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(+)-Arisugacin A—Computational evidence of a dual binding site covalent inhibitor of acetylcholinesterase ⬇️

artículo científico publicado el 16 de diciembre de 2010

(4+3) Cycloaddition Reactions of Nitrogen‐Stabilized Oxyallyl Cations ⬇️

artículo científico publicado el 7 de marzo de 2011

(4R)-3-Allenyl-4-(diphenylmethyl)oxazolidin-2-one, an unsubstituted allenamide

artículo científico publicado en 2004

A Concise Stereoselective Route to the Pentacyclic Frameworks of Arisugacin A and Territrem B

scientific article published on 01 November 2000

A Convenient Synthesis of γ-Amino-Ynamides via Additions of Lithiated Ynamides to Aryl Imines. Observation of an Aza-Meyer-Schuster Rearrangement

artículo científico publicado en 2013

A General Approach to the Quinolizidine Alkaloids via an Intramolecular Aza-[3 + 3] Annulation. Synthesis of (±)-2-Deoxy-Lasubine II

artículo científico publicado en 2008

A Lewis acid-catalyzed formal [3 + 3] cycloaddition of alpha,beta-unsaturated aldehydes with 4-hydroxy-2-pyrone, diketones, and vinylogous esters

scientific article published on 01 January 2006

A Novel and Highly Stereoselective Intramolecular Formal

scientific article published on 01 April 2001

A Novel and Highly Stereoselective Intramolecular Formal [3+3] Cycloaddition Reaction of Vinylogous Amides Tethered with α,β-Unsaturated Aldehydes: A Formal Total Synthesis of (+)-Gephyrotoxin

artículo científico publicado en 2001

A Rhodium(I)-Xylyl-BINAP Catalyzed Asymmetric Ynamide-[2 + 2 + 2] Cycloaddition in the Synthesis of Optically Enriched N,O-Biaryls

artículo científico publicado en 2009

A Silver(I)-Catalyzed Intramolecular Ficini's [2 + 2] Cycloaddition Employing Ynamides

artículo científico publicado en 2015

A Stereodivergent Approach for Accessing Both C2,8a-Syn and C2,8a-Anti Relative Stereochemical Manifolds in the Lepadin Family via a TiCL(4)-Promoted Aza-[3 + 3] Annulation

artículo científico publicado en 2009

A Tandem 1,3-H-Shift–6π-Electrocyclization–Cyclic 2-Amido-diene Intramolecular Diels–Alder Cycloaddition Approach to BCD-Ring of Atropurpuran ⬇️

artículo científico publicado el 13 de diciembre de 2011

A computational view on the significance of E-ring in binding of (+)-arisugacin A to acetylcholinesterase

artículo científico publicado en 2015

A concise total synthesis of (-)-cylindricine C through a stereoselective intramolecular aza-[3 + 3] annulation strategy

artículo científico publicado en 2006

A copper-catalyzed C-N bond formation involving sp-hybridized carbons. A direct entry to chiral ynamides via N-alkynylation of amides

artículo científico publicado en 2003

A divergent mechanistic course of Pd(0)-catalyzed aza-Claisen rearrangement and aza-Rautenstrauch-type cyclization of N-allyl ynamides

artículo científico publicado en 2010

A formal [3 + 3] cycloaddition reaction. 5. An enantioselective intramolecular formal aza-[3 + 3] cycloaddition reaction promoted by chiral amine salts

artículo científico publicado en 2005

A formal [3 + 3] cycloaddition reaction. Improved reactivity using alpha,beta-unsaturated iminium salts and evidence for reversibility of 6pi-electron electrocyclic ring closure of 1-oxatrienes

artículo científico publicado en 2003

A formal total synthesis of (+)-zincophorin. Observation of an unusual urea-directed Stork-Crabtree hydrogenation

artículo científico publicado en 2007

A highly regio- and stereoselective synthesis of α-fluorinated imides via fluorination of chiral enamides

artículo científico publicado en 2015

A highly stereoselective Diels-Alder cycloaddition of enones with chiral cyclic 2-amidodienes derived from allenamides

artículo científico publicado en 2013

A highly stereoselective addition of lithiated ynamides to Ellman-Davis chiral N-tert-butanesulfinyl imines

artículo científico publicado en 2013

A highly stereoselective synthesis of chiral alpha-amino-beta-lactams via the Kinugasa reaction employing ynamides

artículo científico publicado en 2008

A mutually pi-facial selective cyclopropanation of chiral enamides using dirhodium(II) carbenoids

scientific article published on 19 January 2008

A novel and highly stereoselective approach to aza-spirocycles. A short total synthesis of 2-epi-(+/-)-perhydrohistrionicotoxin and an unprecedented decarboxylation of 2-pyrones

scientific article published on 01 June 2002

A rhodium(I)-catalyzed demethylation-cyclization of o-anisole-substituted ynamides in the synthesis of chiral 2-amido benzofurans

scientific article published on 10 May 2007

A ring-closing yne-carbonyl metathesis of ynamides

scientific article published on 01 January 2006

A sequential metal-catalyzed C-N bond formation in the synthesis of 2-amido-indoles.

