13C-1H heteronuclear chemical shift correlation spectroscopy applied to poly(methyl [carbonyl-13C]methacrylate): an unambiguous method for assigning resonances to configurational sequences

13C=O NMR Signal Assignments for Poly(n-butyl methacrylate-co-methyl methacrylate). Application of 13C-1H Correlation Spectroscopy and 13C Labelling

15N CP/MAS solid-state NMR spectroscopy of a 15N-enriched hindered amine light stabilizer photolyzed in acrylic/melamine and acrylic/urethane coatings

4-Halogeno-3,5-dimethyl-1H -pyrazole-1-carbodithioates: versatile reversible addition fragmentation chain transfer agents with broad applicability

artículo científico publicado en 2017

A More Versatile Route to Block Copolymers and Other Polymers of Complex Architecture by Living Radical Polymerization: The RAFT Process

article by ) Y. K. Chong et al published March 1999 in Macromolecules

A Potential New RAFT - Click Reaction or a Cautionary Note on the Use of Diazomethane to Methylate RAFT-synthesized Polymers

A brief guide to polymer nomenclature (IUPAC Technical Report)

article

A brief guide to polymer nomenclature from IUPAC

A new form of controlled growth free radical polymerization

A novel method for determination of polyester end-groups by NMR spectroscopy

A novel synthesis of functional dithioesters, dithiocarbamates, xanthates and trithiocarbonates

A simple method for determining protic end-groups of synthetic polymers by 1H NMR spectroscopy

article by Almar Postma et al published March 2006 in Polymer

A small-angle X-ray scattering study of the effect of chain architecture on the shear-induced crystallization of branched and linear poly(ethylene terephthalate)

Absolute rate constants for radical-monomer reactions

Advances in RAFT polymerization: the synthesis of polymers with defined end-groups

artículo científico publicado en 2005

Advances in Switchable RAFT Polymerization

Alkoxyamine-Initiated Living Radical Polymerization: Factors Affecting Alkoxyamine Homolysis Rates

Aluminium-chloride-promoted reactions of ethyl acrylate with olefins

An arm-first approach to cleavable mikto-arm star polymers by RAFT polymerization

artículo científico publicado en 2014

Approaches to phthalimido and amino end-functional polystyrene by atom transfer radical polymerisation (ATRP)

Aqueous hydrogen peroxide-induced degradation of polyolefins: A greener process for controlled-rheology polypropylene

Azo and Peroxy Initiators

Binary Copolymerization with Catalytic Chain Transfer. A Method for Synthesizing Macromonomers Based on Monosubstituted Monomers

article

Block copolymers containing organic semiconductor segments by RAFT polymerization

article

Chain Length Dependence of Radical−Radical Termination in Free Radical Polymerization: A Pulsed Laser Photolysis Investigation

Chain Transfer

Chain Transfer Activity of ω-Unsaturated Methacrylic Oligomers in Polymerizations of Methacrylic Monomers

Chain Transfer Activity of ω-Unsaturated Methyl Methacrylate Oligomers

Chain Transfer Kinetics of Acid/Base Switchable N-Aryl-N-Pyridyl Dithiocarbamate RAFT Agents in Methyl Acrylate, N-Vinylcarbazole and Vinyl Acetate Polymerization

Chain Transfer to Polymer: A Convenient Route to Macromonomers

article

Characterization of poly(ethylene terephthalate) and poly(ethylene terephthalate) blends

Characterization of polyolefin melts using the polymer reference interaction site model integral equation theory with a single-site united atom model

ChemInform Abstract: Toward Living Radical Polymerization

Chemical modification of starch by reactive extrusion

article published in 2011

Chemistry of Bimolecular Termination

Compatibilisation of polystyrene-polyolefin blends

Computer simulation of the chemical properties of copolymers

Consistent values of rate parameters in free radical polymerization systems

Consistent values of rate parameters in free radical polymerization systems. II. Outstanding dilemmas and recommendations

Controlled RAFT Polymerization in a Continuous Flow Microreactor

article

Controlled Synthesis of Multifunctional Polymers by RAFT for Personal Care Applications

Controlled synthesis of block polyesters by reactive extrusion

Controlled-Growth Free-Radical Polymerization of Methacrylate Esters: Reversible Chain Transfer versus Reversible Termination

