Lista de obras - Richard Schrock - Dominio Público Uruguay

A Well-Defined, Silica-Supported Tungsten Imido Alkylidene Olefin Metathesis Catalyst

scholarly article by Bouchra Rhers et al published July 2006 in Organometallics

A tungstenVI nitride having a W2(mu-N)2 core

artículo científico publicado en 2008

A well-defined silica-supported tungsten oxo alkylidene is a highly active alkene metathesis catalyst

artículo científico publicado en 2013

Alkylation of dinitrogen in [(HIPTNCH(2)CH(2))(3)N]Mo complexes (HIPT = 3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3)).

artículo científico publicado en 2009

Alkylidene and metalacyclic complexes of tungsten that contain a chiral biphenoxide ligand. synthesis, asymmetric ring-closing metathesis, and mechanistic investigations

artículo científico publicado en 2003

Alkylidene complexes of niobium and tantalum

scholarly article by Richard R. Schrock published March 1979 in Accounts of Chemical Research

Better characterization of surface organometallic catalysts through resolution enhancement in proton solid state NMR spectra

article by Frédéric Blanc et al published 13 November 2006 in Inorganic Chemistry

Beyond fossil fuel-driven nitrogen transformations

artículo científico publicado en 2018

Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes

artículo científico publicado en 2012

Bulky aryloxide ligand stabilizes a heterogeneous metathesis catalyst

artículo científico publicado en 2014

Catalyst-controlled stereoselective olefin metathesis as a principal strategy in multistep synthesis design: a concise route to (+)-neopeltolide

artículo científico publicado en 2014

Catalytic Z-selective cross-metathesis in complex molecule synthesis: a convergent stereoselective route to disorazole C1.

artículo científico publicado en 2014

Catalytic Z-selective olefin cross-metathesis for natural product synthesis

artículo científico publicado en 2011

Catalytic Z‐Selective Cross‐Metathesis with Secondary Silyl‐ and Benzyl‐Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis ⬇️

artículo científico publicado el 21 de junio de 2013

Catalytic asymmetric ring-opening metathesis/cross metathesis (AROM/CM) reactions. Mechanism and application to enantioselective synthesis of functionalized cyclopentanes

artículo científico publicado en 2001

Catalytic homologation of vinyltributylstannane to allyltributylstannane by Mo(IV) complexes in the presence of ethylene

artículo científico publicado en 2004

Catalytic hydrogenation using cationic rhodium complexes. I. Evolution of the catalytic system and the hydrogenation of olefins

article

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

artículo científico publicado en 2005

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

artículo científico publicado en 2003

Catalytic reduction of dinitrogen to ammonia at well-defined single metal sites

artículo científico publicado en 2005

Catalytic reduction of dinitrogen to ammonia by molybdenum: theory versus experiment

artículo científico publicado en 2008

Cationic Hafnium Alkyl Complexes that Are Stable toward β-Hydride Elimination below 10 °C and Active as Initiators for the Living Polymerization of 1-Hexene ⬇️

artículo científico publicado el 31 de octubre de 2001

Conformational disorder in long polyenes

Correction to "Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes".

artículo científico publicado en 2017

Dedication to the Special Volume for Dietmar Seyferth†

Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis

artículo científico publicado en 2009

Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts

artículo científico publicado en 2006

Dipyrrolyl precursors to bisalkoxide molybdenum olefin metathesis catalysts

artículo científico publicado en 2006

Direct observation of reaction intermediates for a well defined heterogeneous alkene metathesis catalyst

artículo científico publicado en 2008

Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis

artículo científico publicado en 2016

Dramatic Improvements of Well-Defined Silica Supported Mo-Based Olefin Metathesis Catalysts by Tuning the N-Containing Ligands

scientific article published in 2007

Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations

artículo científico publicado en 2008

EPR study of the low-spin [d(3); S =(1)/(2)], Jahn-Teller-active, dinitrogen complex of a molybdenum trisamidoamine

artículo científico publicado en 2007

EPR/ENDOR and Theoretical Study of the Jahn-Teller-Active [HIPTN3N]MoVL Complexes (L = N-, NH).

