Lista de obras - Adrian Chaplin - Dominio Público Uruguay

2,6-Bis[1-(2,4,6-tri-methyl-phenyl-imino)-eth-yl]pyridine.

artículo científico publicado en 2013

A case for linear agostic interactions: identification by DFT calculation in a complex of Ta containing a uniquely caged triphenylmethyl C-H hydrogen.

artículo científico publicado en 2004

A convenient method for the generation of {Rh(PNP)} and {Rh(PONOP)} fragments: reversible formation of vinylidene derivatives

artículo científico publicado en 2019

A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes

artículo científico publicado en 2020

Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate

artículo científico publicado en 2008

Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes

artículo científico publicado en 2010

Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes

scientific article published on 10 October 2008

Amino-borane oligomers bound to a Rh(I) metal fragment

artículo científico publicado en 2010

Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling

artículo científico publicado en 2012

B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes

artículo científico publicado en 2010

Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center

scientific article published on 01 January 2009

C-C activation in the solid state in an organometallic σ-complex.

artículo científico publicado en 2011

C-F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene.

artículo científico publicado en 2016

Catalytic Activity of Bis-phosphine Ruthenium(II)−Arene Compounds: Chemoselective Hydrogenation and Mechanistic Insights

Catalytic Activity of Bis-phosphine Ruthenium(II)−Arene Compounds: Structure−Activity Correlations

Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H3B·NMeHBH2·NMeH2Bound to Iridium

scientific article published on 01 July 2011

Conformational flexibility in 2,2'-Dioxybiphenyl-chloro-cyclotetraphosphazenes and its relevance to polyphosphazene analogues

artículo científico publicado en 2007

Coordination chemistry of a calix[4]arene-based NHC ligand: dinuclear complexes and comparison to I(i)Pr2Me2

artículo científico publicado en 2016

Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment

artículo científico publicado en 2011

Electrochemical synthesis of polypyrrole in ionic liquids

article

Gold(I) and platinum(II) complexes with a new diphosphine ligand based on the cyclotriphosphazene platform

scientific article published on 23 December 2005

Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation

artículo científico publicado en 2011

Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(κ2-triphos)(p-cymene)]PF6

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.

artículo científico publicado en 2012

Isolation and structural characterisation of rhodium(iii) η2-fluoroarene complexes: experimental verification of predicted regioselectivity

artículo científico publicado en 2020

Linked Metal-cluster Systems: Isolation and Characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

Low-coordinate iridium NHC complexes derived from selective and reversible C-H bond activation of fluoroarenes

artículo científico publicado en 2015

Mechanistic Studies on the Formation of η2-Diphosphine (η6-p-cymene)ruthenium(II) Compounds

Monomeric and oligomeric amine-borane sigma-complexes of rhodium. intermediates in the catalytic dehydrogenation of amine-boranes

artículo científico publicado en 2009

NHC-based pincer ligands: carbenes with a bite.

artículo científico publicado en 2015

On the Influence of “Arm-on, Arm-off” Processes on Alkene Hydrogenation Catalysed by a Rhodium Triphos Complex

scholarly article by Adrian B Chaplin & Paul J. Dyson published November 2007 in European Journal of Inorganic Chemistry

One-Electron Oxidation of [M(P(t) Bu3 )2 ] (M=Pd, Pt): Isolation of Monomeric [Pd(P(t) Bu3 )2 ](+) and Redox-Promoted C-H Bond Cyclometalation

artículo científico publicado en 2016

Organometallic chemistry using partially fluorinated benzenes

artículo científico publicado en 2017

Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

artículo científico publicado en 2020

Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)

scientific article published on 07 September 2018

Pendant−Bridging−Chelating−Cleavage: A Series of Bonding Modes in Ruthenium(II)-BINAPO Complexes

Potassium Binding Adjacent to Cationic Transition-Metal Fragments: Unusual Heterobimetallic Adducts of a Calix[4]arene-Based Thione Ligand

artículo científico publicado en 2017

Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study

artículo científico publicado en 2019

Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all

artículo científico publicado en 2020

Reactivity and catalytic activity of a robust ruthenium(II)-triphos complex

artículo científico publicado en 2007

Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation.

artículo científico publicado en 2010

Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation

artículo científico publicado en 2010

Revisiting the Electronic Structure of Phosphazenes

artículo científico publicado en 2005

Rhodium(I) Pincer Complexes of Nitrous Oxide

scientific article published on 12 September 2019

Rhodium(III) Complexes Featuring Coordinated CF 3 Appendages

artículo científico publicado en 2019

Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen

artículo científico publicado en 2018

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch

scientific article published on 19 April 2011

Rotaxane synthesis exploiting the M(i)/M(iii) redox couple

artículo científico publicado en 2017

Solution, solid-state, and computational analysis of agostic interactions in a coherent set of low-coordinate rhodium(III) and iridium(III) complexes

artículo científico publicado en 2018

Solvent promoted reversible cyclometalation in a tethered NHC iridium complex

artículo científico publicado en 2013

Synthesis and Characterization of Organometallic Ionic Liquids and a Heterometallic Carbene Complex Containing the Chromium Tricarbonyl Fragment

