Lista de obras - Matthew Sigman - Dominio Público Uruguay

A Cancer-Selective Zinc Ionophore Inspired by the Natural Product Naamidine A

scientific article published on 08 January 2019

A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation

artículo científico publicado en 2019

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms

artículo científico publicado en 2019

Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines

artículo científico publicado en 2021

Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles

artículo científico publicado en 2019

Catalytic asymmetric C–H insertion reactions of vinyl carbocations

artículo científico publicado en 2022

Combining traditional 2D and modern physical organic-derived descriptors to predict enhanced enantioselectivity for the key aza-Michael conjugate addition in the synthesis of Prevymis™ (letermovir)

artículo científico publicado en 2018

Correction to "Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction"

artículo científico publicado en 2019

Correction to "Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes"

scientific article published on 13 December 2018

Correction to "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates"

scientific article published on 17 September 2019

Correction to "Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines"

artículo científico publicado en 2018

Developing a Predictive Solubility Model for Monomeric and Oligomeric Cyclopropenium-Based Flow Battery Catholytes

artículo científico publicado en 2019

Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration

scientific article published on 10 April 2019

Electrochemical Ruthenium-Catalyzed C-H Hydroxylation of Amine Derivatives in Aqueous Acid

scientific article published on 18 May 2020

Enantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterization

artículo científico publicado en 2018

Enantioselective Allenoate-Claisen Rearrangement Using Chiral Phosphate Catalysts

scientific article published on 23 March 2020

Enantioselective C2-alkylation of indoles via a redox-relay Heck reaction of 2-indole triflates

scientific article published on 11 December 2018

Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines.

artículo científico publicado en 2019

Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction

artículo científico publicado en 2019

Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer-Type Transformation using Phase-Transfer Catalysis.

artículo científico publicado en 2017

Enantioselective construction of remote tertiary carbon-fluorine bonds

artículo científico publicado en 2019

Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions

artículo científico publicado en 2018

Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes.

artículo científico publicado en 2017

Formation of Chiral Allylic Ethers via an Enantioselective Palladium-Catalyzed Alkenylation of Acyclic Enol Ethers.

artículo científico publicado en 2018

Generality-oriented optimization of enantioselective aminoxyl radical catalysis

artículo científico publicado en 2023

Integrating Electrochemical and Statistical Analysis Tools for Molecular Design and Mechanistic Understanding

scientific article published on 10 January 2020

Interrogation of 2,2'-Bipyrimidines as Low-Potential Two-Electron Electrolytes

artículo científico publicado en 2021

Inverting Conventional Chemoselectivity in Pd-Catalyzed Amine Arylations with Multiply Halogenated Pyridines.

artículo científico publicado en 2017

Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates

scientific article published on 11 January 2019

Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery

scientific article published on 10 September 2019

Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates.

artículo científico publicado en 2017

Mechanistic Studies Inform Design of Improved Ti(salen) Catalysts for Enantioselective [3 + 2] Cycloaddition

artículo científico publicado en 2020

Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization

scientific article published on 15 November 2019

Mechanistic Study of Ruthenium-Catalyzed C–H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest

scientific article published on 02 January 2019

Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C–H Functionalization Reactions

artículo científico publicado en 2022

Multidimensional Correlations in Asymmetric Catalysis through Parameterization of Uncatalyzed Transition States.

artículo científico publicado en 2017

Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines.

artículo científico publicado en 2017

Noncovalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis

artículo científico publicado en 2019

Organic Chemistry: A Call to Action for Diversity and Inclusion

artículo científico publicado en 2020

Palladium-Catalyzed Enantioselective Alkenylation of Enelactams Using a Relay Heck Strategy

artículo científico publicado en 2019

Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters.

artículo científico publicado en 2017

Palladium-Catalyzed Enantioselective Relay Heck Arylation of Enelactams: Accessing α,β-Unsaturated δ-Lactams.

artículo científico publicado en 2018

Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives

scientific article published on 17 June 2019

Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones

artículo científico publicado en 2018

Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.

artículo científico publicado en 2017

Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis.

artículo científico publicado en 2017

Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications.

