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2-(methoxycarbonyl)ethyl as a removable N-protecting group: synthesis of indoloisoquinolinones by Pd(II)-catalyzed intramolecular diamination of alkynes

artículo científico publicado en 2015

A concise total synthesis of (±)-trigonoliimine B

artículo científico publicado en 2012

Access to macrocycles with an endo aryl ether and an endo aryl-aryl bond, development and application.

artículo científico publicado en 2011

Amidation of aldehydes and alcohols through α-iminonitriles and a sequential oxidative three-component Strecker reaction/thio-Michael addition/alumina-promoted hydrolysis process to access β-mercaptoamides from aldehydes, amines, and thiols

artículo científico publicado en 2012

An Enantioselective Total Synthesis of (-)-Isoschizogamine.

artículo científico publicado en 2015

Aqueous Titanium Trichloride Promoted Reductive Cyclization of o-Nitrostyrenes to Indoles: Development and Application to the Synthesis of Rizatriptan and Aspidospermidine

artículo científico publicado en 2015

Catalytic Atropenantioselective Heteroannulation between Isocyanoacetates and Alkynyl Ketones: Synthesis of Enantioenriched Axially Chiral 3-Arylpyrroles

scientific article published on 21 December 2018

Catalytic Enantioselective Benzilic Ester Rearrangement

artículo científico publicado en 2020

Catalytic Enantioselective Double Carbopalladation/C-H Functionalization with Statistical Amplification of Product Enantiopurity: A Convertible Linker Approach.

artículo científico publicado en 2017

Catalytic Enantioselective Pinacol and Meinwald Rearrangements for the Construction of Quaternary Stereocenters

artículo científico publicado en 2019

Catalytic Enantioselective α-Ketol Rearrangement

artículo científico publicado en 2018

Catalytic Kinetic Resolution by Enantioselective Aromatization: Conversion of Racemic Intermediates of the Barton-Zard Reaction into Enantioenriched 3-Arylpyrroles

scientific article published on 29 May 2019

Catalytic enantioselective Michael addition of α-aryl-α-isocyanoacetates to vinyl selenone: synthesis of α,α-disubstituted α-amino acids and (+)- and (-)-trigonoliimine A.

artículo científico publicado en 2013

Chiral Phosphoric Acid-Catalyzed Enantioselective Formal [3+2] Cycloaddition of Azomethine Imines with Enecarbamates

artículo científico publicado en 2016

Cooperative Pd/Cu Catalysis: Multicomponent Synthesis of Tetrasubstituted Imidazolones from Methyl α-Isocyanoacetates, Primary Amines, and Aryl(vinyl) Iodides.

artículo científico publicado en 2017

Copper-Catalyzed 1,2-Methoxy Methoxycarbonylation of Alkenes with Methyl Formate

artículo científico publicado en 2019

Copper-Catalyzed Arylation of Remote C(sp3 )-H Bonds in Carboxamides and Sulfonamides

scientific article published on 05 September 2018

Copper-Catalyzed Enantioselective Arylative Desymmetrization of Prochiral Cyclopentenes with Diaryliodonium Salts

artículo científico publicado en 2018

Copper-Catalyzed Enantioselective Domino Arylation/Semipinacol Rearrangement of Allylic Alcohols with Diaryliodonium Salts.

artículo científico publicado en 2017

Copper-Catalyzed Formal [2+2+1] Heteroannulation of Alkenes, Alkylnitriles, and Water: Method Development and Application to a Total Synthesis of (±)-Sacidumlignan D.

artículo científico publicado en 2016

Copper-Catalyzed Three-Component Carboazidation of Alkenes with Acetonitrile and Sodium Azide

artículo científico publicado en 2017

Copper-catalysed cyanoalkylative cycloetherification of alkenes to 1,3-dihydroisobenzofurans: development and application to the synthesis of citalopram

artículo científico publicado en 2016

Copper-catalyzed cyanomethylation of allylic alcohols with concomitant 1,2-aryl migration: efficient synthesis of functionalized ketones containing an α-quaternary center

artículo científico publicado en 2015

Copper-catalyzed intermolecular carboetherification of unactivated alkenes by alkyl nitriles and alcohols

artículo científico publicado en 2015

Copper-catalyzed methylative difunctionalization of alkenes

artículo científico publicado en 2018

Copper-catalyzed remote C(sp)-H azidation and oxidative trifluoromethylation of benzohydrazides

artículo científico publicado en 2019

Copper-mediated/catalyzed oxyalkylation of alkenes with alkylnitriles.

artículo científico publicado en 2014

Desymmetrization of Prochiral Cyclopentenes Enabled by Enantioselective Palladium-Catalyzed Oxidative Heck Reaction

scientific article published on 17 December 2019

Dual Photoredox/Copper Catalysis for the Remote C(sp3 )-H Functionalization of Alcohols and Alkyl Halides by N-Alkoxypyridinium Salts

scientific article published on 18 January 2019

Enantioselective Synthesis of (+)-Peganumine A.