artículo científico publicado en 2017

Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, am

artículo científico publicado el 23 de enero de 2013

Electroluminescence from New Polynorbornenes That Contain Blue-Light-Emitting and Charge-Transport Side Chains

Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis

artículo científico publicado en 2009

Enantioselective synthesis of cyclic amides and amines through mo-catalyzed asymmetric ring-closing metathesis

artículo científico publicado en 2005

Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes ⬇️

artículo científico publicado el 20 de enero de 2011

Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes

artículo científico publicado en 2009

Energetics and Dynamics of the Low-Lying Electronic States of Constrained Polyenes: Implications for Infinite Polyenes ⬇️

artículo científico publicado el 5 de febrero de 2013

Enhancement of enantioselectivity by THF in asymmetric mo-catalyzed olefin metathesis. Catalytic enantioselective synthesis of cyclic tertiary ethers and spirocycles

artículo científico publicado en 2002

Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes

artículo científico publicado en 2012

Ethenolysis reactions catalyzed by imido alkylidene monoaryloxide monopyrrolide (MAP) complexes of molybdenum

artículo científico publicado en 2009

Experimental and theoretical EPR study of Jahn-Teller-active [HIPTN(3)N]MoL complexes (L = N(2), CO, NH(3)).

artículo científico publicado en 2010

Facile Synthesis of a Tungsten Alkylidyne Catalyst for Alkyne Metathesis

scholarly article by Zachary J. Tonzetich et al published January 2007 in Organometallics

Formation of High-Oxidation-State Metal–Carbon Double Bonds

Formation of {[HIPTN(3)N]Mo(III)H}(-) by heterolytic cleavage of H(2) as established by EPR and ENDOR spectroscopy

artículo científico publicado en 2010

Fundamental studies of tungsten alkylidene imido monoalkoxidepyrrolide complexes.

artículo científico publicado en 2009

Grafting mechanism and olefin metathesis activity of well-defined silica-supported Mo imido alkyl alkylidene complexes

High-oxidation-state molybdenum and tungsten alkylidyne complexes

scholarly article by Richard R. Schrock published November 1986 in Accounts of Chemical Research

High-oxidation-state pentamethylcyclopentadienyl tungsten hydrazine and hydrazido complexes and cleavage of the nitrogen-nitrogen bond

scholarly article by Richard R. Schrock et al published March 1993 in Journal of the American Chemical Society

Highly Active, Stable, and Selective Well-Defined Silica Supported Mo Imido Olefin Metathesis Cata-lysts [J. Am. Chem. Soc.2007,129, 1044−1045]

scientific article published in 2007

Highly Z- and enantioselective ring-opening/cross-metathesis reactions catalyzed by stereogenic-at-Mo adamantylimido complexes

artículo científico publicado en 2009

Highly Z-selective metathesis homocoupling of terminal olefins

artículo científico publicado en 2009

Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis

artículo científico publicado en 2008

Inversion of configuration at the metal in diastereomeric imido alkylidene monoaryloxide monopyrrolide complexes of molybdenum

artículo científico publicado en 2009

Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures ⬇️

artículo científico publicado el 7 de julio de 2011

Kinetically controlled E-selective catalytic olefin metathesis

artículo científico publicado en 2016

Living ring-opening metathesis polymerization catalyzed by well-characterized transition-metal alkylidene complexes