artículo científico publicado en 2017

Predictive Multivariate Linear Regression Analysis Guides Successful Catalytic Enantioselective Minisci Reactions of Diazines

artículo científico publicado en 2019

Predictive and mechanistic multivariate linear regression models for reaction development.

artículo científico publicado en 2018

Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis

artículo científico publicado en 2017

Quantitative Modeling of Bis(pyridine)silver(I) Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates

artículo científico publicado en 2017

Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives

artículo científico publicado en 2017

Site-selective acylation of natural products with BINOL-derived phosphoric acids

scientific article published on 01 October 2019

The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes.

artículo científico publicado en 2017

Lista de obras de Matthew Sigman

A Cancer-Selective Zinc Ionophore Inspired by the Natural Product Naamidine A

A Physical Organic Approach to Tuning Reagents for Selective and Stable Methionine Bioconjugation

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms

Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines

Catalytic Carbonyl-Olefin Metathesis of Aliphatic Ketones: Iron(III) Homo-Dimers as Lewis Acidic Superelectrophiles

Catalytic asymmetric C–H insertion reactions of vinyl carbocations

Combining traditional 2D and modern physical organic-derived descriptors to predict enhanced enantioselectivity for the key aza-Michael conjugate addition in the synthesis of Prevymis™ (letermovir)

Correction to "Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction"

Correction to "Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes"

Correction to "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates"

Correction to "Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines"

Developing a Predictive Solubility Model for Monomeric and Oligomeric Cyclopropenium-Based Flow Battery Catholytes

Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration

Electrochemical Ruthenium-Catalyzed C-H Hydroxylation of Amine Derivatives in Aqueous Acid

Enantiodivergent Pd-catalyzed C-C bond formation enabled through ligand parameterization

Enantioselective Allenoate-Claisen Rearrangement Using Chiral Phosphate Catalysts

Enantioselective C2-alkylation of indoles via a redox-relay Heck reaction of 2-indole triflates

Enantioselective Markovnikov Addition of Carbamates to Allylic Alcohols for the Construction of α-Secondary and α-Tertiary Amines.

Enantioselective N-Alkylation of Indoles via an Intermolecular Aza-Wacker-Type Reaction

Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer-Type Transformation using Phase-Transfer Catalysis.

Enantioselective construction of remote tertiary carbon-fluorine bonds

Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactions

Exploiting and Understanding the Selectivity of Ru-N-Heterocyclic Carbene Metathesis Catalysts for the Ethenolysis of Cyclic Olefins to α,ω-Dienes.

Formation of Chiral Allylic Ethers via an Enantioselective Palladium-Catalyzed Alkenylation of Acyclic Enol Ethers.

Generality-oriented optimization of enantioselective aminoxyl radical catalysis

Integrating Electrochemical and Statistical Analysis Tools for Molecular Design and Mechanistic Understanding

Interrogation of 2,2'-Bipyrimidines as Low-Potential Two-Electron Electrolytes

Inverting Conventional Chemoselectivity in Pd-Catalyzed Amine Arylations with Multiply Halogenated Pyridines.

Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates

Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery

Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates.

Mechanistic Studies Inform Design of Improved Ti(salen) Catalysts for Enantioselective [3 + 2] Cycloaddition

Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization

Mechanistic Study of Ruthenium-Catalyzed C–H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest

Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C–H Functionalization Reactions

Multidimensional Correlations in Asymmetric Catalysis through Parameterization of Uncatalyzed Transition States.

Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines.

Noncovalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis

Organic Chemistry: A Call to Action for Diversity and Inclusion

Palladium-Catalyzed Enantioselective Alkenylation of Enelactams Using a Relay Heck Strategy

Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters.

Palladium-Catalyzed Enantioselective Relay Heck Arylation of Enelactams: Accessing α,β-Unsaturated δ-Lactams.

Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives

Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones

Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.

Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis.

Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications.

Predictive Multivariate Linear Regression Analysis Guides Successful Catalytic Enantioselective Minisci Reactions of Diazines

Predictive and mechanistic multivariate linear regression models for reaction development.

Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis

Quantitative Modeling of Bis(pyridine)silver(I) Permanganate Oxidation of Hydantoin Derivatives: Guidelines for Predicting the Site of Oxidation in Complex Substrates

Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives

Site-selective acylation of natural products with BINOL-derived phosphoric acids

The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes.