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Lista de obras de Karl Wieghardt

(.mu.-Hydroxo)bis(.mu.-carboxylato)diruthenium and (.mu.-oxo)bis(.mu.-carboxylato)diruthenium Complexes Containing Weatk Intramolecular Ru.cntdot..cntdot..cntdot.Ru interactions

(1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)iron(III): a model for the iron-sulfur center in nitrile hydratase from Brevibacterium, sp

article

(Alpha-diimine)chromium complexes: molecular and electronic structures; a combined experimental and density functional theoretical study

artículo científico publicado en 2008

(Photo)ionization of tris(phenolato)iron(III) complexes: generation of phenoxyl radical as ligand

scientific article published in 1993

(μ-Hydroxo)bis(μ-acetato)dimetal complexes: structural and magnetochemical characterization of the Cr(III)Ni(II) and the Cr(III)Cr(III) species

article

.mu.-Oxalato-cobalt(III) complexes

scholarly article by K. L. Scott et al published March 1973 in Inorganic Chemistry

1,2-Bis(pyridine-2-carboxamido)benzenate(2−), (bpb)2-: A Noninnocent Ligand. Syntheses, Structures, and Mechanisms of Formation of [(n-Bu)4N][FeIV2(μ-N)(bpb)2(X)2] (X = CN-, N3-) and the Electronic Structures of [MIII(bpbox1)(CN)2] (M = Co, Fe)

scientific article published on 01 July 2000

1,4,7-Triazacyclononane and N,N'N''-trimethyl-1,4,7-triazacyclononane - two versatile macrocycles for the synthesis of monomeric and oligomeric metal complexes

2,2'-Bipyridine compounds of group 14 elements: a density functional theory study

artículo científico publicado en 2013

?-Hydroxo- and ?-Oxobis(?-acetato)diruthenium Complexes with Weak Intramolecular Ru?Ru Interactions

scholarly article by Peter Neubold et al published July 1988 in Angewandte Chemie International Edition

?-Nitro-di-?-hydroxo-bis[trinitro-kobaltat(III)]-Komplexe

A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(mu-OH)2NiL].

artículo científico publicado en 2008

A Binuclear, Mixed-Valence MoVI/V-Complex; The Crystal Structure of[(C9H21N3)2Mo2VIO5](Br3)2

scholarly article by Karl Wieghardt et al published November 1984 in Angewandte Chemie International Edition

A Hemerythrin Model Complex with Catalase Activity

article

A Magnetostructural and Electrochemical Study of CuII and FeIII Complexes Containing a Tetradentate Aminebis(phenolate) Ligand with a Pendent Tetrahydrofuran Group

A New Structure–Magnetism Relationship for Face-Sharing Transition-Metal Complexes with d3–d3 Electronic Configuration

scholarly article by Andrea Niemann et al published March 1992 in Angewandte Chemie International Edition

A Paramagnetic Copper(III) Complex Containing an Octahedral CuIIIS6 Coordination Polyhedron

scientific article published on 01 February 1999

A Step beyond the Feltham–Enemark Notation: Spectroscopic and Correlated ab Initio Computational Support for an Antiferromagnetically Coupled M(II)–(NO)− Description of Tp*M(NO) (M = Co, Ni)

article

A Structural Model for the Water-Oxidizing Manganese Cluster in Photosystem II

article

A heteropolyoxomolybdenum(VI)iron(III) cation. Synthesis and crystal structure of [(LFeIII)3MoVI4O14(µ-OMe)3](ClO4)2(L =N,N′,N″-trimethyl-1,4,7-triazacyclononane)

A new tetranuclear oxohydroxoiron(III) cluster: crystal structure, magnetic properties, and EXAFS investigation of [L4Fe4(.mu.-O)2(.mu.-OH)4]I4.cntdot.3H2O (L = 1,4,7-triazacyclononane)

A novel mixed-valent MnIII–MnIV-dimer, [L2Mn2(µ-O)2(µ-MeCO2)][BPh4]2·MeCN: crystal structure, magnetic properties, and e.s.r. spectrum (L = 1,4,7-triazacyclononane)

article published in 1987

A structural and magnetochemical study of some copper(II) complexes containing the ligands 1,4,7-triazacyclononane-N-acetate (L1) and N-(2-hydroxybenzyl)-1,4,7-triazacyclononane (HL2)

A structural, spectroscopic and computational study of the molecular and electronic structure of a [bis(α-diiminato)manganese(ii)] π radical complex

A theoretical study of zero-field splitting in Fe(IV)S6 (S=1) and Fe(III)S6 (S=1/2) core complexes, [FeIV(Et2dtc)3−n(mnt)n](n−1)− and [FeIII(Et2dtc)3−n(mnt)n]n− (n=0, 1, 2, 3): The origin of the magnetic anisotropy

A trinuclear complex containing MnIIMnIIIMnIV, radicals, quinone and chloride ligands potentially relevant to PS II

A unique series of dinuclear transition metal-polyradical complexes with a m-phenylenediamine spacer and their catalytic reactivity

artículo científico publicado en 2003

Accessing the different redox states of alpha-iminopyridines within cobalt complexes

artículo científico publicado en 2009

Acid-catalyzed anti .fwdarw. syn isomerization of the {WV2O4}2+ core. Crystal structures of anti-tetraoxobis(1,4,7-triazacyclononane)ditungsten(2+) diiodide and syn-bis[tetraoxobis(1,4,7-triazacyclononane)ditungsten(2+)] dithionate diiodide dihydrate

Activation energies for an intramolecular electron transfer reaction

Adiabatic intramolecular electron transfer in pyrazine-2,6-dicarboxylato-bridged complexes of cobalt(III)-ruthenium(II) and of cobalt(III)-iron(II): comparison of inner-sphere vs. outer-sphere activated complexes

scholarly article by Ademir Neves et al published October 1984 in Inorganic Chemistry

Aerial oxidation of primary alcohols and amines catalyzed by Cu(II) complexes of 2,2'-selenobis(4,6-di-tert-butylphenol) providing [O,Se,O]-donor atoms

artículo científico publicado en 2004

Aerobic Oxidation of Primary Alcohols (Including Methanol) by Copper(II)− and Zinc(II)−Phenoxyl Radical Catalysts

scholarly article by Phalguni Chaudhuri et al published October 1999 in Journal of the American Chemical Society

Aerobic Oxidation of Primary Alcohols by a New Mononuclear CuII-Radical Catalyst

scientific article published on 01 January 1999

An Electron-Transfer Series of High-Valent Chromium Complexes with Redox Non-Innocent, Non-Heme Ligands

scholarly article by Connie C. Lu et al published 11 August 2008 in Angewandte Chemie International Edition

An unusual CuII-promoted desulphurisation of thiourea: synthesis and crystal structure of di-µ-hydrogencyanamido(1–)-bis[(N,N′,N″-trimethyl-1,4,7-triazacyclononane)copper(II)] di-perchlorate monohydrate

Analysis and Interpretation of Metal-Radical Coupling in a Series of Square Planar Nickel Complexes: Correlated Ab Initio and Density Functional Investigation of [Ni(LISQ)2] (LISQ=3,5-di-tert-butyl-o-diiminobenzosemiquinonate(1-))

article

Anilino Radical Complexes of Cobalt(III) and Manganese(IV) and Comparison with Their Phenoxyl Analogues

scholarly article by Frank N. Penkert et al published October 2000 in Journal of the American Chemical Society

Assembly and structural characterization of binuclear µ-oxo-di-µ-acetato bridged complexes of manganese(III). Analogues of the di-iron(III) centre in hemerythrin

Asymmetric Heterodinuclear FeIIIMII (M = Zn, Cu, Ni, Fe, Mn), CoIIIFeII and FeIICoIII Species: Synthesis, Structure, Redox Behavior, and Magnetism

article

Asymmetric Heterodinuclear[L′Ru(μ-O)(μ-CH3CO2)2ML]2⊕ Complexes(M Fe, Mn, V): Electronic Structure and Magnetic Properties

scholarly article by Rainer Hotzelmann et al published June 1990 in Angewandte Chemie International Edition

Asymmetric mixed valence manganese complexes containing the [MnIII(µ-O)2(µ-MeCo2)MnIV]2+core and their catalase reactivity

article

Base-Induced Intramolecular Formation of a Mo?Mo Bond in [L2Mo2III?-OH(?-CH3CO2)2]3?(L =N,N?,N?-Trimethyl-1,4,7-triazacyclononane)

scholarly article by Ademir Neves et al published May 1988 in Angewandte Chemie International Edition

Bioinorganic model complexes for the active site in manganese containing catalases. The crystal structures of [L2MnII2(μ-OH)(μ-O2CCH3)2] (PF6)·CH3OH and [L′2MnIII2(μ-O)(μ-O2CCH3)2] (I3)I·H2O

article

Biomimetic metal-radical reactivity: aerial oxidation of alcohols, amines, aminophenols and catechols catalyzed by transition metal complexes

artículo científico publicado en 2005

Bis(alpha-diimine)iron complexes: electronic structure determination by spectroscopy and broken symmetry density functional theoretical calculations

artículo científico publicado en 2008

Bis(alpha-diimine)nickel complexes: molecular and electronic structure of three members of the electron-transfer series [Ni(L)(2)](z)() (z = 0, 1+, 2+) (L = 2-Phenyl-1,4-bis(isopropyl)-1,4-diazabutadiene). A combined experimental and theoretical stu

artículo científico publicado en 2007

Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives

article

Characterization and electronic structures of five members of the electron transfer series [Re(benzene-1,2-dithiolato)3](z) (z = 1+, 0, 1-, 2-, 3-): a spectroscopic and density functional theoretical study

artículo científico publicado en 2009

Characterization of a Genuine Iron(V)−Nitrido Species by Nuclear Resonant Vibrational Spectroscopy Coupled to Density Functional Calculations

article

Characterization of three members of the electron-transfer series [Fe(pda)2]n (n=2-, 1-, 0) by spectroscopy and density functional theoretical calculations [pda=redox non-innocent derivatives of N,N'-bis(pentafluorophenyl)-o-phenylenediamide(2-, 1.-

artículo científico publicado en 2008

Charakterisierung von Distorsionsisomeren der Anionen Pentacyano-oxo-molybdat(IV) sowie Tetracyano-oxo-aqua-molybdat(IV) im festen Zustand. Kristallstrukturen von [(C6H5)4P]3[MoO(CN)5] � 7 H2O(gr�n), [(C6H5)4As]2 [MoO(OH2)(CN)4] � 4 H2O (blau)