Living ring-opening metathesis polymerization of 2,3-difunctionalized 7-oxanorbornenes and 7-oxanorbornadienes by Mo(CHCMe2R)(NC6H3-iso-Pr2-2,6)(O-tert-Bu)2 and Mo(CHCMe2R)(NC6H3-iso-Pr2-2,6)(OCMe2CF3)2

article

Living ring-opening metathesis polymerization of 2,3-difunctionalized norbornadienes by Mo(:CHBu-tert)(:NC6H3Pr-iso2-2,6)(OBu-tert)2

scientific article published in 1990

Metathesis by Molybdenum and Tungsten Catalysts

artículo científico publicado en 2015

Mo-catalyzed asymmetric olefin metathesis in target-oriented synthesis: enantioselective synthesis of (+)-africanol

scholarly article

Molybdenum Complexes that Contain a Calix[6]azacryptand Ligand as Catalysts for Reduction of N2 to Ammonia

artículo científico publicado en 2018

Molybdenum Imido Alkylidene Metathesis Catalysts that Contain Electron Withdrawing Biphenolates or Binaphtholates

artículo científico publicado en 2007

Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin‐Metathesis Catalysts ⬇️

artículo científico publicado el 6 de octubre de 2003

Molybdenum chloride catalysts for Z-selective olefin metathesis reactions

artículo científico publicado en 2017

Molybdenum triamidoamine systems. Reactions involving dihydrogen relevant to catalytic reduction of dinitrogen

artículo científico publicado en 2009

Molybdenum tris(2,5-dimethylpyrrolide), a rare homoleptic molybdenum(III) monomer

artículo científico publicado en 2008

Molybdenum-based complexes with two aryloxides and a pentafluoroimido ligand: catalysts for efficient Z-selective synthesis of a macrocyclic trisubstituted alkene by ring-closing metathesis

artículo científico publicado en 2013

Monoaryloxide Pyrrolide (MAP) Imido Alkylidene Complexes of Molybdenum and Tungsten That Contain 2,6-Bis(2,5-R2-pyrrolyl)phenoxide (R = i-Pr, Ph) Ligands and an Unsubstituted Metallacyclobutane on Its Way to Losing Ethylene

artículo científico publicado en 2013

Multiple Metal–Carbon Bonds for Catalytic Metathesis Reactions (Nobel Lecture)

artículo científico publicado en 2006

Multiple metal-carbon bonds. 16. Tungsten-oxo alkylidene complexes as olefins metathesis catalysts and the crystal structure of W(O)(CHCMe3(PEt3)Cl2

scholarly article by Jeffrey H. Wengrovius et al published June 1980 in Journal of the American Chemical Society

Multiple metal-carbon bonds. 43. Well-characterized, highly active, Lewis acid free olefin metathesis catalysts

artículo científico publicado en 1986

New Enantiomerically Pure Alkylimido Mo-Based Complexes. Synthesis, Characterization, and Activity as Chiral Olefin Metathesis Catalysts

artículo científico publicado en 2007

On the trail of metathesis catalysts

Optical Spectroscopy of Long Polyenes

Organometallic Complexes of Tantalum That Contain the Triamidoamine Ligand, [(Me3SiNCH2CH2)3N]3-, Including an Ethylidene Complex Formed via a Phosphine-Catalyzed Rearrangement of an Ethylene Complex

scholarly article by Joel S. Freundlich et al published July 1994 in Journal of the American Chemical Society

Oxidative reactions of the Mo(IV) dialkyl complex [{(3-CF3C6H4NCH2CH2)2NMe}Mo(CH2SiMe3)2].

artículo científico publicado en 2007

Phosphinidenetantalum(V) Complexes of the Type[(N3N)TaPR] as Phospha-Wittig Reagents

article

Phosphinidentantal(v)-Komplexe des Typs [(N3N)TaPR] als Phospha-Wittig-Reagentien (R = Ph, Cy,tBu; N3N = (Me3SiNCH2CH2)3N)

article

Preparation and characterization of active niobium, tantalum and tungsten metathesis catalysts

scholarly article by Richard R. Schrock et al published May 1980 in Journal of molecular catalysis