artículo científico publicado en 2008

A stereoselective intramolecular cyclopropanation via a de novo class of push–pull carbenes derived from DMDO-epoxidations of chiral ynamides ⬇️

artículo científico publicado el 1 de enero de 2010

A stereoselective intramolecular halo-etherification of chiral enamides in the synthesis of halogenated cyclic ethers

artículo científico publicado en 2007

A tandem epoxidation/stereoselective intramolecular [4+3] cycloaddition reaction involving nitrogen-stabilized oxyallyl cations derived from chiral allenamides

scientific article published on 01 February 2004

A triazole-templated ring-closing metathesis for constructing novel fused and bridged triazoles

artículo científico publicado en 2007

AlCl₃-Catalyzed Ring Expansion Cascades of Bicyclic Cyclobutenamides Involving Highly Strained Cis,Trans-Cycloheptadienone Intermediates

artículo científico publicado en 2015

Allenamides: a powerful and versatile building block in organic synthesis

artículo científico publicado en 2013

An Efficient Synthesis of de novo Imidates via Aza-Claisen Rearrangements of N-Allyl Ynamides ⬇️

artículo científico publicado el 1 de octubre de 2010

An Enantioselective Synthesis of the ABD Tricycle for (-)-Phomactin A Featuring Rawal's Asymmetric Diels-Alder Cycloaddition

artículo científico publicado en 2008

An N-acyliminium cyclization approach to a total synthesis of (+)-cylindricine C

scientific article published on 01 May 2005

An anomeric control on remote stereochemistry in the synthesis of spiroketals

artículo científico publicado en 2005

An approach to cyclohepta[b]indoles through an allenamide (4 + 3) cycloaddition-Grignard cyclization-Chugaev elimination sequence

artículo científico publicado en 2014

An approach toward constructing the trioxadispiroketal core in the DEF-ring of (+)-spirastrellolide A.

artículo científico publicado en 2014

An efficient and practical entry to 2-amido-dienes and 3-amido-trienes from allenamides through stereoselective 1,3-hydrogen shifts

artículo científico publicado en 2011

An enantioselective total synthesis of (+)-aigialospirol

scientific article published on 20 October 2007

An intramolecular [2 + 2] cycloaddition of ketenimines via palladium-catalyzed rearrangements of N-allyl-ynamides

artículo científico publicado en 2012

An intramolecular aza-[3+3] annulation approach to azaphenalene alkaloids. Total synthesis of myrrhine

artículo científico publicado en 2007

An unusual cationic [2 + 2] cycloaddition in a divergent total synthesis of hongoquercin A and rhododaurichromanic acid A

artículo científico publicado en 2006

An unusual stereoselectivity in the anomeric substitution with carbamates promoted by HNTf2

scientific article published on 08 December 2006

Assignment of the C5' relative stereochemistry in (+)-lepadin F and (+)-lepadin G and absolute configuration of (+)-lepadin G.

artículo científico publicado en 2009

Asymmetric aza-[3+3] annulation in the synthesis of indolizidines: an unexpected reversal of regiochemistry

artículo científico publicado en 2011

Aza- and Carbo-[3 + 3] Annulations of Exo-Cyclic Vinylogous Amides and Urethanes. Synthesis of Tetrahydroindolizidines and An Unexpected Formation of Hexahydroquinolines

artículo científico publicado en 2008

Aza-[3 + 3] Annulations: A New Unified Strategy in Alkaloid Synthesis ⬇️

artículo científico publicado el 1 de agosto de 2010

Brønsted acid-catalyzed highly stereoselective arene-ynamide cyclizations. A novel keteniminium Pictet-Spengler cyclization in total syntheses of (+/-)-desbromoarborescidines A and C

artículo científico publicado en 2005

Carbocyclization Cascades of Allyl Ketenimines viaAza-Claisen Rearrangements ofN-Phosphoryl-N-allyl-ynamides ⬇️

artículo científico publicado el 13 de marzo de 2012

Challenges in the synthesis of a unique mono-carboxylic acid antibiotic, (+)-zincophorin

artículo científico publicado en 2009

Chiral Lewis acid-catalyzed highly enantioselective [4 + 3] cycloaddition reactions of nitrogen-stabilized oxyallyl cations derived from allenamides

artículo científico publicado en 2005

Cinchonine induces apoptosis of HeLa and A549 cells through targeting TRAF6.