Chloride ligation in inorganic manganese model compounds relevant to photosystem II studied using X-ray absorption spectroscopy

artículo científico publicado en 2004

Co-ordination chemistry of 1,4,7-triazacyclononane (L) and its N-methylated derivative (L′) with silver(I) and mercury(II). The crystal structures of [AgL′2]PF6and [AgL′(SCN)]

Co-ordination chemistry of 1,4-bis(o-aminobenzyl)-1,4-diazacyclohexane (L) with nickel(II), copper(II) and palladium(II)

scholarly article by Oliver Schlager et al published 1996 in Dalton transactions RSC

Cobalt-59 nuclear magnetic resonance study of some polynuclear cobalt(III) complexes

scholarly article by Wolfgang Hackbusch et al published 1975 in Dalton transactions RSC

Cobalt-59 nuclear magnetic resonance study of µ-carboxylato-di-µ-hydroxo-bis[triamminecobalt(III)] complexes

scholarly article by Wolfgang Hackbusch et al published 1975 in Dalton transactions RSC

Competing Exchange Interactions and Ground-State Variability: Linear Homo- and Heterotrinuclear Manganese(III, IV) Complexes with Tris(dimethylglyoximato)metalate(II) Tetraanions as Bridging Ligands

Complexes of (hydroxylamido-O,N)molybdenum(VI). Preparation and crystal structures of [MoO(H(CH3)NO)2(HNC(S)N(CH3)O)] and [MoO(H(CH3)NO)(HNC(S)N(CH3)O)(H2NC(S)N(CH3)O)].H2O

article published in 1980

Complexes of thallium(I) and -(III) containing 1,4,7-triazacyclononane (L) ligands. Kinetics and mechanism of the reduction of [L2TlIII]3+. Crystal structure of (N,N',N"-trimethyl-1,4,7-triazacyclononane)thallium(I) hexafluorophosphate

scholarly article by Karl Wieghardt et al published April 1986 in Inorganic Chemistry

Configurational Isomerization ofN,N-Disubstituted Hydroxylamido(1-)-O,N-Molybdenum(VI) Complexes

scholarly article by Edgar Hofer et al published March 1981 in Angewandte Chemie International Edition

Coordinated o-Dithio- and o-Iminothiobenzosemiquinonate(1−) π Radicals in [MII(bpy)(L.)](PF6) Complexes

scholarly article by Prasanta Ghosh et al published 3 February 2003 in Angewandte Chemie International Edition

Coordination Modes, Oxidation, and Protonation Levels of 2,6-Pyridinediimine and 2,2′:6′,2′́-Terpyridine Ligands in New Complexes of Cobalt, Zirconium, and Ruthenium. An Experimental and Density Functional Theory Computational Study

artículo científico publicado en 2018

Coordination chemistry of 2-(8-aminoquinolino)-4,6-di-tert-butylphenol with manganese(IV), iron(III), and cobalt(II/III):N,O-coordinated o-iminobenzosemiquinonate(1-) pi radical monoanions vs.o-iminophenolate(2-) dianions

artículo científico publicado en 2003

Coordination chemistry of the bimacrocyclic, potentially binucleating ligand 1,2-bis(1,4,7-triaza-1-cyclononyl)ethane (dtne). Electrochemistry of its first transition series metal(II,III) complexes. Characterization of the new hemerythrin model compl

article

Coordination of 4,7-bis(2-hydroxybenzyl)-1-oxa-4,7-diazacyclononane (LH2) with manganese(II) and -(III) and zinc(II). Crystal structure of [(LH)2Zn2(.mu.-OH)](PF6).cntdot.0.5CH3OH

Coordination of the macrocyclic thioether 1,4,7-trithiacyclononane (TTCN) to chromium(3+) and to dimolybdenum(2+) di-acetato bridged molecules

Crown Thioether Complexes of AgI and CuI: The Crystal Structures of [{Ag3L3}AgL{AgL2}](ClO4)4 and [LCuI] (L = 1, 4, 7-Trithiacyclononane)

scholarly article by Heinz-Josef Küppers et al published June 1987 in Angewandte Chemie International Edition

Crystal structure of bis[bis(1,4,7-triazacyclononane)nickel(III)] dithionate heptahydrate and its single-crystal EPR spectrum

scholarly article by Karl Wieghardt et al published May 1986 in Inorganic Chemistry

Crystal structure of di-µ-hydroxo-trans-diaquo-bis[triamminecobalt(III)] tetranitrate dihydrate, and a possible mechanism for the formation of the cation

Crystallographic study of the low-spin iron(II) and iron(III) bis complexes of 1,4,7-triazacyclononane

article

Cubane-type Co4S4 clusters: synthesis, redox series, and magnetic ground states

artículo científico publicado en 2009

C–H Activation of co-ordinated crowns thioethers: deprotonation and ring-opening of [M([9]aneS3)2]3+(M = Co, Rh, Ir). Crystal structure of [Rh(H2CCHS(CH2)2S(CH2)2S)([9]aneS3)](PF6)2([9]aneS3= 1,4,7-trithiacyclononane)

Dependence of the Magnetic Superexchange on the CrċCr Distance in Dinuclear Chromium(II) Complexes

scholarly article by Ursula Bossek et al published September 1990 in Angewandte Chemie International Edition

Description of the ground-state covalencies of the bis(dithiolato) transition-metal complexes from X-ray absorption spectroscopy and time-dependent density-functional calculations

artículo científico publicado en 2007

Determining the Electronic Structure of a Series of [(phen)3M]0(M = Ti, V, Mo) and [(pdi)2M]n+(M = Cr, Mo) Complexes: Coordination of Neutral Ligands vs. π-Radical Anions

Di-?-sulfato-?-hydroxo-bis[triamminkobalt(III)]- und Di-?-selenato-?-hydroxo-bis[triamminkobalt(III)]-Komplexe

Die Kinetik und der Mechanismus der Reduktion zweier isomerer ?-Cyanobenzoato-di-?-hydroxo-bis [triamminkobalt(III)] Komplexe mit Chrom(II) und Vanadin(II)

Die Kristall- und Molekülstruktur von [Co3(NH3)8(OH)2(NO2)2(CN)2](ClO4)3.NaClO4.2H2O

article

Die Kristallstrukturen von Hexamminchrom(III)-Hexafluoromanganat(III) und Hexamminchrom(III)-Hexafluoroferrat(III)

Die Molek�l- und Kristallstruktur von Di-?-sulfato-?-hydroxo- bis[triamminkobalt(III)]sulfat-8-Hydrat

Die Molek�l- und Kristallstruktur von [Co3(CN)2 {(OH)4} (NH3)8][Co2(NO2)6 {(OH)2, NO2}] � H2O

Dieter Sellmann (1941–2003): Coordination Chemistry of N2 Fixation

scholarly article by Karl Wieghardt published 30 June 2003 in Angewandte Chemie International Edition

Dimerization Processes of Square Planar [PtII(tbpy)(dithiolato•)]+Radicals

Dinuclear Bis(1,2-diaryl-1,2-ethylenedithiolato)iron Complexes: [FeIII2(L)4]n(n= 2−, 1−, 0, 1+)

Dinuclear Manganese(II,III,IV) Model Complexes for the Active Center of the Metalloprotein Photosystem II: Synthesis, Magnetism, and Crystal Structure of [LMnIII(?-O)(?-CH3CO2)2MnIVL][ClO4]3 (L = N,N?N?-Trimethyl-1,4,7-triazacyclononane)

article

Dinuclear and mononuclear manganese(IV)-radical complexes and their catalytic catecholase activity

artículo científico publicado en 2004

Dinuclear cyano complexes of cobalt(III) and Iron(III) containing noninnocent 1,2,4,5-tetrakis(2-pyridinecarboxamido)benzene bridging ligands

artículo científico publicado en 2003

Dipicolinato(hydroxylamido-O,N)(nitrosyl)aquavanadate—A Nitrosyl Complex of Vanadium with“side on” Coordinated Hydroxylamine

scholarly article by Karl Wieghardt et al published May 1978 in Angewandte Chemie International Edition

Distortional Isomers of [LWOCl2]+ in the Solid State and in Solution; Crystal Structures of the Blue and Green Forms of [LWOCl2]PF6

scholarly article by Karl Wieghardt et al published September 1985 in Angewandte Chemie International Edition

Dithiolene radicals: Sulfur K-edge X-ray absorption spectroscopy and Harry's intuition

Divalent Transition Metal Complexes [LMII](ClO4)2 (M = Mn, Fe, Co, Ni, Cu, Pd) of the Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane (L)

article

Do S,S'-coordinated o-dithiobenzosemiquinonate(1-) radicals exist in coordination compounds? the [AuIII(1,2-C6H4S2)2]1 -/0 couple

artículo científico publicado en 2003

EPR and 55Mn cw-ENDOR study of an antiferrogmagnetically coupled dinuclear manganese (MnIII MnIV) complex

Effect of N-Methylation of Macrocyclic Amine Ligands on the Spin State of Iron(III): A Tale of Two Fluoro Complexes

article

Electron paramagnetic resonance and electron nuclear double resonance investigation of the diradical bis(alpha-iminopyridinato)zinc complex

artículo científico publicado en 2009

Electron transfer through a carbon–carbon triple bond: kinetics and mechanisms of the reductions of µ(carboxyacetylenecarboxylato-OO′)-di-µ-hydroxo-bis[triamminecobalt(III)] and related complexes by chromium(II) and vanadium(II)

Electronic Structure of 2,2′-Bipyridine Organotransition-Metal Complexes. Establishing the Ligand Oxidation Level by Density Functional Theoretical Calculations

Electronic Structure of Antiferromagnetically Coupled Dinuclear Manganese (MnIIIMnIV) Complexes Studied by Magnetic Resonance Techniques

article

Electronic Structure of Linear Thiophenolate-Bridged Heterotrinuclear Complexes [LFeMFeL]n+(M = Cr, Co, Fe;n= 1−3): Localized vs Delocalized Models

scientific article published in 1999

Electronic Structure of Nitric Oxide Adducts of Bis(diaryl-1,2-dithiolene)iron Compounds: Four-Membered Electron-Transfer Series [Fe(NO)(L)2]z(z= 1+, 0, 1−, 2−)

Electronic Structure of Square Planar Bis(benzene-1,2-dithiolato)metal Complexes [M(L)2]z(z= 2−, 1−, 0; M = Ni, Pd, Pt, Cu, Au): An Experimental, Density Functional, and Correlated ab Initio Study

Electronic Structure of a Weakly Antiferromagnetically Coupled MnIIMnIIIModel Relevant to Manganese Proteins: A Combined EPR,55Mn-ENDOR, and DFT Study

article

Electronic Structures and Spectroscopy of the Electron Transfer Series [Fe(NO)L2]z(z= 1+, 0, 1–, 2–,3–; L = Dithiolene)

