Lista de obras - Stuart A Macgregor - Dominio Público Uruguay

14-Vertex Heteroboranes with 14 Skeletal Electron Pairs: An Experimental and Computational Study.

artículo científico publicado en 2016

A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes

scientific article published on 14 October 2020

A Rhodium-Pentane Sigma-Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques

artículo científico publicado en 2016

A Structurally Characterized Cobalt(I) σ-Alkane Complex

artículo científico publicado en 2020

A combined experimental and computational study of fluxional processes in sigma amine-borane complexes of rhodium and iridium.

artículo científico publicado en 2013

A computational study of the methanolysis of palladium-acyl bonds

artículo científico publicado en 2007

A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation.

artículo científico publicado en 2010

Accurate computed spin-state energetics for Co(iii) complexes: implications for modelling homogeneous catalysis

artículo científico publicado en 2020

Activation of H2 over the Ru-Zn Bond in the Transition Metal-Lewis Acid Heterobimetallic Species [Ru(IPr)2(CO)ZnEt](.).

artículo científico publicado en 2016

Activation of an alkyl C-H bond geminal to an agostic interaction: an unusual mode of base-induced C-H activation

artículo científico publicado en 2009

Adducts of the supraicosahedral stannacarborane 1,6-Me2-4,1,6-closo-SnC2B10H10; synthetic, structural and computational studies.

artículo científico publicado en 2009

Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate

artículo científico publicado en 2008

Base-Promoted, Remote C-H Activation at a Cationic (η-CMe)Ir(III) Center Involving Reversible C-C Bond Formation of Bound CMe

artículo científico publicado en 2019

Benzoate Cyclometalation Enables Oxidative Addition of Haloarenes at a Ru(II) Center

article

Beyond the icosahedron: the first 13-vertex carborane

artículo científico publicado en 2003

Catalytic Hydrodefluorination of Pentafluorobenzene by [Ru(NHC)(PPh3)2(CO)H2]: A Nucleophilic Attack by a Metal‐Bound Hydride Ligand Explains an Unusual ortho‐Regioselectivity ⬇️

artículo científico publicado el 17 de febrero de 2011

Chirality Transfer in Gold(I)-Catalysed Direct Allylic Etherifications of Unactivated Alcohols: Experimental and Computational Study

artículo científico publicado en 2015

Cobalt-Catalyzed Oxidase C-H/N-H Alkyne Annulation: Mechanistic Insights and Access to Anticancer Agents

artículo científico publicado en 2016

Combined experimental and computational investigations of rhodium- and ruthenium-catalyzed C-H functionalization of pyrazoles with alkynes

scientific article published on 24 February 2014

Combined experimental and computational investigations of rhodium-catalysed C - H functionalisation of pyrazoles with alkenes

artículo científico publicado en 2014

Comparison of the photochemistry of organometallic N-heterocyclic carbene and phosphine complexes of manganese.

artículo científico publicado en 2011

Competing C-F activation pathways in the reaction of Pt(0) with fluoropyridines: phosphine-assistance versus oxidative addition

artículo científico publicado en 2008

Computation provides chemical insight into the diverse hydride NMR chemical shifts of [Ru(NHC)4(L)H]0/+ species (NHC = N-heterocyclic carbene; L = vacant, H2, N2, CO, MeCN, O2, P4, SO2, H-, F- and Cl-) and their [Ru(R2PCH2CH2PR2)2(L)H]+ congeners.

artículo científico publicado en 2017

Computational Studies of Carboxylate-Assisted C-H Activation and Functionalization at Group 8-10 Transition Metal Centers

artículo científico publicado en 2017

Computational and synthetic studies on the cyclometallation reaction of dimethylbenzylamine with [IrCl2Cp*]2: role of the chelating base.

artículo científico publicado en 2009

Computational chemistry of molecular inorganic systems ⬇️

artículo científico publicado el 29 de septiembre de 2011

Computational studies on the mechanism of the gold(i)-catalysed rearrangement of cyclopropenes

artículo científico publicado en 2012

Computational study of ethene hydroarylation at [Ir(κ(2)-OAc)(PMe3)Cp]+.

artículo científico publicado en 2010

Computational study of the double C-Cl bond activation of dichloromethane and phosphine alkylation at [CoCl(PR3)3].

