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Lista de obras de Robert E. Mulvey

1-Alkali-metal-2-alkyl-1,2-dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

artículo científico publicado en 2017

A Record-Breaking Magnesium Hydride Molecular Cluster: Implications for Hydrogen Storage

article

A hetero-alkali-metal version of the utility amide LDA: lithium-potassium diisopropylamide

artículo científico publicado en 2013

A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base

artículo científico publicado en 2004

A mechanistic study of the C-P bond cleavage reaction of 1,2-(PH2)2-C6H4 with nBuLi/Sb(NMe2)3.

artículo científico publicado en 2008

A monomeric three-coordinate magnesium bis(amide).

artículo científico publicado en 2001

A new Na/Mg inverse crown ether

artículo científico publicado en 2003

A polymeric solvent-free variant of a hydridomagnesium inverse crown

artículo científico publicado en 2006

A structural and computational study of synthetically important alkali-metal/tetramethylpiperidide (TMP) amine solvates

artículo científico publicado en 2008

A μ4-oxide-containing a dimeric variant of a sodium dialkyl(amido)zincate reagent

article

Accessible heavier s-block dihydropyridines: structural elucidation and reactivity of isolable molecular hydride sources

article

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

article

Adding a Structural Context to the Deprotometalation and Trans-Metal Trapping Chemistry of Phenyl-Substituted Benzotriazole.

artículo científico publicado en 2015

After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products

article

Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic Molecule

article

Alkali-Metal-Mediated Manganation: A Method for Directly Attaching Manganese(II) Centers to Aromatic Frameworks

article

Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry

artículo científico publicado en 2019

Alkali-Metal-Mediated Zincation of Anisole: Synthesis and Structures of Three Instructive Ortho-Zincated Complexes

article

Alkali-Metal-Mediated Zincation of Ferrocene: Synthesis, Structure, and Reactivity of a Lithium Tmp/Zincate Reagent

article

Alkali-Metal-Mediated Zincation of Polycyclic Aromatic Hydrocarbons: Synthesis and Structures of Mono- and Dizincated Naphthalenes

article

Alkali-metal-mediated manganation(II) of naphthalenes: constructing metalla-anthracene and metalla-phenanthrene structures

artículo científico publicado en 2009

Alkali-metal-mediated manganationII of functionalized arenes and applications of ortho-manganated products in Pd-catalyzed cross-coupling reactions with iodobenzene.

artículo científico publicado en 2008

Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal–magnesium–alkoxide–diisopropylamides

article

Ambient temperature zincation of N-Boc pyrrolidine and its solvent dependency

article

An Unprecedented Hexapotassium-Hexamagnesium 24-Membered Macrocyclic Amide: A Polymetallic Cationic Host to Six Monodeprotonated Arene Anions This work was supported by the UK Engineering and Physical Science Research Council (Grant award No. GR/M78

artículo científico publicado en 2000

An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry ⬇️

artículo científico publicado el 21 de mayo de 2013

Avant-garde metalating agents: structural basis of alkali-metal-mediated metalation

artículo científico publicado en 2009

Backbone Reactivity of Lithium β-Diketiminate (NacNac) Complexes with CO2 , tBuNCO and iPrNCO

artículo científico publicado en 2019

Bis[(μ-cyclopentylamino-N:N)dimethylaluminium(III)]

artículo científico publicado en 2000

Building an extended inverse crown motif via alkali-metal-mediated alpha-magnesiation of furan

artículo científico publicado en 2006

Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran

artículo científico publicado en 2010

Closer insight into the reactivity of TMP-dialkyl zincates in directed ortho-zincation of anisole: experimental evidence of amido basicity and structural elucidation of key reaction intermediates

artículo científico publicado en 2009

Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set

scientific article published on 09 July 2018

Concealed cyclotrimeric polymorph of lithium 2,2,6,6-tetramethylpiperidide unconcealed: X-ray crystallographic and NMR spectroscopic studies

artículo científico publicado en 2013

Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity

article

Contrasting Synergistic Heterobimetallic (Na-Mg) and Homometallic (Na or Mg) Bases in Metallation Reactions of Dialkylphenylphosphines and Dialkylanilines: Lateral versus Ring Selectivities

artículo científico publicado en 2018

Contrasting the group 6 metal-metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies

artículo científico publicado en 2017

Crossing Organolithium Compounds with Organolithium Compounds: Molecular Squares and a Cage-Encapsulating Reaction

article

Crystal structure of a heavier alkali metal diisopropylamide complex: a discrete (KN)2 ring dimer with TMEDA chelation and short intramolecular K⋯H(C) contacts

article

Crystallographic characterisation of binary alkali metal alkoxide-magnesium bis(alkyl) mixtures: differential binding of Na+ and K+ to a common dinuclear diorganomagnesiate

artículo científico publicado en 2004

Dehydromethylation of alkali metal salts of the utility amide 2,2,6,6-tetramethylpiperidide (TMP)

article

Deprotonative metalation using ate compounds: synergy, synthesis, and structure building

artículo científico publicado en 2007

Developing a hetero-alkali-metal chemistry of 2,2,6,6-tetramethylpiperidide (TMP): stoichiometric and structural diversity within a series of lithium/sodium, lithium/potassium and sodium/potassium TMP compounds

artículo científico publicado en 2011

Developing lithium chemistry of 1,2-dihydropyridines: from kinetic intermediates to isolable characterized compounds

artículo científico publicado en 2015

Dichlorobis(dibenzylamino)bis(tetrahydrofuran)zirconium(IV) toluene hemisolvate

artículo científico publicado en 2001

Diisopropylamide and TMP turbo-Grignard reagents: a structural rationale for their contrasting reactivities.

artículo científico publicado en 2010

Direct C-H metalation with chromium(II) and iron(II): transition-metal host/benzenediide guest magnetic inverse-crown complexes.

artículo científico publicado en 2009

Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation

artículo científico publicado en 2014

Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation

artículo científico publicado en 2006

Diverse outcomes of CO2 fixation using alkali metal amides including formation of a heterobimetallic lithium-sodium carbamato-anhydride via lithium-sodium bis-hexamethyldisilazide

scientific article published on 01 January 2019

Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation

article

Dizincation of a 2-substituted thiophene: constructing a cage with a [16]crown-4 zincocyclic core

artículo científico publicado en 2012

Donor-activated alkali metal dipyridylamides: co-complexation reactions with zinc alkyls and reactivity studies with benzophenone

article

Donor-influenced Structure-Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido-Monohydrido-Dialkylaluminates

artículo científico publicado en 2018

Evaluating cis-2,6-dimethylpiperidide (cis-DMP) as a base component in lithium-mediated zincation chemistry

artículo científico publicado en 2013

Exploiting σ/π Coordination Isomerism to Prepare Homologous Organoalkali Metal (Li, Na, K) Monomers with Identical Ligand Sets

article

Exposing elusive cationic magnesium-chloro aggregates in aluminate complexes through donor control

artículo científico publicado en 2016

Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent

article

Formation of the Unprecedented Trilithio-Capped Heteroadamantanyl Iminoalane Anion [(HAl)4 (NPh)6 {Li(OEt2 )}3 ]- : An Open Cage Derived from a Rhombododecahedron

scientific article published on 01 November 2000

Heterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C–H bond cleavage/dimethylamino capture or intact DMPEA complex

article

Hexameric Mg-O stacks with six THF-solvated sodium amide appendages: "super" variants of inverse crown ethers generated by cleavage of THF

artículo científico publicado en 2002

Hydride encapsulation in s-block metal inverse crown chemistry

article

Interview with Robert Mulvey ⬇️

artículo científico publicado el 10 de abril de 2012

Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

artículo científico publicado en 2004

Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry.

artículo científico publicado en 2007

Ketone Deprotonation Mediated by Mono- and Heterobimetallic Alkali and Alkaline Earth Metal Amide Bases: Structural Characterization of Potassium, Calcium, and Mixed Potassium−Calcium Enolates

article

Landmark Crystal Structure of an Experimentally Utilized Tetralithium-Tetrapotassium Amide-Alkoxide Superbase

artículo científico publicado en 2001

Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane

article

LiTMP Trans-Metal-Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

artículo científico publicado en 2017

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

artículo científico publicado en 2016

Lithium and aluminium carbamato derivatives of the utility amide 2,2,6,6-tetramethylpiperidide

article

Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

artículo científico publicado en 2018

Lithium, sodium and potassium picolyl complexes: syntheses, structures and bonding

article

Lithium-Aluminate-Catalyzed Hydrophosphination Applications

artículo científico publicado en 2019

Main Group Metals for Homogeneous Catalysis

article published in 2017

Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc synergistic effects.