Electronic Structures of the Electron Transfer Series [M(bpy)3]n, [M(tpy)2]n, and [Fe(tbpy)3]n(M = Fe, Ru;n= 3+, 2+, 1+, 0, 1-): A Mössbauer Spectroscopic and DFT Study

article

Electronic Structures of the [V(tbpy)3]z (z = 3+, 2+, 0, 1−) Electron Transfer Series

artículo científico publicado en 2012

Electronic Structures of “Low-Valent” Neutral Complexes [NiL2]0(S= 0; L = bpy, phen, tpy) - An Experimental and DFT Computational Study

article

Electronic and Molecular Structures of the Members of the Electron Transfer Series [Cr(tbpy)3]n(n= 3+, 2+, 1+, 0): An X-ray Absorption Spectroscopic and Density Functional Theoretical Study

article

Electronic structure of bis(imino)pyridine iron dichloride, monochloride, and neutral ligand complexes: a combined structural, spectroscopic, and computational study

artículo científico publicado en 2006

Electronic structure of linear thiophenolate-bridged heteronuclear complexes [LFeMFeL](n)(+) (M = Cr, Co, Fe; n = 1-3): a combination of kinetic exchange interaction and electron delocalization

artículo científico publicado en 2003

Electronic structure of mononuclear bis(1,2-diaryl-1,2-ethylenedithiolato)iron complexes containing a fifth cyanide or phosphite ligand: a combined experimental and computational study

artículo científico publicado en 2006

Electronic structure of the [tris(dithiolene)chromium](z) (z = 0, 1-, 2-, 3-) electron transfer series and their manganese(IV) analogues. An X-ray absorption spectroscopic and density functional theoretical study

artículo científico publicado en 2009

Electronic structure of the members of the electron transfer series [NiL](z) (z = 3+, 2+, 1+, 0) and [NiL(X)](n) (X = Cl, CO, P(OCH(3))(3)) species containing a tetradentate, redox-noninnocent, Schiff base macrocyclic ligand L: an experimental and d

artículo científico publicado en 2010

Electronic structures of [Ru(II)(cyclam)(Et(2)dtc)](+), [Ru(cyclam)(tdt)](+), and [Ru(cyclam)(tdt)](2+): an X-ray absorption spectroscopic and computational study (tdt = toluene-3,4-dithiolate; Et(2)dtc = N,N-diethyldithiocarbamate(1-)).

artículo científico publicado en 2009

Electronic structures of homoleptic [tris(2,2'-bipyridine)M]n complexes of the early transition metals (M = Sc, Y, Ti, Zr, Hf, V, Nb, Ta; n = 1+, 0, 1-, 2-, 3-): an experimental and density functional theoretical study

artículo científico publicado en 2013

Elektronentransfer bei Übergangsmetallkomplexen

Elektronentransferbarrieren als Funktion der Ligandenstruktur in CoN63+/CoN62+-Paaren Beziehungen zwischen der Struktur und der Redoxreaktivit�t

Encapsulation by a Chromium(III)-Containing Bicyclic Ligand Cage. Synthesis, Structures, and Physical Properties of Heterometal Complexes CrIIIMCrIII[M = (H+)2, Li(I), Mg(II), Cu(II), Ni(II), Ni(IV), Co(III), Fe(II), Fe(III), Mn(II)]

Exchange Coupling in Homo- and Heterodinuclear Complexes CuIIM [M = Cr(III), Mn(III), Mn(II), Fe(III), Co(III), Co(II), Ni(II), Cu(II), Zn(II)]. Synthesis, Structures, and Spectroscopic Properties

article

Exchange Coupling in Symmetricallysyn,syn-Mono(carboxylato)-Bridged Dinuclear Copper(II) Complexes

artículo científico publicado en 1996

Exchange Coupling in an Isostructural Series of Face-Sharing Bioctahedral Complexes [LM(II)(&mgr;-X)(3)M(II)L]BPh(4) (M = Mn, Fe, Co, Ni, Zn; X = Cl, Br; L = 1,4,7-Trimethyl-1,4,7-triazacyclononane).

artículo científico publicado en 1997

Exchange Interactions and Covalency in Dinuclear Complexes of Iron(III) and Gallium(III) Containing the Redox-Noninnocent Ligand 1,2-Bis(3,5-di-tert-butyl-2-hydroxyphenyl)oxamide

scholarly article by Udo Beckmann et al published May 2003 in European Journal of Inorganic Chemistry

Exchange and Double-Exchange Phenomena in Linear Homo- and Heterotrinuclear Nickel(II,III,IV) Complexes Containing Six μ2-Phenolato or μ2-Thiophenolato Bridging Ligands

scholarly article by Thomas Beissel et al published January 1996 in Journal of the American Chemical Society

Exchange coupling across multiple-atom bridges: crystal structure and magnetic properties of a chloranilate bridged dicopper(II) complex

Exchange coupling in tris(.mu.-hydroxo)bis[(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)] triperchlorate trihydrate

article

Exchange interactions in a trigonal chromium (III) dimer. Optical spectroscopy of tris-(μ-hydroxo)-bis-[(1,4,7-trimethyl-1, 4,7-triazacyclononane) chromium(III)] triperchlorate

article

Excited-State Contributions to Ground-State Properties of Mixed-Valence Dimers: Spectral and Electronic-Structural Studies of [Fe2(OH)3(tmtacn)2]2+Related to the [Fe2S2]+Active Sites of Plant-Type Ferredoxins

article

Excited-State Distortions and Electron Delocalization in Mixed-Valence Dimers: Vibronic Analysis of the Near-IR Absorption and Resonance Raman Profiles of [Fe(2)(OH)(3)(tmtacn)(2)](2+).

artículo científico publicado en 1996

Experimental Fingerprints for Redox-Active Terpyridine in [Cr(tpy)2](PF6)n (n = 3–0), and the Remarkable Electronic Structure of [Cr(tpy)2]1–

Ferromagnetic intramolecular interactions in a bis(.mu.-bromo)-bridged copper(II) dimeric compound: crystal structure and molecular structure determination, electron paramagnetic resonance studies, and magnetic susceptibility measurements on bis(.mu.

First-row transition metal complexes of the hexadentate macrocycle 1,4,7-tris(5-tert-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (LH3). Crystal structures of [LTiIV]BPh4, [LCrIII], [LFeIII], and [(LH)2FeIII2](ClO4)2.2H2O

First-row transition-metal complexes of mixed ‘pendant-arm’ derivatives of 1,4,7-triazacyclononane containing phenolate and carboxylate functional groups

article

From Structural Models of Galactose Oxidase to Homogeneous Catalysis: Efficient Aerobic Oxidation of Alcohols

artículo científico publicado en 1998

From a Paramagnetic, Mononuclear Supersulfidonickel(II) Complex to a Diamagnetic Dimer with a Four-Sulfur Two-Electron Bond

article

General route to .mu.-hydroxo-bis(.mu.-acetato)-bridged heterometal dinuclear complexes. Syntheses, magnetic and redox properties, electronic spectra, and molecular structures of the [Cr(III)-Co(II)] and [Cr(III)-Fe(II)] species

article

Hidden Noninnocence: Theoretical and Experimental Evidence for Redox Activity of a β-Diketiminate(1−) Ligand

article

High-field EPR investigations of MnIIIMnIV and MnIIMnIII states of dimanganese catalase and related model systems

article

How“Innocent” Are Pentane-2,4-dionebis(S-alkylisothiosemicarbazonato) Ligands in Biomimetic FeII and FeIV Complexes?

scholarly article by Ulrich Knof et al published November 1993 in Angewandte Chemie International Edition

Hydroxylamido(1-)-Komplexe des Titan(IV) und Zirkonium(IV) Die Kristall- und Molek�lstruktur von Tetrakis-(N,N-diethylhydroxylamido(1-)-O,N)titan(IV)

Hydroxylamido(1-)-O,N-Komplexe des Molybd�ns(VI) mit terminalen Oxo-, Sulfido- und Selenido-Liganden Die Kristallstrukturen von [MoO2(C5H10NO)2] und von [MoS2(C5H10NO)2]

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Hydroxylamine complexes of chromium. The crystal structure of diaquanitrosyl(pyridine-2,6-dicarboxylato)chromium

Influence of the Redox Active Ligand on the Reactivity and Electronic Structure of a Series of Fe(TIM) Complexes

Integer-Spin Multifrequency EPR Spectroscopy of a Ferromagnetically Coupled, Oxo-Bridged MnIVMnIV Model Complex

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Intramolecular Electron Transfer from Iron(II) to Cobalt(III) through 2,4,6-Pyridinetricarboxylate as Mediating Bridging Ligand

scholarly article by Horst Bertram & Karl Wieghardt published March 1978 in Angewandte Chemie International Edition

Intramolecular Electron Transfer from Mn or Ligand Phenolate to Photochemically Generated RuIIIin Multinuclear Ru/Mn Complexes. Laser Flash Photolysis and EPR Studies on Photosystem II Models

scientific article published in 1999

Intramolecular Electron Transfer of Coordinated Pyrazinecarboxylato Radicals to Cobalt(III): A Pulse Radiolytic Study

scholarly article by Karl Wieghardt et al published August 1978 in Angewandte Chemie International Edition

Intramolecular Long-Range Exchange Coupling in Dinuclear Copper(II) Complexes with Cu…Cu Separations Greater than 10Å

Intramolecular Spin Interactions in Bis(phenoxyl)metal Complexes of Zinc(II) and Copper(II)

Intramolecular electron-transfer reactions in bridged polynuclear ruthenium(II)-cobalt(III) complexes containing a (.mu.-carboxylato)bis(.mu.-hydroxo)bis[(amine)cobalt(III)] and a pentaammineruthenium(II) structural unit

scholarly article by Ademir Neves et al published September 1984 in Journal of the American Chemical Society

Intramolecular, base-induced formation of a metal-metal bond in [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2]3+ (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). Crystal structures of [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2](ClO4)3.cntdot.H2O and [L2MoIII2(.mu.-O)(.mu.-CH

Intramolekulare Oxidation isomerer Dihydroxybenzoesäuren durch Kobalt(III): Kinetik und Mechanismus

Iron Complexes of New Pentadentate Ligands Containing the 1,4,7-Triazacyclononane-1,4-diacetate Motif. Spectroscopic, Electro-, and Photochemical Studies

article by Yu-Fei Song et al published March 2007 in Inorganic Chemistry

Isomeric pyrimidinecarboxylic acids as electron-mediating bridging ligands in the inner-sphere reduction of cobalt(III) by chromium(II)

scholarly article by H. Bertram et al published February 1978 in Inorganic Chemistry