artículo científico publicado en 2017

Constructing the Architecturally Distinctive ABD-Tricycle of Phomactin A through an Intramolecular Oxa-[3 + 3] Annulation Strategy

artículo científico publicado en 2011

Control of regioselectivity and stereoselectivity in (4 + 3) cycloadditions of chiral oxyallyls with unsymmetrically disubstituted furans

artículo científico publicado en 2012

Copper sulfate-pentahydrate-1,10-phenanthroline catalyzed amidations of alkynyl bromides. Synthesis of heteroaromatic amine substituted ynamides

artículo científico publicado en 2004

Copper(II)-catalyzed amidations of alkynyl bromides as a general synthesis of ynamides and Z-enamides. An intramolecular amidation for the synthesis of macrocyclic ynamides

artículo científico publicado en 2006

Copper-Catalyzed Ficini [2 + 2] Cycloaddition of Ynamides ⬇️

artículo científico publicado el 3 de septiembre de 2010

Copper-catalyzed stereospecific N-allenylations of amides. Syntheses of optically enriched chiral allenamides

artículo científico publicado en 2005

De novo chiral amino alcohols in catalyzing asymmetric additions to aryl aldehydes

scientific article published on 01 April 2006

Developing a Diastereoselective Intramolecular [4 + 3] Cycloaddition of Nitrogen-Stabilized Oxyallyl Cations Derived from N-Sulfonyl-Substituted Allenamides ⬇️

artículo científico publicado el 8 de abril de 2011

Enamide-benzyne-[2 + 2] cycloaddition: stereoselective tandem [2 + 2]-pericyclic ring-opening-intramolecular N-tethered [4 + 2] cycloadditions

artículo científico publicado en 2009

Establishing the concept of aza-[3 + 3] annulations using enones as a key expansion of this unified strategy in alkaloid synthesis

artículo científico publicado en 2013

Facile Synthesis of 3-Amido-Dienynes via a Tandem α-Propargylation-Isomerization of Chiral Allenamides and their Applications in Diels-Alder Cycloadditions.

artículo científico publicado en 2017

First Stereoselective [4 + 2] Cycloaddition Reactions of 3-Cyanochromone Derivatives with Electron-Rich Dienes: An Approach to the ABC Tricyclic Frame of Arisugacin(1)

scientific article published on 01 November 1997

Formal [3 + 3] Cycloaddition Approach to Chromenes and Chromanes. Concise Total Syntheses of (±)-Rhododaurichromanic Acids A and B and Methyl (±)-Daurichromenic Ester ⬇️

artículo científico publicado el 16 de octubre de 2003

Gassman's cationic [2 + 2] cycloadditions using temporary tethers

artículo científico publicado en 2012

Gassman's intramolecular [2 + 2] cationic cycloaddition. formal total syntheses of raikovenal and epi-raikovenal

artículo científico publicado en 2008

Highly regioselective radical cyclizations of allenamides

artículo científico publicado en 2005

Highly stereoselective Saucy-Marbet rearrangement using chiral ynamides. Synthesis of highly substituted chiral homoallenyl alcohols

scientific article published on 01 July 2003

Highly stereoselective [4 + 3] cycloadditions of nitrogen-stabilized oxyallyl cations with pyrroles: an approach to parvineostemonine

artículo científico publicado en 2007

Highly stereoselective synthesis of novel alpha-haloenamides via a mild and efficient hydrohalogenation of ynamides

scientific article published on 01 May 2003

Highly substituted 2-amido-furans from Rh(II)-catalyzed cyclopropenations of ynamides

artículo científico publicado en 2009

Highly torquoselective electrocyclizations and competing 1,7-hydrogen shifts of 1-azatrienes with silyl substitution at the allylic carbon

artículo científico publicado en 2015

In vitro and in vivo cancer cell apoptosis triggered by competitive binding of Cinchona alkaloids to the RING domain of TRAF6

scientific article published on 20 December 2018

Intramolecular formal aza-[3 + 3] cycloaddition approach to indoloquinolizidine alkaloids. A stereoselective total synthesis of (+/-)-tangutorine

scientific article published on 01 November 2003

Intramolecular formal oxa-[3 + 3] cycloaddition approach to the ABD system of phomactin A

