrogen activation by phosphine-boranes

artículo científico publicado en 2009

On the origins of kinetic resolution of cyclohexane-1,2-diols through stereoselective acylation by chiral tetrapeptides

scientific article published on 01 August 2009

On the relative preference of enamine/iminium pathways in an organocatalytic Michael addition reaction

artículo científico publicado en 2009

Organoselenium chemistry: role of intramolecular interactions

artículo científico publicado en 2010

Origin of Kinetic Resolution of Hydroxy Esters through Catalytic Enantioselective Lactonization by Chiral Phosphoric Acids

artículo científico publicado en 2016

Origin of Stereodivergence in Cooperative Asymmetric Catalysis with Simultaneous Involvement of Two Chiral Catalysts

artículo científico publicado en 2015

Origin of stereoselectivity in a chiral N-heterocyclic carbene-catalyzed desymmetrization of substituted cyclohexyl 1,3-diketones

artículo científico publicado en 2012

Origin of stereoselectivity in the amination of alcohols using cooperative asymmetric dual catalysis involving chiral counter-ions

scientific article published on 25 June 2018

Palladium(II)-catalyzed direct alkoxylation of arenes: evidence for solvent-assisted concerted metalation deprotonation

artículo científico publicado en 2011

Photochemistry of 1-(N,N-diethylamino)diazen-1-ium-1,2-diolate: an experimental and computational investigation

artículo científico publicado en 2003

Photoreactions with a Twist: Atropisomerism-Driven Divergent Reactivity of Enones with UV and Visible Light.

artículo científico publicado en 2016

Probing intramolecular interactions in arylselenides using a property descriptor based approach

artículo científico publicado en 2008

Quantification of binding affinities of essential sugars with a tryptophan analogue and the ubiquitous role of C-H···π interactions

artículo científico publicado en 2011

Quantification of intramolecular nonbonding interactions in organochalcogens

artículo científico publicado en 2006

Rational design of catalysts for asymmetric diamination reaction using transition state modeling

scientific article published on 01 May 2014

Rearrangement pathways of 2-hydroxy-2-methylpropylidene: an experimental and computational study

artículo científico publicado en 2002

Refined transition-state models for proline-catalyzed asymmetric Michael reactions under basic and base-free conditions

artículo científico publicado en 2012

Retro Diels-Alder reaction under mild conditions: experimental and theoretical studies

artículo científico publicado en 2006

Reversing Enantioselectivity Using Noncovalent Interactions in Asymmetric Dearomatization of β-Naphthols: The Power of 3,3' Substituents in Chiral Phosphoric Acid Catalysts

artículo científico publicado en 2017

Revisiting sesquiterpene biosynthetic pathways leading to santalene and its analogues: a comprehensive mechanistic study

Rhodium Catalyzed Asymmetric Hydroamination of Internal Alkynes with Indoline: Mechanism, Origin of Enantioselectivity, and Role of Additives

artículo científico publicado en 2018

Stereocontrol in proline-catalyzed asymmetric amination: a comparative assessment of the role of enamine carboxylic acid and enamine carboxylate

artículo científico publicado el 18 de abril de 2011

Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides: Reaction Development and Mechanistic Studies.

artículo científico publicado en 2013

Synthesis of azoaromatic dyes via redox driven C-N bond fusion

artículo científico publicado en 2009

The mechanism of catalytic methylation of 2-phenylpyridine using di-tert-butyl peroxide

artículo científico publicado en 2014

The mechanism of the NHC catalyzed aza-Morita-Baylis-Hillman reaction: insights into a new substrate-catalyzed bimolecular pathway

artículo científico publicado en 2014

The role of noninnocent solvent molecules in organocatalyzed asymmetric Michael addition reactions

artículo científico publicado en 2008

Theoretical and Experimental Evidence for a New Kind of Spin-Coupled Singlet Species: Isomeric Mixed-Valent Complexes Bridged by a Radical Anion Ligand

artículo científico publicado en 2005

Transition State Models for Understanding the Origin of Chiral Induction in Asymmetric Catalysis

artículo científico publicado en 2016

Transition state models for probing stereoinduction in Evans chiral auxiliary-based asymmetric aldol reactions.

artículo científico publicado en 2010

Transposed Paternò-Büchi Reaction.

artículo científico publicado en 2016

Two chiral catalysts in action: insights into cooperativity and stereoselectivity in proline and cinchona-thiourea dual organocatalysis

scientific article published on 17 September 2018

Unraveling high precision stereocontrol in a triple cascade organocatalytic reaction

artículo científico publicado en 2008

Water catalysis in the Morita-Baylis-Hillman reaction: a mechanistic perspective

artículo científico publicado en 2008

o-hydroxylmethylphenylchalcogens: synthesis, intramolecular nonbonded chalcogen...OH interactions, and glutathione peroxidase-like activity

artículo científico publicado en 2005