Joint spectroscopic and theoretical investigations of transition metal complexes involving non-innocent ligands

Kinetics and mechanism of some reactions of chelated complexes of titanium(IV) with hydrogen peroxide. Synthesis and crystal structure of cesium tetra-.mu.-oxo-tetrakis[(nitrilotriacetato)titanate(IV)] hexahydrate

scholarly article by Karl Wieghardt et al published September 1980 in Inorganic Chemistry

Kinetics and mechanism of the equilibration reaction between (2,2′,2″-nitrilotriethoxy)nitrosylvanadate(1–) and cyanide. Crystal structures of sodium (2,2′,2″-nitrilotriethoxy)nitrosylvanadate(I)–sodium perchlorate tetrahydrate and of bar

Kinetics and mechanism of the outer-sphere electron-transfer-induced formation of cis-dioxovanadium(V) species from vanadyl(IV) complexes. Crystal structures of [VO(TCDA)].cntdot.H2O and [VO2(TCDAH)].cntdot.2H2O (TCDA = 1,4,7-triazacyclononane-N,N'-d

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Kinetics and mechanism of the oxidation of bis(.mu.-hydroxo)bis[aqua(1,4,7-triazacyclononane)molybdenum(III)](4+) by perchlorate. Acid-base-catalyzed trans .fwdarw. cis isomerization of bis(.mu.-oxo)-trans-dioxobis[(1,4,7-triazacyclononane)molybdenum

scholarly article by Manfred Hahn & Karl Wieghardt published November 1984 in Inorganic Chemistry

Kinetics of the diperoxovanadate(V)-monoperoxovanadate(V) conversion in perchloric acid media

article published in 1979

Kinetics, mechanism, and spectroscopy of the reversible binding of nitric oxide to aquated iron(II). An undergraduate text book reaction revisited

artículo científico publicado en 2002

Komplexchemie des Gallium(III) mit makrozyklischen Liganden Darstellung und Kristallstruktur von Di-?-hydroxo-?-acetato-bis[(1,4,7-triazacyclononan)gallium(III)]triiodid � Monohydrat

scholarly article by Karl Wieghardt et al published May 1986 in Journal of inorganic and general chemistry

Komplexe des Chroms mit 1,5,9-Triazacyclododecan: Darstellung, Magnetismus und Kristallstruktur von Tri-?-hydroxo-bis[(1,5,9-triazacyclododecan)chrom(III)] tribromid Dihydrat; Kinetik und Mechanismus der Br�ckenspaltung mit Hydroxidionen

Kronenthioetherkomplexe des Blei(II), Zink(II) und Cadmium (II) und Cadmium(II). Die Kristallstrukturen von [PbL2(ClO4)2] und [ZnL2](ClO4)2 � CH3CN (L = 1,4,7 - Trithiacyclononan)

Kronenthioetherkomplexe des Cobalt(III): Ligandenstruktur und Redoxreaktivit�t Struktur, Elektrochemie und Kinetik des Elektronenaustausches von [Co(tacn)(ttcn)]Br3 � 3 H2O (tacn = 1,4,7-Triazacyclononan, ttcn = 1,4,7-Trithiacyclononan)

scholarly article by H.-J. K�ppers et al published 1989 in Journal of inorganic and general chemistry

Ligand-Based Redox Isomers of [ZnII(C28H40NO2)2]: Molecular and Electronic Structures of a Diamagnetic Green and a Paramagnetic Red Form

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Ligating properties of monomeric cis-trioxometal(VI) complexes of molybdenum(VI) and tungsten(VI). Preparation and spectroscopic characterization of LMO3 and [(LMO3)4CoII](ClO4)2 (M = Mo, W; L = cyclic triamine)

scholarly article by Partha S. Roy & Karl Wieghardt published June 1987 in Inorganic Chemistry

Linear trinuclear oximato-bridged complexes MnIII,IVMIIMnIII,IV (M = Zn, Cu or Mn): synthesis, structure, redox behaviour and magnetism ‡

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Linkage isomerism in exchange coupled dinuclear Ni(II) complexes with three azide bridges; tris(μ-1,1-azido) versus tris(μ-1,3-azido) binding. Crystal structures of [L2Ni2(μ-1,1-N3)3]ClO4 and [L2Ni2(N3)2-(μ-1,3-N3)2] (L = 1,4,7-trimethyl-1,4,7-tr

Long-Distance Magnetic Interaction between a MnIIIMnIV (S=1/2) Core and an Organic Radical: A Spectroscopic Model for the S2Yz. State of Photosystem II

scholarly article by Dana S. Marlin et al published 16 December 2002 in Angewandte Chemie International Edition

Long-range exchange interactions and integer-spin S(t) = 2 EPR spectra of a Cr(III)Zn(II)Cr(III) species with multiplet mixing.

artículo científico publicado en 2001

Macrocyclic complexes of indium(III): novel .mu.-hydroxo- and .mu.-oxo-bridged complexes. Crystal structures of [L4In4(.mu.-OH)6](S2O6)3.4H2O and [L2In2(CH3CO2)4(.mu.-O)].2NaClO4 (L = 1,4,7-triazacyclononane)

scholarly article by Karl Wieghardt et al published May 1986 in Inorganic Chemistry

Macrocyclic complexes of lead(II): crystal structures of LPb(ClO4)2 and LPb(NO3)2 (L = 1,4,7-triazacyclononane)

Magnetic exchange coupling in a nearly linear iron(III)nickel(II)nickel(II)iron(III) complex

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Magnetic exchange interactions in some novel .mu.-azido-bridged copper(II) dimers. Crystal structures of [L2Cu2(.mu.-N3)(N3)2](ClO4).cntdot.H2O, LCu(N3)2, [L2Cu2(.mu.-N3)2(ClO4)2], and L'Cu(N3)2 (L = N,N',N"-trimethyl-1,4,7-triazacyclononane and L' =

Magnetic interactions in dinuclear Mn(III)Mn(IV) complexes covalently tethered to organic radicals: spectroscopic models for the S(2)Y(z)(*) state of photosystem II.

artículo científico publicado en 2005

Magnetic properties of an octanuclear iron(III) cation

Manganese complexes of mixed O, X, O-donor ligands (X = S or Se): synthesis, characterization and catalytic reactivity

article

Mehrkernige Kobalt(III)-Ammin-Komplexe mit Oxalat als zwei- und dreiz�hnigem Liganden

Metal-to-ligand electron transfer in diiminopyridine complexes of Mn-Zn. A theoretical study.

artículo científico publicado en 2001

Metal-versusLigand-Centered Oxidations in Phenolato−Vanadium and −Cobalt Complexes: Characterization of Phenoxyl−Cobalt(III) Species

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Metallocorroles with Formally Tetravalent Iron

scholarly article by Emanuel Vogel et al published 18 April 1994 in Angewandte Chemie International Edition

Mixed-valent [FeIV(mu-O)(mu-carboxylato)2FeIII]3+ core

artículo científico publicado en 2003

Model compounds for the oxidized uteroferrin-phosphate complex. Syntheses, crystal structures, and magnetic properties of .mu.-phosphato-, .mu.-arsenato-, and .mu.-chromato-bridged binuclear iron(III) complexes

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Moderately strong antiferromagnetic exchange coupling in a dinuclear complex containing a µ-hydroxo-µ-carboxylatodicopper(II) core

Molecular Recognition of Hexaaqua Transition Metal(II) Ions

scholarly article by Ulf Auerbach et al published May 1993 in Angewandte Chemie International Edition

Molecular and Electronic Structure of Nitridochromium(V) Complexes with Macrocyclic Amine Ligands

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Molecular and Electronic Structure of Nitridocyanometalates of Chromium(V) and Manganese(V): A Combined Experimental and DFT Study

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Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n(n= 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)†

artículo científico publicado en 2000

Molecular and Electronic Structures of Homoleptic Six-Coordinate Cobalt(I) Complexes of 2,2':6',2″-Terpyridine, 2,2'-Bipyridine, and 1,10-Phenanthroline. An Experimental and Computational Study

artículo científico publicado en 2015

Molecular and Electronic Structures of Mononuclear and Dinuclear Titanium Complexes Containing π-Radical Anions of 2,2′-Bipyridine and 1,10-Phenanthroline: An Experimental and DFT Computational Study

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Molecular and Electronic Structures of Oxo-bis(benzene-1,2-dithiolato)chromate(V) Monoanions. A Combined Experimental and Density Functional Study

Molecular and electronic structure of [Mn(V)N(cyclam-acetato)]PF6. A combined experimental and DFT study.

artículo científico publicado en 2001

Molecular and electronic structure of a mixed-valent class II, dinuclear complex containing a linear [FeII–O–FeIII]3+ core

Molecular and electronic structure of five-coordinate complexes of iron(II/III) containing o-diiminobenzosemiquinonate(1-) pi radical ligands

artículo científico publicado en 2005

Molecular and electronic structure of four- and five-coordinate cobalt complexes containing two o-phenylenediamine- or two o-aminophenol-type ligands at various oxidation levels: an experimental, density functional, and correlated ab initio study

artículo científico publicado en 2004

Molecular and electronic structure of square planar complexes [PdII(tbpy)(LIPN,O)]0, [PdII(tbpy)(LISQN,O)](PF6), and [PdII(tbpy)(LIBQN,O)](PF6)(BF4)·2CH2Cl2: an o-iminophenolato based ligand centered, three-membered redox series

article

Molecular and electronic structure of square-planar gold complexes containing two 1,2-Di(4-tert-butylphenyl)ethylene-1,2-dithiolato ligands: [Au(2L)2]1+/0/1-/2-. A combined experimental and computational study

artículo científico publicado en 2007

Molecular and electronic structure of the square planar bis(o-amidobenzenethiolato)iron(III) anion and its bis(o-quinoxalinedithiolato)iron(III) analogue

artículo científico publicado en 2008

Molecular and electronic structures of bis-(o-diiminobenzosemiquinonato)metal(II) complexes (Ni, Pd, Pt), their monocations and -anions, and of dimeric dications containing weak metal-metal bonds

artículo científico publicado en 2003

Molecular and electronic structures of iron complexes containing N,S-coordinated, open-shell o-iminothionebenzosemiquinonate(1-) pi radicals

artículo científico publicado en 2003

Molecular and electronic structures of iron(II)/(III) complexes containing N,S-coordinated, closed-shell o-aminothiophenolato(1-) and o-iminothiophenolato(2-) ligands

artículo científico publicado en 2003

Molecular and electronic structures of new iron complexes containing N,S-coordinated o-iminothionebenzosemiquinonate(1-) π radical ligands: An experimental and density functional theoretical study