artículo científico publicado en 2013

Computational study of the mechanism of cyclometalation by palladium acetate

artículo científico publicado en 2005

Computational study of the reaction of C6F6 with [IrMe(PEt3)3]: identification of a phosphine-assisted C-F activation pathway via a metallophosphorane intermediate

artículo científico publicado en 2008

Correction: Dehydrocoupling of phosphine-boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies

scientific article published on 09 February 2016

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

article

Dehydrocoupling of phosphine-boranes using the [RhCp*Me(PMe)(CHCl)][BAr] precatalyst: stoichiometric and catalytic studies

Dehydrogenative boron homocoupling of an amine-borane

artículo científico publicado en 2013

Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts

artículo científico publicado en 2017

Electrophilic C-H activation at Cp*Ir: ancillary-ligand control of the mechanism of C-H activation

scientific article published on 01 April 2006

Exceedingly Facile Ph-X Activation (X = Cl, Br, I) with Ruthenium(II): Arresting Kinetics, Autocatalysis, and Mechanisms

artículo científico publicado en 2015

Experimental and Computational Studies of the Copper Borate Complexes [(NHC)Cu(HBEt3 )] and [(NHC)Cu(HB(C6 F5 )3 )].

artículo científico publicado en 2016

Experimental and DFT Studies Explain Solvent Control of C-H Activation and Product Selectivity in the Rh(III)-Catalyzed Formation of Neutral and Cationic Heterocycles

artículo científico publicado en 2015

Experimental and computational investigation of C-N bond activation in ruthenium N-heterocyclic carbene complexes.

artículo científico publicado en 2010

Fluxionality of [(Ph3P)3M(X)] (M = Rh, Ir). The red and orange forms of [(Ph3P)3Ir(Cl)]. Which phosphine dissociates faster from Wilkinson's catalyst?

artículo científico publicado en 2010

Fluxionality of [(Ph3P)3Rh(X)]: the extreme case of X = CF3

artículo científico publicado en 2009

Formation of [Ru(NHC)4(eta(2)-O2)H]+: an unusual, high frequency hydride chemical shift and facile, reversible coordination of O2.

artículo científico publicado en 2009

Gold(I)-catalysed direct thioetherifications using allylic alcohols: an experimental and computational study

artículo científico publicado en 2014

Gold-Catalyzed Proto- and Deuterodeboronation

artículo científico publicado en 2015

Icosahedral metallacarborane/carborane species derived from 1,1'-bis(o-carborane).

artículo científico publicado en 2015

Impact of the Novel Z-Acceptor Ligand Bis{(ortho-diphenylphosphino)phenyl}zinc (ZnPhos) on the Formation and Reactivity of Low-Coordinate Ru(0) Centers

artículo científico publicado en 2020

Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine).

artículo científico publicado en 2008

Isomerisation of nido-[C2B10H12]2- dianions: unprecedented rearrangements and new structural motifs in carborane cluster chemistry.

artículo científico publicado en 2015

Isothiourea-catalysed enantioselective pyrrolizine synthesis: synthetic and computational studies.

artículo científico publicado en 2016

Mechanisms of C-H bond activation: rich synergy between computation and experiment.

artículo científico publicado en 2009

Mechanisms of catalyst poisoning in palladium-catalyzed cyanation of haloarenes. remarkably facile C-N bond activation in the [(Ph3P)4Pd]/[Bu4N]+ CN- system.

artículo científico publicado en 2008

Mild sp2Carbon-Oxygen Bond Activation by an Isolable Ruthenium(II) Bis(dinitrogen) Complex: Experiment and Theory

artículo científico publicado en 2017

Model studies of beta-scission ring-opening reactions of cyclohexyloxy radicals: application to thermal rearrangements of dispiro-1,2,4-trioxanes

artículo científico publicado en 2007

Modulation of σ-Alkane Interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) Systems by Variation of the Chelating Phosphine and Alkane: Access to η2,η2-σ-Alkane Rh(I), η1-σ-Alkane Rh(III) Complexes, and Alkane Encapsula

scientific article published in 2018

N,N-Chelate-control on the regioselectivity in acetate-assisted C-H activation

artículo científico publicado en 2013

New chemistry of 1,2-closo-P2B10H10 and 1,2-closo-As2B10H10; in silico and gas electron diffraction structures, and new metalladiphospha- and metalladiarsaboranes

artículo científico publicado en 2011

On the prebiotic potential of reduced oxidation state phosphorus: the H-phosphinate-pyruvate system

artículo científico publicado en 2010

Palladium-catalyzed direct C-H functionalization of benzoquinone

artículo científico publicado en 2014

Photochemical isomerization of N-heterocyclic carbene ruthenium hydride complexes: in situ photolysis, parahydrogen, and computational studies

artículo científico publicado en 2006

Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation.