artículo científico publicado en 2011

Manganese(ii)–lithium and –sodium inverse crown ether (ICE) complexes

article

Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

artículo científico

Mixed lithium amide-lithium halide compounds: unusual halide-deficient amido metal anionic crowns

artículo científico publicado en 2011

Modifying alkylzinc reactivity with 2,2'-dipyridylamide: activation of tBu-Zn bonds for para-alkylation of benzophenone

artículo científico publicado en 2013

Molecular Structures of THF-Solvated Alkali-Metal 2,2,6,6-Tetramethylpiperidides Finally Revealed: X-ray Crystallographic, DFT, and NMR (including DOSY) Spectroscopic Studies

article

Monomerizing alkali-metal 3,5-dimethylbenzyl salts with tris(N, N-dimethyl-2-aminoethyl)amine (Me6TREN): structural and bonding implications

artículo científico publicado en 2013

N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: trapping oligomeric organo s-block fragments with NHCs

article

Neutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or four pyrrolyl ligands

article

New reactivity and structural insights of alkali-metal-mediated alumination in directed ortho-alumination of a tertiary aromatic amide

article

Organometallic polymers assembled from cation-pi interactions: use of ferrocene as a ditopic linker within the homologous series [{(Me3Si)2NM}2.(Cp2Fe)]infinity (M=Na, K, Rb, Cs; Cp=cyclopentadienyl).

artículo científico publicado en 2007

Organozinc pivalate reagents: segregation, solubility, stabilization, and structural insights

artículo científico publicado en 2014

Post-Metalation Structural Insights into the Use of Alkali-Metal-Mediated Zincation for Directedortho-Metalation of a Tertiary Aromatic Amide

article

Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

artículo científico publicado en 2009

Potassium-zinc induced synergic enhancement of the basicity of hexamethyldisilazide (HMDS) towards methylbenzene molecules

artículo científico publicado en 2003

Pre-Metalation Structural Insights into the Use of Alkali-Metal-Mediated Zincation for Directedortho-Metalation of a Tertiary Aromatic Amide

article

Reactions of ammonium salts with butyllithium and with lithium hydride: new routes to fully anhydrous inorganic lithium complexes

artículo científico publicado en 1987

Regioselective Tetrametalation of Ferrocene in a Single Reaction: Extension of s-Block Inverse Crown Chemistry to the d-Block This work was supported by the UK Engineering and Physical Science Research Council through grant award no GR/M78113.

artículo científico publicado en 2001

Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations

article

Remarkable Reaction of Hetero-S-Block-Metal Amides with Molecular Oxygen: Cationic (NMNMg)2 Ring Products (M=Li or Na) with Anionic Oxo or Peroxo Cores

scientific article published on 01 December 1998

Revealing the remarkable structural diversity of the alkali metal transfer agents of the trans-calix[2]benzene[2]pyrrolide ligand

artículo científico publicado en 2016

Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation

artículo científico publicado en 2005

Selective mono- and dimetallation of a group 3 sandwich complex

artículo científico publicado en 2019

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ-tBu)Zn(tBu)] towards TEMPO and chalcone

article

Sodium congener of the classical lithium methylchromate dimer: synthetic, X-ray crystallographic, and magnetic studies of Me8Cr2[Na(OEt2)]4.

artículo científico publicado en 2011

Sodium dialkyl-amidozincates: alkyl or amido bases? An experimental and theoretical case study

artículo científico publicado en 2005

Sodium-Mediated Manganation: Direct Mono- and Dimanganation of Benzene and Synthesis of a Transition-Metal Inverse-Crown Complex

article

Sodium-mediated magnesiation of thiophene and tetrahydrothiophene: structural contrasts with furan and tetrahydrofuran.

artículo científico publicado en 2010

Split Personality of Lithium Chloride: Recent Salt Effects in Organometallic Recipes

article

Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

article

Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

article

Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilino Ligand.

artículo científico publicado en 2016

Structural and magnetic insights into the trinuclear ferrocenophane and unexpected hydrido inverse crown products of alkali-metal-mediated manganation(II) of ferrocene

artículo científico publicado en 2009

Structural basis for regioisomerization in the alkali-metal-mediated zincation (AMMZn) of trifluoromethyl benzene by isolation of kinetic and thermodynamic intermediates.