artículo científico publicado en 2003

Intramolecular oxyallyl-carbonyl (3 + 2) cycloadditions

artículo científico publicado en 2013

Introducing a New Class of N-Phosphoryl Ynamides via Cu(I)-Catalyzed Amidations of Alkynyl Bromides ⬇️

artículo científico publicado el 17 de agosto de 2011

N-Allyl-N-sulfonyl Ynamides as Synthetic Precursors to Amidines and Vinylogous Amidines. An Unexpected N-to-C 1,3-Sulfonyl Shift in Nitrile Synthesis ⬇️

artículo científico publicado el 24 de mayo de 2011

NMR studies on epoxidations of allenamides. Evidence for formation of nitrogen-substituted allene oxide and spiro-epoxide via trapping experiments

artículo científico publicado en 2002

Novel ynamide structural analogues and their synthetic transformations

artículo científico publicado en 2014

Oppolzer-type intramolecular Diels-Alder cycloadditions via isomerizations of allenamides

artículo científico publicado en 2011

Reactive intermediates from DMDO oxidation of ynamides. Trapping of a de novo chiral push-pull carbene via cyclopropanation

artículo científico publicado en 2008

Regio- and stereoselective isomerizations of allenamides: synthesis of 2-amido-dienes and their tandem isomerization-electrocyclic ring-closure

artículo científico publicado en 2009

Regioselectivities of (4 + 3) cycloadditions between furans and oxazolidinone-substituted oxyallyls

artículo científico publicado en 2010

Resveratrol metabolites do not elicit early pro-apoptotic mechanisms in neuroblastoma cells

artículo científico publicado en 2011

Rhodium(I)-catalyzed [2 + 2 + 2] cycloadditions of ynamides in the synthesis of amide-substituted chiral biaryls

artículo científico publicado en 2006

SYNTHESIS OF DE NOVO CHIRAL γ-AMINO-YNAMIDES USING LITHIATED YNAMIDES. OBSERVATION OF A UNIQUE 5-ENDO-DIG CYCLIZATION WITH AN INVERSION OF S-CENTER.

artículo científico publicado en 2014

Saucy-Marbet Rearrangements of Alkynyl Halides in the Synthesis of Highly Enantiomerically Enriched Allenyl Halides

artículo científico publicado en 2008

Sequential 1,2-Addition-Electrocyclic Ring Closures Involving Acyclic alpha,beta-Unsaturated Iminiums: A Formal [3 + 3] Cycloaddition Strategy to Unique Pyranyl Spirocycles

scientific article published on 01 February 1999

Sonogashira cross-couplings of ynamides. Syntheses of urethane- and sulfonamide-terminated conjugated phenylacetylenic systems

scientific article published on 01 June 2004

Stereochemical control of both C-C and C-N axial chirality in the synthesis of chiral N,O-biaryls

artículo científico publicado en 2007

Stereodivergent total syntheses of precoccinelline, hippodamine, coccinelline, and convergine.

artículo científico publicado en 2006

Stereoselective 6π-electron electrocyclic ring closures of 2-halo-amidotrienes via a remote 1,6-asymmetric induction.

artículo científico publicado en 2010

Stereoselective Intramolecular [4 + 3] Cycloadditions of Nitrogen-Stabilized Chiral Oxyallyl Cations via Epoxidation of N-Tethered Allenamides ⬇️

artículo científico publicado el 22 de octubre de 2003

Stereoselective formal [3 + 3] cycloaddition approach to cis-1-azadecalins and synthesis of (-)-4a,8a-diepi-pumiliotoxin C. evidence for the first highly stereoselective 6pi-electron electrocyclic ring closures of 1-azatrienes

artículo científico publicado en 2002

Stereoselective ketal-tethered intramolecular diels-alder cycloadditions. An approach to the 2-oxadecalin spiroketal core of antifungal agent fusidilactone C

scientific article published on 01 June 2004

Stereoselective synthesis of isoquinuclidines through an aza-[4 + 2] cycloaddition of chiral cyclic 2-amidodienes

artículo científico

StereoselectiveSimmons-Smith cyclopropanation of chiral enamides

scientific article published on 01 January 2007

Stereoselectivities and regioselectivities of (4 + 3) cycloadditions between allenamide-derived chiral oxazolidinone-stabilized oxyallyls and furans: experiment and theory

artículo científico

Stereoselectivity in Oxyallyl-Furan 4+3 Cycloadditions: Control of Intermediate Conformations and Dispersive Stabilisation with Evans' Oxazolidinones