artículo científico publicado en 2010

Redox-mediated reactions of vinylferrocene: toward redox auxiliaries

artículo científico publicado en 2016

Reductive Elimination at Carbon under Steric Control

scientific article published on 14 June 2019

Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes

scientific article published on 16 July 2019

Room Temperature Iron-Catalyzed Transfer Hydrogenation and Regioselective Deuteration of Carbon-Carbon Double Bonds

artículo científico publicado en 2018

Room Temperature Regioselective Catalytic Hydrodefluorination of Fluoroarenes with trans-[Ru(NHC)4 H2 ] through a Concerted Nucleophilic Ru-H Attack Pathway

artículo científico publicado en 2017

Room-temperature C-C bond cleavage of an arene by a metallacarborane

artículo científico publicado en 2010

Selective C-H Activation at a Molecular Rhodium Sigma-Alkane Complex by Solid/Gas Single-Crystal to Single-Crystal H/D Exchange

artículo científico publicado en 2016

Smooth C(alkyl)–H bond activation in rhodium complexes comprising abnormal carbene ligands

Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates

artículo científico publicado en 2017

Solid-state synthesis and characterization of σ-alkane complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine).

artículo científico publicado en 2015

Spectroscopic, structural, computational and (spectro)electrochemical studies of icosahedral carboranes bearing fluorinated aryl groups

artículo científico publicado en 2011

Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex

artículo científico publicado en 2003

Supraicosahedral indenyl cobaltacarboranes.

artículo científico publicado en 2010

Symmetric and asymmetric 13-vertex bimetallacarboranes by polyhedral expansion

artículo científico publicado en 2007

Synthesis and characterization of a rhodium(I) σ-alkane complex in the solid state

artículo científico publicado en 2012

Synthesis of Functionalized 1,4-Azaborinines by the Cyclization of Di-tert-butyliminoborane and Alkynes

artículo científico publicado en 2016

Synthesis, Electronic Structure, and Magnetism of [Ni(6-Mes)2]+: A Two-Coordinate Nickel(I) Complex Stabilized by Bulky N-Heterocyclic Carbenes

artículo científico publicado en 2013

Synthetic, structural and computational studies on adducts of the 4,1,2-SnC2B10 supraicosahedral stannacarborane.

artículo científico publicado en 2010

The F/Ph rearrangement reaction of [(Ph3P)3RhF], the fluoride congener of Wilkinson's catalyst

artículo científico publicado en 2005

The Importance of Kinetic and Thermodynamic Control when Assessing Mechanisms of Carboxylate-Assisted C-H Activation

artículo científico publicado en 2019

The Simplest Amino-borane H2 B=NH2 Trapped on a Rhodium Dimer: Pre-Catalysts for Amine-Borane Dehydropolymerization

artículo científico publicado en 2016

The conformations of 13-vertex ML2C2B10 metallacarboranes: experimental and computational studies

artículo científico publicado en 2007

The influence of N-heterocyclic carbenes (NHC) on the reactivity of [Ru(NHC)(4)H](+) with H(2), N(2), CO and O(2).

artículo científico publicado en 2009

The mechanism of reduction and metalation of para carboranes: the missing 13-vertex MC2B10 isomer

artículo científico publicado en 2007

Theoretical Study of the Electronic Structure of Group 6 [M(CO)(5)X](-) Species (X = NH(2), OH, Halide, H, CH(3)) and a Reinvestigation of the Role of pi-Donation in CO Lability

scientific article published on 01 October 1999

Three-coordinate nickel(I) complexes stabilised by six-, seven- and eight-membered ring n-heterocyclic carbenes: synthesis, EPR/DFT studies and catalytic activity

artículo científico publicado en 2013

Understanding electronic effects on carboxylate-assisted C-H activation at ruthenium: the importance of kinetic and thermodynamic control

scientific article published on 01 December 2019

Unprecedented steric deformation of ortho-carborane

artículo científico publicado en 2008

Well-Defined Heterobimetallic Reactivity at Unsupported Ruthenium-Indium Bonds.

artículo científico publicado en 2017

Why Is .beta.-Me Elimination Only Observed in d0 Early-Transition-Metal Complexes? An Organometallic Hyperconjugation Effect with Consequences for the Termination Step in Ziegler-Natta Catalysis

Why Nickel(II) Binds CO Best in Trigonal Bipyramidal and Square Pyramidal Geometries and Possible Consequences for CO Dehydrogenase

scholarly article by Stuart A Macgregor et al published August 1994 in Inorganic Chemistry

Zn-Promoted C-H Reductive Elimination and H2 Activation via a Dual Unsaturated Heterobimetallic Ru-Zn Intermediate

artículo científico publicado en 2020

[Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2

artículo científico publicado en 2011

[Pd4(μ3-SbMe3)4(SbMe3)4]: A Pd(0) Tetrahedron with μ3-Bridging Trimethylantimony Ligands.

artículo científico publicado en 2016

Lista de obras de Stuart A Macgregor

14-Vertex Heteroboranes with 14 Skeletal Electron Pairs: An Experimental and Computational Study.