Preparation of macrocyclic Z-enoates and (E,Z)- or (Z,E)-dienoates through catalytic stereoselective ring-closing metathesis

artículo científico publicado en 2014

Protonation Studies of Molybdenum(VI) Nitride Complexes That Contain the [2,6-(ArNCH2)2NC5H3]2- Ligand (Ar = 2,6-Diisopropylphenyl)

scientific article published on 26 February 2019

Protonation of the Dinitrogen-Reduction Catalyst [HIPTN3N]MoIII Investigated by ENDOR Spectroscopy ⬇️

artículo científico publicado el 14 de diciembre de 2010

Q&A: A sustainable chemist. Interview by Jonathan Moerdyk

artículo científico publicado en 2013

Recent advances in high oxidation state Mo and W imido alkylidene chemistry

artículo científico publicado en 2009

Reducing Them Down To Charge Them Up: Low Temperature Catalyst Activation

artículo científico publicado en 2016

Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes

artículo científico publicado en 2017

Reduction of dinitrogen

artículo científico publicado en 2006

Reduction of dinitrogen to ammonia at a well-protected reaction site in a molybdenum triamidoamine complex

artículo científico publicado en 2002

Room Temperature Z-Selective Homocoupling of α Olefins by Tungsten Catalysts

artículo científico publicado en 2011

Silica-Supported Molybdenum Oxo Alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis

scientific article published on 11 July 2019

Studies relevant to catalytic reduction of dinitrogen to ammonia by molybdenum triamidoamine complexes

artículo científico publicado en 2005

Surface versus Molecular Siloxy Ligands in Well-Defined Olefin Metathesis Catalysts: [{(RO)3SiO}Mo(NAr)(CHtBu)(CH2tBu)]

scholarly article by Frédéric Blanc et al published 13 February 2006 in Angewandte Chemie International Edition

Syntheses of Molybdenum Adamantylimido and t-Butylimido Alkylidene Chloride Complexes Using HCI and Diphenylmethylphosphine

scientific article published on 23 October 2017

Syntheses of Molybdenum Oxo Alkylidene Complexes through Addition of Water to an Alkylidyne Complex.

artículo científico publicado en 2018

Syntheses of Molybdenum Oxo Benzylidene Complexes

artículo científico publicado en 2018

Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene

artículo científico publicado en 2016

Synthesis and optical spectroscopy of oligo(1,6-heptadiynes) with a single basic structure prepared through adamantylimido-based molybdenum Wittig and metathesis chemistry

artículo científico publicado en 2009

Synthesis and reactions of molybdenum triamidoamine complexes containing hexaisopropylterphenyl substituents

artículo científico publicado en 2003

Synthesis of 2,6-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X = I, Li, OH, SH, N3, or NH2.

artículo científico publicado en 2017

Synthesis of Cis,syndiotactic A-alt-B Copolymers from Two Enantiomerically Pure Trans-2,3-Disubstituted-5,6-Norbornenes

artículo científico publicado en 2016

Synthesis of E- and Z-trisubstituted alkenes by catalytic cross-metathesis

artículo científico publicado en 2017

Synthesis of High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes

artículo científico publicado en 2013

Synthesis of High-Oxidation-State Mo═CHX Complexes, Where X = Cl, CF3, Phosphonium, CN

scientific article published on 21 May 2018

Synthesis of Linear (Z)-α,β-Unsaturated Esters by Catalytic Cross-Metathesis. The Influence of Acetonitrile

artículo científico publicado en 2016

Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands

artículo científico publicado en 2014

Synthesis of Molybdenum and Tungsten Complexes That Contain Triamidoamine Ligands of the Type (C6F5NCH2CH2)3N and Activation of Dinitrogen by Molybdenum

article

Synthesis of Terminal Vanadium(V) Imido, Oxo, Sulfido, Selenido, and Tellurido Complexes by Imido Group or Chalcogenide Atom Transfer to Trigonal Monopyramidal V[N3N] (N3N = [(Me3SiNCH2CH2)3N]3-)