artículo científico publicado en 2010

Studies on a urea-directed Stork-Crabtree hydrogenation. Synthesis of the C1-C9 subunit of (+)-zincophorin

artículo científico publicado en 2007

Syntheses of 2,5-disubstituted dihydrofurans from gamma-substituted chiral allenamides

artículo científico publicado en 2005

Synthesis of alpha-keto-imides via oxidation of ynamides

artículo científico publicado en 2008

Synthesis of amidines using N-allyl ynamides. A palladium-catalyzed allyl transfer through an ynamido-pi-allyl complex

artículo científico publicado en 2009

Synthesis of amido-spiro[2.2]pentanes via Simmons-Smith cyclopropanation of allenamides

artículo científico publicado en 2009

Synthesis of cyclopentenimines from N-allyl ynamides via a tandem aza-Claisen rearrangement-carbocyclization sequence.

artículo científico publicado en 2013

Synthesis of the C1-C23 fragment of Spirastrellolide A

scientific article published on 17 May 2008

Synthesis of the C11-C23 fragment of spirastrellolide A. A ketal-tethered RCM approach to the construction of spiroketals

artículo científico publicado en 2005

Tandem azidination- and hydroazidination-Huisgen [3 + 2] cycloadditions of ynamides. Synthesis of chiral amide-substituted triazoles

artículo científico publicado en 2006

Tetronamides as latent acyclic vinylogous amides in formal aza-[3 + 3] cycloaddition reactions with alpha,beta-unsaturated iminium salts. An unexpected rearrangement and an approach to synthesis of substituted piperidines

artículo científico publicado en 2004

The Emergence of Allenamides in Organic Synthesis ⬇️

artículo científico publicado el 1 de octubre de 2003

The first stereoselective Ficini-Claisen rearrangement using chiral ynamides

artículo científico publicado en 2002

The first successful base-promoted isomerization of propargyl amides to chiral ynamides. Applications in ring-closing metathesis of ene-ynamides and tandem RCM of diene-ynamides

scientific article published on 01 July 2002

Thermal intramolecular [4 + 2] cycloadditions of allenamides: a stereoselective tandem propargyl amide isomerization-cycloaddition

artículo científico publicado en 2009

Torquoselective 6pi-electron electrocyclic ring closure of 1-azatrienes containing acyclic chirality at the C-terminus

artículo científico publicado en 2006

Torquoselective ring closures of chiral amido trienes derived from allenamides. A tandem allene isomerization-pericyclic ring-closure-intramolecular Diels-Alder cycloaddition

artículo científico publicado en 2010

Torquoselective ring opening of fused cyclobutenamides: evidence for a cis,trans-cyclooctadienone intermediate

artículo científico publicado en 2014

Total Syntheses of (±)-Rhodonoids A and B and C12-epi-Rhodonoid B.

artículo científico publicado en 2016

Total Syntheses of (±)-Rhodonoids C, D, E, F, and G and Ranhuadujuanine B

artículo científico publicado en 2017

Total Syntheses of Proposed (±)-Trichodermatides B and C.

artículo científico publicado en 2013

Total Synthesis of (±)-Phomactin A. Lessons Learned from Respecting a Challenging Structural Topology ⬇️

artículo científico publicado el 5 de agosto de 2011

Total syntheses of (+)-cylindricines C-E and (-)-lepadiformine through a common intermediate derived from an aza-Prins cyclization and Wharton's rearrangement

scientific article published on 01 October 2004

Total syntheses of cannabicyclol, clusiacyclol A and B, iso-eriobrucinol A and B, and eriobrucinol

artículo científico publicado en 2013

Total syntheses of chelidonine and norchelidonine via an enamide-benzyne-[2 + 2] cycloaddition cascade

artículo científico publicado en 2012

Total syntheses of enantiomerically enriched R-(+)- and S-(-)-deplancheine

artículo científico publicado en 2005

Total synthesis of (+)-lepadin F.

artículo científico publicado en 2008

Total synthesis of phomactin A.

artículo científico publicado en 2009

Two remarkable epimerizations imperative for the success of an asymmetric total synthesis of (+)-aigialospirol ⬇️

artículo científico publicado el 1 de enero de 2011

Unique structural topology and reactivities of the ABD tricycle in phomactin A.

artículo científico publicado en 2005

Ynamides in ring forming transformations

artículo científico publicado en 2013

Ynamides: a modern functional group for the new millennium

artículo científico publicado en 2010

α-Aryl-substituted allenamides in an imino-Nazarov cyclization cascade catalyzed by Au(I).

artículo científico publicado en 2012

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