Controlling Polymerization

Copolymerization

article published in 2005

Correction

scholarly article published in Australian Journal of Chemistry

Corrigendum to “The synthesis of polyolefin graft copolymers by reactive extrusion” [Progress in Polymer Science 1999;24:81–142]

scholarly article published in Progress in Polymer Science

Cover Image, Volume 66, Issue 11

artículo científico publicado en 2017

Critical Points in Binary Copolymerization and the Penultimate Group Effect

Critical-Points (Azeotropic Compositions) in Multicomponent Copolymerization

article

Crystallisation kinetics of novel branched poly(ethylene terephthalate): a small-angle X-ray scattering study

article

Cyclization of 3-allylhex-5-enyl radical: mechanism, and implications concerning the structures of cyclopolymers

Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007)

article

Developments in the synthesis of maleated polyolefins by reactive extrusion

Direct Measurement of Primary Radical Concentrations in Pulsed Laser Photolysis

Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertion

artículo científico publicado en 2018

Dithiocarbamate RAFT agents with broad applicability – the 3,5-dimethyl-1H-pyrazole-1-carbodithioates

Effect of ethyl aluminium sesquichloride on the relative reactivities of styrene and methyl methacrylate towards the 1-cyano-1-methylethyl and the 1-methyl-1-(methoxycarbonyl)ethyl radicals

Effect of ethyl aluminium sesquichloride on the specificity of the reactions of 1-methyl-1-methoxycarbonylethyl radical

Effect of the Z- and Macro-R-Group on the Thermal Desulfurization of Polymers Synthesized with Acid/Base "Switchable" Dithiocarbamate RAFT Agents

artículo científico publicado en 2018

Effects of solvent on model copolymerization reactions. A 13C-NMR study

article

End groups of poly(methyl methacrylate-co-styrene) prepared with tert-butoxy, methyl, and/or phenyl radical initiation: effects of solvent, monomer composition, and conversion

article

End-functional polymers, thiocarbonylthio group removal/transformation and reversible addition-fragmentation-chain transfer (RAFT) polymerization

article

Enhancement of MHC-I antigen presentation via architectural control of pH-responsive, endosomolytic polymer nanoparticles.

artículo científico publicado en 2014

Evaluation of propagation rate constants for the free radical polymerization of methacrylonitrile by pulsed laser photolysis

Fate of the initiator in the azobisisobutyronitrile-initiated polymerization of styrene

Functional polymers for optoelectronic applications by RAFT polymerization

Further studies on the thermal decomposition of AIBN—implications concerning the mechanism of termination in methacrylonitrile polymerization

Glossary of terms related to kinetics, thermodynamics, and mechanisms of polymerization (IUPAC Recommendations 2008)

Glossary of terms relating to thermal and thermomechanical properties of polymers (IUPAC Recommendations 2013)

artículo científico publicado en 2013

Head additon of radicals to methyl methacrylate

How powerful are composition data in discriminating between the terminal and penultimate models for binary copolymerization?

article

Imidazolidinone Nitroxide-Mediated Polymerization

Influences of the initiation and termination reactions on the molecular weight distribution and compositional heterogeneity of functional copolymers: an application of Monte Carlo simulation

article

Initiating free radical polymerization

Initiation

Initiation. The reactions of primary radicals

Intramolecular addition in hex-5-enyl, hept-6-enyl, and oct-7-enyl radicals

article

Introduction

Invited Review. Understanding and Controlling Radical Polymerization

article

Kinetic Simulation of Polymerization Involving Termination by Reversible Chain Transfer

Kinetic data for coupling of primary alkyl radicals with a stable nitroxide

Kinetics and Mechanism of RAFT Polymerization

Kinetics of the coupling reactions of the nitroxyl radical 1,1,3,3-tetramethylisoindoline-2-oxyl with carbon-centered radicals

Light-Induced RAFT Single Unit Monomer Insertion in Aqueous Solution-Toward Sequence-Controlled Polymers

artículo científico publicado en 2018

Living Free Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT Polymerization): Approaches to Star Polymers

article

Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer: The RAFT Process

article

Living Polymers by the Use of Trithiocarbonates as Reversible Addition−Fragmentation Chain Transfer (RAFT) Agents: ABA Triblock Copolymers by Radical Polymerization in Two Steps

article

Living Radical Polymerization

Living Radical Polymerization by the RAFT Process

Living Radical Polymerization by the RAFT Process ? A Third Update

article published in 2012

Living Radical Polymerization by the RAFT Process – A Second Update

article by Graeme Moad et al published 2009 in Australian Journal of Chemistry

Living Radical Polymerization by the RAFT Process—A First Update

article by Graeme Moad et al published 2006 in Australian Journal of Chemistry

Living Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT Polymerization) Using Dithiocarbamates as Chain Transfer Agents

article

Living Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT): Direct ESR Observation of Intermediate Radicals

article

Living free radical polymerization with reversible addition - fragmentation chain transfer (the life of RAFT)

article

Living polymerization: Rationale for uniform terminology

article

Measurements of Primary Radical Concentrations Generated by Pulsed Laser Photolysis Using Fluorescence Detection