Molecular and electronic structures of six-coordinate "low-valent" [M((Me)bpy)3]0 (M = Ti, V, Cr, Mo) and [M(tpy)2]0 (M = Ti, V, Cr), and seven-coordinate [MoF((Me)bpy)3](PF6) and [MX(tpy)2](PF6) (M = Mo, X = Cl and M = W, X = F).

artículo científico publicado en 2013

Molecular and electronic structures of tetrahedral complexes of nickel and cobalt containing N,N'-disubstituted, bulky o-diiminobenzosemiquinonate(1-) pi-radical ligands

artículo científico publicado en 2006

Molecular and electronic structures of the members of the electron transfer series [Mn(bpy)3]n (n = 2+, 1+, 0, 1-) and [Mn(tpy)2]m (m = 4+, 3+, 2+, 1+, 0). An experimental and density functional theory study

artículo científico publicado en 2014

Molybdenum-95 NMR studies of dioxo, oxo-sulfido, oxo-selenido, and disulfido complexes of molybdenum(VI)

article

Mono- and Dinuclear Transition Metal Complexes of the Hexadentate Ligand Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane (L)

artículo científico publicado en 1996

Mono- and dinuclear (o-thioetherphenolato)-copper(II) complexes. Structural models for galactose oxidase

Mono- and dinuclear titanium(III)/titanium(IV) complexes with 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structures of a compositionally disordered green and a blue form of [LTiCl3]. Structures of [LTi(O)(NCS)2], [LTi(OCH3)Br2](ClO4), and [

article

Mono- and dinuclear zinc(II) complexes of biological relevance. Crystal structures of [L2Zn](PF6)2, [L'Zn(O2CPh)2(H2O)], [L'2Zn2(.mu.-OH)2](ClO4)2, and [L'2Zn2(.mu.-OH)(.mu.-CH3CO2)2](ClO4).cntdot.H2O (L = 1,4,7-triazacyclononane, L' = 1,4,7-trimethy

article published in 1992

Monoanionic Molybdenum and Tungsten Tris(dithiolene) Complexes: A Multifrequency EPR Study

scholarly article by Stephen Sproules et al published August 2011 in Inorganic Chemistry

Monomeric complexes of tungsten (0-VI) containing the ligand N,N',N"-trimethyl-1,4,7-triazacyclononane and their electrochemical properties. Preparation of [L2W2O5](PF6)2 and identification of its mixed-valence tungsten (VI)/tungsten(V) complex

scholarly article by Gabriele Backes-Dahmann & Karl Wieghardt published November 1985 in Inorganic Chemistry

Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)FeIII(N3)]+and Ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+in Water/Acetone Mixtures‡

scientific article published on 01 November 2000

Mononuclear and dinuclear ruthenium complexes containing the LRu(acac) fragment. Crystal structures of [LRuIII(acac)(OH)]PF6.cntdot.H2O, [{LRuIII(acac)}2(.mu.-O2H3)](PF6)3, and [{LRuIII(acac)}2(.mu.-O)](PF6)2. Characterization of the mixed-valence sp

scholarly article by Ralf Schneider et al published October 1993 in Inorganic Chemistry

Multifrequency EPR Investigation of Dimanganese Catalase and Related Mn(III)Mn(IV) Complexes

Mössbauer Spectroscopy of Spin-Coupled Iron−Chromium Complexes: μ-Hydroxo−Bis(μ-acetato)-Bridged Iron(2+)−Chromium(3+) and μ-Oxo−Bis(μ-acetato)-Bridged Iron(3+)−Chromium(3+)

scientific article published in 1996

Mössbauer study of a novel binuclear Fe(II/III) delocalized-valence compound

article published in 1990

Mössbauer, magnetic susceptibility, EPR, and EXAFS investigations of the vibrationally-induced low-spin/high-spin transition in a biomimetic Fe(III) complex

N,N-coordinated pi radical anions of S-methyl-1-phenyl-isothiosemicarbazide in two five-coordinate ferric complexes [Fe III(L Me*)(2)X] (X = CH3S-, Cl-).

artículo científico publicado en 2004

NMR spectra of dinuclear manganese and iron compounds containing 1,4,7-triazacyclononane and 1,4,7-trimethyl-1,4,7-triazacyclononane

Neue μ-Hydroxo-Übergangsmetallkomplexe, I. Darstellung und Struktur destrans-Diaqua-di-μ-hydroxo-bis[(1,4,7-triazacyclononan)cobalt(III)]-Kations; Kinetik und Mechanismus seiner Bildung

scholarly article by Karl Wieghardt et al published June 1979 in European Journal of Inorganic Chemistry

Neue μ-Hydroxo-Übergangsmetallkomplexe, II. Darstellung mehrkerniger Komplexe des Chroms(III) mit dreizähnigen Amin-Liganden. Struktur des μ[cis-Dihydroxo(O,O′)-hydroxo(l,4,7-triazacyclononan)chrom(III)]-di-μ-hydroxobis[(1,4,7-triazacyclononan

Neue μ-Hydroxo-Übergangsmetallkomplexe, III. Darstellung zweikerniger Komplexe des Rhodiums(III) mit einer μ-Acetato- und μ-Carbonato-Brücke. Die Struktur destrans-Diaqua-di-μ-hydroxo-bis[(1,4,7-triazacyclononan)rhodium(III)]-Kations

Neutral bis(1,4-diaza-1,3-butadiene)nickel complexes and their corresponding monocations: molecular and electronic structures. A combined experimental and density functional theoretical study

artículo científico publicado en 2007

Neutral bis(alpha-iminopyridine)metal complexes of the first-row transition ions (Cr, Mn, Fe, Co, Ni, Zn) and their monocationic analogues: mixed valency involving a redox noninnocent ligand system

artículo científico publicado en 2008

Neutral-Ligand Complexes of Bis(imino)pyridine Iron: Synthesis, Structure, and Spectroscopy

New .mu.-disulfido and .mu.-diselenido complexes of ruthenium(III). Crystal structure of [{LRuIII(acac)}2(.mu.-S2)](PF6)2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane; acac = pentane-2,4-dionate)

New complexes of chromium(III) containing organic π-radical ligands: an experimental and density functional theory study

artículo científico publicado en 2013

New mono- and dinuclear titanium(III) complexes. The crystal structure of and exchange coupling in [{LTiIII(NCO)2}2(.mu.-O)] (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)

scholarly article by Peter Jeske et al published January 1994 in Inorganic Chemistry

Nitridocyanometalates of CrV, MnV, and MnVI †

Nitridomanganese(V) and -(VI) Complexes Containing Macrocyclic Amine Ligands

artículo científico publicado en 1998

Noninnocence of the Ligand Glyoxal-bis(2-mercaptoanil). The Electronic Structures of [Fe(gma)]2, [Fe(gma)(py)]·py, [Fe(gma)(CN)]1-/0, [Fe(gma)I], and [Fe(gma)(PR3)n] (n= 1, 2). Experimental and Theoretical Evidence for “Excited State” Coordinati

article

Noninnocent Behavior of Nitrosoarene-Pyridine Hybrid Ligands: Ruthenium Complexes Bearing a 2-(2-Nitrosoaryl)Pyridine Monoanion Radical

article

Nonoxovanadium(IV) and oxovanadium(V) complexes with mixed O, X, O-donor ligands (X = S, Se, P, or PO).

artículo científico publicado en 2004

Novel cofacial bioctahedral complexes of ruthenium: syntheses and properties of the mixed-valence species [LRu2.5(.mu.-X)3Ru2.5L]2+ (X = Cl, Br, I, OH). Crystal structures of [LRu2.5(.mu.-OH)3Ru2.5L](PF6)2.cntdot.H2O and [LRuIV(.mu.-O)3RuIVL](PF6)2.c

article

Nucleophilic behaviour of monomeric cis-trioxotungsten(VI) complexes LWO3 (L = tridentate N-macrocycle)

O,N-Coordinated o-iminobenzoquinone and o-iminobenzosemiquinonato(1–) ligands in complexes of Ni(ii), Co(iii) and Fe(iii)

Octahedral (cis-cyclam)iron(III) complexes with O,N-coordinated o-iminosemiquinonate(1-) pi radicals and o-imidophenolate(2-) anions

artículo científico publicado en 2002

Octahedral monodithiolene complexes of cobalt(III) and chromium(III). Spectroscopic and density functional theoretical characterization of S,S'-coordinated benzene-1,2-dithiolate(1-) pi radicals.

artículo científico publicado en 2009

Octahedral monodithiolene complexes of iron: characterization of S,S'-coordinated dithiolate(1-) pi radical monoanions: a spectroscopic and density functional theoretical investigation.

artículo científico publicado en 2009

Octahedral non-heme non-oxo Fe(IV) species stabilized by a redox-innocent N-methylated cyclam-acetate ligand

artículo científico publicado en 2005

Octahedral non-heme oxo and non-oxo Fe(IV) complexes: an experimental/theoretical comparison

artículo científico publicado en 2006

One- and Two-Electron Reduced 1,2-Diketone Ligands in [CrIII(L•)3] (S= 0) and Na2(Et2O)2[VIV(LRed)3] (S=1/2)

One- and two-electron reduced 1,2-diketone ligands in [Zn(II)(L*)2(Et2O)], [Co(II)(L*)2(Et2O)], and Na2(Et2O)4[Co(II)(LRed)2].

artículo científico publicado en 2008

Optical absorption and luminescence spectroscopy of bis(acetato)hydroxobis(1,4,7-trimethyl-1,4,7-triazacyclononane)dichromium(3+) perchlorate and bis(acetato)hydroxobis(1,4,7-trimethyl-1,4,7-triazacyclononane)chromiumzinc(2+) perchlorate hemihydrate

article published in 1988

Outer Sphere Electron Transfer Reactions: A Novel Linear Relationship between the Selectivity and the Normal Potential of the Reducing Agent

Outer-sphere electron-transfer reactions of binuclear complexes of cobalt(III): assessment of an inductive effect on the rates. A linear relationship between the selectivity of redox reactions and the reduction potentials of the reductants

scholarly article by Hans Michael Huck & Karl Wieghardt published December 1980 in Inorganic Chemistry

Oxidative addition of carbon-carbon bonds with a redox-active bis(imino)pyridine iron complex

artículo científico publicado en 2012

Pendent arm macrocyclic complexes: crystal structures of AI(TCTA) and In(TS-TACN)

Phenoxyl Radical Complexes of Gallium, Scandium, Iron and Manganese

scholarly article by Britta Adam et al published February 1997 in Chemistry—A European Journal

Phenoxyl Radical Complexes of Zinc(II)

article

Phenoxyl radical complexes of chromium(III)

Phenoxyl radical complexes of chromium(III), manganese(III), cobalt(III), and nickel(II)

scholarly article by Jochen Müller et al published January 2000 in Inorganica Chimica Acta

Phenoxyl-copper(II) complexes: models for the active site of galactose oxidase

article

Phenylthiyl radical complexes of gallium(III), iron(III), and cobalt(III) and comparison with their phenoxyl analogues.

artículo científico publicado en 2001

Photolysis ofcis- andtrans-[FeIII(cyclam)(N3)2]+Complexes: Spectroscopic Characterization of a Nitridoiron(V) Species

article

Polynuclear Complexes Containing the Redox Noninnocent Schiff Base Ligand 2-[(E)-2-Mercaptophenylimino]methyl-4,6-di-tert-butylphenolate(2-)

Polynuclear complexes of the pendent-arm ligand 1,4,7-tris(acetophenoneoxime)-1,4,7-triazacyclononane

artículo científico publicado en 2002

Preparation and characterization of binuclear (1,4,7-triazacyclononane)molybdenum(III) complexes. Crystal structures of [MoIII2(.mu.-OH)2Cl2(C6H15N3)2]I2 and [MoIII2(.mu.-OH)2(.mu.-O2CCH3)(C6H15N3)2]I3.H2O

scholarly article by Karl Wieghardt et al published January 1984 in Inorganic Chemistry

Preparation and characterization of binuclear complexes of molybdenum(III) and molybdenum(V) via oxidative decarbonylation. Reactions of LMo(CO)3 (L = 1,5,9-triazacyclododecane) and crystal structure of anti-[L2Mo2O4](ClO4)2.2H2O

scholarly article by Karl Wieghardt et al published September 1985 in Inorganic Chemistry

Preparation and characterization of dipicolinatovanadium(V) complexes. Kinetics and mechanism of their reaction with hydrogen peroxide in acidic media

article published in 1978

Preparation and characterization of polynuclear cobalt(III) complexes with bridging carboxylato-ligands

scholarly article by Karl Wieghardt published 1973 in Dalton transactions RSC

Preparation and crystal structure of tetrameric [Ti4(C6H15N3)4(μ-O)6]Br4·4H2O containing an adamantane Ti4O6 Core

Preparation and electrochemical investigation of monomeric complexes of molybdenum(0-VI) with the ligand 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structure of [MoIVLBr3](PF6)

scholarly article by Gabriele Backes-Dahmann et al published February 1985 in Inorganic Chemistry

Preparation and magnetism of the binuclear iron(II) complexes [{Fe(C9H21N3)X2}2](X = NCS, NCO, or N3) and their reaction with NO. Crystal structures of [{Fe(C9H21N3)(NCS)2}2] and [Fe(C9H21N3)(NO)(N3)2]

article published in 1987

Preparation and properties of a novel cobalt-chromium(Co2IIICrIII) complex

scholarly article by Peter Leupin et al published April 1983 in Inorganic Chemistry

Preparation, Magnetism, and Crystal Structures of the Tautomers [LCu(?2-OH)2CuL](ClO4)2 (Blue) and [LCu(?2-OH2)(?2-O)CuL](ClO?4)?2 (Green): ?-Aqua-?-oxo vs. Di-?-hydroxo Linkage

Preparation, characterization, and electrochemistry of novel, air-stable nitrosyl complexes of molybdenum and tungsten of the type {M-NO}6,5,4 containing the ligand N,N',N"-trimethyl-1,4,7-triazacyclononane

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Preparation, molecular structure, and magnetism of bis(.mu.-carbonate)-.mu.-oxobis[1,4,7-trimethyl-1,4,7-triazacyclononane]diiron 4.25 hydrate

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Reactions of Molybdate(VI) with Hydroxylamine andN-Methylhydroxylamine

scholarly article by Karl Wieghardt et al published July 1979 in Angewandte Chemie International Edition

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Reaktionen von Hydroxylamin mit Molybdän(VI): Synthese von (Hydroxylamido-O,N)nitrosylmolybdän-Komplexen. Die Struktur des [(Hydroxylamido-O,N)nitrosylbis(1,10-phenanthrolin)molybdän]-Kations

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Redox-noninnocence of N,N'-bis(6-methyl-2-pyridylmethylene)ethane-1,2-diamine (L): synthesis and characterization of diamagnetic [Ni(II)2(L**)2] and [Zn(II)2(L)Cl4]((L**)2- pi diradical dianion of L).

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scholarly article by Haim Cohen et al published 1982 in Dalton transactions RSC

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Site-selective luminescence and excitation spectroscopy tris(.mu.-hydroxo)bis[(1,5,9-triazacyclododecane)dichromium(III)] tribromide dihydrate

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Spectroscopic and theoretical studies on a three-iron cluster with linear arrangement

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Synthese von N-phenolat-funktionalisierten Makrocyclen des 1,4,7-Trazacyclononans sowie des 1-Oxa-4,7-diazacyclononans und ihre Komplexchemie mit Eisen(III)

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Syntheses and crystal structures of complexes [L′O(H2O)V(µ-O)WO2L]Cl(ClO4) and [L′(acac)MoIII(µ-O)MoVIO2L′][BPh4]2(L,L′= 1,4,7-triazacyclononane and its 1,4,7-trimethyl derivative; acac = pentane-2,4-dionate)

Syntheses and magnetic properties of a heteropolyoxotungsten(VI)iron(III) cation and [LFeIII(.mu.-MO4)3FeIIIL] complexes (M = chromium(VI), molybdenum(VI)). Crystal structures of L2Fe2(CrO4)3.cntdot.H2O and [L3Fe3W4O14(OCH3)3](ClO4)2.cntdot.0.5H2O (L

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Syntheses of Monomeric, Dimeric, and Trimeric Complexes of Tungsten(VI), (V), (IV), and (III) with the 1,4,7-Triazacyclononane (L) Ligand. Crystal Structures of Dimeric [W2L2(?2?OH)2Br2]Br2 � 2H2O and of Trimeric [W3L3(?3?0)(?2-0)3][ZnBr4]2

Syntheses of [LRe(CO)3]+ and [LRe(NO)(CO)2]2+ and their oxidative decarbonylation product [LReO3]+. Crystal structure of [LReO3]Cl (L = 1,4,7-triazacyclononane)

article published in 1986

Syntheses, electrochemistry, and spectroscopic and magnetic properties of new mononuclear and binuclear complexes of vanadium(III), -(IV, and -(V) containing the tridentate macrocycle 1,4,7-trimethyl-1,4,7-triazacyclononane (L). Crystal structures of

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Syntheses, magnetic properties, and crystal structures of the dimers [LNi(µ-N3)3NiL](ClO4) and [L′2Ni2(N3)2(µ-N3)2](L =N,N′,N″-trimethyl-1,4,7-triazacyclononane; L′= 1,5,9-triazacyclododecane); µ-triazido-vs. µ-diazido-bridging

Syntheses, properties and electrochemistry of transition-metal complexes of the macrocycle 1,4,7-tris(2-pyridylmethyl)-1,4,7-triazacyclononane (L). Crystal structures of [NiL](ClO4)2, [MnL](ClO4)2, and [PdL](PF6)2 containing a distorted-square-base-p

article by Karl Wieghardt et al published December 1986 in Inorganic Chemistry

Synthesis and Characterization of Mononuclear Octahedral Titanium(IV) Complexes Containing Ti:O, Ti(O2), and Ti(OCH3)x (x = 1-3) Structural Units

scholarly article by Peter Jeske et al published May 1994 in Inorganic Chemistry

Synthesis and Characterization of Six-Coordinate Nitrido Complexes of Vanadium(V), Chromium(V), and Manganese(V). Isolation of a Dinuclear, Mixed-Valent μ-Nitrido Chromium(III)/Chromium(V) Species

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Synthesis and Characterization of Tris(bipyridyl)ruthenium(II)-Modified Mono-, Di-, and Trinuclear Manganese Complexes as Electron-Transfer Models for Photosystem II

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Synthesis and Electronic Structure of Reduced Bis(imino)pyridine Manganese Compounds

Synthesis and characterization of (.mu.-hydroxo)bis(.mu.-acetato)diiron(II) and (.mu.-oxo)bis(.mu.-acetato)diiron(III) 1,4,7-trimethyl-1,4,7-triazacyclononane complexes as models for binuclear iron centers in biology; properties of the mixed valence

scientific article published in 1987

Synthesis and characterization of the asymmetrically coordinated dinuclear complex [{L(Ph2acac)FeIII}(μ-O){FeIII(Cl4-cat)L}](ClO4) and its one-electron reduced and oxidized forms. Models for dinuclear non-heme active sites

Synthesis and co-ordination chemistry of the macrocycle 1,4,7-triisopropyl-1,4,7-triazacyclononane

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Synthesis and coordination chemistry of the hexadentate ligands 1,4,7-tris(2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L1) and 1,4,7-tris(3-tert-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L2). Crystal structures of [HL1CuII] and [L2FeIII]acacH

Synthesis and crystal structure of bis(.mu.-hydroxo)bis[oxo(1,4,7-triazacyclononane)vanadium(IV)] dibromide, a .mu.-hydroxo-bridged cation with antiferromagnetically coupled vanadium(IV) centers

scholarly article by Karl Wieghardt et al published May 1984 in Inorganic Chemistry

Synthesis and crystal structure of bis(1,4,7-triazacyclononane-NN′)platinum(II) dibromide dehydrate and its facile oxidation by oxygen: characterisation of bis(1,4,7-triazacyclononane-NN′N″)platinum(IV) tetraperchtorate

Synthesis and crystal structures of the dinuclear complexes [{LM(acac)2}2O](ClO4)2 (MZr(IV), Hf(IV); L=1,4,7-triazacyclononane) containing μ-oxo bridged eight-coordinate metal(IV) ions

Synthesis and electronic structure of cationic, neutral, and anionic bis(imino)pyridine iron alkyl complexes: evaluation of redox activity in single-component ethylene polymerization catalysts

artículo científico publicado en 2010

Synthesis and kinetics of the decarboxylation of two carbonate-bridged complexes of chromium(III) and rhodium(III). Crystal structure of .mu.-carbonato-di-.mu.-hydroxo-bis[(1,4,7-triazacyclononane)chromium(III)] diiodide hydrate

scholarly article by Karl Wieghardt et al published October 1980 in Inorganic Chemistry

Synthesis and molecular and electronic structures of reduced bis(imino)pyridine cobalt dinitrogen complexes: ligand versus metal reduction

artículo científico publicado en 2010

Synthesis and properties of binuclear [LTiCl2(µ-O)TiCl2L]n+(n= 0, 1, 2; L = 1,4,7-trimethyl-1,4,7-triazacyclononane) complexes. The crystal structure of the mixed valence compound [L2Ti2Cl4(µ-O)]Cl·2H2O

Synthesis and reactivity of [LRe(NO)(CO)(NCO)]+ (L = 1,4,7-triazacyclononane). Kinetics and mechanisms of its formation and transformation of [LRe(NO)(CO)X]n+ (X = NH3, Cl, HCO2-, CF3SO3-) and other species. Crystal structure of [LRe(NO)(CO)(NH3)]Br2

Synthesis and reactivity of air-stable carbonyl(methyl)nitrosyl(1,4,7-triazacyclononane)rhenium(1+). Kinetics and mechanism of its reactions with HX (X = Cl, Br, NO3). Formation of [{LRe(NO)(CO)}2(.mu.-CH2OCH2)]I2 containing a bridging 2-oxapropane-1

scholarly article by Christa Pomp & Karl Wieghardt published October 1988 in Inorganic Chemistry

Synthesis and reactivity of tricarbonyl(1,4,7-trithiacyclononane)manganese(1+): kinetics and mechanism of its formation and the crystal structure of [LMn(CO)3]3(PF6)2Br.2H2O (L = 1,4,7-trithiacyclononane)

article published in 1989

Synthesis and x-ray and neutron structures of anti-dihydridodi-.mu.-hydridobis(1,4,7-trimethyl-1,4,7-triazacyclononane)dirhodium(2+) hexafluorophosphate and a related species containing a syn-[Rh2(H)2(.mu.-H)2]2+ core. Isolation of tri-.mu.-hydridobi

article published in 1993

Synthesis of a Hydroxylamido(2?)-O,N-(nitrosyl)molybdenum Complex

scholarly article by Karl Wieghardt & Wolfgang Holzbach published July 1979 in Angewandte Chemie International Edition

Synthesis of a Tetranuclear Manganese(IV) Cluster with Adamantane Skeleton: [(C6H15N3)4Mn4O6]4+

scholarly article by Karl Wieghardt et al published April 1983 in Angewandte Chemie International Edition

Synthesis of low spin [MnII(L2)2]I2·2MeOH and [CuIII(L1)]via condensation of S-methylisothiosemicarbazide and pentane-2,4-dione in the presence of air

Synthesis of novel trimeric µ-oxo-bridged manganese(IV) complexes: [L3Mn3IV(µ2-O)3(µ3-XO4)]Br3(X = P, As, or VV; L = 1,4,7-triazacyclononane)

Synthesis, Structure, Magnetism, and Spectroscopic Properties of Some Mono- and Dinuclear Nickel Complexes Containing Noninnocent Pentane-2,4-dione Bis(S-alkylisothiosemicarbazonate)-Derived Ligands

scholarly article by Vladimir Arion et al published February 1997 in Inorganic Chemistry

Synthesis, crystal structures, Moessbauer, susceptibility, and EPR studies of a series of spin exchange coupled complexes containing the (.mu.-oxo)bis(.mu.-acetato)rutheniummetal core and its hydroxo-bridged analog (metal = vanadium, chromium, mangan

scientific article published in 1992

Synthesis, e.s.r. spectrum and magnetic properties of a heterobinuclear complex containing the {FeIII(µ-O)(µ-MeCO2)2MnIII}2+core

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Synthesis, electrochemistry, and magnetic properties of binuclear cobalt complexes containing the Co2(µ-X)(µ-carboxylato)2n+core (X = OH, Cl, or Br; n= 1–3). The crystal structures of [Co2II(µ-ClH2CCO2)2(µ-Cl)L2]PF6and [CoIICoIII(µ-MeCO2)2(µ-

scholarly article by Phalguni Chaudhuri et al published 1990 in Dalton transactions RSC

Synthesis, magnetic properties, redox behaviour, and crystal structure of the bridged binuclear nickel(II) complex [Ni2(µ-OH)(µ-CH3CO2)2L2]ClO4·H2O

scholarly article by Phalguni Chaudhuri et al published 1988 in Dalton transactions RSC

Synthesis, molecular and electronic structure of complexes [LNaMIVNaL](MRu,Os; H3L = 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)

Synthesis, properties and crystal structures of [MoVL(O)l2]PF6′[MoIVL(O)l2], [MoVL(O)(OMe)2]PF6′[MoVILO2(OMe)]BPh4and [Mo2L2O3(µ-O)l][BPh4]2(L = 1,4,7-trimethyl-1,4,7-triazacyclononane)

Synthesis, properties and crystal structures of [RuIII2(tacn)2(µ-OH)2(µ-CO3)]Br2·3.75H2O and [Ru3.52(dtne)(µ-O)2(µ-CO3)]PF6·5H2O [tacn = 1,4,7-triazacyclononane, dtne = 1,2-bis(1,4,7-triazacyclononan-1-yl)ethane]

Temperature Dependence of the Electron Transfer in a MnIIMnIII(μ-OH) Mixed-Valence Manganese Complex

artículo científico publicado en 1996

Tetradentate bis(o-iminobenzosemiquinonate(1-)) pi radical ligands and their o-aminophenolate(1-) derivatives in complexes of nickel(II), palladium(II), and copper(II).

artículo científico publicado en 2004

The (.mu.-oxo)bis[trichloroferrate(III)] dianion revisited

article published in 1993

The (.mu.-oxo)bis[trichloroferrate(III)] dianion revisited. [Erratum to document cited in CA118(12):113635j]

scholarly article published in Inorganic Chemistry

The Active Sites in Manganese-Containing Metalloproteins and Inorganic Model Complexes

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The Cation Di-?-oxo-trans-dioxobis[(1,4,7-triazacyclononane)molybdenum(V)](Mo?Mo) and its Acid-Catalyzedcis-Isomerization

scholarly article by Karl Wieghardt et al published June 1983 in Angewandte Chemie International Edition

The Chemistry of 1,4,7-Triazacyclononane and Related Tridentate Macrocyclic Compounds

The Cr2+and V2+reduction of µ-carboxylato dicobalt(III) ammine com-plexes. Part VII. The preparation and mechanism of reduction of µ-malonato-, µ-dimethylmalonato-, and µ-glycolato-complexes

The Cr2+and V2+reduction of µ-carboxylato dicobalt(III) ammine complexes. Part VI. Mechanism of the reduction of µ-p-formlybenzoato- and µ-o-formylbenzoato-complexes

The Cr2+and V2+reduction of µ-carboxylato dicobalt(III) ammine complexes. Part VIII. The mechanism of reduction of the di-µ-hydroxo-µ-oxalato-bis[triamminecobalt(III)] complex

The Cr2+and V2+reduction of µ-carboxylato-dicobalt(III) ammine complexes. Part III. The mechanism of reduction of µ-benzoato- and µ-o-chlorobenzoato-complexes

The Cr2+and V2+reduction of µ-carboxylato-dicobalt(III) ammine complexes. Part V. The mechanism of reduction of µ-maleato- and µ-fumarato-complexes

The Cr2+and V2+reductions of µ-carboxylato-dicobalt(III) ammine complexes. Part IV. The mechanism of reduction of the di-µ-hydroxo-µ-phthalato-bis[triamminecobalt(III)] and penta-amminephthalatocobalt(III) complexes

The Crystal Structure and Magnetic Behavior of [Cu2(dien)2CI2](CIO4)2

The Electronic Structure of Non-Heme Iron(III)−Hydroperoxo and Iron(III)−Peroxo Model Complexes Studied by Mössbauer and Electron Paramagnetic Resonance Spectroscopies

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The Electronic Structures of an Isostructural Series of Octahedral Nitrosyliron Complexes {Fe−NO}6,7,8Elucidated by Mössbauer Spectroscopy

artículo científico publicado en 2000

The First Mononuclear Nitrosyl(oxo)molybdenum Complex: Side-On Bonded andμ3-Bridging NO Ligands in[{MoL(NO)(O)(OH)}2]NaPF6·H2O

scholarly article by Jochen Böhmer et al published 2 August 1994 in Angewandte Chemie International Edition

The Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane and Its Complexes with Zinc(II), Cadmium(II), and Mercury(II) in Solution and in the Solid State

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The Mechanism of Substitution Reactions at[LRe(NO)(CO)(CH3)]⊕ in Acid Solution and the Structure of[{LRe(NO)(CO)}2(μ-CH2OCH2)]I2(L= 1,4,7-Triazacyclononane)

scholarly article by Christa Pomp et al published September 1987 in Angewandte Chemie International Edition

The Mixed-Valent (µ-Nitrido)dimanganese Complex Anion

artículo científico publicado en 1999

The Molecular and Electronic Structure of the Electron Transfer Series [Fe2(NO)2(S2C2R2)3]z(z= 0, −1, −2; R = phenyl,p-tolyl,p-tert-butylphenyl)†

The Novel Complex[LRuIV(μ-O)3RuIVL][PF6]2·H2O–a Molecular Section of the Structures of BaRuIVO3(High-Pressure Phase) and Ba5/6Sr1/6RuIVO3

scholarly article by Peter Neubold et al published June 1989 in Angewandte Chemie International Edition

The ReRe Bond in Binuclear Di-μ-oxorhenium Complexes Containing the 1,4,7–Triazacyclononane Ligand

scholarly article by Georg Böhm et al published July 1990 in Angewandte Chemie International Edition

The Rhenium Tris(dithiolene) Electron Transfer Series: Calibrating Covalency

scholarly article by Stephen Sproules et al published 19 December 2011 in Inorganic Chemistry

The S3 state of photosystem II: differences between the structure of the manganese complex in the S2 and S3 states determined by X-ray absorption spectroscopy

artículo científico publicado en 1990

The electrochemistry of a dimeric and two monomeric cis-trioxomolybdenum(VI) complexes containing cyclic triamine ligands in protic and aprotic media: model compounds for the active site informate dehydrogenase

article by Willy Herrmann & Karl Wieghardt published January 1986 in Polyhedron

The electron transfer series [Mo(III)(bpy)3](n) (n = 3+, 2+, 1+, 0, 1-), and the dinuclear species [{Mo(III)Cl((Me)bpy)2}2(μ2-O)]Cl2 and [{Mo(IV)(tpy·)2}2(μ2-MoO4)](PF6)2⋅4 MeCN.