Synthesis of Titanium Complexes That Contain Triamido−Amine Ligands

article

Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand

artículo científico publicado en 2014

Synthesis of Z-(Pinacolato)allylboron and Z-(Pinacolato)alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis ⬇️

artículo científico publicado el 15 de abril de 2013

Synthesis of [(DPPNCH2CH2)3N]3- molybdenum complexes (DPP = 3,5-(2,5-Diisopropylpyrrolyl)2C6H3) and studies relevant to catalytic reduction of dinitrogen

artículo científico publicado en 2010

Synthesis of [(HIPTNCH2CH2)3N]Cr Compounds (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an evaluation of chromium for the reduction of dinitrogen to ammonia

artículo científico publicado en 2006

Synthesis of [(HIPTNCH2CH2)3N]V compounds (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an evaluation of vanadium for the reduction of dinitrogen to ammonia

artículo científico publicado en 2006

Synthesis of bifunctional imido alkylidene bispyrrolide complexes of molybdenum and their conversion into bifunctional imido alkylidene diolate complexes that can be employed as ROMP initiators

artículo científico publicado en 2008

Synthesis of chiral molybdenum ROMP initiators and all-cis highly tactic poly(2,3-(R)2norbornadiene) (R = CF3 or CO2Me)

scholarly article by David H. McConville et al published May 1993 in Journal of the American Chemical Society

Synthesis of cis,syndiotactic-A-alt-B Copolymers from Enantiomerically Pure Endo-2-Substituted-5,6-Norbornenes

artículo científico publicado en 2017

Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis ⬇️

artículo científico publicado el 2 de noviembre de 2011

Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins

article

Synthesis of triamidoamine ligands of the type (ArylNHCH(2)CH(2))(3)N and molybdenum and tungsten complexes that contain an [ArylNCH(2)CH(2))(3)N]3- ligand

artículo científico publicado en 2001

Synthesis of vanadium and titanium complexes of the type RM[(Me3SiNCH2CH2)3N] (R = Cl, alkyl) and the structure of ClV[(Me3SiNCH2CH2)3N]

scholarly article by Christopher C. Cummins et al published April 1992 in Organometallics

Synthesis, structure, and electrochemical studies of molybdenum and tungsten dinitrogen, diazenido, and hydrazido complexes that contain aryl-substituted triamidoamine ligands

artículo científico publicado en 2001

The discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry

artículo científico

The significance of degenerate processes to enantioselective olefin metathesis reactions promoted by stereogenic-at-Mo complexes

artículo científico publicado en 2009

Toward the realization of practicable materials for χ (3) based photonic applications

article published in 2006

Trigonal-Monopyramidal MIII Complexes of the Type[M(N3N)](M= Ti, V, Cr, Mn, Fe; N3N=[(tBuMe2Si)CH2CH2]3N)

Trigonal-monopyramidale MIII-Komplexe des Typs [M(N3N)] (M = Ti, V, Cr, Mn, Fe; N3N = [(tBuMe2Si)CH2CH2]3N)

article

Turkey must end violent response to protests

artículo científico publicado en 2013

Unusual31P Chemical Shielding Tensors in Terminal Phosphido Complexes Containing a Phosphorus−Metal Triple Bond

scientific article published in 1996

Well-characterized olefin metathesis catalysts that contain molybdenum

scholarly article by John S. Murdzek & Richard R. Schrock published June 1987 in Organometallics

Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes ⬇️

artículo científico publicado el 2 de julio de 2012

Z-Selective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts of Molybdenum and Tungsten

Z-Selective and Syndioselective Ring-Opening Metathesis Polymerization (ROMP) Initiated by MonoAryloxidePyrrolide (MAP) Catalysts

artículo científico publicado en 2010

Z-Selective olefin metathesis reactions promoted by tungsten oxo alkylidene complexes

artículo científico publicado en 2011

Z-selective olefin metathesis processes catalyzed by a molybdenum hexaisopropylterphenoxide monopyrrolide complex

artículo científico publicado en 2009

Lista de obras de Richard Schrock

A Well-Defined, Silica-Supported Tungsten Imido Alkylidene Olefin Metathesis Catalyst

A tungstenVI nitride having a W2(mu-N)2 core

A well-defined silica-supported tungsten oxo alkylidene is a highly active alkene metathesis catalyst

Alkylation of dinitrogen in [(HIPTNCH(2)CH(2))(3)N]Mo complexes (HIPT = 3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3)).