artículo científico publicado en 2010

Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like Mg3(2,5-fur-di-yl)3 substructure.

artículo científico publicado en 2008

Structural elaboration of the surprising ortho-zincation of benzyl methyl ether

artículo científico publicado en 2010

Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone

artículo científico publicado en 2012

Structural tracking of the potassium-mediated magnesiation of anisole

artículo científico publicado en 2009

Structural variations in bimetallic sodium–magnesium and sodium–zinc ketimides, and a sodium–zinc alkide–alkoxide–amide: connections to ring-stacking, ring-laddering, and inverse crown concepts

article

Structural variations within group 1 (Li-Cs)+ (2,2,6,6-tetramethyl-1-piperidinyloxy)- complexes made via metallic reduction of the nitroxyl radical.

artículo científico publicado en 2009

Structurally Defined Reactions of Sodium TMP–Zincate with Nitrile Compounds: Synthesis of a Salt-Like Sodium Sodiumdizincate and Other Unexpected Ion-Pair Products

article

Structurally defined potassium-mediated zincation of pyridine and 4-R-substituted pyridines (R = Et, iPr, tBu, Ph, and Me2N) by using dialkyl-TMP-zincate bases

artículo científico publicado en 2009

Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures

artículo científico publicado en 2010

Structurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations

artículo científico publicado en 2011

Structurally stimulated deprotonation/alumination of the TMP anion

artículo científico publicado en 2010

Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation

article

Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines

artículo científico publicado en 2008

Synergic Monodeprotonation of Bis(benzene)chromium by Using Mixed Alkali Metal-Magnesium Amide Bases and Structural Characterization of the Heterotrimetallic Products

article

Synergic Synthesis of Benzannulated Zincabicyclic Complexes, α-Zincated N Ylides, through Sodium-TMEDA-Mediated Zincation of a Haloarene

article

Synergic sedation of sensitive anions: alkali-mediated zincation of cyclic ethers and ethene

artículo científico publicado en 2009

Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture.

artículo científico publicado en 2010

Synthesis and Crystal Structure of[{nBuMg(μ-TMP)}2] and of a Homometallic Inverse Crown in Tetranuclear[{nBuMg2[μ-N(H)Dipp]2(μ3-OnBu)}2]

article

Synthesis and characterisation of a series of alkylmagnesium amide and related oxygen-contaminated "alkoxy" compounds

artículo científico publicado en 2005

Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetylides: structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates.

artículo científico publicado en 2008

Synthesis and crystal structure of trimeric sodium 2,2,6,6-tetramethylpiperidide (NaTMP)

article

Synthesis and structure of the Li13 cage [{[OP(μ-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(μ-NtBu)]22− dianion

article

Synthesis of the mixed lithium–potassium–(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavityElectronic supplementary information (ESI) available: NMR s

article

Synthesis of zirconocene amides and ketimides and an investigation into their ethylene polymerization activity

Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†

article

Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation

artículo científico publicado en 2009

Synthetically important alkali-metal utility amides: lithium, sodium, and potassium hexamethyldisilazides, diisopropylamides, and tetramethylpiperidides

artículo científico publicado en 2013

Trans-Metal-Trapping: Concealed Crossover Complexes En Route to Transmetallation?

artículo científico publicado en 2018

Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.

artículo científico publicado en 2007

Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping

artículo científico publicado en 2016

Trapping, stabilization, and characterization of an enolate anion of a 1,6-adduct of benzophenone chelated by a sodium alkylamidozincate cation

artículo científico publicado en 2005

Trimagnesium-bridged trinuclear ferrocenophanes cocomplexed with solvated mononuclear alkali metal amide molecules

article

Tuning the basicity of synergic bimetallic reagents: switching the regioselectivity of the direct dimetalation of toluene from 2,5- to 3,5-positions

artículo científico publicado en 2008

Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

article

catena-Poly[sodium-μ2-(N,N,N',N'-tetra-methyl-ethane-1,2-diamine)-κ(2) N:N'-sodium-bis-[μ2-bis-(trimethyl-sil-yl)aza-nido-κ(2) N:N]]

artículo científico publicado en 2012

cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?

artículo científico publicado en 2009

“LiZn(TMP)3”, a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic Evidence

article

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