Mechanism and Kinetics of Dithiobenzoate-Mediated RAFT Polymerization - Status of the Dilemma

Mechanism and Kinetics of RAFT-Based Living Radical Polymerizations of Styrene and Methyl Methacrylate

article

Mechanism and kinetics of dithiobenzoate-mediated RAFT polymerization. I. The current situation

article

Modeling the Kinetics of Monolith Formation by RAFT Copolymerization of Styrene and Divinylbenzene

Morphology-property relationships in ABS/PET blends. I. Compositional effects

article

Morphology-property relationships in ABS/PET blends. II. Influence of processing conditions on structure and properties

Multiarm organic compounds for use as reversible chain-transfer agents in living radical polymerizations

article

Narrow Polydispersity Block Copolymers by Free-Radical Polymerization in the Presence of Macromonomers

New Features of the Mechanism of RAFT Polymerization

article published in 2009

New Free-Radical Ring-Opening Acrylate Monomers

Non-Ionic, Poly(ethylene oxide)-Based Surfactants as Intercalants/Dispersants/Exfoliants for Poly(propylene)-Clay Nanocomposites

Novel Copolymers as Dispersants/Intercalants/Exfoliants for Polypropylene-Clay Nanocomposites

On the mechanism of decomposition of geminal diamines

scientific article published in 1978

On the regioselectivity of free radical processes ; reactions of benzoyloxy, phenyl and t-butoxy radicals with some α,β-unsaturated esters

One pot synthesis of higher order quasi-block copolymer libraries via sequential RAFT polymerization in an automated synthesizer

article published in 2014

Other Initiating Systems

Polymerization-Induced Phase Segregation and Self-Assembly of Siloxane Additives to Provide Thermoset Coatings with a Defined Surface Topology and Biocidal and Self-Cleaning Properties

scientific article published on 13 November 2019

Polystyrene-block-poly(vinyl acetate) through the Use of a Switchable RAFT Agent

Porous, functional, poly(styrene-co-divinylbenzene) monoliths by RAFT polymerization

Preparation of 1 : 1 alternating, nucleobase-containing copolymers for use in sequence-controlled polymerization

Preparation of Macromonomers via Chain Transfer with and without Added Chain Transfer Agent

article published in 2000

Propagation

scholarly article

RAFT (Reversible addition-fragmentation chain transfer) crosslinking (co)polymerization of multi-olefinic monomers to form polymer networks

article

RAFT Agent Design and Synthesis

article by Daniel J. Keddie et al published 21 May 2012 in Macromolecules

RAFT Copolymerization and Its Application to the Synthesis of Novel Dispersants—Intercalants—Exfoliants for Polymer—Clay Nanocomposites

RAFT Polymerization with Phthalimidomethyl Trithiocarbonates or Xanthates. On the Origin of Bimodal Molecular Weight Distributions in Living Radical Polymerization

RAFT Polymerization: Adding to the Picture

RAFT Polymerization: Materials of The Future, Science of Today: Radical Polymerization - The Next Stage

RAFT polymerization and some of its applications

artículo científico

RAFT polymerization to form stimuli-responsive polymers

Radical Addition–Fragmentation Chemistry and RAFT Polymerization

article

Radical Reactions

Radical addition–fragmentation chemistry in polymer synthesis

article

Rapid and systematic access to quasi-diblock copolymer libraries covering a comprehensive composition range by sequential RAFT polymerization in an Automated synthesizer

artículo científico publicado en 2013

Reversible Addition Fragmentation Chain Transfer Polymerization of Methyl Methacrylate in the Presence of Lewis Acids: An Approach to Stereocontrolled Living Radical Polymerization

article

Reversible Addition-Fragmentation Chain Transfer Polymerization

article

Rheological properties of high melt strength poly(ethylene terephthalate) formed by reactive extrusion

Ring-opening of some radicals containing the cyclopropylmethyl system

Selective and Rapid Light-Induced RAFT Single Unit Monomer Insertion in Aqueous Solution

artículo científico publicado en 2019

Selectivity of the reaction of free radicals with styrene

Slow nitrogen inversion–N–O rotation in 2-alkoxy-1,1,3,3-tetramethylisoindolines

Solvent effects on the reaction of t-butoxy radicals with methyl methacrylate

Some Recent Developments in RAFT Polymerization

Structural defects in polymers - their identification and significance

Structure of benzoyl peroxide initiated polystyrene: determination of the initiator-derived functionality by carbon-13 NMR

Studies on 6-methyl-5-deazatetrahydropterin and its 4a adducts

scientific article published in 1979

Substituent Effects on RAFT Polymerization with Benzyl Aryl Trithiocarbonates

Switchable Reversible Addition–Fragmentation Chain Transfer (RAFT) Polymerization in Aqueous Solution,N,N-Dimethylacrylamide

article

Synthesis of Defined Polymers by Reversible Addition—Fragmentation Chain Transfer: The RAFT Process

article

Synthesis of Discrete Oligomers by Sequential PET-RAFT Single-Unit Monomer Insertion

Synthesis of Discrete Oligomers by Sequential PET-RAFT Single-Unit Monomer Insertion.

artículo científico publicado en 2016

Synthesis of Well-Defined Polystyrene with Primary Amine End Groups through the Use of Phthalimido-Functional RAFT Agents

Synthesis of cleavable multi-functional mikto-arm star polymer by RAFT polymerization: example of an anti-cancer drug 7-ethyl-10-hydroxycamptothecin (SN-38) as functional moiety

Synthesis of novel architectures by radical polymerization with reversible addition fragmentation chain transfer (RAFT polymerization)

article

Synthesis of the radical scavenger 1,1,3,3-Tetramethylisoindolin-2-yloxyl

Tacticity of Poly(Methyl Methacrylate). Evidence for a Penpenultimate Group Effect in Free-Radical Polymerization

Tailored polymer architectures by reversible addition-frasmentation chain transfer

article

Tailored polymers by free radical processes

article

Termination

book chapter in 'The Chemistry of Radical Polymerization', second edition

Terminology for aggregation and self-assembly in polymer science (IUPAC Recommendations 2013)

Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010)

artículo científico publicado en 2009

The Application of Supercomputers in Modeling Chemical Reaction Kinetics: Kinetic Simulation of 'Quasi-Living' Radical Polymerization

The Chemistry of Radical Polymerization

book published in 2005

The Emergence of RAFT Polymerization

The Reaction of Benzoyloxy Radicals with Styrene—Implications Concerning the Structure of Polystyrene

The kinetics and mechanism of ring opening of radicals containing the cyclobutylcarbinyl system

The philicity of tert-butoxy radicals. What factors are important in determining the rate and regiospecificity of tert-butoxy radical addition to olefins?

article

The reactivity of N-vinylcarbazole in RAFT polymerization: trithiocarbonates deliver optimal control for the synthesis of homopolymers and block copolymers

article published in 2013

The scope for synthesis of macro-RAFT agents by sequential insertion of single monomer units

article

The synthesis of polyolefin graft copolymers by reactive extrusion

article published in 1999

Thermal stability of benzoyl peroxide-initiated polystyrene

Thermal stability of poly(methyl methacrylate)

article published in 1988

Thermolysis of RAFT-Synthesized Poly(Methyl Methacrylate)

Thermolysis of RAFT-Synthesized Polymers. A Convenient Method for Trithiocarbonate Group Elimination

Thiocarbonylthio Compounds (SC(Z)S−R) in Free Radical Polymerization with Reversible Addition-Fragmentation Chain Transfer (RAFT Polymerization). Effect of the Activating Group Z

article

Thiocarbonylthio Compounds [SC(Ph)S−R] in Free Radical Polymerization with Reversible Addition-Fragmentation Chain Transfer (RAFT Polymerization). Role of the Free-Radical Leaving Group (R)

article

Thiocarbonylthio End Group Removal from RAFT-Synthesized Polymers by Radical-Induced Reduction

Thiocarbonylthio end group removal from RAFT-synthesized polymers by a radical-induced process

article

Toward living radical polymerization

artículo científico publicado en 2008

Triple Activity of Lamivudine Releasing Sulfonated Polymers against HIV-1.

artículo científico publicado en 2016

Universal (switchable) RAFT agents.

artículo científico publicado en 2009

Use of Chain Length Distributions in Determining Chain Transfer Constants and Termination Mechanisms

“Weak links” in polystyrene—thermal degradation of polymers prepared with AIBN or benzoyl peroxide as initiator