Alkylidene and metalacyclic complexes of tungsten that contain a chiral biphenoxide ligand. synthesis, asymmetric ring-closing metathesis, and mechanistic investigations

Alkylidene complexes of niobium and tantalum

Better characterization of surface organometallic catalysts through resolution enhancement in proton solid state NMR spectra

Beyond fossil fuel-driven nitrogen transformations

Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes

Bulky aryloxide ligand stabilizes a heterogeneous metathesis catalyst

Catalyst-controlled stereoselective olefin metathesis as a principal strategy in multistep synthesis design: a concise route to (+)-neopeltolide

Catalytic Z-selective cross-metathesis in complex molecule synthesis: a convergent stereoselective route to disorazole C1.

Catalytic Z-selective olefin cross-metathesis for natural product synthesis

Catalytic Z‐Selective Cross‐Metathesis with Secondary Silyl‐ and Benzyl‐Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis ⬇️

Catalytic asymmetric ring-opening metathesis/cross metathesis (AROM/CM) reactions. Mechanism and application to enantioselective synthesis of functionalized cyclopentanes

Catalytic homologation of vinyltributylstannane to allyltributylstannane by Mo(IV) complexes in the presence of ethylene

Catalytic hydrogenation using cationic rhodium complexes. I. Evolution of the catalytic system and the hydrogenation of olefins

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

Catalytic reduction of dinitrogen to ammonia at well-defined single metal sites

Catalytic reduction of dinitrogen to ammonia by molybdenum: theory versus experiment

Cationic Hafnium Alkyl Complexes that Are Stable toward β-Hydride Elimination below 10 °C and Active as Initiators for the Living Polymerization of 1-Hexene ⬇️

Conformational disorder in long polyenes

Correction to "Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes".

Dedication to the Special Volume for Dietmar Seyferth†

Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis

Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts

Dipyrrolyl precursors to bisalkoxide molybdenum olefin metathesis catalysts

Direct observation of reaction intermediates for a well defined heterogeneous alkene metathesis catalyst

Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis

Dramatic Improvements of Well-Defined Silica Supported Mo-Based Olefin Metathesis Catalysts by Tuning the N-Containing Ligands

Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations

EPR study of the low-spin [d(3); S =(1)/(2)], Jahn-Teller-active, dinitrogen complex of a molybdenum trisamidoamine

EPR/ENDOR and Theoretical Study of the Jahn-Teller-Active [HIPTN3N]MoVL Complexes (L = N-, NH).

Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, am

Electroluminescence from New Polynorbornenes That Contain Blue-Light-Emitting and Charge-Transport Side Chains

Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis

Enantioselective synthesis of cyclic amides and amines through mo-catalyzed asymmetric ring-closing metathesis

Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes ⬇️

Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes

Energetics and Dynamics of the Low-Lying Electronic States of Constrained Polyenes: Implications for Infinite Polyenes ⬇️

Enhancement of enantioselectivity by THF in asymmetric mo-catalyzed olefin metathesis. Catalytic enantioselective synthesis of cyclic tertiary ethers and spirocycles

Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes

Ethenolysis reactions catalyzed by imido alkylidene monoaryloxide monopyrrolide (MAP) complexes of molybdenum

Experimental and theoretical EPR study of Jahn-Teller-active [HIPTN(3)N]MoL complexes (L = N(2), CO, NH(3)).

Facile Synthesis of a Tungsten Alkylidyne Catalyst for Alkyne Metathesis

Formation of High-Oxidation-State Metal–Carbon Double Bonds

Formation of {[HIPTN(3)N]Mo(III)H}(-) by heterolytic cleavage of H(2) as established by EPR and ENDOR spectroscopy

Fundamental studies of tungsten alkylidene imido monoalkoxidepyrrolide complexes.