A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes

A Rhodium-Pentane Sigma-Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques

A Structurally Characterized Cobalt(I) σ-Alkane Complex

A combined experimental and computational study of fluxional processes in sigma amine-borane complexes of rhodium and iridium.

A computational study of the methanolysis of palladium-acyl bonds

A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation.

Accurate computed spin-state energetics for Co(iii) complexes: implications for modelling homogeneous catalysis

Activation of H2 over the Ru-Zn Bond in the Transition Metal-Lewis Acid Heterobimetallic Species [Ru(IPr)2(CO)ZnEt](.).

Activation of an alkyl C-H bond geminal to an agostic interaction: an unusual mode of base-induced C-H activation

Adducts of the supraicosahedral stannacarborane 1,6-Me2-4,1,6-closo-SnC2B10H10; synthetic, structural and computational studies.

Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate

Base-Promoted, Remote C-H Activation at a Cationic (η-CMe)Ir(III) Center Involving Reversible C-C Bond Formation of Bound CMe

Benzoate Cyclometalation Enables Oxidative Addition of Haloarenes at a Ru(II) Center

Beyond the icosahedron: the first 13-vertex carborane

Catalytic Hydrodefluorination of Pentafluorobenzene by [Ru(NHC)(PPh3)2(CO)H2]: A Nucleophilic Attack by a Metal‐Bound Hydride Ligand Explains an Unusual ortho‐Regioselectivity ⬇️

Chirality Transfer in Gold(I)-Catalysed Direct Allylic Etherifications of Unactivated Alcohols: Experimental and Computational Study

Cobalt-Catalyzed Oxidase C-H/N-H Alkyne Annulation: Mechanistic Insights and Access to Anticancer Agents

Combined experimental and computational investigations of rhodium- and ruthenium-catalyzed C-H functionalization of pyrazoles with alkynes

Combined experimental and computational investigations of rhodium-catalysed C - H functionalisation of pyrazoles with alkenes

Comparison of the photochemistry of organometallic N-heterocyclic carbene and phosphine complexes of manganese.

Competing C-F activation pathways in the reaction of Pt(0) with fluoropyridines: phosphine-assistance versus oxidative addition

Computation provides chemical insight into the diverse hydride NMR chemical shifts of [Ru(NHC)4(L)H]0/+ species (NHC = N-heterocyclic carbene; L = vacant, H2, N2, CO, MeCN, O2, P4, SO2, H-, F- and Cl-) and their [Ru(R2PCH2CH2PR2)2(L)H]+ congeners.

Computational Studies of Carboxylate-Assisted C-H Activation and Functionalization at Group 8-10 Transition Metal Centers

Computational and synthetic studies on the cyclometallation reaction of dimethylbenzylamine with [IrCl2Cp*]2: role of the chelating base.

Computational chemistry of molecular inorganic systems ⬇️

Computational studies on the mechanism of the gold(i)-catalysed rearrangement of cyclopropenes

Computational study of ethene hydroarylation at [Ir(κ(2)-OAc)(PMe3)Cp]+.

Computational study of the double C-Cl bond activation of dichloromethane and phosphine alkylation at [CoCl(PR3)3].

Computational study of the mechanism of cyclometalation by palladium acetate

Computational study of the reaction of C6F6 with [IrMe(PEt3)3]: identification of a phosphine-assisted C-F activation pathway via a metallophosphorane intermediate

Correction: Dehydrocoupling of phosphine-boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

Dehydrocoupling of phosphine-boranes using the [RhCp*Me(PMe)(CHCl)][BAr] precatalyst: stoichiometric and catalytic studies

Dehydrogenative boron homocoupling of an amine-borane

Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts

Electrophilic C-H activation at Cp*Ir: ancillary-ligand control of the mechanism of C-H activation

Exceedingly Facile Ph-X Activation (X = Cl, Br, I) with Ruthenium(II): Arresting Kinetics, Autocatalysis, and Mechanisms

Experimental and Computational Studies of the Copper Borate Complexes [(NHC)Cu(HBEt3 )] and [(NHC)Cu(HB(C6 F5 )3 )].