artículo científico publicado en 2016

Enantioselective Synthesis of Quaternary α-Amino Acids Enabled by the Versatility of the Phenylselenonyl Group

artículo científico publicado en 2016

Enantioselective Total Syntheses of (-)-Rhazinilam, (-)-Leucomidine B, and (+)-Leuconodine F.

artículo científico publicado en 2015

Enantioselective Total Synthesis of (-)-Terengganensine A.

artículo científico publicado en 2016

Enantioselective total syntheses of leuconolam-leuconoxine-mersicarpine group monoterpene indole alkaloids

artículo científico publicado en 2013

Fluorophores for Excited-State Intramolecular Proton Transfer by an Yttrium Triflate Catalyzed Reaction of Isocyanides with Thiocarboxylic Acids

artículo científico publicado en 2017

From racemic to enantioselective total synthesis of trigonoliimines via development of an organocatalytic enantioselective Michael addition of α-aryl-α-isocyanoacetate to vinyl phenyl selenone.

artículo científico publicado en 2014

Functionalization of remote C(sp3)-H bonds enabled by copper-catalyzed coupling of O-acyloximes with terminal alkynes

scientific article published on 21 January 2020

Heteroannulation of Arynes with α-Amino Imides: Synthesis of 2,2-Disubstituted Indolin-3-ones and Application to the Enantioselective Total Synthesis of (+)-Hinckdentine A.

artículo científico publicado en 2018

Heteroannulation of arynes with N-aryl-α-aminoketones for the synthesis of unsymmetrical N-aryl-2,3-disubstituted indoles: an aryne twist of Bischler-Möhlau indole synthesis

scientific article published on 01 November 2013

Integrated One-Pot Synthesis of 1,3-Oxazinan-2-ones from Isocyanoacetates and Phenyl Vinyl Selenones

artículo científico publicado en 2015

Iron-Catalysed Remote C(sp3 )-H Azidation of O-Acyl Oximes and N-Acyloxy Imidates Enabled by 1,5-Hydrogen Atom Transfer of Iminyl and Imidate Radicals: Synthesis of γ-Azido Ketones and β-Azido Alcohols

scientific article published on 10 May 2019

Ketenimines from Isocyanides and Allyl Carbonates: Palladium-Catalyzed Synthesis of β,γ-Unsaturated Amides and Tetrazoles.

artículo científico publicado en 2016

Mechanistic study on the palladium(II)-catalyzed synthesis of 2,3-disubstituted indoles under aerobic conditions: anion effects and the development of a low-catalyst-loading process.

artículo científico publicado en 2014

Organocatalytic Enantioselective Acyloin Rearrangement of α-Hydroxy Acetals to α-Alkoxy Ketones

artículo científico publicado en 2017

Organocatalytic Enantioselective Vinylogous Pinacol Rearrangement Enabled by Chiral Ion Pairing

artículo científico publicado en 2016

Organocatalytic Nucleophilic Addition of Hydrazones to Imines: Synthesis of Enantioenriched Vicinal Diamines

artículo científico publicado en 2017

Palladium(II)-catalyzed cyclizative cross-coupling of ortho-alkynylanilines with ortho-alkynylbenzamides under aerobic conditions.

artículo científico publicado en 2013

Palladium(II)-catalyzed intramolecular diamination of alkynes under aerobic oxidative conditions: catalytic turnover of an iodide ion

artículo científico publicado en 2012

Palladium-Catalyzed Enantioselective Cacchi Reaction: Asymmetric Synthesis of Axially Chiral 2,3-Disubstituted Indoles

artículo científico publicado en 2019

Palladium-Catalyzed Enantioselective Desymmetrizing Aza-Wacker Reaction: Development and Application to the Total Synthesis of (-)-Mesembrane and (+)-Crinane.

artículo científico publicado en 2018

Palladium-Catalyzed Enantioselective Domino Heck/Intermolecular C-H Bond Functionalization: Development and Application to the Synthesis of (+)-Esermethole.

artículo científico publicado en 2015

Palladium-Catalyzed Enantioselective Narasaka-Heck Reaction/Direct C-H Alkylation of Arenes: Iminoarylation of Alkenes.

artículo científico publicado en 2017

Palladium-Catalyzed Multicomponent Synthesis of Fully Substituted Alkylidene Furanones

artículo científico publicado en 2020

Palladium-Catalyzed Three-Component Reaction of Propargyl Carbonates, Isocyanides, and Alcohols or Water: Switchable Synthesis of Pyrroles and Its Bicyclic Analogues

artículo científico publicado en 2016

Palladium-catalyzed coupling of ortho-alkynylanilines with terminal alkynes under aerobic conditions: efficient synthesis of 2,3-disubstituted 3-alkynylindoles

artículo científico publicado en 2012

Palladium-catalyzed decarboxylative vinylation of potassium nitrophenyl acetate: application to the total synthesis of (±)-goniomitine

artículo científico publicado en 2013

Palladium-catalyzed through-space C(sp(3))-H and C(sp(2))-H bond activation by 1,4-palladium migration: efficient synthesis of [3,4]-fused oxindoles

artículo científico publicado en 2013

Pd-catalyzed dehydrogenative aryl-aryl bond formation via double C(sp(2))-H bond activation: efficient synthesis of [3,4]-fused oxindoles.

artículo científico publicado en 2014

Pd/C-Catalyzed Cyclizative Cross-Coupling of Two ortho-Alkynylanilines under Aerobic Conditions: Synthesis of 2,3'-Bisindoles.

artículo científico publicado en 2015

Phosphoric acid catalyzed desymmetrization of bicyclic bislactones bearing an all-carbon stereogenic center: total syntheses of (-)-rhazinilam and (-)-leucomidine B.

artículo científico publicado en 2014

Remote C(sp3 )-H Arylation and Vinylation of N-Alkoxypyridinium Salts to δ-Aryl and δ-Vinyl Alcohols

scientific article published on 13 August 2019

Silver Nitrate-Catalyzed Isocyanide Insertion/Lactamization Sequence to Imidazolones and Quinazolin-4-ones: Development and Application in Natural Product Synthesis

artículo científico publicado en 2017

Silver-Catalyzed Three-Component 1,1-Aminoacylation of Homopropargylamines: α-Additions for Both Terminal Alkynes and Isocyanides.

artículo científico publicado en 2017

Stereoselective Total Synthesis of Eburnane-Type Alkaloids Enabled by Conformation-Directed Cyclization and Rearrangement

scientific article published on 04 February 2019

Still Unconquered: Enantioselective Passerini and Ugi Multicomponent Reactions

artículo científico publicado en 2018

Sulfonamide and Tertiary Amine as Nucleophiles in Pd(II)-Catalyzed Diamination of Alkynes: Synthesis of Tetracyclic Indolobenzothiazine S,S-Dioxides

artículo científico publicado en 2015

Switchable [3+2] and [4+2] Heteroannulation of Primary Propargylamines with Isonitriles to Imidazoles and 1,6-Dihydropyrimidines: Catalyst Loading Enabled Reaction Divergence

artículo científico publicado en 2016

Synergistic effect of palladium and copper catalysts: catalytic cyclizative dimerization of ortho-(1-alkynyl)benzamides leading to axially chiral 1,3-butadienes

artículo científico publicado en 2012

Synthesis of Diversely Functionalized Oxindoles Enabled by Migratory Insertion of Isocyanide to a Transient σ-Alkylpalladium(II) Complex.

artículo científico publicado en 2016

Synthesis of Oxazolidin-2-ones by Oxidative Coupling of Isonitriles, Phenyl Vinyl Selenone, and Water

artículo científico publicado en 2016

Synthesis of Vinyl Isocyanides and Development of a Convertible Isonitrile.

artículo científico publicado en 2016

Synthesis of functionalized epoxides by copper-catalyzed alkylative epoxidation of allylic alcohols with alkyl nitriles

artículo científico publicado en 2015

Tertiary amines as synthetic equivalents of vinyl cations: zinc bromide promoted coupling of propargylamines with α-isocyanoacetamides to give 2,4,5-trisubstituted oxazoles initiated by an internal redox process

artículo científico publicado en 2013

Three-component Povarov reaction-heteroannulation with arynes: synthesis of 5,6-dihydroindolo[1,2-a]quinolines.

artículo científico publicado en 2014

Total Syntheses of (-)-Mersicarpine, (-)-Scholarisine G, (+)-Melodinine E, (-)-Leuconoxine, (-)-Leuconolam, (-)-Leuconodine A, (+)-Leuconodine F, and (-)-Leuconodine C: Self-Induced Diastereomeric Anisochronism (SIDA) Phenomenon for Scholarisine G a

artículo científico publicado en 2015

Total Synthesis of (±)-Strictamine

artículo científico publicado en 2016

Total synthesis of (±)-aspidophylline A

artículo científico publicado en 2014

Towards the Sarpagine-Ajmaline-Macroline Family of Indole Alkaloids: Enantioselective Synthesis of an N-Demethyl Alstolactone Diastereomer

artículo científico publicado en 2020

Triple role of phenylselenonyl group enabled a one-pot synthesis of 1,3-oxazinan-2-ones from α-isocyanoacetates, phenyl vinyl selenones, and water.

artículo científico publicado en 2014

Tuning the reactivity of isocyano group: synthesis of imidazoles and imidazoliums from propargylamines and isonitriles in the presence of multiple catalysts.

artículo científico publicado en 2014

Unified divergent strategy towards the total synthesis of the three sub-classes of hasubanan alkaloids

artículo científico publicado en 2021

Unified strategy to monoterpene indole alkaloids: total syntheses of (±)-goniomitine, (±)-1,2-dehydroaspidospermidine, (±)-aspidospermidine, (±)-vincadifformine, and (±)-kopsihainanine A.

artículo científico publicado en 2014

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

artículo científico publicado en 2017

Zinc bromide promoted coupling of isonitriles with carboxylic acids to form 2,4,5-trisubstituted oxazoles

artículo científico publicado en 2013

α-Oxo-Ketenimines from Isocyanides and α-Haloketones: Synthesis and Divergent Reactivity.

artículo científico publicado en 2017