Grafting mechanism and olefin metathesis activity of well-defined silica-supported Mo imido alkyl alkylidene complexes

High-oxidation-state molybdenum and tungsten alkylidyne complexes

High-oxidation-state pentamethylcyclopentadienyl tungsten hydrazine and hydrazido complexes and cleavage of the nitrogen-nitrogen bond

Highly Active, Stable, and Selective Well-Defined Silica Supported Mo Imido Olefin Metathesis Cata-lysts [J. Am. Chem. Soc.2007,129, 1044−1045]

Highly Z- and enantioselective ring-opening/cross-metathesis reactions catalyzed by stereogenic-at-Mo adamantylimido complexes

Highly Z-selective metathesis homocoupling of terminal olefins

Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis

Inversion of configuration at the metal in diastereomeric imido alkylidene monoaryloxide monopyrrolide complexes of molybdenum

Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures ⬇️

Kinetically controlled E-selective catalytic olefin metathesis

Living ring-opening metathesis polymerization catalyzed by well-characterized transition-metal alkylidene complexes

Living ring-opening metathesis polymerization of 2,3-difunctionalized 7-oxanorbornenes and 7-oxanorbornadienes by Mo(CHCMe2R)(NC6H3-iso-Pr2-2,6)(O-tert-Bu)2 and Mo(CHCMe2R)(NC6H3-iso-Pr2-2,6)(OCMe2CF3)2

Living ring-opening metathesis polymerization of 2,3-difunctionalized norbornadienes by Mo(:CHBu-tert)(:NC6H3Pr-iso2-2,6)(OBu-tert)2

Metathesis by Molybdenum and Tungsten Catalysts

Mo-catalyzed asymmetric olefin metathesis in target-oriented synthesis: enantioselective synthesis of (+)-africanol

Molybdenum Complexes that Contain a Calix[6]azacryptand Ligand as Catalysts for Reduction of N2 to Ammonia

Molybdenum Imido Alkylidene Metathesis Catalysts that Contain Electron Withdrawing Biphenolates or Binaphtholates

Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin‐Metathesis Catalysts ⬇️

Molybdenum chloride catalysts for Z-selective olefin metathesis reactions

Molybdenum triamidoamine systems. Reactions involving dihydrogen relevant to catalytic reduction of dinitrogen

Molybdenum tris(2,5-dimethylpyrrolide), a rare homoleptic molybdenum(III) monomer

Molybdenum-based complexes with two aryloxides and a pentafluoroimido ligand: catalysts for efficient Z-selective synthesis of a macrocyclic trisubstituted alkene by ring-closing metathesis

Monoaryloxide Pyrrolide (MAP) Imido Alkylidene Complexes of Molybdenum and Tungsten That Contain 2,6-Bis(2,5-R2-pyrrolyl)phenoxide (R = i-Pr, Ph) Ligands and an Unsubstituted Metallacyclobutane on Its Way to Losing Ethylene

Multiple Metal–Carbon Bonds for Catalytic Metathesis Reactions (Nobel Lecture)

Multiple metal-carbon bonds. 16. Tungsten-oxo alkylidene complexes as olefins metathesis catalysts and the crystal structure of W(O)(CHCMe3(PEt3)Cl2

Multiple metal-carbon bonds. 43. Well-characterized, highly active, Lewis acid free olefin metathesis catalysts

New Enantiomerically Pure Alkylimido Mo-Based Complexes. Synthesis, Characterization, and Activity as Chiral Olefin Metathesis Catalysts

On the trail of metathesis catalysts

Optical Spectroscopy of Long Polyenes

Organometallic Complexes of Tantalum That Contain the Triamidoamine Ligand, [(Me3SiNCH2CH2)3N]3-, Including an Ethylidene Complex Formed via a Phosphine-Catalyzed Rearrangement of an Ethylene Complex