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes.

artículo científico publicado en 2019

Synthesis and reactivity of NHC-based rhodium macrocycles

artículo científico publicado en 2014

Synthesis, structure and dynamics of NHC-based palladium macrocycles.

artículo científico publicado en 2013

Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching

artículo científico publicado en 2018

The Synthesis and Characterisation of Bis(phosphane)-Linked (6-p-Cymene)ruthenium(II)-Borane Compounds

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

artículo científico publicado en 2011

Tuning the hydrophobicity of ruthenium(II)-arene (RAPTA) drugs to modify uptake, biomolecular interactions and efficacy

artículo científico publicado en 2007

UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex.

artículo científico publicado en 2017

Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).

artículo científico publicado en 2009

Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles

artículo científico publicado en 2016

[Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2

artículo científico publicado en 2011

Lista de obras de Adrian Chaplin

2,6-Bis[1-(2,4,6-tri-methyl-phenyl-imino)-eth-yl]pyridine.

A case for linear agostic interactions: identification by DFT calculation in a complex of Ta containing a uniquely caged triphenylmethyl C-H hydrogen.

A convenient method for the generation of {Rh(PNP)} and {Rh(PONOP)} fragments: reversible formation of vinylidene derivatives

A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes

Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate

Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes

Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes

Amino-borane oligomers bound to a Rh(I) metal fragment

Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling

B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes

Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center

C-C activation in the solid state in an organometallic σ-complex.

C-F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene.

Catalytic Activity of Bis-phosphine Ruthenium(II)−Arene Compounds: Chemoselective Hydrogenation and Mechanistic Insights

Catalytic Activity of Bis-phosphine Ruthenium(II)−Arene Compounds: Structure−Activity Correlations

Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H3B·NMeHBH2·NMeH2Bound to Iridium

Conformational flexibility in 2,2'-Dioxybiphenyl-chloro-cyclotetraphosphazenes and its relevance to polyphosphazene analogues

Coordination chemistry of a calix[4]arene-based NHC ligand: dinuclear complexes and comparison to I(i)Pr2Me2

Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment

Electrochemical synthesis of polypyrrole in ionic liquids

Gold(I) and platinum(II) complexes with a new diphosphine ligand based on the cyclotriphosphazene platform

Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation

Influence of arene dissociation and phosphine coordination on the catalytic activity of [RuCl(κ2-triphos)(p-cymene)]PF6

Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.

Isolation and structural characterisation of rhodium(iii) η2-fluoroarene complexes: experimental verification of predicted regioselectivity

Linked Metal-cluster Systems: Isolation and Characterisation of {anti-[(p-cymene)RuCl]-μ-[κ 2-P,P′;κ 1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

Low-coordinate iridium NHC complexes derived from selective and reversible C-H bond activation of fluoroarenes

Mechanistic Studies on the Formation of η2-Diphosphine (η6-p-cymene)ruthenium(II) Compounds

Monomeric and oligomeric amine-borane sigma-complexes of rhodium. intermediates in the catalytic dehydrogenation of amine-boranes

NHC-based pincer ligands: carbenes with a bite.

On the Influence of “Arm-on, Arm-off” Processes on Alkene Hydrogenation Catalysed by a Rhodium Triphos Complex

One-Electron Oxidation of [M(P(t) Bu3 )2 ] (M=Pd, Pt): Isolation of Monomeric [Pd(P(t) Bu3 )2 ](+) and Redox-Promoted C-H Bond Cyclometalation

Organometallic chemistry using partially fluorinated benzenes

Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)

Pendant−Bridging−Chelating−Cleavage: A Series of Bonding Modes in Ruthenium(II)-BINAPO Complexes

Potassium Binding Adjacent to Cationic Transition-Metal Fragments: Unusual Heterobimetallic Adducts of a Calix[4]arene-Based Thione Ligand

Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study

Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all

Reactivity and catalytic activity of a robust ruthenium(II)-triphos complex

Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation.

Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation

Revisiting the Electronic Structure of Phosphazenes

Rhodium(I) Pincer Complexes of Nitrous Oxide

Rhodium(III) Complexes Featuring Coordinated CF 3 Appendages

Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch

Rotaxane synthesis exploiting the M(i)/M(iii) redox couple

Solution, solid-state, and computational analysis of agostic interactions in a coherent set of low-coordinate rhodium(III) and iridium(III) complexes

Solvent promoted reversible cyclometalation in a tethered NHC iridium complex

Synthesis and Characterization of Organometallic Ionic Liquids and a Heterometallic Carbene Complex Containing the Chromium Tricarbonyl Fragment

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes.

Synthesis and reactivity of NHC-based rhodium macrocycles

Synthesis, structure and dynamics of NHC-based palladium macrocycles.

Terminal Alkyne Coupling Reactions through a Ring: Mechanistic Insights and Regiochemical Switching

The Synthesis and Characterisation of Bis(phosphane)-Linked (6-p-Cymene)ruthenium(II)-Borane Compounds

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

Tuning the hydrophobicity of ruthenium(II)-arene (RAPTA) drugs to modify uptake, biomolecular interactions and efficacy

UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex.

Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).

Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles

[Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2