artículo científico publicado en 2014

The electronic structure of the isoelectronic, square-planar complexes [FeII(L)2]2- and [CoIII(L Bu)2]- (L2- and (L Bu)2-=benzene-1,2-dithiolates): an experimental and density functional theoretical study

artículo científico publicado en 2005

The geometric and electronic structure of [(cyclam-acetato)Fe(N)]+: a genuine iron(v) species with a ground-state spin S = 1/2.

artículo científico publicado en 2005

The methanol-methanolate CH(3)OH...OCH3(-) bridging ligand: tuning of exchange coupling by hydrogen bonds in dimethoxo-bridged dichromium(III) complexes

artículo científico publicado en 2002

The missing link in the series [L2MIII2(µ-O)(µ-MeCO2)2]2+(M = Ti, V, Cr, Mn, Fe). Synthesis, crystal structure and magnetism of [L2CrIII2(µ-O)(µ-MeCO2)2][BPh4]2

The molecular and electronic structure of [FeIII2(t-buLISQ)4(μ-O)]—a dinuclear ferric complex containing four, O,N-coordinated o-iminobenzosemiquinonate(1−) π radical anions

The molecular and electronic structure of the asymmetric, trinuclear complex [LFeIII(μ-O) (μ-piv)2FeIII(μ-OH)(μ-piv)2FeIII(piv)2]·C6H5CH3 (L=1,4,7-trimethyl-1,4,7-triazacyclononane, piv=pivalate(1-))

article published in 1999

The molecular and electronic structures of monomeric cobalt complexes containing redox noninnocent o-aminobenzenethiolate ligands

scholarly article by Stephen Sproules et al published October 2010 in Inorganica Chimica Acta

The monoanionic pi-radical redox state of alpha-iminoketones in bis(ligand)metal complexes of nickel and cobalt

artículo científico publicado en 2007

The monofunctionalized 1,4,7-triazacyclononane derivatives 1,4,7-triazacyclononane-N-acetate (L1) and N-(2-hydroxybenzyl-1,4,7-triazacyclononane (HL2) and their complexes with vanadium(IV)/(V). Localized and delocalized electronic structures in compo

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The neutral complex [CrIII4(μ3-O)2(μ2-CH3CO2)7(tbpy0)(tbpy•)]0 — a tetranuclear Cr(III) species containing a neutral (bpy0) and a π-radical anion (bpy•)1–

The novel mixed-valence, exchange-coupled, class III dimer [L2Fe2(µ-OH)3]2+(L =N,N′,N″-trimethyl-1,4,7-triazacyclononane)

The reaction of cis-dioxo-bis(N-methylhydroxylamido(1-)-(O,N))molybdenum(VI) with alkyl-isocyanates. Crystal structure of cis-dioxo-bis(N-tert.butyl-N′-methyl-N′-oxo-ureato(1-)-(O,O′))molybdenum(VI)

The reactivity of cationic [trioxo-(1,4,7-triazacyclononane) rhenium(VII)] and oxorhenium(V) complexes containing triazamacrocycles

scholarly article by Christa Pomp & Karl Wieghardt published January 1988 in Polyhedron

The reactivity of the {Mn2(μ-O)(μ-CH3CO2)2}2+ core. The crystal structures of [LMn(N3)3] and [L′Mn(S4)(H2O)] (L = 1,4,7-triazacyclononane, L′= N,N′,N″-trimethyl-1,4,7-triazacyclononane)

The redox chemistry of LMO3·3H2O (MMo(VI), W(VI); L=1,4,7-triazacyclononane). The crystal structures of anti-[L2W2Cl2(μ-O)(μ-OH)]ZnCl4·2H2O and [L3Mo3O4] [Zn(Cl,Br)4]2·H2O

The trivalent copper complex of a conjugated bis-dithiocarbazate Schiff base: stabilization of Cu in three different oxidation states

artículo científico publicado en 2013

The[Mn2IV(μ-O)(μ-PhBO2)2]2+ Unit: A New Structural Model for Manganese-Containing Metalloproteins

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Theoretical Evidence for the Singlet Diradical Character of Square Planar Nickel Complexes Containing Twoo-Semiquinonato Type Ligands

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Thermal intramolecular cobalt(III)-iron(II) and cobalt(III)-titanium(III) electron-transfer reactions involving outer-sphere and inner-sphere precursor complexes

scholarly article by Horst Bertram & Karl Wieghardt published July 1979 in Inorganic Chemistry

Titanium(III) reductions of binuclear and tetranuclear .mu.-carboxylato cobalt(III)-ammine complexes. Evidence for remote attack of titanium(III) at an unprotonated carboxylate

scholarly article by Manfred Hery & Karl Wieghardt published May 1978 in Inorganic Chemistry

Transition-Metal Complexes with Singly Reduced 1,2-Diketone Radical Ligands

scholarly article by Geoffrey H. Spikes et al published 7 April 2008 in Angewandte Chemie International Edition

Trapping of the putative 1,2-dinitrosoarene intermediate of benzofuroxan tautomerization by coordination at ruthenium and exploration of its redox non-innocence

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Tris(pyridinealdoximato)metal complexes as ligands for the synthesis of asymmetric heterodinuclear Cr(III)M species [M = Zn(II), Cu(II), Ni(II), Fe(II), Mn(II), Cr(II), Co(III)]: a magneto-structural study.

artículo científico publicado en 2001

Trivalent Transition Metal Complexes [MIII(L-3H)] (M = Fe, Co) of the Triply Deprotonated Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane (L). Crystal Structure of [MnIV(L-3H)]BPh4

Trivalent iron and ruthenium complexes with a redox noninnocent (2-mercaptophenylimino)-methyl-4,6-di-tert-butylphenolate(2-) ligand

artículo científico publicado en 2009

Tuning of spin transition in radical-containing iron(III) complexes by remote ligand substituents

artículo científico publicado en 2005

Tuning the Electronic Structure of Halidobis(o-imino-benzosemiquinonato)iron(III) Complexes

scientific article published on 01 July 2001

Tuning the electronic structure of octahedral iron complexes [FeL(X)] (L = 1-alkyl-4,7-bis(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane, X = Cl, CH(3)O, CN, NO). The S = 1/2 <==>3/2 Spin equilibrium of [FeL(Pr)(NO)].

artículo científico publicado en 2002

Tuning the oxidation level, the spin state, and the degree of electron delocalization in homo- and heteroleptic bis(alpha-diimine)iron complexes

artículo científico publicado en 2009

Unusual solid-state reaction of [{CrL(acac)}2(µ-H3O2)][PF6]3. Isolation and crystal structures of [CrL(acac)F]PF6and [CrL(acac)(O2PF2)]PF6(L = 1,4,7-trimethyl-1,4,7-triazacyclononane, acac = pentane-2,4-dionate)

Variable-temperature single-crystal electron spin resonance study and crystal structure of bis(1,4,7-triazacyclononane)copper(2+) tricyanocuprate(2-) dihydrate at 110 and 293 K. Static and dynamic Jahn-Teller distortions in the CuN6 polyhedron

Vibrational Markers for the Open-Shell Character of Transition Metal Bis-dithiolenes: An Infrared, Resonance Raman, and Quantum Chemical Study

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Weak Pd…︁S Interactions in Palladium(II) Complexes with 1,4,7-Trithiacyclononane as Ligand

scholarly article by Karl Wieghardt et al published December 1986 in Angewandte Chemie. International edition in English

Zur Kenntnis der Hexafluoromanganate(III)

article published in 1971

Zur Koordinationschemie von cis-Trioxowolfram(VI)-Komplexen. Die Kristallstrukturen von LWO3 � 3 H2O, [L?WO2(OH)]Br, [LWO2Br]Br, [L2W2O5](S2O6) � 4 H2O und [LWO2(?-O)WO(O2)2(OH2)] (L = 1,4,7-Triazacyclononan; L? = 1,4,7-Trimethyl-1,4,7-triazacycl

[(TMEDA)Co(NO)2][BPh4]: A versatile synthetic entry point to four and five coordinate {Co(NO)2}10 complexes

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[L2Fe2II(?-OH)(?-CH3CO2)2](ClO4)�H2O, a Model Compound for the Diiron Centers in Deoxyhemerythrin

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[L2Mn2(.mu.-O)2(.mu.-O2)](ClO4)2. The first binuclear (.mu.-peroxo)dimanganese(IV) complex (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). A model for the S4 .fwdarw. S0 transformation in the oxygen-evolving complex in photosynthesis

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[Tris(o-iminosemiquinone)cobalt(III)]—a radical complex with an St = 3/2 ground state

scholarly article by Cláudio Nazari Verani et al published 1999 in Chemical Communications

[WL(NO)(O)(CH3)]— An Unusual Nitrosyltungsten Complex

[{(C6H15N3)Fe}2(μ-O)(μ-CH3CO2)2]2+ a Dinuclear Iron,(III)Complex with a Metazidohemerythrin-Type Structure

scholarly article by Karl Wieghardt et al published January 1983 in Angewandte Chemie International Edition

[{Fe(tim)}2]: an Fe-Fe dimer containing an unsupported metal-metal bond and redox-active N4 macrocyclic ligands

artículo científico publicado en 2009

cis-Tricyanotriamminkobalt(III)

o-Dithiolene and o-aminothiolate chemistry of iron: Synthesis, structure and reactivity

article published in 2010

o-Iminobenzosemiquinonato complexes of Mn(III) and Mn(IV). Synthesis and characterization of [Mn(III)(L(ISQ))(2)(L(AP))] (S(t) = 1) and [Mn(IV)(L(ISQ))(2)(L(AP)-H)] (S(t) = 1/2).

artículo científico publicado en 2002

o-Iminobenzosemiquinonato(1-) and o-amidophenolato(2-) complexes of palladium(II) and platinum(II): a combined experimental and density functional theoretical study

artículo científico publicado en 2002

Übergangsmetallkomplexe der Pyrazin-2,6-dicarbonsäure und der Pyridin-2,6-dicarbonsäure: Synthesen und Elektrochemie. Die Kristallstruktur von NH₄[RuCl₂(dipicH)₂]

μ-Carboxylatodi-μ-Hydroxo-Bis[Triamminecobalt(III)] Complexes

μ-Nitridodiiron Complexes with Asymmetric[FeIVN-FeIII]4+ and Symmetric[FeIVNFeIV]5+ Structural Elements

scholarly article by Thomas Jüstel et al published 31 March 1995 in Angewandte Chemie International Edition

μ-Oxodiiron(III) Complexes of Porphycenes

scholarly article by Michael Lausmann et al published 18 April 1994 in Angewandte Chemie International Edition

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