Experimental and DFT Studies Explain Solvent Control of C-H Activation and Product Selectivity in the Rh(III)-Catalyzed Formation of Neutral and Cationic Heterocycles

Experimental and computational investigation of C-N bond activation in ruthenium N-heterocyclic carbene complexes.

Fluxionality of [(Ph3P)3M(X)] (M = Rh, Ir). The red and orange forms of [(Ph3P)3Ir(Cl)]. Which phosphine dissociates faster from Wilkinson's catalyst?

Fluxionality of [(Ph3P)3Rh(X)]: the extreme case of X = CF3

Formation of [Ru(NHC)4(eta(2)-O2)H]+: an unusual, high frequency hydride chemical shift and facile, reversible coordination of O2.

Gold(I)-catalysed direct thioetherifications using allylic alcohols: an experimental and computational study

Gold-Catalyzed Proto- and Deuterodeboronation

Icosahedral metallacarborane/carborane species derived from 1,1'-bis(o-carborane).

Impact of the Novel Z-Acceptor Ligand Bis{(ortho-diphenylphosphino)phenyl}zinc (ZnPhos) on the Formation and Reactivity of Low-Coordinate Ru(0) Centers

Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine).

Isomerisation of nido-[C2B10H12]2- dianions: unprecedented rearrangements and new structural motifs in carborane cluster chemistry.

Isothiourea-catalysed enantioselective pyrrolizine synthesis: synthetic and computational studies.

Mechanisms of C-H bond activation: rich synergy between computation and experiment.

Mechanisms of catalyst poisoning in palladium-catalyzed cyanation of haloarenes. remarkably facile C-N bond activation in the [(Ph3P)4Pd]/[Bu4N]+ CN- system.

Mild sp2Carbon-Oxygen Bond Activation by an Isolable Ruthenium(II) Bis(dinitrogen) Complex: Experiment and Theory

Model studies of beta-scission ring-opening reactions of cyclohexyloxy radicals: application to thermal rearrangements of dispiro-1,2,4-trioxanes

Modulation of σ-Alkane Interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) Systems by Variation of the Chelating Phosphine and Alkane: Access to η2,η2-σ-Alkane Rh(I), η1-σ-Alkane Rh(III) Complexes, and Alkane Encapsula

N,N-Chelate-control on the regioselectivity in acetate-assisted C-H activation

New chemistry of 1,2-closo-P2B10H10 and 1,2-closo-As2B10H10; in silico and gas electron diffraction structures, and new metalladiphospha- and metalladiarsaboranes

On the prebiotic potential of reduced oxidation state phosphorus: the H-phosphinate-pyruvate system

Palladium-catalyzed direct C-H functionalization of benzoquinone

Photochemical isomerization of N-heterocyclic carbene ruthenium hydride complexes: in situ photolysis, parahydrogen, and computational studies

Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation.

Redox-mediated reactions of vinylferrocene: toward redox auxiliaries

Reductive Elimination at Carbon under Steric Control

Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes

Room Temperature Iron-Catalyzed Transfer Hydrogenation and Regioselective Deuteration of Carbon-Carbon Double Bonds

Room Temperature Regioselective Catalytic Hydrodefluorination of Fluoroarenes with trans-[Ru(NHC)4 H2 ] through a Concerted Nucleophilic Ru-H Attack Pathway

Room-temperature C-C bond cleavage of an arene by a metallacarborane

Selective C-H Activation at a Molecular Rhodium Sigma-Alkane Complex by Solid/Gas Single-Crystal to Single-Crystal H/D Exchange

Smooth C(alkyl)–H bond activation in rhodium complexes comprising abnormal carbene ligands

Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates

Solid-state synthesis and characterization of σ-alkane complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine).

Spectroscopic, structural, computational and (spectro)electrochemical studies of icosahedral carboranes bearing fluorinated aryl groups

Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex

Supraicosahedral indenyl cobaltacarboranes.

Symmetric and asymmetric 13-vertex bimetallacarboranes by polyhedral expansion

Synthesis and characterization of a rhodium(I) σ-alkane complex in the solid state

Synthesis of Functionalized 1,4-Azaborinines by the Cyclization of Di-tert-butyliminoborane and Alkynes

Synthesis, Electronic Structure, and Magnetism of [Ni(6-Mes)2]+: A Two-Coordinate Nickel(I) Complex Stabilized by Bulky N-Heterocyclic Carbenes